BS PD CEN TS 13388-2015 Copper and copper alloys Compendium of compositions and products《铜和铜合金 组分和产品一览表》.pdf

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1、BSI Standards Publication Copper and copper alloys Compendium of compositions and products PD CEN/TS 13388:2015National foreword This Published Document is the UK implementation of CEN/TS 13388:2015. It supersedes PD CEN/TS 13388:2013 which is withdrawn. The UK participation in its preparation was e

2、ntrusted to Technical Committee NFE/34, Copper and copper alloys. A list of organizations represented on this committee can be obtained on request to its secretary. This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct applicat

3、ion. The British Standards Institution 2015. Published by BSI Standards Limited 2015 ISBN 978 0 580 87727 8 ICS 77.120.30; 77.150.30 Compliance with a British Standard cannot confer immunity from legal obligations. This Published Document was published under the authority of the Standards Policy and

4、 Strategy Committee on 31 May 2015. Amendments/corrigenda issued since publication Date Text affected PUBLISHED DOCUMENT PD CEN/TS 13388:2015 TECHNICAL SPECIFICATION SPCIFICATION TECHNIQUE TECHNISCHE SPEZIFIKATION CEN/TS 13388 May 2015 ICS 77.120.30; 77.150.30 Supersedes CEN/TS 13388:2013 English Ve

5、rsion Copper and copper alloys - Compendium of compositions and products Cuivre et alliages de cuivre - Inventaire des compositions et des produits Kupfer und Kupferlegierungen - bersicht ber Zusammensetzungen und Produkte This Technical Specification (CEN/TS) was approved by CEN on 21 March 2015 fo

6、r provisional application. The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard. CEN members are required to

7、announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS) until the final decision about the possible conversion

8、of the CEN/TS into an EN is reached. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembour

9、g, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2

10、015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TS 13388:2015 E PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 3 Table 12.3 Ingots and castings Copper-tin alloys Composition and casting processes 41 Table 12.4 Ingots and castings C

11、opper-tin-lead alloys Composition and casting processes ) . 42 Table 12.5 Ingots and castings Copper-aluminium alloys Composition and casting processes 44 Table 12.6 Ingots and castings Copper-manganese-aluminium alloys Composition and casting processes . 45 Table 12.7 Ingots and castings Copper-nic

12、kel alloys Composition and casting processes 45 Table 13 Scrap Composition 46 Table 14 Composition of copper alloy according to EN 50149:2012 50 PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 4 Foreword This document (CEN/TS 13388:2015) has been prepared by Technical Committee CEN/TC 133 “Copper and copp

13、er alloys”, the secretariat of which is held by DIN. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes CEN/TS 1

14、3388:2013. In comparison with CEN/TS 13388:2013, the following changes were made: a) modifications regarding materials and compositions from EN 12420:2014, EN 13600:2013, EN 13601:2013 and EN 13602:2013 considered; b) last paragraph of the “Scope” deleted; c) 3.5 “Composition of filler metals” delet

15、ed; d) 4.4 “Filler metals” deleted; e) Clause 5 “Copper and copper alloys standardised by other CEN Technical Committees” deleted; f) Clause 6 “Copper and copper alloys registered by CEN/TC 133” deleted. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the f

16、ollowing countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Nethe

17、rlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 5 Introduction CEN/TC 133 “Copper and copper alloys” was established in 1988 to prepare and maintain standards in the field of unwrought

18、, wrought and cast products made from copper and copper alloys. Its responsibilities included developing, defining, specifying and giving guidance on, as appropriate, material compositions, designations, terminology, dimensions and tolerances, mechanical and physical characteristics, conditions of d

19、elivery and methods of testing peculiar to copper and copper alloys. During the development of standards for copper and copper alloy products, the experts realized the necessity and seized the opportunity: a) to coordinate and in some cases also to rationalize the composition limits which already ex

20、isted for the various product forms; b) to establish unique, new and identifiably European designations for copper and copper alloys, including a numerical option to be particularly convenient for computerized handling; c) to confirm, clarify and redefine where necessary, the terminology which alrea

21、dy existed in common usage, at the international level or in customs nomenclature. CEN/TC 133 decided, in view of the new form of presentation and new parameters for the description and provision of information on copper and copper alloy products, to prepare and publish the present consolidation and

22、 summary of essential details. PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 6 1 Scope This Technical Specification provides a summary of material designations, compositions and the product forms in which they are available, for coppers and copper alloys standardized in European Standards by CEN/TC 133

23、“Copper and copper alloys”. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced d

