BS PD CEN ISO TS 16558-2-2015 Soil quality Risk-based petroleum hydrocarbons Determination of aliphatic and aromatic fractions of semi-volatile petroleum hydrocarbons usin.pdf

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1、BSI Standards Publication Soil quality Risk-based petroleum hydrocarbons Part 2: Determination of aliphatic and aromatic fractions of semi-volatile petroleum hydrocarbons using gas chromatography with flame ionization detection (GC/FID) PD CEN ISO/TS 16558-2:2015National foreword This Published Docu

2、ment is the UK implementation of CEN ISO/TS 16558-2:2015. The UK participation in its preparation was entrusted to Technical Committee EH/4, Soil quality. A list of organizations represented on this committee can be obtained on request to its secretary. This publication does not purport to include a

3、ll the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2015. Published by BSI Standards Limited 2015 ISBN 978 0 580 76263 5 ICS 13.080.10 Compliance with a British Standard cannot confer immunity from legal obligations. This Pu

4、blished Document was published under the authority of the Standards Policy and Strategy Committee on 30 September 2015. Amendments/corrigenda issued since publication Date Text affected PUBLISHED DOCUMENT PD CEN ISO/TS 16558-2:2015 TECHNICAL SPECIFICATION SPCIFICATION TECHNIQUE TECHNISCHE SPEZIFIKAT

5、ION CEN ISO/TS 16558-2 September 2015 ICS 13.080.10 English Version Soil quality - Risk-based petroleum hydrocarbons - Part 2: Determination of aliphatic and aromatic fractions of semi- volatile petroleum hydrocarbons using gas chromatography with flame ionization detection (GC/FID) (ISO/TS 16558-2:

6、2015) Qualit du sol - Hydrocarbures de ptrole risque - Partie 2: Dtermination des fractions aliphatiques et aromatiques des hydrocarbures de ptrole semi- volatiles par chromatographie en phase gazeuse avec dtection dionisation de la flamme (ISO/TS 16558- 2:2015) Bodenbeschaffenheit - Minerallkohlenw

7、asserstoffe fr die Risikobeurteilung - Teil 2: Teil 2: Bestimmung aliphatischer und aromatischer Fraktionen schwerflchtiger Minerallkohlenwasserstoffe mittels Gaschromatographie mit Flammenionisationsdetektion (GC/FID) (ISO/TS 16558-2:2015) This Technical Specification (CEN/TS) was approved by CEN o

8、n 13 July 2015 for provisional application. The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard. CEN members

9、 are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS) until the final decision about the pos

10、sible conversion of the CEN/TS into an EN is reached. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lit

11、huania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17,

12、B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN ISO/TS 16558-2:2015 E PD CEN ISO/TS 16558-2:2015CEN ISO/TS 16558-2:2015 (E) 2 Contents Page European foreword . 3 PD CEN ISO/TS 16558-2:2015CEN ISO/TS 16558-2:20

13、15 (E) 3 European foreword This document (CEN ISO/TS 16558-2:2015) has been prepared by Technical Committee ISO/TC 190 “Soil quality” in collaboration with Technical Committee CEN/TC 345 “Characterization of soils” the secretariat of which is held by NEN. Attention is drawn to the possibility that s

14、ome of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to an

15、nounce this Technical Specification: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,

16、Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorsement notice The text of ISO/TS 16558-2:2015 has been approved by CEN as CEN ISO/TS 16558-2:2015 without any modification. PD CEN ISO/TS 16558-2:2015 ISO/TS 16558-2:2015(E)Foreword iv Introduction v 1 Scope

17、 . 1 2 Normative references 1 3 Terms and definitions . 2 4 Interferences 2 5 Principle 2 6 Reagents 3 7 Apparatus . 4 8 Sampling, sample conservation, and pretreatment . 5 9 Procedure. 5 9.1 Blank 5 9.2 Extraction 6 9.2.1 Total petroleum hydrocarbons 6 9.2.2 Split into aliphatic and aromatic fracti

