EN 15058-2006 0677 Stationary source emissions Determination of the mass concentration of carbon monoxide (CO) Reference method Non-dispersive infrared spectrometry《固定污染源排放 的质量浓度一氧.pdf

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1、BRITISH STANDARDBS EN 15058:2006Stationary source emissions Determination of the mass concentration of carbon monoxide (CO) Reference method: Non-dispersive infrared spectrometryThe European Standard EN 15058:2006 has the status of a British StandardICS 13.040.40g49g50g3g38g50g51g60g44g49g42g3g58g44

2、g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58Licensed Copy: Wang Bin, na, Mon Aug 07 08:13:11 BST 2006, Uncontrolled Copy, (c) BSIBS EN 15058:2006This British Standard was published

3、under the authority of the Standards Policy and Strategy Committee on 30 June 2006 BSI 2006ISBN 0 580 48620 6National forewordThis British Standard is the official English language version of EN 15058:2006. The UK participation in its preparation was entrusted by Technical Committee EH/2, Air qualit

4、y, to Subcommitee EH/2/1, Stationary source emissions, which has the responsibility to:A list of organizations represented on this subcommittee can be obtained on request to its secretary.Cross-referencesThe British Standards which implement international or European publications referred to in this

5、 document may be found in the BSI Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Search” facility of the BSI Electronic Catalogue or of British Standards Online.This publication does not purport to include all the necessary provisions of a contr

6、act. Users are responsible for its correct application.Compliance with a British Standard does not of itself confer immunity from legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for

7、 change, and keep UK interests informed; monitor related international and European developments and promulgate them in the UK.Summary of pagesThis document comprises a front cover, an inside front cover, the EN title page, pages 2 to 41 and a back cover.The BSI copyright notice displayed in this do

8、cument indicates when the document was last issued.Amendments issued since publicationAmd. No. Date CommentsLicensed Copy: Wang Bin, na, Mon Aug 07 08:13:11 BST 2006, Uncontrolled Copy, (c) BSIEUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN 15058May 2006ICS 13.040.40English VersionStationary sourc

9、e emissions Determination of the massconcentration of carbon monoxide (CO) Reference method:Non-dispersive infrared spectrometryEmissions de sources fixes Dtermination de laconcentration massique en monoxyde de carbone (CO) Mthode de rfrence : spectromtrie infrarouge nondispersiveEmissionen aus stat

10、ionren Quellen Bestimmung derMassenkonzentration von Kohlenmonoxid (CO) Referenzverfahren: Nicht-dispersive InfrarotspektrometrieThis European Standard was approved by CEN on 20 April 2006.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for gi

11、ving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the Central Secretariat or to any CEN member.This European Standard exists in three official versio

12、ns (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Cypru

13、s, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT E

14、UROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2006 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 15058:2006: ELicensed Copy: Wang Bin, na, Mon Aug 07 08:13:11 BST 2006,

15、Uncontrolled Copy, (c) BSIEN 15058:2006 (E) 2 Contents Page Foreword3 1 Scope 4 2 Normative references 4 3 Terms and definitions .4 4 Principle9 4.1 General9 4.2 Measuring principle.9 5 Sampling system 10 5.1 General. 10 5.2 Sampling system 10 6 Analyser equipment . 12 6.1 General. 12 6.2 Pressure a

16、nd temperature effects. 12 6.3 Sampling pump for the analyser. 12 6.4 Interferences due to infrared absorbing gases . 12 7 Determination of the characteristics of the method: analyser, sampling and conditioning line 13 7.1 General. 13 7.2 Relevant performance characteristics of the method and perfor

17、mance criteria . 13 7.3 Establishment of the uncertainty budget.14 8 Field operation 15 8.1 Sampling location. 15 8.2 Sampling point 15 8.3 Choice of the measuring system 16 8.4 Setting of the analyser on site. 16 9 Ongoing quality control . 17 9.1 Introduction. 17 9.2 Frequency of checks 17 10 Expr