24、ocument (including any amendments) applies. EN 1976, Copper and copper alloys Cast unwrought copper products EN 1982:2008, Copper and copper alloys Ingots and castings 3 Compositions of coppers and copper alloys standardised by CEN/TC 133 3.1 Composition of coppers The symbol and number designations

25、 and compositions of copper grades are given in the following tables: Table 1.1 Composition of copper cathodes according to EN 1978:1998, Cu-CATH-1 (CR001A) and Cu- CATH-2 (CR002A) Table 1.2 Composition of unalloyed copper grades made from Cu-CATH-1 (CR001A) according to EN 1978 Table 1.3 Compositio

26、n of unalloyed copper grades, other than those made from Cu-CATH-1 (CR001A) according to EN 1978 Table 1.4 Composition of phosphorus-containing copper grades Table 1.5 Composition of silver-containing copper grades (silver-bearing coppers) 3.2 Composition of copper alloys The symbol and number desig

27、nations and compositions of copper alloys are given in the following tables: Table 2 Composition of copper alloys, low alloyed (less than 5 % alloying elements) Table 3 Composition of copper-aluminium alloys Table 4 Composition of copper-nickel alloys Table 5 Composition of copper-nickel-zinc alloys

28、 Table 6 Composition of copper-tin alloys Table 7 Composition of copper-zinc alloys, binary Table 8 Composition of copper-zinc-lead alloys Table 9 Composition of copper-zinc alloys, complex PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 7 3.3 Composition of master alloys The symbol and number designation

29、s and compositions of master alloys in accordance with EN 1981:2003 are given in Table 11. 3.4 Composition of ingots and castings The symbol and number designations and compositions of ingots and castings in accordance with EN 1982:2008 are given in the following tables: Table 12.1 Ingots and castin

30、gs Copper and copper-chromium alloys Compositions and casting processes Table 12.2 Ingots and castings Copper-zinc alloys Composition and casting processes Table 12.3 Ingots and castings Copper-tin alloys Composition and casting processes Table 12.4 Ingots and castings Copper-tin-lead alloys Composi

31、tion and casting processes Table 12.5 Ingots and castings Copper-aluminium alloys Composition and casting processes Table 12.6 Ingots and castings Copper-manganese-aluminium alloys Composition and casting processes Table 12.7 Ingots and castings Copper-nickel alloys Composition and casting processes

32、 3.5 Composition of copper and copper alloy scrap The symbol and number designations and compositions of copper and copper alloy scrap in accordance with EN 12861:1999 are given in Table 13. 4 Available product forms of copper and copper alloys 4.1 Wrought coppers and copper alloys The product forms

33、 and applicable standards are given in Table 10. 4.2 Master alloys The product forms are given in Table 11. 4.3 Ingots and castings The product forms are given in Tables 12.1 to 12.7. 4.4 Scrap The product forms are given in Table 13. 4.5 Copper and copper alloy grooved contact wires The product for

34、ms are given in Table 14. PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 8 Table 1.1 Composition of copper cathodes according to EN 1978:1998, Cu-CATH-1 (CR001A) and Cu-CATH-2 (CR002A) Material designation Composition in % (mass fraction) Element Cu Ag As Bi Cd Co Cr Fe Mn Ni P Pb S Sb Se Si Sn Te Zn Sum

35、 of elements listed in this table other than copper Symbol Number Cu-CATH-1 CR001A min. max. 0,002 5 0,000 5 a0,000 20 b a c a0,001 0 c a c a0,000 5 0,001 5 d0,000 4 a0,000 20 b c c0,000 20 b c0,006 5 Cu-CATH-2 CR002A min. 99,90 e max. 0,000 5 0,005 0,03 excluding Ag a(As + Cd + Cr + Mn + P + Sb) ma

36、ximum 0,001 5 %. b(Bi + Se + Te) maximum 0,000 3 %, of which (Se + Te) maximum 0,000 30 %. c(Co + Fe + Ni + Si + Sn + Zn) maximum 0,002 0 %. dThe sulfur content shall be determined on a cast sample. eIncluding silver up to a maximum of 0,015 %. PD CEN/TS 13388:2015CEN/TS 13388:2015 (E) 9 Table 1.2 C

37、omposition of unalloyed copper grades made from Cu-CATH-1 (CR001A) according to EN 1978 Material designation Composition in % (mass fraction) Symbol Number Element Cu Ag As Bi Cd Co Cr Fe Mn Ni O P Pb unwrought copper wrought copper Cu-ETP1 CR003A CW003A min. max. 0,002 5 0,000 5 a 0,000 20 b a c a

