ASTM D4486-1991(2010) Standard Test Method for Kinematic Viscosity of Volatile and Reactive Liquids.pdf

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1、Designation: D4486 91 (Reapproved 2010)Standard Test Method forKinematic Viscosity of Volatile and Reactive Liquids1This standard is issued under the fixed designation D4486; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year

2、 of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method covers the measurement of kinematicviscosity of transparent, Newtonian liquids which because ofth

3、eir reactivity, instability, or volatility cannot be used inconventional capillary kinematic viscometers. This test methodis applicable up to 2 3 105N/m2(2 atm) pressure andtemperature range from 53 to +135 C (65 to +275 F).1.1.1 For the measurement of the kinematic viscosity ofother liquids, see Te

4、st Method D445.1.2 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.

5、 For specificwarning statements, see 7.2, 7.3, 7.4, and Annex A1.2. Referenced Documents2.1 ASTM Standards:2D445 Test Method for Kinematic Viscosity of Transparentand Opaque Liquids (and Calculation of Dynamic Viscos-ity)D2162 Practice for Basic Calibration of MasterViscometersand Viscosity Oil Stan

6、dardsE1 Specification for ASTM Liquid-in-Glass Thermometers3. Terminology3.1 Definitions of Terms Specific to This Standard:3.1.1 densitythe mass per unit volume of the liquid.3.1.1.1 DiscussionThe cgs unit of density (r) has thedimensions of grams per cubic centimetre. The SI unit ofdensity has the

7、 dimensions of kilograms per cubic metre.3.1.2 kinematic viscosityThe ratio of the viscosity to thedensity of the liquid.3.1.2.1 DiscussionFor gravity flow under a given hydro-static head, the pressure head of a liquid is proportional to itsdensity r. For any particular viscometer, the time of flow

8、of afixed volume of liquid is directly proportional to h/r. This ratiois the kinematic viscosity coefficient (n). The cgs unit ofkinematic viscosity is the stoke and has the dimensions ofcentimetre squared per second: the centistoke (0.01 St) isfrequently used. The SI unit of kinematic viscosity has

9、 thedimensions of metre2/second, and is equivalent to 104St.3.1.3 viscositythe ratio between the applied shear stressand rate of shear.3.1.3.1 DiscussionThis ratio is called the coefficient ofviscosity. The coefficient of viscosity (h) is thus a measure ofthe resistance to flow of the liquid. This i

10、s commonly called theviscosity of the liquid. The cgs unit of viscosity is the poise. P,which has the dimensions of dyne-seconds per square centi-metre: the centipoise (0.01 poise) is frequently used. The SIunit of viscosity has the dimensions of newton second/metre2,and is equivalent to 10 P.3.1.4

11、vulnerable liquida liquid which by reason of itsvolatility, instability or reactivity in the presence of air or anyother specific gaseous medium may undergo physical orchemical changes that may affect its viscosity.4. Summary of Test Method4.1 The time is measured, in seconds, for a fixed volume ofl

12、iquid to flow under gravity through the capillary of theviscometer under a reproducible driving head and at a closelycontrolled temperature. The kinematic viscosity is calculatedfrom the measured flow time and the calibration constant of theviscometer.5. Significance and Use5.1 Kinematic viscosity i

13、s a physical property which is ofimportance in the design of systems in which flowing liquidsare used or handled.6. Apparatus6.1 Viscometer ThermostatAny transparent liquid or va-por bath of sufficient depth such that at no time during themeasurement will any portion of the sample in the viscometerb

14、e less than 20 mm below the surface of the bath liquid or lessthan 20 mm above the bottom of the bath may be used. The1This test method is under the jurisdiction of Committee D02 on PetroleumProducts and Lubricants and is the direct responsibility of Subcommittee D02.11 onEngineering Sciences of Hig

15、h Performance Fluids and Solids.Current edition approved Aug. 1, 2010. Published October 2010. Originallyapproved in 1991. Last previous edition approved in 2006 as D448691(2006).DOI: 10.1520/D4486-91R10.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Se

16、rvice at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.temperature control must be such that for

17、the range from 15 to100 C (60 to 212 F) the temperature of the bath medium doesnot vary by more than 0.02 F (0.01 C) over the length of theviscometers, or between the position of each viscometer, or atthe location of the thermometer. For temperatures outside thisrange, the variation must not exceed

18、0.05 F (0.03 C).6.2 Temperature-Measuring DeviceSuitable liquid-in-glass Kinematic Viscosity Test Thermometers, covering therange of test temperatures indicated in Table 1, as listed inSpecification E1, make certain that they have been standard-ized before use (see 8.2). Any other thermometric devic

19、e ispermissible provided that the same accuracy can be obtained.6.3 Timing DeviceAny timing device may be used pro-vided that the readings can be taken with a discrimination of0.2 s or better, and that it has an accuracy within 60.07 %when tested over intervals of 15 min.6.3.1 Electrical timing devi