18、ons 6 9.3 Determination by gas chromatography . 7 9.3.1 Test of the performance of the gas chromatographic system . 7 9.3.2 Repeatability test . 7 9.3.3 Calibration . 7 9.3.4 Validity check of the calibration function . 7 9.3.5 Measurement 7 9.3.6 Integration . 7 9.3.7 Calculation of the total petro

19、leum hydrocarbons 9 9.3.8 Calculation of the individual extractable fractions . 9 9.4 Quality control . 9 9.4.1 Suitability check of the split procedure . 9 10 Expression of results .10 11 Test report 10 Annex A (informative) Examples of gas chromatograms of total extractable petroleum hydrocarbon a

20、nd aliphatic and aromatic fractions in a standard solution and in soil samples 11 Annex B (informative) Determination of the boiling range of mineral oil hydrocarbons from the gas chromatogram .14 Annex C (informative) Information on split of aliphatic and aromatic fractions using silicagel 16 Bibli

21、ography .20 ISO 2015 All rights reserved iii Contents Page PD CEN ISO/TS 16558-2:2015 ISO/TS 16558-2:2015(E) Foreword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is

22、normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part

23、in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. The procedures used to develop this document and those intended for its further maintenance are described in the ISO/IEC Directives, Part 1. In particula

24、r the different approval criteria needed for the different types of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives). Attention is drawn to the possibility that some of the elements of this

25、document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on the ISO list of patent declarations received (see www.is

26、o.org/patents). Any trade name used in this document is information given for the convenience of users and does not constitute an endorsement. For an explanation on the meaning of ISO specific terms and expressions related to conformity assessment, as well as information about ISOs adherence to the

27、WTO principles in the Technical Barriers to Trade (TBT) see the following URL: Foreword - Supplementary information The committee responsible for this document is ISO/TC 190, Soil quality, Subcommittee SC 3, Chemical methods and soil characteristics. ISO 16558 consists of the following parts, under

28、the general title Soil quality Risk-based petroleum hydrocarbons: Part 1: Determination of aliphatic and aromatic fractions of volatile petroleum hydrocarbons using gas chromatography (static headspace method) Part 2: Determination of aliphatic and aromatic fractions of semi-volatile petroleum hydro

29、carbons using gas chromatography with flame ionization detection (GC/FID) Technical Specificationiv ISO 2015 All rights reserved PD CEN ISO/TS 16558-2:2015 ISO/TS 16558-2:2015(E) Introduction ISO 11504 establishes a basis for the choice of fractions and individual compounds when carrying out analysi

30、s for petroleum hydrocarbons in soils and soil-like materials including sediments. It provides guidance for the appropriate use of the analytical results in risks assessment. This part of ISO 16558 specifies methods for the quantitative determination of the appropriate fractions of aliphatic and aro

31、matic compounds. The methods described in this part of ISO 16558 are based on existing standards mineral oil (ISO 16703) and volatile hydrocarbons (ISO 22155). The general use and relation between the two different parts of ISO 16558 are given in Figure 1. Key a Florisil bclean-up: Only to be applie

32、d in case the test according to ISO 16703 is carried out. If the aliphatic and aromatic fractions have to be analysed, Florisil clean-up is not to be carried out. Florisil is a trade name for a prepared diatomaceous substance, mainly consisting of anhydrous magnesium silicate. b Florisil is an examp

33、le of a suitable product available commercially. This information is given for the convenience of users of this part of ISO 16558 and does not constitute an endorsement by ISO of this product. Figure 1 Use of different analytical International Standards during risk assessment of petroleum hydrocarbo

34、ns ISO 2015 All rights reserved v PD CEN ISO/TS 16558-2:2015 Soil quality Risk-based petroleum hydrocarbons Part 2: Determination of aliphatic and aromatic fractions of semi-volatile petroleum hydrocarbons using gas chromatography with flame ionization detection (GC/FID) 1 Scope This part of ISO 165

35、58 specifies a method for the quantitative determination of the total extractable semi-volatile, aliphatic, and aromatic fractions of petroleum hydrocarbon content in field moist soil samples by gas chromatography. The results of the test carried out can be used for risk assessment studies related t

