BS EN 13832-1-2006 Footwear protecting against chemicals - Terminology and test methods《防化学物质鞋靴 术语和试验方法》.pdf

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1、 g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58The European Standard EN 13832-1:2006 has the status of a British StandardICS 13.340.50Footwear pro

2、tecting against chemicals Part 1: Terminology and test methodsBRITISH STANDARDBS EN 13832-1:2006BS EN 13832-1:2006This British Standard was published under the authority of the Standards Policy and Strategy Committee on 29 September 2006 BSI 2006ISBN 0 580 49263 XAmendments issued since publicationA

3、md. No. Date Commentscontract. Users are responsible for its correct application.Compliance with a British Standard cannot confer immunity from legal obligations. National forewordThis British Standard was published by BSI. It is the UK implementation of EN 13832-1:2006.The UK participation in its p

4、reparation was entrusted to Technical Committee PH/1, Safety, protective and occupational footwear.A list of organizations represented on PH/1 can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a EUROPEAN STANDARDNORME EUROPENNEEU

5、ROPISCHE NORMEN 13832-1August 2006ICS 13.340.50English VersionFootwear protecting against chemicals - Part 1: Terminology andtest methodsChaussures protgeant contre les produits chimiques -Partie 1: Terminologie et mthodes dessaiSchuhe zum Schutz gegen Chemikalien - Teil 1:Terminologie und PrfungThi

6、s European Standard was approved by CEN on 1 August 2006.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references

7、 concerning such nationalstandards may be obtained on application to the Central Secretariat or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its o

8、wn language and notified to the Central Secretariat has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembour

9、g, Malta, Netherlands, Norway, Poland, Portugal, Romania,Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2006 CEN All rights of e

10、xploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 13832-1:2006: EEN 13832-1:2006 (E) 2 Contents Page FOREWORD.3 1 SCOPE 4 2 NORMATIVE REFERENCES4 3 TERMS AND DEFINITIONS4 4 TEST METHODS.6 4.1 SAMPLING AND CONDITIONING .6 4.2 DEGRADATION TEST6 4.2.1 Princ

11、iple.6 4.2.2 Apparatus 6 4.2.3 Preparation of samples .7 4.2.4 Procedure 8 4.2.5 Assessment of the basic physical properties of the footwear after degradation.9 4.2.6 Test report .10 4.3 PERMEATION TEST 10 4.3.1 Principle.10 4.3.2 Collecting media11 4.3.3 Apparatus 11 4.3.4 Test pieces 14 4.3.5 Cali

12、bration .15 4.3.6 Preparation of test pieces and apparatus .15 4.3.7 Assessment of breakthrough time.15 4.3.8 Procedure 15 4.3.9 Examination after the permeation test 17 4.3.10 Expression of results .17 4.3.11 Test report .17 ANNEX A (INFORMATIVE) PRECISION OF THE TEST METHOD.18 ANNEX ZA (INFORMATIV

13、E) RELATIONSHIP BETWEEN THIS EUROPEAN STANDARD AND THE ESSENTIAL REQUIREMENTS OF EU DIRECTIVE 89/686/EEC PERSONAL PROTECTIVE EQUIPMENT.19 BIBLIOGRAPHY.20 EN 13832-1:2006 (E) 3 Foreword This document (EN 13832-1:2006) has been prepared by Technical Committee CEN/TC 161 “Foot and leg protectors”, the

14、secretariat of which is held by BSI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by February 2007, and conflicting national standards shall be withdrawn at the latest by February 2007. This docum

15、ent has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association, and supports essential requirements of EU Directive(s). For relationship with EU Directive(s), see informative Annex ZA, which is an integral part of this document. EN 13832, Footwe

16、ar protecting against chemicals, is published in three parts Part 1: Terminology and test methods Part 2: Requirements for footwear resistant to chemicals under laboratory conditions Part 3: Requirements for footwear highly resistant to chemicals under laboratory conditions It has been assumed in th

17、e drafting of this standard that the execution of its provisions is entrusted to appropriately qualified and experienced people for whose guidance it has been prepared and that appropriate precautions will be taken to avoid injury to health and contamination of the environment. According to the CEN/

18、CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg,

19、Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EN 13832-1:2006 (E) 4 1 Scope This European Standard specifies test methods for the determination of degradation, permeation and penetration resistance of footwear by chemicals a

