DIN EN 14214-2014 Liquid petroleum products - Fatty acid methyl esters (FAME) for use in diesel engines and heating applications - Requirements and test methods German version EN 1.pdf

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1、June 2014 Translation by DIN-Sprachendienst.English price group 13No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 7

2、5.160.20!%25“2151888www.din.deDDIN EN 14214Liquid petroleum products Fatty acid methyl esters (FAME) for use in diesel engines and heatingapplications Requirements and test methods;English version EN 14214:2012+A1:2014,English translation of DIN EN 14214:2014-06Flssige Minerallerzeugnisse Fettsure-M

3、ethylester (FAME) zur Verwendung in Dieselmotoren und als Heizl Anforderungen und Prfverfahren;Englische Fassung EN 14214:2012+A1:2014,Englische bersetzung von DIN EN 14214:2014-06Produits ptroliers liquides Esters mthyliques dacides gras (EMAG) pour moteurs diesel et comme combustible dechauffage E

4、xigences et mthodes dessai;Version anglaise EN 14214:2012+A1:2014,Traduction anglaise de DIN EN 14214:2014-06SupersedesDIN EN 14214:2012-11www.beuth.deIn case of doubt, the German-language original shall be considered authoritative.Document comprises 27 pages 05.14 DIN EN 14214:2014-06 2 A comma is

5、used as the decimal marker. National foreword This document (EN 14214:2012+A1:2014) has been prepared by Technical Committee CEN/TC 19 “Gaseous and liquid fuels, lubricants and related products of petroleum, synthetic and biological origin” (Secretariat: NEN, Netherlands). The responsible German bod

6、y involved in its preparation was the Normenausschuss Materialprfung (Materials Testing Standards Committee), Working Committee NA 062-06-32-01 UA Prfung von FAME of the Fachausschuss Minerall- und Brennstoffnormung (FAM). The DIN Standards corresponding to the International Standards referred to in

7、 this document are as follows: EN ISO 3170 DIN EN ISO 3170, DIN 51750-1 and DIN 51750-2 Notes to Annex C of this European Standard: Because there is no suitable single test method for determining saturated monoglyceride (SMG) content in FAME, this standard gives an “informative recommendation” for t

8、he maximum limit for SMG using a multi-level correlation model based on several test methods having an unknown precision. However, this limitation is completely useless from an analytical point of view due to the rather large estimated error of measurement of 50 % caused by a propagation of errors,

9、especially considering that no verifiable information is available regarding these “problem-free” maximum SMG limits. Because the promised document explaining this situation has not yet been supplied by CEN/TC 19, advice has been given in the National Annex, NB.7 of this standard to avoid any unnece

10、ssary irritation due to additional requirements, e.g. in technical delivery specifications, which make no sense from an analytical and statistical point of view. Amendments This standard differs from DIN EN 14214:2012-11 as follows: a) test methods for CFPP and sulfur content have been added; b) tes

11、t methods for oxidation stability and total contamination have been updated; c) normative references (prEN 12662:2012, prEN 15751:2012, EN 16294:2012, EN 16300:2012 and EN 16329:2013) have been updated; d) further clarification has been provided regarding the use of dyes and markers; e) identificati

12、on of parallel existence with EN 590 has been removed; f) Annex A has been completed to include representative information on reproducibility for all test methods. Previous editions DIN V 51606: 1994-06 DIN EN 14213: 2003-11 DIN EN 14213 Corrigendum 1: 2004-02 DIN EN 14214: 2003-11, 2009-02, 2010-04

13、, 2012-11 DIN EN 14214 Corrigendum 1: 2004-11 DIN EN 14214 Corrigendum 2: 2008-02 DIN EN 14214:2014-06 3 Annex NA (informative) Bibliography DIN 51750-1:1990-12, Sampling of petroleum products General information DIN 51750-2:1990-12, Sampling of liquid petroleum products DIN 51773:1996-03, Testing o

14、f liquid fuels Determination of ignition quality (cetane number) of Diesel fuels with the BASF engine DIN SPEC 51603-6, Liquid fuels Fuel oils Part 6: Fuel oil EL A, Minimum requirements DIN EN ISO 3170:2004-06, Petroleum liquids Manual sampling DIN EN ISO 4259, Petroleum products Determination and

