BS EN 71-7-2014 Safety of toys Finger paints Requirements and test methods《玩具安全 指画颜料 要求和试验方法》.pdf

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1、BSI Standards PublicationBS EN 71-7:2014Safety of toysPart 7: Finger paints Requirements andtest methodsBS EN 71-7:2014 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 71-7:2014. Itsupersedes BS EN 71-7:2002 which is withdrawn.The UK participation in its prepara

2、tion was entrusted to TechnicalCommittee CW/15, Safety of toys.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. Th

3、e British Standards Institution 2014. Published by BSI StandardsLimited 2014ISBN 978 0 580 78517 7ICS 87.040; 97.200.50Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee

4、 on 30 April 2014.Amendments issued since publicationDate Text affectedBS EN 71-7:2014EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 71-7 April 2014 ICS 97.200.50 Supersedes EN 71-7:2002English Version Safety of toys - Part 7: Finger paints - Requirements and test methods Scurit des jouets - P

5、artie 7: Peintures au doigt - Exigences et mthodes dessai Sicherheit von Spielzeug - Fingermalfarben - Teil 7: Anforderungen und Prfverfahren This European Standard was approved by CEN on 8 February 2014. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the c

6、onditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard ex

7、ists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national s

8、tandards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia,

9、 Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2014 CEN All rights of exploitation in any form and by any means res

10、erved worldwide for CEN national Members. Ref. No. EN 71-7:2014 EBS EN 71-7:2014EN 71-7:2014 (E) 2 Contents Page Foreword 4 Introduction .6 1 Scope 7 2 Normative references 7 3 Terms and definitions .7 4 Requirements .8 4.1 General 8 4.2 Colourants 8 4.3 Preservatives 9 4.4 Migration of certain elem

11、ents .9 4.5 Limits for impurities 9 4.5.1 Limits for primary aromatic amines .9 4.5.2 Limits for other impurities . 10 4.6 Taste and smell . 10 4.7 pH-value . 11 4.8 Binding agents, extenders, humectants and surfactants 11 4.9 N-Nitrosamines . 11 4.10 Containers . 11 5 Product information 11 5.1 Gen

12、eral . 11 5.2 Marking 11 5.2.1 Primary packaging 11 5.2.2 Container . 12 D.1 General . 24 D.2 Reagents 25 D.3 Apparatus 26 D.4 Instrumentation . 26 D.5 Sampling procedure . 26 D.6 Procedure 26 D.7 Calculation . 35 D.8 Precision 36 D.8.1 Linearity . 36 D.8.2 Limits of Detection (LOD) and Quantificati

13、on (LOQ) 36 D.8.3 Repeatability and reproducibility data for soluble aromatic amines 37 D.8.4 Repeatability and reproducibility data for reductively cleaved aromatic amines 38 D.8.5 Recovery 39 D.9 Report 40 D.10 Additional Information . 40 E.1 Principle . 41 E.2 Standards, reagents and solvents 41

14、BS EN 71-7:2014EN 71-7:2014 (E) 3 E.3 Apparatus . 43 E.4 Instrumentation . 43 E.5 Sampling. 44 E.6 Procedure . 44 E.6.1 General . 44 E.6.2 Sample preparation . 44 E.6.3 Solvent extraction . 44 E.6.4 Solid phase extraction 45 E.6.5 Sample concentration for determining HCB and PCB congeners . 45 E.6.6

15、 Sample concentration for determining BP . 45 E.6.7 Gas chromatography conditions . 45 E.6.8 Mass spectrometry 46 E.6.9 SIM mode 46 E.7 Calculation . 51 E.8 Precision. 53 E.8.1 Linearity 53 E.8.2 Limits of detection (LOD) and Quantification (LOQ) . 53 E.8.3 Repeatability and reproducibility data for

16、 HCB, PCB congeners and BP 53 E.8.4 Recovery. 54 E.9 Report . 54 E.10 Additional information 55 F.1 Finger paints (see 3.1 and 3.2) . 59 F.2 Colourants (see 4.2.1) . 59 F.3 Preservatives (see 4.3) 59 F.4 Elements (see 4.4) . 59 F.5 Primary aromatic amines (see 4.5.1.2, Tables 1 and 2 and Annex D) 59

