EN 15058-2017 en Stationary source emissions - Determination of the mass concentration of carbon monoxide - Standard reference method non-dispersive infrared spectrometry《固定源辐射-一氧化.pdf

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1、BS EN 15058:2017Stationary source emissions Determination of themass concentration ofcarbon monoxide Standard reference method:non-dispersive infraredspectrometryBSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06BS EN 15058:2017 BRITISH STANDARDNational forewordThis Br

2、itish Standard is the UK implementation of EN 15058:2017.It supersedes BS EN 15058:2006 which is withdrawn.The UK participation in its preparation was entrusted to Technical Committee EH/2/1, Stationary source emission.A list of organizations represented on this committee can be obtained on request

3、to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2017.Published by BSI Standards Limited 2017ISBN 978 0 580 85053 0 ICS 13.040.40 Compliance with a British St

4、andard cannot confer immunity from legal obligations.This British Standard was published under the authority of the Standards Policy and Strategy Committee on 31 January 2017.Amendments/corrigenda issued since publicationDate T e x t a f f e c t e dBS EN 15058:2017EUROPEAN STANDARD NORME EUROPENNE E

5、UROPISCHE NORM EN 15058 January 2017 ICS 13.040.40 Supersedes EN 15058:2006English Version Stationary source emissions - Determination of the mass concentration of carbon monoxide - Standard reference method: non-dispersive infrared spectrometry missions de sources fixes - Dtermination de la concent

6、ration massique de monoxyde de carbone - Mthode de rfrence normalise : spectromtrie infrarouge non dispersive Emissionen aus stationren Quellen - Bestimmung der Massenkonzentration von Kohlenmonoxid - Standardreferenzverfahren: Nicht-dispersive Infrarotspektrometrie This European Standard was approv

7、ed by CEN on 26 September 2016. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationa

8、l standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language

9、 and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hu

10、ngary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUN

11、G CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2017 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15058:2017 EBS EN 15058:2017EN 15058:2017 (E) 2 Contents Page European foreword . 5 1 Scope 6 2 Normative refer

12、ences 6 3 Terms and definitions . 6 4 Symbols and abbreviations 13 4.1 Symbols 13 4.2 Abbreviated terms . 14 5 Principle 14 5.1 General . 14 5.2 Measuring principle 14 6 Description of the measuring system . 15 6.1 General . 15 6.2 Sampling and sample gas conditioning system . 16 6.2.1 Sampling prob

13、e . 16 6.2.2 Filter 16 6.2.3 Sample gas line 16 6.2.4 Sample gas conditioning system . 16 6.2.5 Sample gas pump 17 6.2.6 Secondary filter . 17 6.2.7 Flow controller and flow meter 17 6.3 Analyser equipment 17 6.3.1 General . 17 6.3.2 Pressure and temperature effects . 18 6.3.3 Sampling pump for the

14、analyser . 18 6.3.4 Interferences due to infrared absorbing gases . 18 7 Performance characteristics of the SRM 18 8 Suitability of the measuring system for the measurement task . 20 9 Field operation 20 9.1 Measurement planning 20 9.2 Sampling strategy. 21 9.2.1 General . 21 9.2.2 Measurement secti

15、on and measurement plane 21 9.2.3 Minimum number and location of measurement points . 21 9.2.4 Measurement ports and working platform 21 9.3 Choice of the measuring system . 21 9.4 Setting of the measuring system on site 22 9.4.1 General . 22 9.4.2 Preliminary zero and span check, and adjustments .