15、application of precision data in relation to methods of test BImSchV 10, Zehnte Verordnung zur Durchfhrung des Bundes-Immissionsschutzgesetzes (Verordnung ber die Beschaffenheit und die Auszeichnung der Qualitten von Kraft- und Brennstoffen 10. BImSchV) (Tenth ordinance on the implementation of the

16、Federal Immission Control Act (Ordinance on the quality and labelling of fuels) as of 8 December 2010, BGBI (German Federal Law Gazette), 2010, No. 62, pp. 1849-18611)1)Registered in the DITR database of DIN Software GmbH, obtainable from: Beuth Verlag GmbH, 10772 Berlin.DIN EN 14214:2014-06 4 Annex

17、 NB (normative) National specifications concerning Clauses 3, 4, 5.4 and 5.5.3 NB.1 Sampling Samples shall be taken in accordance with DIN 51750-1:1990-12 and DIN 51750-2:1990-12. NB.2 Pump marking Pump marking shall be as in BlmSchV 10. NB.3 Cold flow properties of FAME for use as heating fuel The

18、national specifications required in 5.4.1 for the use of FAME as a heating fuel or as a blend component for heating fuel are as follows for Germany: The cold flow properties of FAME for use as heating oil (Heating oil DIN 51603-6 EL A Bio 100) shall meet the requirements of DIN SPEC 51603-6. FAME us

19、ed as a blend component in heating fuel EL A shall meet the requirements for the cold flow properties of the blend component laid down in DIN SPEC 51603-6. NB.4 Climate-related requirements for FAME being used at 100 % (V/V) concentration (see Table 2a) The following requirements for cold filter plu

20、gging points apply: 15 April to 30 September Grade B CFPP max. 0 C 1 October to 15 November Grade D CFPP max. 10 C 16 November to 28 February2)Grade F CFPP max. 20 C 1 March to 14 April Grade D CFPP max. 10 C NB.5 Climate-related requirements for FAME being used as blend component (see Tables 3a and

21、 3b) The following requirements for the CFPP and cloud point (CP) apply (see Table 3a): 15 April to 30 September Grade d CP / CFPP max. 5 C / 0 C 1 October to 15 November Grade e CP / CFPP max. 0 C / 5 C 16 November to 28 February3)Grade f CP / CFPP max. 3 C / 10 C 1 March to 14 April Grade e CP / C

22、FPP max. 0 C / 5 C 2)In leap years 29.02.3)In leap years 29.02.DIN EN 14214:2014-06 5 The following national requirements for the monoglyceride content apply (see Table 3b): 15 April to 30 September max. 0,70 % (m/m) Grade 6 1 October to 15 November max. 0,70 % (m/m) Grade 6 16 November to 28 Februa

23、ry4)max. 0,70 % (m/m) Grade 6 1 March to 14 April max. 0,70 % (m/m) Grade 6 NB.6 Determination of the cetane number The method specified in DIN 51773:1996-03 may be used as an alternative method in accordance with 5.5.3 of the present standard; i.e. the BASF engine may be used to determine the cetan

24、e number as long as the measured value is corrected to correlate with values obtained using a CFR engine. NB.7 Notes to Annex C Table C.1 in Annex C provides estimates for recommended maximum saturated monoglyceride contents under the assumption that batches with these maximum contents will not caus

25、e any problems in cold climates. However, these estimates are not verifiable. Furthermore, there is no method for determining saturated monoglyceride content, so that an estimate can only be made on the basis of a number of assumptions: a) The ratio of saturated monoglycerides to the total monoglyce

26、ride content is depending on the process involved proportionate to the ratio of the saturated fatty acids to the total fatty acid content. This is a plausible assumption, but has not been proven and in considering proportionality, dependent on the sum of errors in the determinations of the total fat

27、ty acid content, the saturated fatty acid content and the total monoglyceride content. b) Because there is also no acceptable method for determining the saturated fatty acid content, an attempt has been made to use cloud points to produce a correlation. This means there are additional modelling erro

28、rs (deviations from the best-fit line) in this correlation as well as errors of measurement for the cloud point determination. c) The “classes” in Table C.1 represent (with a correct, increasing sorting of the “measured values”) a min/max scale for which the spacing of classes is to be “4R” in accor