17、 F.6 Limit for BenzoPyrene (see 4.5.2) . 60 F.7 Embittering agents (see 4.6). 60 F.8 pH value (see 4.7) 60 F.9 N-Nitrosamines (see 4.9). 60 F.10 Container (see 4.10) 60 F.11 Labelling phrases (see 5.2.1.2) 61 F.12 List of polychlorinated biphenyl congeners (see Annex E) 61 F.13 Reference materials (

18、see Annex D and E) 61 F.14 PCB Analytical Method (see E.6) . 61 Annex ZA (informative) Relationship between this European Standard and the Essential Requirements of EU Directive 2009/48/EC 64 Bibliography 65 BS EN 71-7:2014EN 71-7:2014 (E) 4 Foreword This document (EN 71-7:2014) has been prepared by

19、 Technical Committee CEN/TC 52 “Safety of toys”, the secretariat of which is held by DS. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by October 2014 and conflicting national standards shall be wi

20、thdrawn at the latest by October 2014. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 71-7:2002. This doc

21、ument has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association, and supports essential requirements of EU Directive 2009/48/EC. For relationship with EU Directive 2009/48/EC, see informative Annex ZA, which is an integral part of this document

22、. EN 71, Safety of toys, consists of the following parts: Part 1: Mechanical and physical properties Part 2: Flammability Part 3: Migration of certain elements Part 4: Experimental sets for chemistry and related activities Part 5: Chemical toys (sets) other than experimental sets Part 7: Finger pain

23、ts Requirements and test methods Part 8: Activity toys for domestic use Part 9: Organic chemical compounds Requirements Part 10: Organic chemical compounds Sample preparation and extraction Part 11: Organic chemical compounds Methods of analysis Part 12: N-Nitrosamines and N-nitrosatable substances

24、Part 13: Olfactory board games, cosmetic kits and gustative games Part 14: Trampolines for domestic use NOTE 1 In addition to the above parts of EN 71, the following guidance documents have been published: CEN Report, CR 14379:2002, Classification of toys - Guidelines, CEN Technical Report CEN/TR 15

25、071:2005, Safety of toys - National translations of warnings and instructions for use in EN 71 and CEN/TR 15371:2013, Safety of toys - Replies to requests for interpretation of EN 71-1, EN 71-2, and EN 71-8. This part 7 of the EN 71 series is intended to be read in conjunction with EN 71, part 1. BS

26、 EN 71-7:2014EN 71-7:2014 (E) 5 NOTE 2 Words in italics are defined in Clause 3 (Terms and definitions). According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croat

27、ia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and th

28、e United Kingdom. BS EN 71-7:2014EN 71-7:2014 (E) 6 Introduction This European Standard contains requirements which are intended to reduce the risks to children when finger paints are used as intended or in a foreseeable way, bearing in mind the behaviour of children. It is intended to complete the

29、essential safety requirements of Directive 2009/48/EC by providing special requirements for finger paints. It is recognized that finger paints when compared to other toy products present different risks because of the intended use by fingers or hands and the age of the child. For example, prolonged

30、skin contact or possible ingestion of paint material cannot be ruled out. Therefore, the safety requirements outlined in other parts of EN 71 needed to be expanded upon for finger paints. In order to address the risks associated with the use of finger paints by children, this part of EN 71 contains

31、requirements relating to preservatives as well as other ingredients that may be used in the manufacture of finger paints and requirements relating to impurities, migration of certain elements and other attributes. Chemical Abstract Service Registry Number (CAS), European Inventory of Existing Chemic

32、al Substances Number (EINECS) or Colour Index Number given in the tables are provided for information purposes only. BS EN 71-7:2014EN 71-7:2014 (E) 7 1 Scope This part of EN 71 specifies requirements for the substances and materials used in finger paints and applies to finger paints only. Additiona

33、l requirements are specified for markings, labelling and containers. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated reference

34、s, the latest edition of the referenced document (including any amendments) applies. EN 71-3, Safety of toys - Part 3: Migration of certain elements EN 71-12, Safety of toys - Part 12: N-Nitrosamines and N-nitrosatable substances EN ISO 787-9, General methods of test for pigments and extenders - Par

35、t 9: Determination of pH value of aqueous suspension (ISO 787-9) 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 finger paint aqueous semi-solid or liquid, coloured mixture specially designed for children to apply directly to suitable surface

36、s with the fingers and hands 3.2 colourant pigment or dyestuff Note 1 to entry: For definitions of pigment and dyestuff, see EN ISO 4618. 3.3 extender material in granular or powder form, insoluble in the medium and used to modify or influence certain physical properties SOURCE: EN ISO 4618:2006, 2.