16、22 9.4.3 Zero and span checks after measurement 23 BS EN 15058:2017EN 15058:2017 (E) 3 10 Ongoing quality control 23 10.1 Introduction 23 10.2 Frequency of checks 23 11 Expression of results . 24 12 Equivalence of an alternative method 25 13 Measurement report . 25 Annex A (informative) Validation o

17、f the method in the field . 26 A.1 General . 26 A.2 Characteristics of installations 26 A.3 Repeatability and reproducibility in the field 27 A.3.1 General . 27 A.3.2 Repeatability 28 A.3.3 Reproducibility 29 Annex B (informative) Schematics of non-dispersive infrared spectrometer 31 Annex C (inform

18、ative) Calculation of the uncertainty associated with a concentration expressed on dry gas and at an oxygen reference concentration . 33 C.1 Uncertainty associated with a concentration expressed on dry gas 33 C.2 Uncertainty associated with a concentration expressed at a oxygen reference concentrati

19、on . 35 Annex D (informative) Example of assessment of compliance of non-dispersive infrared method for CO with requirements on emission measurements 37 D.1 General . 37 D.2 Elements required for the uncertainty determinations . 37 D.2.1 Model equation 37 D.2.2 Combined uncertainty 38 D.2.3 Expanded

20、 uncertainty . 38 D.2.4 Determination of uncertainty contributions in case of rectangular distributions . 39 D.2.5 Determination of uncertainty contributions by use of sensitivity coefficients . 39 D.3 Example of an uncertainty calculation 40 D.3.1 Site specific conditions . 40 D.3.2 Performance cha

21、racteristics 41 D.3.3 Determination of the uncertainty contributions 42 D.3.4 Result of uncertainty calculation 45 D.3.4.1 Standard uncertainties . 45 D.3.4.2 Combined uncertainty 46 D.3.4.3 Expanded uncertainty . 46 D.3.4.4 Evaluation of the compliance with the required measurement quality . 46 Ann

22、ex E (informative) Example of correction of data from drift effect . 47 BS EN 15058:2017EN 15058:2017 (E) 4 Annex F (informative) Significant technical changes . 49 Bibliography . 50 BS EN 15058:2017EN 15058:2017 (E) 5 European foreword This document (EN 15058:2017) has been prepared by Technical Co

23、mmittee CEN/TC 264 “Air quality”, the secretariat of which is held by DIN. This document supersedes EN 15058:2006. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by July 2017, and conflicting nation

24、al standards shall be withdrawn at the latest by July 2017. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. Annex F provides details o

25、f significant technical changes between this document and the previous edition. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republi

26、c, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.

27、 BS EN 15058:2017EN 15058:2017 (E) 6 1 Scope This European Standard specifies the standard reference method (SRM) based on the infrared (IR) absorption principle. It includes the sampling and the gas conditioning system, and allows the determination of the carbon monoxide CO in flue gases emitted to

28、 the atmosphere from ducts and stacks. This European Standard specifies the characteristics to be determined and the performance criteria to be fulfilled by portable automated measuring systems (P-AMS) using the IR measurement method. It applies for periodic monitoring and for the calibration or con

29、trol of automated measuring systems (AMS) permanently installed on a stack, for regulatory or other purposes. This European Standard specifies criteria for demonstration of equivalence of an alternative method (AM) to the SRM by application of EN 14793:2017. This European Standard has been validated

30、 during field tests on waste incineration, co-incineration and large combustion plants and on a recognized test bench. It has been validated for CO concentrations with sampling periods of 30 min in the range of 0 mg/m3to 400 mg/m3for large combustion plants and 0 mg/m3to 740 mg/m3for waste and co-in

31、cineration. Directive 2010/75/EU lays down emission values which are expressed in mg/m3, on dry basis at a specified value of oxygen and at standard conditions (273 K and 101,3 kPa). NOTE The characteristics of installations, the conditions during field tests and the values of repeatability and repr

32、oducibility in the field are given in Annex A. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition

33、of the referenced document (including any amendments) applies. EN 14793:2017, Stationary source emission Demonstration of equivalence of an alternative method with a reference method EN 15259:2007, Air quality - Measurement of stationary source emissions - Requirements for measurement sections and s

34、ites and for the measurement objective, plan and report EN 15267-4:2017, Air quality Certification of automated measuring systems Part 4: Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources EN ISO 14956:2002, Air qua