20、ces may be used if the currentfrequency is controlled to an accuracy of 0.05 % or better.Alternating currents, as provided by some public power sys-tems, are intermittently rather than continuously controlled.When used to actuate electrical timing devices, such controlcan cause large errors in visco

21、sity flow measurements.7. Reagents and Materials7.1 Viscosity Oil Standards, conforming to ASTM viscosityoil standards having the approximate kinematic viscosityshown in Table 2. Certified kinematic viscosity values arecompared by annual cooperative tests by a number of labora-tories and are supplie

22、d with each portion.7.2 Chromic Acid (Cleaning Solution)(WarningCauses severe burns.Arecognized carcinogen. Strong oxidizer,contact with organic material may cause fire. Hygroscopic. SeeA1.2.)7.2.1 Other suitable cleaning solutions3are available. Inreferee testing situations, glassware shall be clea

23、ned with acleaning solution agreed upon by the parties involved.7.3 Acetone(WarningExtremely flammable. Vaporsmay cause flash fire. See Annex A1.3.)7.4 Hydrochloric Acid (Concentrated)(WarningPoison. Corrosive. May be fatal if swallowed. Liquid andvapor cause severe burns. Harmful if inhaled. See An

24、nexA1.4.)8. Standardization8.1 ViscometersOnly calibrated viscometers standardizedas described in Annex A2 shall be used.8.2 ThermometersLiquid-in-glass thermometers shall bechecked to the nearest 0.01 C (0.02 F) by direct comparisonwith a suitable standardized thermometer. Kinematic ViscosityTest T

25、hermometers shall be standardized at “total immersion”which means immersion to the top of the mercury column, withthe remainder of the stem and the expansion chamber at the topof the thermometer exposed to room temperature; do notsubmerge the expansion bulb at the top of the thermometer. Itis essent

26、ial that the ice point of standardized thermometers bedetermined periodically and the official corrections be adjustedto conform to the change in ice point.8.3 TimersStandard time signals available in some na-tions may be used in checking the accuracy of timing devices.In the United States of Americ

27、a, time signals, as broadcast bythe National Bureau of Standards, Station WWV, Washington,DC 20234, at 2.5, 5, 10, 15, 20, 25, 30, and 35 MHz are aconvenient and primary standard reference for calibratingtiming devices; the signals are broadcast 24 h daily. StationCHU from Ottawa, Canada, at 3.330,

28、7.335, and 14.670 MHzor Station MSF at Rugby, United Kingdom, at 2.5, 5, and 10MHz may be received better in some locations.8.4 Viscosity standards may also be used to check theover-all kinematic viscosity procedure in a laboratory. If themeasured kinematic viscosity does not agree within 60.35 %of

29、the certified value, each step in the procedure should berechecked, including thermometer and viscometer calibrationto locate source of error.9. Cleaning of Viscometer9.1 Between successive determinations, clean the viscom-eter thoroughly by several rinsings with an appropriate solventcompletely mis

30、cible with the sample, followed by a completelyvolatile solvent. Dry the viscometer with vacuum attached toTube A or by placing viscometer in a vacuum oven.9.2 Periodically clean the instrument with chromic acid(WarningSee 7.2 and A1.2.) to remove organic deposits,rinse thoroughly with distilled wat

31、er and acetone (WarningSee 7.3 and A1.3.), and dry with clean dry air. Inorganic3Other suitable chromium free, sulfuric acid-based cleaning solutions areavailable.TABLE 1 Kinematic Viscosity Test ThermometersATest Temperature Scale ErrorBThermometerNumberF C ASTMCIPD65 53.9 74F 69F, C60 to 35 51 to

32、35 43F 65F, C40 40 73F, C 68F, C0 17.8 72F 67F, C32 0 33F, C68 and 70 20 and 21.1 44F, C 29F, C77 25 45F, C 30F, C86 30 118F, C100 37.8 28F 31F, C40 120C122 50 46F, C 66F, C130 54.4 29F 34F, C140 60 47F, C 35F, C180 82.2 48F 90F, C200 93.3 36F, C210 and 212 98.9 and 100 30F 32F, C100 121C275 135 110

33、F, C20 99C80 100C40 120C 92CAThe smallest graduation of the Fahrenheit thermometers is 0.1 F and for theCelsius thermometers is 0.05 C except for ASTM 43F and IP 65F for which it is0.2 F.BScale error for the Fahrenheit thermometers is not to exceed 60.2 F (exceptfor ASTM 110F which is 60.3 F); for t

34、he Celsius thermometers it is 60.1 C.These scale errors are required to apply only at the given test temperature.CComplete construction detail is given in Specification E1.DComplete construction detail is given in Part 1 of IP Standards for Petroleumand its Products.D4486 91 (2010)2deposits may be r

35、emoved by hydrochloric acid (WarningSee 7.4 and A1.4.) treatment before use of cleaning acid,particularly if barium salts are suspected.NOTE 1Do not allow chromic acid or hydrochloric acid to stand incontact with the Kovar fitting on the viscometer. Use a glass pipet tointroduce these acids into the

