ASTM B965-2009(2018) Standard Specification for High Performance Tin-Coated Annealed Copper Wire Intended for Electrical and Electronic Application for Solderability.pdf

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1、Designation: B965 09 (Reapproved 2018)Standard Specification forHigh Performance Tin-Coated Annealed Copper WireIntended for Electrical and Electronic Application forSolderability1This standard is issued under the fixed designation B965; the number immediately following the designation indicates the

2、 year oforiginal adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This specification covers tin-coated annealed coppe

3、rwire intended for electrical and electronic applications wheresolderability is a requirement.1.2 The values stated in inch-pound units are to be regardedas standard. The values given in parentheses are mathematicalconversions to SI units that are provided for information onlyand are not considered

4、standard.1.2.1 ExceptionsThe SI values for density, resistivity, andvolume are to be regarded as standard.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety, h

5、ealth, and environmental practices and deter-mine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accor-dance with internationally recognized principles on standard-ization established in the Decision on Principles for theDevelopment of Inter

6、national Standards, Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade (TBT) Committee.2. Referenced Documents2.1 ASTM Standards:2B49 Specification for Copper Rod for Electrical PurposesB193 Test Method for Resistivity of Electrical ConductorMaterialsB258 S

7、pecification for Standard Nominal Diameters andCross-Sectional Areas of AWG Sizes of Solid RoundWires Used as Electrical Conductors2.2 Other Standards:IPC/ECA J-STD-002 Solderability Test for ComponentLeads, Lugs, Terminals and Wires3NBS Handbook 100 Copper Wire Tables43. Ordering Information3.1 Ord

8、ers for material under this specification shall includethe following information:3.1.1 Quantity of each size,3.1.2 Wire size-diameter in inches (see 5.3 and Table 1),3.1.3 Type of copper, if special (see 4.2),3.1.4 Package size (see 10.1),3.1.5 Special packaging marking, if required, and3.1.6 Place

9、of inspection (see 7.1).4. Material4.1 Tin for CoatingThe tin shall be electroplated for thecoating and shall be commercially pure (Explanatory Note 1).For purposes of this specification, the tin shall be consideredcommercially pure if the total of other elements, exclusive ofcopper, does not exceed

10、 1 %. Not withstanding the previoussentence, chemical analysis of the tin coating or of the tin usedfor coating shall not be required under this specification.4.2 Copper-Base MetalThe base metal shall be copper ofsuch quality and purity that the finished product shall haveproperties and characterist

11、ics prescribed in this specification.NOTE 1Specification B49 defines copper suitable for use.5. General Requirements (See Section 8)5.1 Tensile Strength and Elongation (Explanatory Note4)The tinned wire shall conform to the requirements forelongation prescribed in Table 1. No requirements for tensil

12、estrength are specified. For wire whose nominal diameter ismore than 0.001 in. (0.025 mm) greater than a size listed in1This specification is under the jurisdiction of ASTM Committee B01 onElectrical Conductors and is the direct responsibility of Subcommittee B01.04 onConductors of Copper and Copper

13、 Alloys.Current edition approved Oct. 1, 2018. Published October 2018. Originallyapproved in 2009. Last previous edition approved in 2014 as B965 09 (2014).DOI: 10.1520/B0965-09R18.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.or

14、g. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3Available from IPC, 3000 Lakeside Drive, Suite 309S, Bannockburn, IL60015,http:/www.ipc.org, and ECA 2500 Wilson Blvd., Arlington, VA 22201, http:/www.ec-central.org.4Available fr

15、om National Technical Information Service (NTIS), 5285 PortRoyal Rd., Springfield, VA 22161, http:/www.ntis.gov.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United StatesThis international standard was developed in accordance with internationall

16、y recognized principles on standardization established in the Decision on Principles for theDevelopment of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.1Table 1, but less than that of the next larger size, ther

17、equirements of the next larger size shall apply.5.2 Resistivity (Explanatory Note 1 and Note 3)The elec-trical resistivity of tinned wire at a temperature of 20C shallnot exceed the values prescribed in Table 2.5.3 Dimensions and Permissible Variations (ExplanatoryNote 2)The wire sizes shall be expr

18、essed as the diameter ofthe wire in decimal fractions of an inch to the nearest 0.0001 in.(0.0025 mm). The tin-coated wire shall not vary from thespecified diameter by more than the amounts prescribed inTable 3.5.4 Continuity of CoatingThe tin coating shall be continu-ous. The continuity of coating

19、on the wire shall be determinedon representative samples taken before stranding or insulating.The continuity of tinning shall be determined by the hydro-chloric acid-sodium polysulfide test in accordance with 6.4.5.5 Thickness of CoatingThe wire shall have adequatefree tin (Explanatory Note 1) to in

20、sure meeting solderabilityrequirements as prescribed in 5.8. The thickness of coatingshall be at the manufacturers discretion or as agreed uponbetween the manufacturer and purchaser to insure complianceto 5.8 and further processing for solderability performanceafter insulation.5.6 Adherence of Coati