18、ession of results . 18 11 Evaluation of the method in the field 19 12 Equivalency with an alternative method 19 13 Test report . 20 Annex A (informative) Schematics of non-dispersive infrared spectrometer 21 Annex B (informative) Example of assessment of compliance of non-dispersive infrared method

19、for CO with requirements on emission measurements 23 Annex C (informative) Evaluation of the method in the field. 35 Annex D (informative) Procedure of correction of data from drift effect 39 Annex E (informative) Relationship with EU Directives . 40 Bibliography. 41 Licensed Copy: Wang Bin, na, Mon

20、 Aug 07 08:13:11 BST 2006, Uncontrolled Copy, (c) BSIEN 15058:2006 (E) 3 Foreword This document (EN 15058:2006) has been prepared by Technical Committee CEN/TC 264 “Air quality”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either

21、by publication of an identical text or by endorsement, at the latest by November 2006, and conflicting national standards shall be withdrawn at the latest by November 2006. This document has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association

22、, and supports essential requirements of EU Directive(s). According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Ger

23、many, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Licensed Copy: Wang Bin, na, Mon Aug 07 08:13:11 BST 2006, Uncontrolled Copy, (c) BSIEN 15058:2006

24、(E) 4 1 Scope This European Standard specifies the Standard Reference Method (SRM) for sampling, and determining car-bon monoxide content in ducts and stacks emitting to atmosphere. It describes the Non Dispersive Infra-Red (NDIR) analytical technique, including the sampling system and sample gas co

25、nditioning system, to determine CO in flue gases. This European Standard is the reference method for periodic monitoring and for calibration or control of Automatic Measuring Systems (AMS) permanently installed on a stack, for regulatory purposes or other purposes. To be used as the SRM, it is neces

26、sary to demonstrate that the performance characteristics of the method are lower than the performance criteria defined in this European standard and that the overall uncertainty of the method is less than 6 % relative at the daily Emission Limit Value (ELV). NOTE When the NDIR method is used as an A

27、MS, refer to EN 14181 and other relevant standards provided by CEN TC 264. It is necessary for anybody who would like to use an Alternative Method instead of this Standard Reference Method to work out the demonstration of the equivalence according to the Technical Specification TS 14793, providing t

28、hat his capability to carry out this demonstration is officially recognised by his national accreditation body or law. This Standard Reference Method has been evaluated during field tests on waste incineration, co-incineration installations and large combustion plants. It has been validated for CO c

29、oncentrations with sampling periods of 30 min in the range of 0 mg/m3to 400 mg/m3for large combustion plants and 0 mg/m3 740 mg/m3for waste and co-incineration. For waste incineration plants, Council Directive 2000/76/EC lays down emission values which are expressed in mg/m3, on dry basis at a speci

30、fied value of O2and at reference conditions of 273 K and 101,3 kPa. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated refer-ences, only the edition cited applies. For undated references, the latest edition of the referenced do

31、cument (including any amendments) applies. ENV 13005, Guide to the expression of uncertainty in measurement. CEN/TS 14793: Stationary source emission - Intralaboratory validation procedure for an alternative method compared to a reference method. EN ISO 14956, Air Quality Evaluation of the suitabili

32、ty of a measurement procedure by comparison with a required measurement uncertainty (ISO 14956:2002). ISO 5725-2, Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method. ISO

33、 5725-6:1994, Accuracy (trueness and precision) of measurement methods and results - Part 6: Use in practice of accuracy values. VIM 1994, International vocabulary of basic and general terms in metrology. 3 Terms and definitions For the purposes of this document the following terms and definitions a

34、pply. Licensed Copy: Wang Bin, na, Mon Aug 07 08:13:11 BST 2006, Uncontrolled Copy, (c) BSIEN 15058:2006 (E) 5 3.1 adjustment (of a measuring system) operation of bringing a measuring system into a state of performance suitable for its use VIM 4.30 3.2 ambient temperature temperature of the air arou

