ASTM B727-2004(2014) Standard Practice for Preparation of Plastics Materials for Electroplating《电镀用塑料材料制备的标准实施规程》.pdf

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1、Designation: B727 04 (Reapproved 2014)Standard Practice forPreparation of Plastics Materials for Electroplating1This standard is issued under the fixed designation B727; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of l

2、ast revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This practice is a guide to the surface preparation ofplastic materials for decorative and functional electroplating,wh

3、ere the sequence of chemical treatments may include:cleaning, conditioning, etching, neutralizing, catalyzing,accelerating, and autocatalytic metal deposition. Surface prepa-ration also includes electrodeposition of metallic strike coat-ings immediately after autocatalytic metal deposition. Thesetre

4、atments result in the deposition of thin conductive metalfilms on the surface of molded-plastic materials, and aredescribed in this practice.1.2 Once molded-plastics materials have been madeconductive, they may be electroplated with a metal or combi-nation of metals in conventional electroplating so

5、lutions. Theelectroplating solutions and their use are beyond the scope ofthis practice.1.3 The values stated in SI units are to be regarded as thestandard. The values given in parentheses are for informationonly.1.4 This standard does not purport to address all of thesafety concerns, if any, associ

6、ated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use. (See Section 4.)2. Referenced Documents2.1 ASTM Standards:2B532 Specification for Appearance of Elect

7、roplated PlasticSurfacesB533 Test Method for Peel Strength of Metal ElectroplatedPlasticsB553 Test Method for Thermal Cycling of ElectroplatedPlastics (Withdrawn 1991)3B604 Specification for Decorative Electroplated Coatings ofCopper Plus Nickel Plus Chromium on Plastics3. Significance and Use3.1 A

8、variety of metals can be electrodeposited on plasticsfor decorative or engineering purposes. The most widely usedcoating consists of three layerscopper plus nickel pluschromiumfor decorative applications. However, brass,silver, tin, lead, cadmium, zinc, gold, other metals, andcombinations of these a

9、re used for special purposes. The key toproducing electroplated plastics of high quality lies in the caretaken in preparing plastics for electroplating. The informationcontained in this practice is useful in controlling processes forthe preparation of plastics for electroplating.4. Hazards4.1 Some c

10、hemical solutions are exothermic upon mixing orin use, thereby requiring cooling and proper containment toprevent injury to personnel.4.2 For details on the proper operation and safety precau-tions to be followed by vapor degreasing, seeASTM STP 310.45. General Considerations5.1 Nature of Plastics S

11、uitable for Electroplating:5.1.1 Plastics suitable for electroplating may be a combina-tion of one or more polymers so formulated as to allowselective etching of one or more constituents. The mostcommonly electroplated material, acrylonitrile-butadiene-styrene (ABS), is a terpolymer. During etching,

12、 soft butadienerubber particles dispersed in the acrylonitrile-styrene matrixare selectively attacked. The microscopic pockets formed bythe etching process provide sites for the physical interlockingof the plastic substrate and subsequently applied metalliccoatings. The resultant mechanical bonding

13、is instrumental inachieving metal to plastic adhesion.5.2 Plastics Suitable for Electroplating:5.2.1 The plastics materials commonly used for injectionmolded articles to be electroplated are:1This practice is under the jurisdiction of ASTM Committee B08 on Metallicand Inorganic Coatings and is the d

14、irect responsibility of Subcommittee B08.02 onPre Treatment.Current edition approved Nov. 1, 2014. Published November 2014. Originallyapproved in 1983. Discontinued January 2004 and reinstated in 2004 as B72704.Last previous edition approved in 2009 as B72709. DOI: 10.1520/B0727-04R14.2For reference

15、d ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3The last approved version of this historical standard is referenced onwww.

16、astm.org.4Handbook of Vapor Degreasing, ASTM STP 310A, ASTM, 1976.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States15.2.1.1 Acrylonitrile-butadiene-styrene (ABS),5.2.1.2 Polypropylene,5.2.1.3 Polysulfone,5.2.1.4 Modified Polyphenylene O

17、xide,5.2.1.5 Polycarbonate,5.2.1.6 Polyester, and5.2.1.7 Nylon.5.2.2 The preparation of these materials for electroplatinggenerally involves the basic steps described in this practice, butsubstantial variations may be necessary to achieve optimumresults with plastics other than ABS.5.3 Molding Consi

18、derations:5.3.1 The chemical nature of plastics combined with thenature of the injection molding process produces plastic partsthat are somewhat heterogeneous in composition and structure.During the molding of ABS, for example, the shape, size, anddistribution of butadiene rubber particles may vary