21、ngThe tin coating shall be firmlyadherent to the surface of the copper. The adherence of coatingon the wire shall be determined on representative samplestaken after electroplating and prior to final drawing. Theadherence of coating shall be determined by the wrapping testin accordance with 6.6.5.7 J

22、ointsNecessary joints in the completed wire and inthe wire and rods prior to final drawing shall be made inaccordance with the best commercial practice.5.8 SolderabilityThe solder must cover greater than 95 %of the surface of the specimen and show evidence of goodwetting and of bonding. The solderab

23、ility shall be tested inaccordance with 6.7.5.9 FinishThe coating shall consist of a smooth continu-ous layer, firmly adherent to the surface of the copper. The wireshall be free of all imperfections not consistent with the bestcommercial practice.6. Test Methods6.1 Tensile Strength and Elongation (

24、Explanatory Note 4):6.1.1 No test for tensile strength shall be required.6.1.2 The elongation of wire with a nominal diametergreater than 0.0808 in. (2.052 mm) shall be determined as thepermanent increase in length due to the breaking of the wire intension. The elongation shall be measured between g

25、age marksplaced originally 10 in. (242 mm) apart upon the test specimenand expressed in percent of the original length.6.1.3 The elongation of wire with a nominal diameter equalto or less than 0.0808 in. (2.053 mm) may be determined asdescribed above or by measurements made between the jaws ofthe te

26、sting machine. When measurements are made betweenthe jaws, the zero length shall be the distance between the jawsat the start of the tension test and be as near 10 in. (254 mm)as practicable. The final length shall be the distance betweenthe jaws at the time of rupture. The fracture shall be between

27、gage marks or jaws of the testing machine, depending onmethod used, and not closer than 1 in. (25.4 mm) to either gagemark or jaw.6.2 Resistivity (Explanatory Note 3)The electrical resis-tivity of the material shall be determined in accordance withTest Method B193. The purchaser may accept certifica

28、tion thatthe wire was drawn from rod stock meeting the internationalstandard for annealed copper instead of resistivity tests on thefinished wire.TABLE 1 Tensile RequirementsDiameter Area at 20C Elongationin10 in. (250mm),%minin. mm cmil in.2mm20.4600 11.684 211 600 0.1662 107.0 300.4096 10.404 167

29、800 0.1318 85.0 300.3648 9.266 133 100 0.1045 67.4 300.3249 8.252 105 600 0.08291 53.5 300.2893 7.348 83 690 0.06573 42.4 250.2576 6.543 66 360 0.05212 33.6 250.2294 5.827 52 620 0.04133 26.7 250.2043 5.189 41 740 0.03278 21.2 250.1819 4.620 33 090 0.02599 16.8 250.1620 4.115 26 240 0.02061 13.3 250

30、.1443 3.665 20 820 0.01635 10.5 250.1285 3.264 16 510 0.01297 8.37 250.1144 2.906 13 090 0.01028 6.63 250.1019 2.588 10 380 0.008155 5.26 200.0907 2.304 8 230 0.00646 4.17 200.0808 2.052 6 530 0.00513 3.31 200.0720 1.829 5 180 0.00407 2.63 200.0641 1.628 4 110 0.00323 2.08 200.0571 1.450 3 260 0.002

31、56 1.65 200.0508 1.290 2 580 0.00203 1.31 200.0453 1.151 2 050 0.00161 1.04 200.0403 1.024 1 620 0.00128 0.823 200.0359 0.912 1 290 0.00101 0.654 200.0320 0.813 1 020 0.000804 0.517 200.0285 0.724 812 0.000638 0.411 200.0253 0.643 640 0.000503 0.324 200.0226 0.574 511 0.000401 0.259 200.0201 0.511 4

32、04 0.000317 0.205 150.0179 0.455 320 0.000252 0.162 150.0159 0.404 253 0.000199 0.128 150.0142 0.361 202 0.000158 0.102 150.0126 0.320 159 0.000125 0.081 150.0113 0.287 128 0.000100 0.065 150.0100 0.254 100 0.0000785 0.051 100.0089 0.226 79.2 0.0000622 0.040 100.0080 0.203 64.0 0.0000503 0.032 100.0

33、071 0.180 50.4 0.0000396 0.026 100.0063 0.160 39.7 0.0000312 0.020 100.0056 0.142 31.4 0.0000246 0.016 100.0050 0.127 25.0 0.0000196 0.013 100.0045 0.114 20.2 0.0000159 0.010 100.0040 0.102 16.0 0.0000126 0.0081 100.0035 0.089 12.2 0.00000962 0.0062 100.0031 0.079 9.61 0.00000755 0.0049 10B965 09 (2

34、018)26.3 Dimensional MeasurementsDimensional measure-ments shall be made with a micrometer caliper equipped witha vernier graduated in 0.0001 in. (0.0025 mm). Measurementsshall be made on at least three places on each unit selected forthis test. If accessible, one measurement shall be taken on eache

35、nd and one near the middle. The average of the threemeasurements shall determine compliance with the require-ments.6.4 Continuity of Coating:6.4.1 Length of SpecimensTest specimens shall have alength of about 6 in. (152 mm). They shall be tagged or markedto correspond with the coil, spool, or reel f

