NAVY MIL-PRF-32295 A-2010 CLEANER NON-AQUEOUS LOW-VOC HAP-FREE《无HAP低VOC的无水清洁剂》.pdf

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1、 PERFORMANCE SPECIFICATION CLEANER, NON-AQUEOUS, LOW-VOC, HAP-FREE This specification is approved for use by all Departments and Agencies of the Department of Defense. 1. SCOPE 1.1 Scope. This specification covers non-aqueous cleaners that are free of hazardous air pollutants (HAP) and contain a low

2、 amount (no more than 25 grams per liter) of volatile organic compounds (VOC), for cleaning aircraft components, ground support equipment, and other general cleaning applications (see 6.1 and 6.8). 1.2 Types. The cleaners are of the following types as specified (see 6.2). Type I Vapor pressure 7 mil

3、limeters of mercury Type II Vapor pressure 45 millimeters of mercury Type III Exempt solvent (VOC = 0 g/L) with no vapor pressure limit Part or Identifying number (PIN). The PINs to be used for cleaners acquired to this specification are created as follows: M 32295 X 1 Type I Vapor pressure 7 millim

4、eters of mercury 2 Type II Vapor pressure 45 millimeters of mercury 3 Type III Exempt solvent with no vapor pressure limit Specification number M prefix AMSC N/A FSC 6850 MIL-PRF-32295A 19 April 2010 SUPERSEDING MIL-PRF-32295 5 November 2008 Comments, suggestions, or questions on this document shoul

5、d be addressed to: Commander, Naval Air Warfare Center Aircraft Division, Code 4L8000B120-3, Highway 547, Lakehurst, NJ 08733-5100 or emailed to michael.sikoranavy.mil. Since contact information can change, you may want to verify the currency of this address information using the ASSIST Online datab

6、ase at https:/assist.daps.dla.mil. NOT MEASUREMENT SENSITIVE Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32295A 2 2. APPLICABLE DOCUMENTS 2.1 General. The documents listed in this section are specified in sections 3 and 4 of this specific

7、ation. This section does not include documents cited in other sections of this specification or recommended for additional information or as examples. While every effort has been made to ensure the completeness of this list, document users are cautioned that they must meet all specified requirements

8、 of documents cited in sections 3 and 4 of this specification, whether or not they are listed. 2.2 Government documents. 2.2.1 Specifications and standards. The following specifications and standards form a part of this document to the extent specified herein. Unless otherwise specified, the issues

9、of these documents are those cited in the solicitation or contract. DEPARTMENT OF DEFENSE SPECIFICATIONS MIL-PRF-10924 - Grease, Automotive and Artillery MIL-G-21164 - Grease, Molybdenum Disulfide, for Low and High Temperatures, NATO Code Number G-353 MIL-PRF-81733 - Sealing And Coating Compound, Co

10、rrosion Inhibitive MIL-PRF-83282 - Hydraulic Fluid, Fire Resistant, Synthetic Hydrocarbon Base, Metric, NATO Code Number H-537 MIL-W-81381/11 - Wire, Electric, Fluorocarbon/polyimide Insulated, Medium Weight, Silver Coated Copper Conductor, 600 Volts, 200 Deg. C, Nominal 8.4 or 15.4 Mil Wall DEPARTM

11、ENT OF DEFENSE STANDARDS MIL-STD-1916 - DoD Preferred Methods for Acceptance of Product (Copies of these documents are available online at https:/assist.daps.dla.mil/quicksearch/ or https:/assist.daps.dla.mil or from the Standardization Document Order Desk, 700 Robbins Avenue, Building 4D, Philadelp

12、hia, PA 19111-5094.) 2.2.2 Other Government documents and publications. The following other Government documents and publications form a part of this document to the extent specified herein. Unless otherwise specified, the issues are those cited in the solicitation or contract. CODE OF FEDERAL REGUL

13、ATIONS (CFR) 40 CFR 401 - Protection of Environment 40 CFR 82 - Protection of Stratospheric Ozone (Copies of these documents are available from http:/www.gpoaccess.gov/cfr or Superintendent of Documents, US Government Printing Office, Washington, DC 20402.) Provided by IHSNot for ResaleNo reproducti

14、on or networking permitted without license from IHS-,-,-MIL-PRF-32295A 3 SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT (SCAQMD) SCAQMD Method 313 - Determination of Volatile Organic Compounds (VOC) by Gas Chromatography/Mass Spectrometry (GC/MS) (Copies of these documents are available online at http:

15、/www.aqmd.gov or from South Coast Air Quality Management District, 21865 Copley Drive, Diamond Bar, CA 91765.) 2.3 Non-Government publications. The following documents form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cit

16、ed in the solicitation or contract. ASTM INTERNATIONAL ASTM D56 - Standard Test Method for Flash Point by Tag Closed Cup Tester (DoD Adopted) ASTM D130 - Standard Test Method for Corrosiveness to Copper from Petroleum Products by Copper Strip Test (DoD Adopted) ASTM D891 - Standard Test Methods for

