EN 4106-2013 en Aerospace series - Non-metallic materials - Structural adhesive systems - Paste adhesive - Technical specification《航空航天系列 非金属材料 结构胶系统 粘贴胶 技术规格》.pdf

《EN 4106-2013 en Aerospace series - Non-metallic materials - Structural adhesive systems - Paste adhesive - Technical specification《航空航天系列 非金属材料 结构胶系统 粘贴胶 技术规格》.pdf》由会员分享，可在线阅读，更多相关《EN 4106-2013 en Aerospace series - Non-metallic materials - Structural adhesive systems - Paste adhesive - Technical specification《航空航天系列 非金属材料 结构胶系统 粘贴胶 技术规格》.pdf（22页珍藏版）》请在麦多课文档分享上搜索。

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 4106:2013Aerospace series Non-metallic materials Structuraladhesive systems Pasteadhesive TechnicalspecificationBS EN 4106:2013 BRITISH STANDARDNational forewordThis Britis

2、h Standard is the UK implementation of EN 4106:2013.The UK participation in its preparation was entrusted to TechnicalCommittee ACE/65, Non-metallic materials for aerospace purposes.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does

3、 not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2013. Published by BSI StandardsLimited 2013ISBN 978 0 580 80247 8ICS 49.025.50Compliance with a British Standard cannot confer immunity fromlegal ob

4、ligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 31 January 2013.Amendments issued since publicationDate Text affectedBS EN 4106:2013EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 4106 January 2013 ICS 49.025.50 English Version

5、Aerospace series - Non-metallic materials - Structural adhesive systems - Paste adhesive - Technical specification Srie arospatiale - Matriaux non-mtalliques - Systmes dadhsifs structuraux - Adhsif en pte - Spcification technique Luft- und Raumfahrt - Nichtmetallische Werkstoffe - Strukturelle Klebs

6、toffsysteme - Klebstoffpasten - Technische Lieferbedingungen This European Standard was approved by CEN on 10 November 2012. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard wi

7、thout any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any othe

8、r language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic,

9、Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMI

10、TTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2013 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 4106:2013: EBS EN 4106:2013EN 4106:201

11、3 (E) 2 Contents Page Foreword 3 Introduction .4 1 Scope 5 2 Normative references 5 3 Terms, definitions, symbols and abbreviations .6 4 Requirements .7 5 Qualification 10 6 Release testing 11 7 Preparation for delivery . 14 8 Declaration of conformity 15 BS EN 4106:2013EN 4106:2013 (E) 3 Foreword T

12、his document (EN 4106:2013) has been prepared by the Aerospace and Defence Industries Association of Europe - Standardization (ASD-STAN). After enquiries and votes carried out in accordance with the rules of this Association, this Standard has received the approval of the National Associations and t

13、he Official Services of the member countries of ASD, prior to its presentation to CEN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by July 2013, and conflicting national standards shall be withdr

14、awn at the latest by July 2013. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN/CENELEC Internal Regulations, the

15、 national standards organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia

16、, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 4106:2013EN 4106:2013 (E) 4 Introduction This standard is part of the series of EN non-metallic materials standards for aerospace appli

17、cations. The general organisation of this series is described in EN 4385. This document is a level 3 document as defined in EN 4385. It has been prepared in accordance with EN 4387. BS EN 4106:2013EN 4106:2013 (E) 5 1 Scope This European Standard defines the requirements for manufacture, qualificati

18、on, inspection and testing of products in structural adhesive systems where the adhesive is supplied in the form of a paste, either a one-part or two-part system, for aerospace applications. The adhesive may be used in conjunction with a primer whose requirements are also included in this European S

19、tandard. It is applicable whenever referenced on a material standard. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated referenc

20、es, the latest edition of the referenced document (including any amendments) applies. EN 542, Adhesives Determination of density EN 924, Adhesives Solvent-borne and solvent-free adhesives Determination of flashpoint EN 2243-1, Aerospace series Non-metallic materials Structural adhesives Test methods