36、rom which they werecut.6.4.2 Treatment of SpecimensThe specimens shall bethoroughly cleaned by immersion in a suitable organic solventfor at least 3 min; then removed and wiped dry with a clean,soft cloth (Cautionsee Explanatory Note 5). The specimensthus cleaned shall be kept wrapped in a clean, dr

37、y cloth untiltested. That part of the specimen to be immersed in the testsolution shall not be handled. Care shall be taken to avoidabrasion by the cut ends.6.4.3 Special Solutions Required:6.4.3.1 Hydrochloric Acid Solution (HCl) (sp gr 1.088)Commercial HCl (sp gr 1.12) shall be diluted with distil

38、ledwater to a specific gravity of 1.088 measured at 15.6C (60F).A portion of HCl solution having a volume of 180 mL shall beconsidered to be exhausted when the number of test specimensprescribed in Table 4 of a size as indicated in 6.4.3 have beenimmersed in it for two cycles.6.4.3.2 Sodium Polysulf

39、ide Solution (sp gr 1.142) (Explana-tory Note 6)A concentrated solution shall be made bydissolving sodium sulfide crystals (cp) in distilled water untilthe solution is saturated at about 21C (70F), and addingsufficient flowers of sulfur (in excess of 250 g/L of solution) toprovide complete saturatio

40、n, as shown by the presence in thesolution of an excess of sulfur after the solution has beenallowed to stand for at least 24 h. The test solution shall bemade by diluting a portion of the concentrated solution withdistilled water to a specific gravity of 1.135 to 1.145 at 15.6C(60F). The sodium pol

41、ysulfide test solution should havesufficient strength to blacken thoroughly a piece of cleanuntinned copper wire in 5 s. The test solution used for testingsamples shall be considered exhausted if it fails to blacken apiece of clean copper as described above.6.4.4 Procedure:6.4.4.1 Immersion of Speci

42、mensImmerse a length of atleast 4-1/2 in. (114 mm) from each of the clean specimens, inaccordance with the following cycles, in test solutions main-tained at a temperature between 15.6 and 21C (60 and 70F):(1) Immerse the specimen for 1 min in the HCl solutiondescribed in 6.4.2, wash, and wipe dry;

43、(2) immerse thespecimen for 30 s in the sodium polysulfide solution describedin 6.4.2, wash, and wipe dry; (3) immerse the specimen for 1min in the HCl solution, wash, and dry; (4) immerse thespecimen for 30 s in the sodium polysulfide solution, wash, andwipe dry.TABLE 2 Electrical Resistivity Requi

44、rementsNominal Diameter Resistivity at 20Cin. mm lb/mile2g/m20.460 to 0.290, incl 11.7 to 7.4, incl 896.15 0.15695Under 0.290 to 0.103, incl Under 7.4 to 2.6, incl 900.77 0.15776Under 0.103 to 0.0201, incl Under 2.6 to 0.51, incl 910.15 0.15940Under 0.0201 to 0.0111, incl Under 0.51 to 0.28, incl 92

45、9.52 0.16279Under 0.0111 to 0.0030, incl Under 0.28 to 0.076, incl 939.51 0.16454TABLE 3 Permissible Variations in DiameterNominal Diameter of Wire Permissible Variations in Diameterin. mmin. mm plus minus plus minusUnder0.0100Under0.250.0003 0.00010 0.0076 0.00250.0100and over0.25 andover3% 1% 3% 1

46、%TABLE 4 Limiting Number of Test Specimens for Coating TestsNominal DiameterMaximum Number of Specimens to beTested for 2 Cyclesin 180 mL of Acid Solutionin. mm0.460 to 0.141, incl 11.7 to 3.6, incl 2Under 0.141 to 0.0851, incl Under 3.6 to 2.2, incl 4Under 0.0851 to 0.0501, incl Under 2.2 to 1.3, i

47、ncl 6Under 0.0501 to 0.0381, incl Under 1.3 to 0.97, incl 10Under 0.0381 to 0.0301, incl Under 0.97 to 0.76, incl 12Under 0.0301 to 0.0030, incl Under 0.76 to 0.076, incl 14B965 09 (2018)36.4.4.2 Washing SpecimensAfter each immersion, imme-diately wash the specimens thoroughly in clean water and wip

48、edry with a clean, soft cloth.6.4.4.3 Examination of SpecimensAfter immersion andwashing, examine the specimens to ascertain if copper exposedthrough openings in the tin coating has been blackened byaction of the sodium polysulfide. The specimens shall beconsidered to have failed if, by such blacken

49、ing, exposedcopper is revealed. No attention shall be paid to blackeningwithin 0.5 in. (12.7 mm) of the cut end. A grayish brownappearance of the coating shall not constitute failure.6.5 Thickness of CoatingConformance to free tin require-ments may be determined in accordance with Test MethodAasprescribed in Appendix X1.6.6 Adherence of Coating:6.6.1 Specimens:6.6.1.1 Length of SpecimensTest specimens shall be ap-proximately 20 in. (508 mm) prior to wrapping and shall betagged or marked to correspond with the coil, spool, or reelfrom wh