17、Specific Gravity, Apparent, of Liquid Industrial Chemicals (DoD Adopted) ASTM D1296 - Standard Test Method for Odor of Volatile Solvents and Diluents (DoD Adopted) ASTM D1353 - Standard Test Method for Nonvolatile Matter in Volatile Solvents for Use in Paint, Varnish, Lacquer, and Related Products (

18、DoD Adopted) ASTM D1613 - Standard Test Method for Acidity in Volatile Solvents and Chemical Intermediates Used in Paint, Varnish, Lacquer, and related products (DoD Adopted) ASTM D2240 - Standard Test Method for Rubber Property-Durometer Hardness (DoD Adopted) ASTM D2879 - Standard Test Method for

19、Vapor Pressure-Temperature Relationship and Initial Decomposition Temperature of Liquids by Isoteniscope (DoD Adopted) ASTM D3755 - Standard Test Method for Dielectric Breakdown Voltage and Dielectric Strength of Solid Electrical Insulating Materials Under Direct-Voltage Stress ASTM F483 - Standard

20、Test Method for Total Immersion Corrosion Test for Aircraft Maintenance Chemicals (DoD Adopted) ASTM F484 - Standard Test Method for Stress Crazing of Acrylic Plastics in Contact with Liquid or Semi-liquid Compounds (DoD Adopted) ASTM F485 - Standard Test Method for Effects of Cleaners on Unpainted

21、Aircraft Surfaces Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32295A 4 ASTM F502 - Standard Test Method for Effects of Cleaning and Chemical Maintenance Materials on Painted Aircraft Surfaces (DoD Adopted) ASTM F519 - Standard Test Method

22、 for Mechanical Hydrogen Embrittlement Evaluation of Plating/Coating Processes and Service Environments (DoD adopted) ASTM F945 - Standard Test Method for Stress-Corrosion of Titanium Alloys by Aircraft Engine Cleaning Materials (DoD Adopted) ASTM F1110 - Standard Test Method for Sandwich Corrosion

23、Test (DoD Adopted) ASTM F1111 - Standard Test Method for Corrosion of Low-Embrittling Cadmium Plate by Aircraft Maintenance Chemicals (DoD Adopted) (Copies of these documents are available from http:/www.astm.org or ASTM International, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959.) SOCIET

24、Y OF AUTOMOTIVE ENGINEERS (SAE INTERNATIONAL) SAE AMS 4377 - Magnesium Alloy, Sheet and Plate, 3.0Al-1.0 Zn-0.20Mn (AZ31B-H24), Cold Rolled, Partially Annealed (DoD Adopted) SAE AMS 4911 - Titanium Alloy, Sheet, Strip, and Plate 6Al-4V Annealed (DoD Adopted) SAE AMS 5040 - Steel, Sheet and Strip 0.1

25、5 Carbon, Maximum Deep Forming Grade (DoD Adopted) SAE AMS-M-3171 - Magnesium Alloy, Processes for Pretreatment and Prevention of Corrosion on (DoD Adopted) SAE AMS-P-83310 - Plastic Sheet, Polycarbonate, Transparent (DoD Adopted) SAE AMS-QQ-A-250/4 - Aluminum Alloy 2024, Plate And Sheet (DoD Adopte

26、d) SAE AMS-QQ-A-250/12 - Aluminum Alloy 7075, Plate and Sheet (DoD Adopted) SAE AMS-S-8802 - Sealing Compound, Temperature-Resistant, Integral Fuel Tanks and Fuel Cell Cavities, High Adhesion (DoD Adopted) (Copies of these documents are available from http:/www.sae.org or SAE World Headquarters, 400

27、 Commonwealth Drive, Warrendale, PA 15096-0001.) 2.4 Order of precedence. Unless otherwise noted herein or in the contract, in the event of a conflict between the text of this document and the references cited herein, the text of this document takes precedence. Nothing in this document, however, sup

28、ersedes applicable laws and regulations unless a specific exemption has been obtained. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32295A 5 3. REQUIREMENTS 3.1 Qualification. The cleaners furnished under this specification shall be produc

29、ts that are authorized by the qualifying activity for listing on the applicable qualified products list before contract award (see 4.2 and 6.3). 3.2 Material. The cleaners supplied under this specification shall be homogenous liquids that are clear (without turbidity), stable, and free of haze and s

30、uspended matter. 3.2.1 Composition. The cleaners shall be of the same composition and specific gravity as that of the qualification sample. If the cleaner contains any halogenated solvent, adequate acid acceptance stabilizers shall also be present. Any change in the formulation of a qualified produc

31、t shall require requalification. 3.2.2 Prohibited materials. The cleaners shall contain no known or suspected human carcinogens (see 6.8.1), no hazardous air pollutants (see 6.8.2), no toxic pollutants (see 40 CFR 401), and no ozone depleting substances (see 40 CFR 82). 3.3 Toxicity. The cleaners su

32、pplied under this specification shall have no adverse effect on the health of personnel when all precautions are followed for its usage in accordance with the applicable Material Safety Data Sheet (MSDS) (see 4.5.12 and 6.7). 3.4 Performance requirements. The cleaners shall meet the performance requ