36、o contaminations with petroleum hydrocarbons. This part of ISO 16558 provides a method applicable to petroleum hydrocarbon contents from about 100 mg/kg soil expressed as dry matter for the whole aliphatic fraction C 10to C 40,as well as the aromatic fraction C 10to C 40 . For sub-fractions, lower l

37、imits of determination can be reached. If lower detection limits are required, large volume injection can be used or concentration of the final extract can be carried out. NOTE 1 Low concentrations of aliphatic and aromatic compounds can be found in natural uncontaminated organic rich soils like pea

38、t soils. With this method, all hydrocarbons with a boiling range of 174 C to 525 C, n-alkanes between C 10 H 22to C 40 H 82 , isoalkanes, cycloalkanes, alkyl benzenes, and alkyl naphthalenes and polycyclic aromatic compounds are determined as total extractable semi-volatile petroleum hydrocarbons C

39、10to C 40 ; besides that, semi-volatile aliphatic and aromatic fractions are specified. For the determination of volatile aliphatic and aromatic fractions of petroleum hydrocarbons in soil samples, see ISO 16558-1. NOTE 2 The sub-fractions proposed in this part of ISO 16558 have shown to be suitable

40、 for risk assessment studies. However, other sub-fractions between C 10 H 22to C 40 H 82can also be determined in conformity with this part of ISO 16558. On the basis of the peak pattern of the gas chromatogram and of the boiling points of the individual n-alkanes listed in Annex B, the approximate

41、boiling range of the mineral oil and some qualitative information on the composition of the contamination can be achieved. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references,

42、 only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 8466-1, Water quality Calibration and evaluation of analytical methods and estimation of performance characteristics Part 1: Statistical evaluation of the li

43、near calibration function ISO 10381-1, Soil quality Sampling Part 1: Guidance on the design of sampling programmes TECHNICAL SPECIFICATION ISO/TS 16558-2:2015(E) ISO 2015 All rights reserved 1 PD CEN ISO/TS 16558-2:2015 ISO/TS 16558-2:2015(E) ISO 11465, Soil quality Determination of dry matter and w

44、ater content on a mass basis Gravimetric method ISO 14507, Soil quality Pretreatment of samples for determination of organic contaminants ISO 16703, Soil quality Determination of content of hydrocarbon in the range C10 to C40 by gas chromatography ISO 18512, Soil quality Guidance on long and short t

45、erm storage of soil samples 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 total extractable semi-volatile petroleum hydrocarbon content by gas chromatography sum of compounds extractable with acetone/n-heptane (2+1) that can be detected wit

46、h a flame ionization detector and chromatographed on a non-polar capillary column with retention times between those of n-decane (C 10 H 22 ) and n-tetracontane (C 40 H 82 ) Note 1 to entry: Substances that comply with that definition are mainly long chain or branched aliphatic, alicyclic, lower pol

47、ycyclic, or alkyl substituted aromatic hydrocarbons. 3.2 semi-volatile aliphatic fraction of petroleum hydrocarbons fraction of the total semi-volatile petroleum hydrocarbons which are eluted with pentane, hexane, or heptane after adsorption on silicagel Note 1 to entry: This is a method defined in

48、this part of ISO 16558. It is unknown and unpredictable if the same compounds will elute from the silicagel with other solvents. 3.3 semi-volatile aromatic fraction of petroleum hydrocarbons fraction of the total semi-volatile petroleum hydrocarbons which are eluted with dichloromethane or with a 1:

49、1 mixture of dichloromethane and n-heptane after adsorption on silicagel Note 1 to entry: This is a method defined in this part of ISO 16558. It is unknown and unpredictable if the same compounds will elute from the silicagel with other solvents. 4 Interferences Compounds not related to petroleum hydrocarbon contaminations with a boiling point between C 10and C 40(e.g. halogenated hydrocarbons) might interfere with the determination. 5 Principle A known amount of the homogenized soil sample is extracted by mec