35、nd the measuring system 3.3 automatic measuring system (AMS) measuring system permanently installed on site for continuous monitoring of emissions NOTE 1 An AMS is a method which is traceable to a reference method. NOTE 2 Apart from the analyser, an AMS includes facilities for taking samples (e.g. p

36、robe, sample gas lines, flow me-ters, regulators, delivery pumps) and for sample conditioning (e.g.dust filter, moisture removal devices, converters, dilut-ers). This definition also includes testing and adjusting devices that are required for regular functional checks. 3.4 calibration statistical r

37、elationship between values of the measurand indicated by the measuring system (AMS) and the corresponding values given by the standard reference method (SRM) used during the same period of time and giving a representative measurement on the same sampling plane NOTE The result of calibration permits

38、to establish the relationship between the values of the SRM and the AMS (calibration function). 3.5 drift difference between two zero (zero drift) or span readings (span drift) at the beginning and at the end of a measuring period 3.6 emission limit value (ELV) emission limit value according to EU D

39、irectives on the basis of 30 min, 1 hour or 1 day 3.7 influence quantity quantity that is not the measurand but that affects the result of the measurement adapted VIM 2.7 EXAMPLES ambient temperature; atmospheric pressure; presence of interfering gases in the flue gas matrix; pressure of the gas sam

40、ple. Licensed Copy: Wang Bin, na, Mon Aug 07 08:13:11 BST 2006, Uncontrolled Copy, (c) BSIEN 15058:2006 (E) 6 3.8 interference negative or positive effect upon the response of the measuring system, due to a component of the sample that is not the measurand 3.9 lack of fit systematic deviation within

41、 the range of application between the measurement result obtained by applying the calibration function to the observed response of the measuring system measuring test gases and the corre-sponding accepted value of such test gases NOTE 1 Lack of fit may be a function of the measurement result. NOTE 2

42、 The expression “lack of fit” is often replaced in everyday language by “linearity” or “deviation from linearity”. 3.10 measurand particular quantity subject to measurement VIM 2.6 3.11 measuring system complete set of measuring instruments and other equipment assembled to carry out specified measur

43、ements VIM 4.5 3.12 performance characteristic one of the quantities (described by values, tolerances, range) assigned to equipment in order to define its performance 3.13 repeatability in the laboratory closeness of the agreement between the results of successive measurements of the same measurand

44、carried out under the same conditions of measurement NOTE 1 Repeatability conditions include: same measurement procedure; same laboratory; same measuring system, used under the same conditions; same location; repetition over a short period of time. NOTE 2 Repeatability may be expressed quantitativel

45、y in terms of the dispersion characteristics of the results. In this European Standard the repeatability is expressed as a value with a level of confidence of 95 %. VIM 3.6 3.14 repeatability in the field closeness of the agreement between the results of simultaneous measurements of the same measura

46、nd car-ried out with two sets of equipment under the same conditions of measurement Licensed Copy: Wang Bin, na, Mon Aug 07 08:13:11 BST 2006, Uncontrolled Copy, (c) BSIEN 15058:2006 (E) 7 NOTE 1 These conditions include: same measurement procedure; two sets of equipment, the performance of which fu

47、lfils the requirements of the reference method, used under the same conditions; same location; implemented by the same laboratory; typically calculated on short periods of time in order to avoid the effect of changes of influence parameters (e.g. 30 min). NOTE 2 Repeatability may be expressed quanti

48、tatively in terms of the dispersion characteristics of the results. In this European Standard the repeatability under field conditions is expressed as a value with a level of confi-dence of 95 %. 3.15 reproducibility in the field closeness of the agreement between the results of simultaneous measure

49、ments of the same measurand car-ried out using several sets of equipment under the same conditions of measurement NOTE 1 These conditions are called field reproducibility conditions and include: same measurement procedure; several sets of equipment, the performance of which fulfils the requirements of the reference method, used under the same conditions; same location; implemented by several laboratories. NOTE 2 Reproducibility may be expressed quantitatively in terms of the dispersion characteristics of the