19、consider-ably within a part and may affect the uniformity of subsequentsurface etching treatments.As a result, under- and over-etchingof the surface may occur, either of which can interfere with theadhesion of metal coatings. The use of a properly formulatedetchant combined with an organic condition

20、er may overcomeproblems of nonuniform etching.5.3.2 Although it may be possible to overcome problems ofnonuniform etching by suitable chemical treatments, control ofthe injection molding process is critical if plastic parts are to beelectroplated successfully. It is essential that the resin bethorou

21、ghly dried before molding. The temperature of the moldand all heating zones, the pressure, the total cycle time, and thefill time must be controlled and monitored. Devices exist forcontrolling all molding parameters precisely.5.3.3 The visible defects that may arise in the moldingprocess are describ

22、ed in Specification B532. Molded parts thatare obviously defective should not be processed without theapproval of the purchaser.5.3.4 Mold release agents interfere with the adhesion ofmetallic coatings on plastic substrates and should not be used.5.4 Process Selection:5.4.1 Due to the complexity and

23、 proprietary nature ofcommercially available processes for preparing plastics forelectroplating, a complete process should be selected for aspecific type of plastic, and operated according to the specificinstructions of the supplier of the process.5.5 Handling of Molded Plastic Parts:5.5.1 Molded-pl

24、astic parts must be kept clean and carefullyhandled. It is a common practice to use cotton gloves inremoving parts from the mold and for all subsequent handling.5.5.2 The trimming of plastic parts and the removal of flashand runners should be done with care to avoid introducingsurface defects. These

25、 and other mechanical finishing opera-tions should be completed before beginning the chemicaltreatment of parts for electroplating. Runners are sometimesleft intact to facilitate racking for electroplating at a later stage.5.6 Racking:55.6.1 Molded-plastic parts can be prepared for electroplat-ing i

26、n barrels, trays, or baskets and then transferred to racksdesigned specifically for electroplating, or they can be pro-cessed on racks that are used in both the preparation andelectroplating cycles. Which method of racking to use may bedictated by the size of the parts, by efficiency, and otherconsi

27、derations. The first is the bulk method; the second iscalled “through-racking.”5.6.2 Bulk MethodSmall parts are often processed inpolypropylene baskets or plastic-coated steel baskets. Some-what larger parts can be processed in layered baskets made ofstainless steel (UNS Types S30400 or S31600), tit

28、anium, orplastic-coated mild steel. Parts are placed as closely as possiblecompatible with the need to provide for complete solutionwetting and drainage.5.6.3 Through-Racking:5.6.3.1 The design of racks to be used in both preparationand electroplating processes is dictated by the requirements ofelec

29、troplating and the corrosive nature of the solutions.5.6.3.2 Rack splines and hooks are generally made ofcopper or copper alloys. Rack cross bars are made of copper orcopper alloys if they are to conduct current from the splines tothe contacts, but may be made of steel if their function is solelyto

30、strengthen and make the rack rigid. Rack contacts areusually stainless steel, although titanium has also been used. Ifspring action is necessary, phosphor bronze may be used as thecontact member with a short stainless steel piece for the tip.5.6.3.3 The entire rack is sandblasted, primed, and coated

31、with plastisol before use, except for the stainless steel contacts.During the preparation process, the rack coating may becomecoated with metal, but this does not usually occur becausehexavalent chromium is absorbed in the plastisol and preventsautocatalytic metal deposition from occurring.5.6.3.4 C

32、ontrol of immersion times in neutralizing,catalyzing, and accelerating steps is critical to prevent metaldeposition on the rack coating.5.6.3.5 Parts are positioned on racks to optimize the thick-ness and appearance of electrodeposited coatings, and tominimize solution dragout.5.6.3.6 It may be nece

33、ssary to use current thieves, shields,or auxiliary anodes to obtain uniform metal distribution. Thenumber of contacts is greater for plastic parts than forcomparable metal parts. For example, if the total area beingelectroplated in less than 0.02 m2, one contact point is usuallysufficient; if the ar

34、ea is 0.25 to 0.60 m2, 16 contact points arerecommended.5.6.3.7 Metal deposited autocatalytically or electrolyticallymust be chemically removed from contacts after each cycle.This is usually accomplished by using nitric acid-containingsolutions, or proprietary rack strippers.6. Preparation of Plasti

35、c Substrates66.1 Alkaline Cleaning:6.1.1 Cleaning in alkaline solutions is optional. If the partsare carefully handled and kept clean after molding, alkalinecleaning can usually be avoided.5Standards and GuidelinesElectroplated Plastics, American Society of Elec-troplated Plastics, Washington, DC, S

