ASTM A385 A385M-2017 Standard Practice for Providing High-Quality Zinc Coatings (Hot-Dip)《提供高质量锌涂层(热浸)的标准实施规程》.pdf
《ASTM A385 A385M-2017 Standard Practice for Providing High-Quality Zinc Coatings (Hot-Dip)《提供高质量锌涂层(热浸)的标准实施规程》.pdf》由会员分享,可在线阅读,更多相关《ASTM A385 A385M-2017 Standard Practice for Providing High-Quality Zinc Coatings (Hot-Dip)《提供高质量锌涂层(热浸)的标准实施规程》.pdf(11页珍藏版)》请在麦多课文档分享上搜索。
1、Designation: A385/A385M 15A385/A385M 17Standard Practice forProviding High-Quality Zinc Coatings (Hot-Dip)1This standard is issued under the fixed designation A385/A385M; the number immediately following the designation indicates the yearof original adoption or, in the case of revision, the year of
2、last revision. A number in parentheses indicates the year of last reapproval.A superscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope Scope*1.1 This practice covers the precautions that should be taken to obtain high-quality hot-dip galvanized coatings.1.
3、2 Where experience on a specific product indicates a relaxing of any provision, the mutually acceptable change shall be amatter for agreement between the manufacturer and purchaser.1.3 This specification is applicable to orders in either inch-pound units (as A385) or in SI units (as A385M). Inch-pou
4、nd unitsand SI units are not necessarily exact equivalents. Within the text of this specification and where appropriate, SI units are shownin brackets. Each system shall be used independently of the other without combining values in any way.1.4 This international standard was developed in accordance
5、 with internationally recognized principles on standardizationestablished in the Decision on Principles for the Development of International Standards, Guides and Recommendations issuedby the World Trade Organization Technical Barriers to Trade (TBT) Committee.2. Referenced Documents2.1 ASTM Standar
6、ds:2A123/A123M Specification for Zinc (Hot-Dip Galvanized) Coatings on Iron and Steel ProductsA143/A143M Practice for Safeguarding Against Embrittlement of Hot-Dip Galvanized Structural Steel Products and Procedurefor Detecting EmbrittlementA153/A153M Specification for Zinc Coating (Hot-Dip) on Iron
7、 and Steel HardwareA384/A384M Practice for Safeguarding Against Warpage and Distortion During Hot-Dip Galvanizing of Steel AssembliesA563 Specification for Carbon and Alloy Steel Nuts2.2 American Institute of Steel Construction (AISC) Documents:3Steel Construction Manual3. Steel Selection3.1 The pro
8、duction of a galvanized coating has as its basis the metallurgical reaction between the steel and the molten zinc,resulting in the formation of several iron-zinc compound layers, for example, gamma (not always visible microscopically), delta,and zeta in Fig. 1. In addition, a layer of the molten zin
9、c adheres to the surface of the compound layers as the steel is withdrawnfrom the galvanizing bath. Upon solidification, this adherent zinc forms the eta layer.3.2 It is known that the exact structural nature of the galvanized coating, as typified by Fig. 1, may be modified in accordancewith the exa
10、ct chemical nature of the steel being galvanized. Certain elements found in steels are known to have an influence onthe coating structure. The elements carbon in excess of about 0.25 %, phosphorus in excess of 0.04 %, or manganese in excess ofabout 1.3 % will cause the production of coatings differe
11、nt from the coating typified by Fig. 1. Steels with silicon in the range0.04 % to 0.15 % or above 0.22 % can produce galvanized coating growth rates much higher than those The element with the mostsignificant effect on the galvanized coating is silicon. This element has two composition regions that
12、can produce thick and dullcoatings. The first region is silicon concentration between 0.06 % and 0.13 % and is known as the Sandelin region. The secondregion is silicon concentration above 0.25 %. When producing or purchasing steels to be hot-dip galvanized, a good practice isto aim for steels with
13、silicon levels below 0.04 % and between 0.15 % and 0.22 %. a silicon concentration target of 0.15 % to 0.22% and a minimum of 0.13 % and a maximum of 0.25 % to avoid both the Sandelin region and the high silicon region. Recentstudies have shown that even in cases where the silicon and phosphorous ar
14、e individually held to desirable limits, a combined effectbetween them can produce a coating as shown in Fig. 2, which typically would have a mottled or dull gray appearance. The valuesof silicon in the mill test reports of steel can give an indication of the reactivity of the steel in the hot-dip g
15、alvanizing process butare not a guarantee. The best practice is to galvanize test pieces to get a better indication of the reactivity of the steel.3.3 These elements manifest their structural effect as an accelerated growth of the compound layers, particularly the zeta layer,and the virtual eliminat
16、ion of the eta layer. Cosmetically this accelerated growth is seen as a gray matte finished coating as opposedto the usual bright and smooth appearance of galvanized coatings. Sometimes, a large surface may have adjacent areas of mattefinish and bright finish leading to a mottled appearance.3.4 Ther
17、e is some evidence that the coatings resulting from this accelerated growth are more brittle and less adherent thannormal coatings. There is also evidence that these coatings are subject to a premature red staining in atmospheric exposure;however, this staining has been found not to be associated wi
18、th corrosion of the substrate steel.3.5 A problem with steel chemistry is not usually apparent until after an item has been galvanized. Not all combinations ofsilicon, phosphorus, carbon, and manganese can be galvanized successfully. When the steel chemistry is known beforehand,experienced galvanize
19、rs can in some, but not all, instances exercise limited control over the coatings as shown in Fig. 2. Also, thecombination of two different steel types or thicknesses in one item may result in a nonuniform galvanizing finish. The experienceof the steel supplier, designer, manufacturer, and galvanize
20、r should determine the steel selection.3.6 In general, galvanized coatings are specified because of their corrosion resistance, not because of their appearance. Therelative corrosion resistance of the normal and abnormal coatings is, for all practical purposes, equal.FIG. 1 Photomicrograph of Normal
21、 Galvanized Coating (X 400)FIG. 2 Photomicrograph of Dull Gray, Thick-Galvanized Coating (X 200)A385/A385M 1723.7 Steels with very low levels of silicon (less than 0.02%) and aluminum-killed steels regularly present a challenge indeveloping a galvanized coating that meets the thickness requirements
22、of Specifications A123/A123M or A153/A153M.Phosphorus (less than 0.020%) can also exhibit low coating thicknesses. For these steels, it may be difficult to meet the coatingthickness requirements of Specifications A123/A123M or A153/A153M. In these cases the galvanizer and the purchaser shouldagree o
23、n a plan of action. Some choices are to accept the lower coating thickness, apply a paint coating over the galvanized coating(Duplex System), blast clean the steel before hot-dip galvanizing to increase the coating thickness, over-pickle the steel in sulfuricacid to roughen the surface and increase
24、the coating thickness, or other possible solutions.4. Assemblies of Different Materials or Different Surfaces or Both4.1 Whenever possible, assemblies should consist of elements of similar steel chemistry and surface condition.4.2 Whenever different analyses of steel or different surfaces of steel a
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