33、irements listed in table I. 3.5 Storage stability. The cleaners, after storage in the original, unopened container for not less than one year at a temperature of 90 2 F (34 1 C), shall meet all the requirements of this specification. In addition, the containers shall exhibit no corrosion, distortion

34、, leakage, or other evidence of incompatibility. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32295A 6 TABLE I. Properties and Test Methods. PROPERTY REQUIREMENT TEST METHOD VOC content, grams/liter (maximum) Type I 25 Type II 25 Type III

35、0 SCAQMD Method 313 Apparent specific gravity, 60/60 F No change from qualification sample ASTM D891 Vapor pressure, mm Hg at 20 C (maximum) Type I 7 Type II 45 Type III No limitASTM D2879 Flash point, F (C) (minimum) 140 (60) ASTM D56 Nonvolatile residue, mg/100ml, (maximum) 5 ASTM D1353 Acidity (w

36、eight %) 0.02 ASTM D1613 Odor Non-offensive, low intensity, non-residual ASTM D1296 and 4.5.10 Miscibility with water Immiscible 4.5.1 Drying time, minutes (maximum) 50 4.5.2 Low temperature stability No freezing and no separation 4.5.3 Sandwich corrosion (maximum) Rating of 1 ASTM F1110 Immersion c

37、orrosion, mg/cm2/day (maximum) Aluminum, Titanium, Steel Magnesium 0.04 0.20 ASTM F483 and 4.5.4 Cadmium corrosion test, mg/cm2/day (maximum) 0.20 ASTM F1111 Copper corrosion rating (maximum) 1b ASTM D130 and 4.5.5 Effect on unpainted surfaces No streaks or stains ASTM F485 Hydrogen embrittlement No

38、 failures in less than 150 hours when specimens are loaded to 45 percent of fracture strength and immersed in cleaner ASTM F519 and 4.5.6 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32295A 7 TABLE I. Properties and Test Methods Continued.

39、 PROPERTY REQUIREMENT TEST METHODTitanium stress corrosion (examined with 500X magnification) No cracking ASTM F945 Method A Effect on painted surfaces No streaks, fading, blisters, or discoloration No softening 1 pencil hardness ASTM F502 Effect on plastics Acrylic, type A threaded surfaces shall n

40、ot be plated. Plated specimens shall be baked in accordance with ASTM F519. 4.5.6.2 Test procedure. Each specimen shall be stressed by applying a load equivalent to 45 percent of notch fracture strength. The notch shall be immersed in the cleaner for the duration of the test. Discontinue the test if

41、 no fractures occur after 150 hours of immersion. If a failure occurs in one of four specimens tested, a second set of 4 specimens shall be evaluated. A minimum of 7 out of 8 specimens shall meet the 150 hour duration. 4.5.7 Effect on polyimide insulated wire. Approximately 24 in. (61 cm) of wire co

42、nforming to MIL-W-81381/11 shall be formed into a coil. Place the coil in a 4 ounce (118 ml) wide mouth jar. Add to the jar sufficient cleaner to completely cover the coil of wire. Cap the jar and store it at room temperature for 14 days. Concurrently, perform this procedure using distilled water fo

43、r comparison. At the end of the storage period, remove both coils and rinse thoroughly with tap water at room temperature. Suspend each coil and allow it to drain until completely dry. Each wire shall then be uncoiled and wrapped tightly on a 0.125 in. (3 mm) mandrel noting the appearance of any cra

44、cks in the insulation. Each wire shall then be unwrapped and rewrapped in the opposite direction, again noting appearance of cracks. If the test wire shows no more cracks than the comparison wire, it shall be immersed in a 5 percent by weight sodium chloride solution and subjected to a one minute di

45、electric test of 2,500 volts (root mean square) without breakdown or leakage in accordance with ASTM D3755. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-32295A 10 4.5.8 Effect on polysulfide sealants. The effect of the cleaner on polysulfi

46、de sealants shall be determined as specified in 4.5.8.1 and 4.5.8.2. 4.5.8.1 Preparation of test specimens. Sealants in accordance with MIL-PRF-81733, Class 1, Grade B, Type II and AMS-S-8802, Class B shall be mixed as specified by their respective manufacturers and pressed into 1/8 inch thick sheet

47、 molds. Sealants shall be cured for 14 days at 77 5 F (25 3 C) at 50 percent humidity or an accelerated cure for 48 hours minimum at standard conditions followed by 48 hours at 140 F (60 C). The cured sealants are the sheet stock from which the specimens for each sealant shall be cut. 4.5.8.2 Test p

48、rocedure. The Shore A hardness of each sealant specimen shall be measured as specified in ASTM D2240 (stacking two specimens of the same sealant to make a -inch thickness) before exposing it to the cleaner. Two specimens of each sealant shall be immersed in cleaner at room temperature. After 30 minu

49、tes, specimens shall be removed, wiped dry and tested (as above) within 30 minutes for Shore A hardness. 4.5.9 Cleaning efficiency. 4.5.9.1 Preparation of test specimens. Stainless steel coupons 1 by 2 by 0.05 inches (25 by 50 by 1.3 mm) shall be polished with 240 grit aluminum oxide abrasive paper or c