ASTM D1319-2003e1 Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption《用荧光指示剂吸附法测定液态石油产品中烃类物质的标准试验方法》.pdf
《ASTM D1319-2003e1 Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption《用荧光指示剂吸附法测定液态石油产品中烃类物质的标准试验方法》.pdf》由会员分享,可在线阅读,更多相关《ASTM D1319-2003e1 Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption《用荧光指示剂吸附法测定液态石油产品中烃类物质的标准试验方法》.pdf(8页珍藏版)》请在麦多课文档分享上搜索。
1、Designation: D 1319 03e1Designation: 156/97An American National StandardStandard Test Method forHydrocarbon Types in Liquid Petroleum Products byFluorescent Indicator Adsorption1This standard is issued under the fixed designation D 1319; the number immediately following the designation indicates the
2、 year oforiginal adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Dep
3、artment of Defense.e1NOTEFootnote 7 and Table 2 were updated editorially in June 2006.1. Scope*1.1 This test method covers the determination of hydrocar-bon types over the concentration ranges from 5 to 99 volume %aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume %saturates in petroleum frac
4、tions that distill below 315C. Thistest method may apply to concentrations outside these ranges,but the precision has not been determined. Samples containingdark-colored components that interfere in reading the chro-matographic bands cannot be analyzed.1.2 This test method is intended for use with f
5、ull boilingrange products. Cooperative data have established that theprecision statement does not apply to narrow boiling petroleumfractions near the 315C limit. Such samples are not elutedproperly, and results are erratic.1.3 The applicability of this test method to products derivedfrom fossil fuel
6、s other than petroleum, such as coal, shale, ortar sands, has not been determined, and the precision statementmay or may not apply to such products.1.4 This test method has two precision statements depictedin tables. The first table is applicable to unleaded fuels that donot contain oxygenated blend
7、ing components. It may or maynot apply to automotive gasolines containing lead antiknockmixtures. The second table is applicable to oxygenate blended(for example, MTBE, ethanol) automotive spark ignition fuelsamples with a concentration range of 1340 volume percentaromatics, 433 volume percent olefi
8、ns, and 4568 volumepercent saturates.1.5 The oxygenated blending components, methanol, etha-nol, methyl-tert-butylether (MTBE), tert-amylmethylether(TAME), and ethyl-tert-butylether (ETBE), do not interferewith the determination of hydrocarbon types at concentrationsnormally found in commercial blen
9、ds. These oxygenatedcomponents are not detected since they elute with the alcoholdesorbent. Other oxygenated compounds shall be individuallyverified. When samples containing oxygenated blending com-ponents are analyzed, correct the results to a total-sample basis.1.6 The values stated in SI units ar
10、e to be regarded asstandard.NOTE 1For the determination of olefins below 0.3 volume %, othertest methods are available, such as Test Method D 2710.1.7 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this sta
11、ndard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use. For specific hazardstatements, see Section 7, 8.1, and 10.5.2. Referenced Documents2.1 ASTM Standards:2D86 Test Method for Distillation of Petroleum Products atAtmosph
12、eric PressureD 1655 Specification for Aviation Turbine FuelsD 2710 Test Method for Bromine Index of Petroleum Hy-drocarbons by Electrometric TitrationD 3663 Test Method for Surface Area of Catalysts andCatalyst CarriersD 4057 Practice for Manual Sampling of Petroleum andPetroleum ProductsD 4815 Test
13、 Method for Determination of MTBE, ETBE,TAME, DIPE, tertiary-Amyl Alcohol and C1to C4Alco-hols in Gasoline by Gas Chromatography1This test method is under the jurisdiction of ASTM Committee D02 onPetroleum Products and Lubricants and is the direct responsibility of SubcommitteeD02.04 on Hydrocarbon
14、Analysis.In the IP, this test method is under the jurisdiction of the StandardizationCommittee. This test method has been approved by the sponsoring committees andaccepted by the cooperating societies in accordance with established procedures.Current edition approved Nov. 1, 2003. Published January
15、2004. Originallyapproved in 1954. Last previous edition approved in 2002 as D 131902a.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary
16、 page onthe ASTM website.1*A Summary of Changes section appears at the end of this standard.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.D 5599 Test Method for Determination of Oxygenates inGasoline by Gas Chromatography and Oxygen
17、 SelectiveFlame Ionization DetectionE11 Specification for Wire Cloth and Sieves for TestingPurposes2.2 Other Standards:GC/OFID EPA Test MethodOxygen and Oxygenate Con-tent Analysis3BS4101 2000 Test sieves. Technical requirements andtesting. Test sieves of metal wire cloth43. Terminology3.1 Definitio
18、ns of Terms Specific to This Standard:3.1.1 aromaticsthe volume % of monocyclic and polycy-clic aromatics, plus aromatic olefins, some dienes, compoundscontaining sulfur and nitrogen, or higher boiling oxygenatedcompounds (excluding those listed in 1.5).3.1.2 olefinsthe volume % of alkenes, plus cyc
19、loalkenes,and some dienes.3.1.3 saturatesthe volume % of alkanes, plus cycloal-kanes.4. Summary of Test Method4.1 Approximately 0.75 mL of sample is introduced into aspecial glass adsorption column packed with activated silicagel. A small layer of the silica gel contains a mixture offluorescent dyes
20、. When all the sample has been adsorbed on thegel, alcohol is added to desorb the sample down the column.The hydrocarbons are separated in accordance with theiradsorption affinities into aromatics, olefins, and saturates. Thefluorescent dyes are also separated selectively, with the hydro-carbon type
21、s, and make the boundaries of the aromatic, olefin,and saturate zones visible under ultraviolet light. The volumepercentage of each hydrocarbon type is calculated from thelength of each zone in the column.5. Significance and Use5.1 The determination of the total volume % of saturates,olefins, and ar
22、omatics in petroleum fractions is important incharacterizing the quality of petroleum fractions as gasolineblending components and as feeds to catalytic reformingprocesses. This information is also important in characterizingpetroleum fractions and products from catalytic reforming andfrom thermal a
23、nd catalytic cracking as blending componentsfor motor and aviation fuels. This information is also importantas a measure of the quality of fuels, such as specified inSpecification D 1655.6. Apparatus6.1 Adsorption Columns, with precision bore (“true bore” IPdesignation) tubing, as shown on the right
24、 in Fig. 1, made ofglass and consisting of a charger section with a capillary neck,a separator section, and an analyzer section; or with standardwall tubing, as shown on the left in Fig. 1. Refer to Table 1 forcolumn tolerance limits.6.1.1 The inner diameter of the analyzer section for theprecision
- 1.请仔细阅读文档,确保文档完整性,对于不预览、不比对内容而直接下载带来的问题本站不予受理。
- 2.下载的文档,不会出现我们的网址水印。
- 3、该文档所得收入(下载+内容+预览)归上传者、原创作者;如果您是本文档原作者,请点此认领!既往收益都归您。
下载文档到电脑,查找使用更方便
10000 积分 0人已下载
下载 | 加入VIP,交流精品资源 |
- 配套讲稿:
如PPT文件的首页显示word图标,表示该PPT已包含配套word讲稿。双击word图标可打开word文档。
- 特殊限制:
部分文档作品中含有的国旗、国徽等图片,仅作为作品整体效果示例展示,禁止商用。设计者仅对作品中独创性部分享有著作权。
- 关 键 词:
- ASTMD13192003E1STANDARDTESTMETHODFORHYDROCARBONTYPESINLIQUIDPETROLEUMPRODUCTSBYFLUORESCENTINDICATORADSORPTION
链接地址:http://www.mydoc123.com/p-509624.html