21、 Part 1: Single lap shear EN 2243-2, Aerospace series Non-metallic materials Structural adhesives Test method Part 2: Peel metal-metal EN 2243-6, Aerospace series Non-metallic materials Structural adhesives Test method Part 6: Determination of shear stress and shear strain EN 2379, Aerospace series

22、Fluids for assessment of non-metallic materials 1)EN 2757, Aerospace series Structural adhesives system Test method Determination of the drying and ignition residues of primers EN 2781, Aerospace series Non-metallic materials Structural adhesives Test methods Determination of the primer thickness EN

23、 4385, Aerospace series Non-metallic materials General organisation of standardisation Links between types of standards 1)EN 4387, Aerospace series Non-metallic materials Rules for drafting and presentation of technical specifications 1)EN 6040, Aerospace series Non-metallic materials Test method An

24、alysis of thermoset systems by High Performance Liquid Chromatography (HPLC) 1)EN 6041, Aerospace series Non-metallic materials Test method Analysis of non-metallic materials (uncured) by Differential Scanning Calorimetry (DSC) 1)EN 6042, Aerospace series Organic compounds Test method Analysis by in

25、frared spectroscopy 1)EN 6064, Aerospace series Non-metallic materials Analysis of non-metallic materials (cured) for the determination of the extent of cure by Differential Scanning Calorimetry (DSC) 1)1) Published as ASD-STAN Prestandard at the date of publication of this standard (www.asd-stan.or

26、g). BS EN 4106:2013EN 4106:2013 (E) 6 EN 9100, Quality Management Systems Requirements for Aviation, Space and Defence Organizations EN 9133, Aerospace series Quality management systems Qualification procedure for aerospace standard parts EN 12092, Adhesives Determination of viscosity ISO Guide 22,

27、General criteria for suppliers declaration of conformity ISO 3768:1976, Metallic coatings Neutral salt spray test (NSS test) ESA PSS-01-702, A thermal vacuum test for the screening of space materials TR 7000-6, Aerospace series Non-metallic materials Rules for the drafting and presentation of materi

28、al standards Part 6: Structural adhesive systems 2)3 Terms, definitions, symbols and abbreviations For the purposes of this document, the terms, definitions, symbols and abbreviations given in EN 9100, EN 9133, TR 7000-6 and the following, apply. 3.1 batch quantity of adhesive material which is homo

29、genous and has been manufactured from a single mix of each of its individual ingredients in one continuous production run 3.2 product in this document the word product refers to all forms of paste adhesive, either a single component or comprised of two parts 3.3 adhesive system combination of a past

30、e adhesive and primer 3.4 adhesive material any paste or primer of which an adhesive system may be composed 3.5 filler inorganic material incorporated in an adhesive to improve its cure rheology and service performance 3.6 corrosion inhibitor substance added to the primer to improve its corrosion in

31、hibiting characteristics 2) Published as ASD-STAN Technical Report at the date of publication of this standard (www.asd-stan.org). BS EN 4106:2013EN 4106:2013 (E) 7 3.7 primer material used to coat the substrates prior to the application of adhesive to improve either the durability of the joint or a

32、dhesion characteristics and/or to protect a pre-treated metal surface prior to bonding, so allowing an increased period of handling Note 1 to entry: Standard adhesive primers for adhesive systems consist of solvents and polymers. Note 2 to entry: Corrosion inhibiting adhesive primers for adhesive sy

33、stems consist of solvents, polymers and solid inhibitors. The solid inhibitors reduce corrosion of the substrate. 3.8 shelf life period of time during which the adhesive material when stored in accordance with the specified conditions shall meet the specified property requirements 3.9 shop life maxi

34、mum cumulative period of time during which the adhesive material can be held out of refrigerated storage before commencement of cure 3.10 pot life period of time at room temperature during which a two part paste adhesive and/or a primer may be used, after mixing 3.11 lot consignment of adhesive mate