35、lity - Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty (ISO 14956:2002) ISO/IEC Guide 98-3:2008, Uncertainty of measurement Part 3: Guide to the expression of uncertainty in measurement (GUM:1995) 3 Terms and definitions For the purposes

36、 of this document, the following terms and definitions apply. 3.1 standard reference method SRM reference method prescribed by European or national legislation SOURCE: EN 15259:2007 BS EN 15058:2017EN 15058:2017 (E) 7 3.2 reference method RM measurement method taken as a reference by convention, whi

37、ch gives the accepted reference value of the measurand Note 1 to entry: A reference method is fully described. Note 2 to entry: A reference method can be a manual or an automated method. Note 3 to entry: Alternative methods can be used if equivalence to the reference method has been demonstrated. SO

38、URCE: EN 15259:2007 3.3 measurement method method described in a written procedure containing all the means and procedures required to sample and analyse, namely field of application, principle and/or reactions, definitions, equipment, procedures, presentation of results, other requirements and meas

39、urement report SOURCE: EN 14793:2017 3.4 alternative method AM measurement method which complies with the criteria given by this European Standard with respect to the reference method Note 1 to entry: An alternative method can consist of a simplification of the reference method. SOURCE: EN 14793:201

40、6 3.5 measuring system set of one or more measuring instruments and often other devices, including any reagent and supply, assembled and adapted to give information used to generate measured quantity values within specified intervals for quantities of specified kinds SOURCE: JCGM 200:2012 3.6 automa

41、ted measuring system AMS entirety of all measuring instruments and additional devices for obtaining a result of measurement Note 1 to entry: Apart from the actual measuring device (the analyser), an AMS includes facilities for taking samples (e.g. probe, sample gas lines, flow meters and regulator,

42、delivery pump) and for sample conditioning (e.g. dust filter, pre-separator for interferents, cooler, converter). This definition also includes testing and adjusting devices that are required for functional checks and, if applicable, for commissioning. Note 2 to entry: The term “automated measuring

43、system” (AMS) is typically used in Europe. The term “continuous emission monitoring system” (CEMS) is also typically used in the UK and USA. SOURCE: EN 15267-4:2017 BS EN 15058:2017EN 15058:2017 (E) 8 3.7 portable automated measuring system P-AMS automated measuring system which is in a condition or

44、 application to be moved from one to another measurement site to obtain measurement results for a short measurement period Note 1 to entry: The measurement period is typically 8 h for a day. Note 2 to entry: The P-AMS can be configured at the measurement site for the special application but can be a

45、lso set-up in a van or mobile container. The probe and the sample gas lines are installed often just before the measurement task is started. SOURCE: EN 15267-4:2017 3.8 calibration set of operations that establish, under specified conditions, the relationship between values of quantities indicated b

46、y a measuring method or measuring system, and the corresponding values given by the applicable reference Note 1 to entry: In case of automated measuring system (AMS) permanently installed on a stack the applicable reference is the standard reference method (SRM) used to establish the calibration fun

47、ction of the AMS. Note 2 to entry: Calibration should not be confused with adjustment of a measuring system. 3.9 adjustment set of operations carried out on a measuring system so that it provides prescribed indications corresponding to given values of a quantity to be measured Note 1 to entry: The a

48、djustment can be made directly on the instrument or using a suitable calculation procedure. 3.10 span gas test gas used to adjust and check a specific point on the response line of the measuring system 3.11 measurand particular quantity subject to measurement SOURCE: EN 15259:2007 Note 1 to entry: T

49、he measurand is a quantifiable property of the stack gas under test, for example mass concentration of a measured component, temperature, velocity, mass flow, oxygen content and water vapour content. 3.12 interference negative or positive effect upon the response of the measuring system, due to a component of the sample that is not the measurand BS EN 15058:2017EN 15058:2017 (E) 9 3.13 influence quantity quantity that is not the measurand but that affects the result of the measurement Note 1 to entry: Influence quantities are e.g. presence of inte