29、dance with DIN EN ISO 4259. Assuming errors of about 50 % of the measured value, this prerequisite is not met on any account. In light of the shortcomings discussed above, and considering the need for technically accurate data and limits, we strongly advise against using the data given in Annex C, f

30、or instance in technical delivery specifications, because in cases of dispute the considerations discussed above will be brought up. 4)In leap years 29.02.DIN EN 14214:2014-06 6 This page is intentionally blank EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 14214:2012+A1 January 2014 ICS 75.16

31、0.20 Supersedes EN 14214:2012 English Version Liquid petroleum products - Fatty acid methyl esters (FAME) for use in diesel engines and heating applications - Requirements and test methods Produits ptroliers liquides - Esters mthyliques dacides gras (EMAG) pour moteurs diesel et comme combustible de

32、 chauffage - Exigences et mthodes dessai Flssige Minerallerzeugnisse - Fettsure-Methylester (FAME) zur Verwendung in Dieselmotoren und als Heizl - Anforderungen und Prfverfahren This European Standard was approved by CEN on 20 July 2012 and includes Amendment 1 approved by CEN on 10 November 2013. C

33、EN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on ap

34、plication to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC

35、Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, L

36、atvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue M

37、arnix 17, B-1000 Brussels 2014 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 14214:2012+A1:2014 E EN 14214:2012+A1:2014 (E)2 Contents Page Foreword . 3 Introduction . 5 1 Scope 6 2 Normative references 6 3 Sampling . 8 4 Pump mar

38、king 8 5 Requirements and test methods 8 5.1 Dyes and markers 8 5.2 Additives . 8 5.2.1 General . 8 5.2.2 Oxidation stability enhancing additives 8 5.2.3 Non-FAME components 9 5.3 Generally applicable requirements and related test methods 9 5.4 Climate dependent requirements and related test methods

39、 . 11 5.4.1 General . 11 5.4.2 FAME being used at 100 % as fuel for diesel engines and heating applications . 11 5.4.3 FAME being used as blend component in diesel fuel . 12 5.5 Precision and dispute . 13 Annex A (normative) Details of interlaboratory test programme . 15 Annex B (normative) Correcti

40、on factor for calculation of density of FAME . 17 Annex C (informative) Background information for national climate grades selection 18 C.1 General . 18 C.2 Calculation model for saturated monoglycerides in pure FAME . 19 C.3 Calculation of EN 590 diesel fuel saturated monoglyceride content . 19 Bib

41、liography 21 DINEN 14214:2014-06EN 14214:2012+A1:2014 (E) 3 Foreword This document (EN 14214:2012+A1:2014) has been prepared by Technical Committee CEN/TC 19 “Gaseous and liquid fuels, lubricants and related products of petroleum, synthetic and biological origin”, the secretariat of which is held by

42、 NEN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by July 2014, and conflicting national standards shall be withdrawn at the latest by July 2014. Attention is drawn to the possibility that some o

43、f the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 14214:2012. This document includes Amendment 1 approved by CEN on 2013-11-10. The start and finish of text

44、introduced or altered by amendment is indicated in the text by tags . This document has originally been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association, and supports essential requirements of EU Directive(s). Deleted text Significant technical

45、 changes between this European Standard and the previous edition are: extension towards distillate heating fuels. The former specification for FAME for heating fuel applications (EN 14213) also needed to be aligned, but effectively only one quality was supplied and required by heating fuel suppliers

46、 in the European market; further clarification regarding the use of dyes and markers due to its new heating fuel application; an update of the specification in the perspective of blending at up to 10 % (V/V) of FAME in automotive diesel fuel; removal of identification of parallel existence with EN 5

47、90 as FAME is being used for more than one blending purpose; discrimination between climate requirements for use for 100 % as fuel for diesel engines and for use as blend component in diesel fuel. This is done by introducing a new Table 3 for seasonal grades to be set nationally. It thus requires co

48、untries to present two sets of seasonal choices in a national annex to this standard; introduction of additional requirements for FAME for use as a blending component as a first, intermediate, step towards solving precipitation problems observed in the market during cold periods. Further work towards limitation of impurities, more specifically steryl-glycosides, and DIN EN 14214:2014-06 EN 14214:2012+A1:2014 (E) 4 regarding monoglyceride determination is