37、98 3.4 humectant substance that delays the drying process 3.5 binding agent water soluble or miscible, non-volatile component that binds the paint to the surface to which it has been applied 3.6 preservative substance that prevents the growth of undesirable micro-organisms BS EN 71-7:2014EN 71-7:201

38、4 (E) 8 3.7 surfactant surface active substance 3.8 embittering agent substance that gives the product a bitter taste 4 Requirements NOTE The requirements of this standard apply to finger paints in the form used by the child. In the case of powdered finger paints (for example to which water might be

39、 added before use) the requirements apply to the finger paint prepared according to the manufacturers instructions. 4.1 General Finger paints shall not contain dangerous substances or mixtures in amounts which can harm the health of children using them. NOTE 1 For more information, see Directive 199

40、9/45/EC 2 and Regulation No. (EC) 1272/2008 1. Finger paints shall not fulfil the criteria of any of the following hazard classes: “acute toxicity” (hazard class 3.1), “Skin corrosion/irritation” (hazard class 3.2), “Serious eye damage/eye irritation” (hazard class 3.3), “Respiratory or skin sensiti

41、sation” (hazard class 3.4), “Germ cell mutagenicity” (hazard class 3.5), “Carcinogenicity” (hazard class 3.6), “Reproductive toxicity” (hazard class 3.7), “Specific target organ toxicity single exposure” (hazard class 3.8), “Specific target organ toxicity repeated exposure” (hazard class 3.9), “Aspi

42、ration hazard” (hazard class 3.10). NOTE 2 The classification is detailed in Regulation (EC) No. 1272/2008 1 (Annex I, Part 3: Health Hazards). 4.2 Colourants 4.2.1 Only colourants and colouring materials which are not fulfilling the hazard criteria in 4.1 shall be used in finger paints. NOTE A non-

43、exhaustive list of commonly used colourants, subject to meeting purity requirements, is given in Annex A consisting of colourants falling in one or more of the following categories: Colourants permitted for use in food and/or cosmetics and other pigments which meet the general requirements of 4.1. 4

44、.2.2 Finger paints shall not contain azo colourants that by cleavage of one or more azo groups can produce the primary aromatic amines listed in Tables 1 and 2 when tested in accordance with the test method specified in Annex D. BS EN 71-7:2014EN 71-7:2014 (E) 9 4.3 Preservatives Finger paints shall

45、 be preserved using only the preservatives listed in Annex B. The determination of preservatives shall be in accordance with the methods approved under EU Cosmetics Legislation, where available (see Directive 82/434/EEC 6, Directive 83/514/EEC 7, Directive 85/490/EEC 8, Directive 93/73/EEC 9, Direct

46、ive 95/32/EC 10, Directive 96/45/EC 11). When tested in accordance with these methods, the maximum concentrations specified in the column ”maximum allowed concentration” of Table B.1 and the limitations and requirements specified in the column ”Limitations and requirements” of Table B.1 shall be obs

47、erved. 4.4 Migration of certain elements When tested in accordance with EN 71-3 the concentration of elements shall not exceed the limit values specified in EN 71-3. 4.5 Limits for impurities 4.5.1 Limits for primary aromatic amines 4.5.1.1 The primary aromatic amines listed in Table 1 shall not be

48、determinable when tested in accordance with the test method in Annex D. Table 1 Primary aromatic amines Primary aromatic amines CAS number Benzidine 92875 2-Naphthylamine 91598 4-Chloro-2-methyl-aniline (4-Chloro-o-toluidine) 95692 4-Aminobiphenyl 92671 4.5.1.2 Finger paints shall not contain carcin

49、ogenic primary aromatic amines (see Table 2 for a non-exhaustive list of relevant substances) in a total amount exceeding 20 mg/kg, with no individual primary aromatic amine exceeding 10 mg/kg, when tested in accordance with Annex D. The limitation does not apply to aromatic aminocarboxylic acids or aminosulfonic acids. Table 2 Other carcinogenic primary aromatic amines (non-exhaustive list) Carcinogenic primary aromatic amine CAS number o-Aminoazotoluene (4-o-tolyazo-o-toluidi