38、0,001 0 c a c 0,040 a 0,000 5 Cu-OF1 CR007A CW007A min. max. 0,002 5 0,000 5 a 0,000 20 b a c a 0,001 0 c a c d a 0,000 5 Cu-OFE CR009A CW009A min. max. 99,99 0,002 5 0,000 5 0,000 20 0,000 1 0,001 0 0,000 5 0,001 0 d 0,000 3 0,000 5 Cu-PHCE CR022A CW022A min. max. 99,99 0,002 5 0,000 5 0,000 20 0,0

39、00 1 0,001 0 0,000 5 0,001 0 d0,001 0,006 0,000 5 Material designation Composition in % (mass fraction) Symbol Number Element S Sb Se Si Sn Te Zn Elements listed in this table other than copper unwrought copper wrought copper total excluding Cu-ETP1 CR003A CW003A min. max. 0,001 5 0,000 4 a 0,000 20

40、 b c c 0,000 20 b c 0,006 5 O Cu-OF1 CR007A CW007A min. max. 0,001 5 0,000 4 a 0,000 20 b c c 0,000 20 b c 0,006 5 O Cu-OFE CR009A CW009A min. max. 0,001 5 0,000 4 0,000 20 0,000 2 0,000 20 0,000 1 Cu-PHCE CR022A CW022A min. max. 0,001 5 0,000 4 0,000 20 0,000 2 0,000 20 0,000 1 a(As + Cd + Cr + Mn

41、+ P + Sb) max. 0,001 5 %. b(Bi + Se + Te) max. 0,000 3 %, of which (Se + Te) max. 0,000 30 %. c(Co + Fe + Ni + Si + Sn + Zn) max. 0,002 0 %. dThe oxygen content shall be controlled by the manufacturer so that the material conforms to the hydrogen embrittlement requirements of EN 1976. PD CEN/TS 1338

42、8:2015CEN/TS 13388:2015 (E) 10 Table 1.3 Composition of unalloyed copper grades, other than those made from Cu-CATH-1 (CR001A) according to EN 1978 Material designation Composition in % (mass fraction) Symbol Number Other elements (see note) unwrought copper wrought copper Element Cu aBi O Pb total

43、excluding Cu-ETP CR004A CW004A min. max. 99,90 0,000 5 0,040 b 0,005 0,03 Ag, O Cu-FRHC CR005A CW005A min. max. 99,90 0,040 b 0,06 dAg, O Cu-FRTP CR006A CW006A min. max. 99,90 0,100 0,05 Ag, Ni, O Cu-OF CR008A CW008A min. max. 99,95 0,000 5 c 0,005 0,03 Ag NOTE The total of other elements (than copp

44、er) is defined as the sum of Ag, As, Bi, Cd, Co, Cr, Fe, Mn, Ni, O, P, Pb, S, Sb, Se, Si, Sn, Te and Zn, subject to the exclusion of any individual elements indicated. aIncluding silver, up to a maximum of 0,015 %. bOxygen content up to 0,060 % is permitted, subject to agreement between the purchase

45、r and the supplier. cThe oxygen content shall be controlled by the manufacturer so that the material conforms to the hydrogen embrittlement requirements of EN 1976. dHigher total impurities content is permitted, subject to agreement between the purchaser and the supplier. Table 1.4 Composition of ph

46、osphorus-containing copper grades Material designation Composition in % (mass fraction) Symbol Number Other elements (see note) unwrought copper wrought copper Element Cu aBi P Pb total excluding Cu-PHC CR020A CW020A min. max. 99,95 0,000 5 0,001 0,006 0,005 0,03 bAg, P Cu-HCP CR021A CW021A min. max

47、. 99,95 0,000 5 0,002 0,007 0,005 0,03 bAg, P Cu-DLP CR023A CW023A min. max. 99,90 0,000 5 0,005 0,013 0,005 0,03 Ag, Ni, P Cu-DHP CR024A CW024A min. max. 99,90 0,015 0,040 c Cu-DXP CR025A min. max. 99,90 0,000 5 0,04 0,06 0,005 0,03 Ag, Ni, P NOTE The total of other elements (than copper) is defined as the sum of Ag, As, Bi, Cd, Co, Cr, Fe, Mn, Ni, O, P, Pb, S, Sb, Se, Si, Sn, Te and Zn, subject to the exclusion of any individual elements indicated. aIncluding silver, up to a maximum of 0,015 %. bThe oxygen content shall be controlled by the manufacturer so that the material conforms