36、econd Edition, 1979.6Adcock, J. L., “Electroplating Plasticsan AES Illustrated Lecture,” AmericanElectroplaters Society, Inc., Winter Park, FL, 1978.B727 04 (2014)26.1.2 Fingerprints, grease, and other shop soil should beremoved by soaking plastic-molded parts in mild alkalinesolutions that are comm

37、ercially available. A suitable solutionmay contain 25 g/L of sodium carbonate and 25 g/L oftrisodium phosphate operated at 55 to 65C. Parts are im-mersed in the solution for 2 to 5 min (see Note 1).NOTE 1Thorough rinsing after alkaline cleaning and after each of thefollowing processing steps is esse

38、ntial. Multiple water rinses are recom-mended.6.2 Conditioning:6.2.1 Conditioning is an optional step that precedes theetching step. Conditioning can eliminate adhesion problemsassociated with inadequate etching. The conditioner may be asolution of chromic and sulfuric acids, or it may contain anorg

39、anic solvent. Proprietary solutions are available and shouldbe operated according to suppliers directions.6.2.2 Chromic/Sulfuric Acid TypeThis type of conditionermay contain 30 g/L of chromic acid and 300 mL/L of sulfuricacid (93 mass %; density 1.83 g/mL) dissolved in water and ismaintained at a te

40、mperature of 60C 6 3C. Parts are im-mersed in the solution for 1 to 2 min. Because of the relativelylarge amount of sulfuric acid in the solution, the acrylonitrile-styrene matrix, as well as the butadiene phase, are attacked.6.2.3 Organic Solvent TypeThis type of conditioner is asolution of an orga

41、nic solvent in deionized water. The organicsolvent may be acetone or other ketone; for example, 2,4-pentadione is sometimes used.7The solution may contain 100to 125 mL/L of the appropriate organic solvent and is main-tained at a temperature of 40 to 45C. Treatment is byimmersion of the plastic parts

42、 for 2.0 to 2.5 min (see Note 2and Note 3).NOTE 2Solutions containing volatile organic solvents require ad-equate ventilation and must not contact metals. These materials chelateionic metal contaminants. Annealed polypropylene tanks are thereforeused to hold this type of solution.NOTE 3Multiple hot

43、water rinses are required after using the organicsolvent-type conditioner. Because organic solvents soften and swell theplastic surface, time of immersion and of transfer to rinse tanks may affectthe appearance of the final product, and should be controlled.6.3 Etching:6.3.1 Etchants are strong oxid

44、izing solutions that micror-oughen and chemically alter the surface of molded plasticparts. The etching step is the most important step in achievingserviceable adhesion of metals to plastics. Commercially usedetchants are either chromic acid types, chromic/sulfuric acidtypes, or chromic-sulfuric-pho

45、sphoric acid types.6.3.2 Chromic Acid TypeConcentrated etchants usuallycontain greater than 850 g/L of chromic acid and as much as1200 g/L.8,9The temperature of the solution is maintained at 506 3C and treatment is by immersion for 8 to 10 min.Concentrated solutions of chromic acid tend to oxidize b

46、uta-diene rubber particles in the case of ABS, selectively.6.3.3 Chromic/Sulfuric Acid TypeThis type of etchant maycontain 250 to 350 g/L of chromic acid and 200 to 250 mL/Lof sulfuric acid (93 mass %, density 1.83 mL/L) dissolved inwater. Immersion times of 5 to 10 min at a solution temperatureof 6

47、5 6 5C are commonly used. Several proprietary baths areavailable.6.3.4 Chromic-Sulfuric-Phosphoric Acid Type10This typeof etchant solution normally consists of 3 % by mass chromicacid, 56 % by mass sulfuric acid (density 1.83 g/mL), 10.5 %by mass phosphoric acid (density 1.87 g/mL), and the balancew

48、ater. An immersion time of about 3 min at 74 to 77C iscommonly used.6.4 Neutralizing (Sensitizing):6.4.1 After thorough rinsing, all residual chromic acid mustbe chemically removed from the surface of the molded-plasticparts. Neutralizers are used and are typically mild acid oralkaline solutions con

49、taining complexing or reducing agents.In the case of ABS, it is common to use a solution containinga mixture of an acidsalt and a reducing agent, such as sodiumbisulfite, to eliminate all traces of chromic acid. Typicalprocessing conditions are 1 to 2 min immersion at 40C.6.4.2 Neutralizers may also contain ionic surfactants toincrease the adsorption of catalyst. The use of surfactants,however, can lead to activation of the rack coating andsubsequent metal deposition on the rack. Surfactants shouldtherefore be used with caution. Ionic surfactants are notnormal