ASTM D79-1986(2014) Standard Specification for Zinc Oxide Pigments《氧化锌颜料的标准规格》.pdf

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1、Designation: D79 86 (Reapproved 2014) American Association StateHighway and Transportation Officials StandardAASHTO No.: M124Standard Specification forZinc Oxide Pigments1This standard is issued under the fixed designation D79; the number immediately following the designation indicates the year of o

2、riginaladoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.Asuperscriptepsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the U.S. Department of

3、 Defense.1. Scope1.1 This specification covers the pigments commerciallyknown as “zinc white” or zinc oxide. The pigments may bepurchased in the dry form or as a paste in oil.NOTE 1Zinc oxides are used in many industries. For additionalinformation, see Classification D4295 and Test Methods D4315 for

4、descriptions of zinc oxide use in rubber compounding.1.2 The values stated in SI units are to be regarded as thestandard. The values given in parentheses are for informationonly.2. Referenced Documents2.1 ASTM Standards:2D185 Test Methods for Coarse Particles in PigmentsD280 Test Methods for Hygrosc

5、opic Moisture (and OtherMatter Volatile Under the Test Conditions) in PigmentsD281 Test Method for Oil Absorption of Pigments bySpatula Rub-outD332 Test Method for Relative Tinting Strength of WhitePigments by Visual ObservationD1483 Test Method for Oil Absorption of Pigments byGardner-Coleman Metho

6、dD2745 Test Method for Relative Tinting Strength of WhitePigments by Reflectance MeasurementsD3280 Test Methods for Analysis of White Zinc PigmentsD4295 Classification for Rubber Compounding MaterialsZinc OxideD4315 Test Methods for Rubber Compounding MaterialZinc OxideE20 Practice for Particle Size

7、 Analysis of Particulate Sub-stances in the Range of 0.2 to 75 Micrometres by OpticalMicroscopy (Withdrawn 1994)33. Significance and Use3.1 Zinc oxide functions as both a chemical and a pigment.It is used in a variety of applications including rubber, paint,reprography, glass, chemicals, etc. In pai

8、nt, it contributes tomildew protection, ultraviolet absorption, hiding power, andneutralization of acids formed upon oxidation of the paint film.4. Composition and Properties4.1 Dry Pigment, French ProcessIn the manufacture ofFrench process zinc oxide, metallic zinc is vaporized, either ina boiler o

9、r a refining column, and the resulting vapor is burnedin a controlled manner in an orifice. The fine particles of zincoxide are cooled enough to agglomerate and are collected by asystem of fabric bags. French process oxide shall conform tothe properties listed in Table 1.4.2 Dry Pigment, American Pr

10、ocessIn the manufacture ofAmerican process zinc oxide, zinc ore is reduced in thepresence of a carbonaceous fuel. The resulting vapor is burnedin a combustion chamber, and the fine particles of zinc oxideare cooled enough to agglomerate and are collected by asystem of fabric bags.American process ox

11、ide shall conform tothe properties listed in Table 1.4.3 Paste in OilThe paste shall be made by thoroughlygrinding the specified pigment with linseed oil. As received itshall not be caked in the container and shall break up readily inoil to form a smooth paint of brushing consistency. The pasteshall

12、 conform to the following requirements:Pigment, % 80 to 86Linseed oil, % 14 to 20Moisture and other volatile matter, max, % 0.5Coarse particles and skins (total residue retained on aNo. 325 (45-m) sieve), max, % of the dry pigment1.54.4 In such physical properties as are specified by thepurchaser, t

13、he pigment shall satisfactorily match a referencesample mutually agreed upon by the purchaser and the seller.The most frequently specified properties are oil absorption,1This specification is under the jurisdiction of ASTM Committee D01 on Paintand Related Coatings, Materials, and Applications and i

14、s the direct responsibility ofSubcommittee D01.31 on Pigment Specifications.Current edition approved Dec. 1, 2014. Published December 2014. Originallyapproved in 1921. Last previous edition approved in 2009 as D79 86 (2009). DOI:10.1520/D0079-86R14.2For referenced ASTM standards, visit the ASTM webs

15、ite, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3The last approved version of this historical standard is referenced onwww.astm.org.Copyright ASTM International

16、, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1tinting strength, and particle shape. Appropriate test methodsare listed in Section 6. In the event that either an acicular typeor a nodular (spherical) type of zinc oxide is desired, theparticle shape shall be det

17、ermined by examining or photo-graphing microscopic mounts (1000 or more) of the sampleand the mutually agreed upon standard that are to be preparedas specified in Practice E20.5. Sampling5.1 Two samples shall be taken at random from differentpackages from each lot, batch, days pack, or other unit of

18、production in a shipment. When no markings distinguishingbetween units of production appear, samples shall be takenfrom different packages in the ratio of two samples for each4540 kg (10 000 lb), except that for shipments of less than10 000 lb, two samples shall be taken. At the option of thepurchas

19、er, the samples may be tested separately or afterblending in equal quantities the samples from the sameproduction unit to form a composite sample.6. Test Methods6.1 Tests shall be conducted in accordance with the appro-priate ASTM test methods, where applicable. Test proceduresnot covered by ASTM te

20、st methods shall be mutually agreedupon by the purchaser and the seller.6.1.1 Coarse ParticlesTest Methods D185.6.1.2 Moisture in PigmentsTest Methods D280.6.1.3 Chemical Analysis of Dry PigmentsTest MethodsD3280.6.1.4 Oil Absorption of Pigments by Gardner-ColemanMethodTest Method D1483.6.1.5 Oil Ab

21、sorption of Pigments by Spatula Rub-OutTestMethod D281.6.1.6 Instrumental Tinting Strength of White PigmentsTest Method D2745.6.1.7 Tinting Strength of White PigmentsTest MethodD332.7. Keywords7.1 American process; French process; mildew protection;ultraviolet absorption; zinc oxide; zinc whiteASTM

22、International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are enti

23、rely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand

24、 should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on

25、 Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at

26、 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ 1 CompositionFrenc

27、hProcessAmericanProcessZinc oxide, min, % 99 98.5Total sulfur, max, % 0.1 0.2Moisture and other volatile matter, max, % 0.5 0.5Total impurities, including moisture andother volatile matter, max, %1.0 1.5Coarse particles (total residue retained ona No. 325 (45-m) sieve), max, %0.10 0.25D79 86 (2014)2