36、 viscometer in such a manner that contactwith the metal fittings is kept to an absolute minimum.NOTE 2Viscometers used for silicone fluids, fluorocarbons, and otherliquids which are difficult to remove by the use of a cleaning agent, shouldbe reserved for the exclusive use of those fluids except whe

37、n standardiz-ing. Such viscometers should be subjected to standardization checks atfrequent intervals.10. Procedure for Kinematic Viscosity10.1 Maintain the bath at the test temperature within thelimits given in 6.1. Apply the necessary corrections, if any, toall thermometer readings.10.2 Select a c

38、lean, dry, calibrated viscometer that will givea flow time not less than the minimum specified for theviscometer (see Table 3), or 200 s, whichever is the greater.10.3 Charge the viscometer through Tube A (see Fig. 1)until Bulb B is half filled.10.4 Test samples that are not stable in the presence o

39、f air atthe test temperature must have the air in the viscometer purgedby a working gas that does not react with the test sample.10.4.1 For the vulnerable-liquid viscometer (Fig. 1), attachTube A to a controlled source of a working gas.Tilt the chargedviscometer until the liquid sample no longer cov

40、ers the end ofTube C. Pressure purge the viscometer with working gas.Release the pressure and repeat the purge at least four times.10.4.2 Multiple purges are not required in the case ofvulnerable samples that are volatile but stable in the presenceof air at the test temperature.10.5 Adjustment of Pr

41、essure:10.5.1 In the vulnerable-liquid viscometer, adjust the pres-sure in the viscometer to the predetermined test pressure.Thispressure may be equal to the ambient in the case of reactivesamples or it may be an elevated pressure sufficient to repressthe boiling of a volatile sample. In any case th

42、e pressure insidethe viscometer must not be permitted to exceed 2 3 105kPa(2 atm).10.6 Mount the viscometer in the viscometer holder, andplace assembly in the constant-temperature bath. Ensure thatthe Working Capillary D is held vertical. Allow the chargedviscometer to remain in the bath long enough

43、 to reach the testTABLE 2 Approximate Values of the ASTM Viscosity StandardsViscosityStandardConformingto ASTMStandardsAApproximate Kinematic Viscosity, cStAt53.89C(65F)At 40C(40F)At 20C(68F)At 25C(77F)AtB37.78C(100F)At 40C(104F)At 50C(122F)AtB98.89C(210F)At 100C(212F)S-3 300 80 4.6 4.0 3.0 2.9 . 1.

44、2 1.2S-6 . . 11 8.9 6.0 5.7 . 1.8 1.8S-20 . . 44 34 20 18 . 4.0 3.9S-60 . . 170 120 60 54 . 7.4 7.2S-200 . . 640 450 200 180 . 17 17S-600 . . 2400 1600 600 520 280 33 32S-2000 . . 8700 5600 2000 1700 . 78 75S-8000 . . 37 000 23 000 8000 6700 . . .S-30000 . . . 81 000 27 000 23 000 11 000 . .AThe act

45、ual values for the standards listed above are established and annually reaffirmed by cooperative tests. In 1971, tests were made using 15 different types ofviscometers in 26 laboratories located in 9 countries.BStandardizations at 37.78 C and 98.89 C are to be discontinued Jan 1, 1977.TABLE 3 Dimens

46、ions for Vulnerable Liquid and TiltingViscometersSizeNo.Approxi-mateConstant,cSt/sViscosityRange,cStInsideDiameterof Tube D,mm (62%)VolumeBulb FmL (65%)Liquid Tilting Liquid Tilting25 0.002 0.5Ato 2 0.31 0.31 1.5 1.550 0.004 0.8 to 4 0.44 0.37 3.0 1.575 0.008 1.6 to 8 0.54 0.46 3.0 1.5100 0.015 3 to

47、 15 0.63 0.52 3.0 1.5150 0.035 7 to 35 0.78 0.65 3.0 1.5200 0.1 20 to 100 1.01 0.84 3.0 1.5300 0.25 50 to 250 1.26 1.05 3.0 1.5A250 s minimum flow time.FIG. 1 Viscometer for Vulnerable LiquidsD4486 91 (2010)3temperature. Because this time may vary with the viscosity ofthe sample and test temperature

48、, establish a safe temperatureequilibrium time by trial.10.7 Fill the timing Bulb F with sample as follows: Increasethe pressure in the viscometer by an amount sufficient to forcethe sample upward through Tubes D and E to fill Bulb Fentirely and Bulb G partially. Since the inside diameter of TubeE i

49、s greater than that of Tube D, Bulb F is filled mainly byliquid that flows through Tube E and Bulb G. Restore thepressure in the system to the prechecked test pressure. As thisis done the sample begins to drain from the capillary and upperbulbs of the viscometer. Tubes E and C are sufficiently large ina diameter that they drain completely before the liquid level inBulb G reaches the upper timing mark.10.8 With the sample flowing freely, measure in seconds, towithin 0.2 s (see 6.3), the time required