35、rial which is either whole or part of a batch 3.12 T min. minimum service temperature of the material 3.13 T max. maximum service temperature of the material 3.14 Tg glass transition temperature of the material 4 Requirements 4.1 General requirements 4.1.1 Manufacturing schedule for paste adhesive T

36、he product shall be manufactured to fulfil the requirements of the relevant material standard and this technical specification in accordance with EN 9133. The manufacturer shall define the raw material, processes and inspection requirements in a manufacturing schedule. Once approved any modification

37、s to the manufacturing schedule shall be in accordance with EN 9133. 4.1.2 Traceability All products shall be traceable to the raw material batches at all stages of manufacture and delivery. Similarly, each raw material batch shall be traceable to all products at all stages of manufacture and delive

38、ry. BS EN 4106:2013EN 4106:2013 (E) 8 4.1.3 Freedom from defects All products shall be free from defects not complying with the requirements of the material standard or order and this technical specification, or which may be prejudicial to the subsequent manufacture and/or use of the products. Each

39、primer component shall: a) be uniform in colour; b) be free from deleterious contamination, foreign matter or other defects; c) mix readily to a homogenous solution or suspension of consistency suitable for application; d) be free from lumps; e) not settle out or separate during a normal working day

40、 or the pot life, whichever is the shorter. The adhesive shall: 1) be uniform in colour; 2) be free from deleterious contamination, foreign matter or other defects; 3) be free from lumps. In the case of two part adhesives it shall also: i) mix readily to a homogenous solution or suspension of consis

41、tency suitable for application; ii) not settle out or separate during a normal working day or the pot life, whichever is the shorter. 4.1.4 Health and safety It is the responsibility of the supplier to establish satisfactory health and safety information to ensure conformity with any European, Natio

42、nal or local laws/regulations. The safety data sheet shall be available and shall be provided prior to qualification testing. 4.1.5 Dimensions Not applicable. 4.2 Technical requirements 4.2.1 General The product shall satisfy the requirements of the relevant material standard and/or the order. 4.2.2

43、 Required testing Unless otherwise specified in the material standard, the test method and the test frequency for screening, qualification testing and release testing are given in Table 3 to Table 7. The manufacturer, having regard for the provisions of EN 9133, shall implement a test programme unde

44、r the supervision of the mandated body, on a minimum of three production batches of both the primer and the adhesive. BS EN 4106:2013EN 4106:2013 (E) 9 For the purposes of qualification a fixed combination of primer and adhesive, as defined in the material standard, shall be used throughout. Each pa

45、ir of adhesive and primer involves a separate qualification programme. Alloys, surface preparation, test panel manufacturing, machining and conditioning before testing of test pieces shall conform to the requirements of the Material Standard. 4.2.3 Test samples Samples and associated test pieces sha

46、ll be marked in such manner that their identity with respect to the product and the batch is maintained. Samples taken from fully finished products (condition of use) shall not be further processed. Samples representing products in a condition other than the condition of use shall be processed in ac

47、cordance with the material standard before testing. 4.2.4 Shelf life The adhesive system shall maintain all of its physical, chemical and mechanical properties within the specification requirements for the period of time (shelf life) specified in the material standard, when stored under the specifie

48、d conditions. Shelf life shall start from the date of manufacture. 4.2.5 Shoplife The product shall meet the physical, chemical and mechanical properties of the material standard for a period of time known as the shoplife during storage under normal shop conditions. These requirements will be met at

49、 all stages of the shelf life. 4.2.6 Requirements specific to paste adhesive systems 4.2.6.1 Colour The colour of the primer and adhesive shall be established between the manufacturer and the mandated body at the time of qualification. 4.2.6.2 Composition There shall be no restriction on the chemical type or composition of the material except as limited by the material standard. 4.2.6.3 Curing The adhesive and/or primer shall cure satisfactorily at the temperature, press