20、nd defines the terms to be used. This standard allows a comparison to be made of the resistance of footwear against selected chemicals under laboratory conditions. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references,

21、only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN ISO 868, Plastics and ebonite - Determination of indentation hardness by means of a durometer (Shore hardness) (ISO 868:2003) EN ISO 20344: 2004, Personal prot

22、ective equipment - Test methods for footwear (ISO 20344:2004) ISO 23529, Rubber - General procedures for preparing and conditioning test pieces for physical test methods 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 footwear material materi

23、al or combination of materials used in footwear for the purpose of isolating the feet and legs from direct contact with chemicals 3.2 degradation deleterious change in one or more properties of a footwear material due to contact with a chemical NOTE These changes may include, e.g. flaking, swelling,

24、 disintegration, embrittlement, discoloration, dimensions, appearance, hardening and softening. 3.3 penetration movement of a chemical through porous materials, seams, pinholes, or other imperfections in a footwear material at a non-molecular level 3.4 permeation process by which a chemical moves th

25、rough a footwear material at a molecular level NOTE Permeation involves the following: absorption of molecules of the chemical into the contacted (outside) surface of a material; diffusion of the absorbed molecules into the material; desorption of the molecules from the opposite (inside) surface of

26、the material. 3.5 test chemical chemical or mixture of chemicals that is used to determine the breakthrough time under the laboratory test conditions. The chemical will be one that can cause adverse effects to the human body by contact with the skin. EN 13832-1:2006 (E) 5 3.6 breakthrough time elaps

27、ed time between the initial application of a test chemical to the outside surface of a footwear material and its subsequent presence on the other side of the material, measured in accordance with this standard 3.7 chemical resistant footwear any material or combination of materials used in footwear

28、for the purpose of isolating the feet or feet and legs from a contact with a sprayed chemical NOTE This footwear (classification I or II, see Clause 4 of EN 13832-2: 2006) conforms to EN 13832-2 has been tested with at least two chemicals under laboratory conditions 3.8 footwear highly resistant to

29、chemical any material or combination of materials used in footwear for the purpose of isolating the feet or feet and legs from direct contact with a chemical. NOTE This footwear (classification II, see Clause 4 of EN 13832-3: 2006) conforms to EN 13832-3 has been tested with at least three chemicals

30、 under laboratory conditions 3.9 collecting medium medium in which the test chemical is freely soluble to saturation mass or volume fraction greater than 0,5 % 3.10 delay time time between actual arrival of the test chemical on the collecting side of the specimen and the analytical instrumentation r

31、egistering a response to it 3.11 permeation rate mass of test chemical permeating the footwear per unit area per unit time (g.cm-2.min-1) 3.12 closed loop breakthrough detection system in which the collecting medium is recirculated through the sampling compartment of the cell test NOTE Closed loop s

32、ystems are not used with gaseous collecting media. 3.13 open loop breakthrough detection system in which the collecting medium passes through the sampling compartment of the cell test without recirculation NOTE Open loop systems may be used with either liquid or gaseous collecting media. 3.14 shrink

33、age reduction in one or more linear dimensions of a test piece of greater than 0,5 % as a result of degradation 3.15 growth increase in one or more linear dimensions of a test piece of greater than 12 % as a result of degradation EN 13832-1:2006 (E) 6 4 Test methods 4.1 Sampling and conditioning The

34、 minimum number of samples, i.e. separate items of footwear, to be tested in order to verify compliance with the requirements specified in Clause 6 and EN ISO 20344, together with the minimum number of test pieces to be taken from each sample, are given in Table 1. Wherever possible, test pieces sha

35、ll be taken from the whole footwear item unless otherwise stated. NOTE If it is not possible to obtain a large enough test piece from the footwear, then a sample of the material from which the component has been manufactured may be used instead and this should be noted in the test report. Where samp

36、les are required from each of three sizes, these shall comprise the largest, smallest and a middle size of the footwear under test. All test pieces shall be conditioned in a standard atmosphere of (23 2) C and (50 5) % relative humidity for a minimum of 48 h before testing, unless otherwise stated i

37、n the test method. The maximum time which shall elapse between removal from the conditioning atmosphere and the start of testing shall be not greater than 10 min, unless otherwise stated in the test method. Table 1 Minimum number of samples and test specimens or test pieces Tests Number of samples N

38、umber of test pieces from each sample Test only on the final footwear Table 1 of EN ISO 20344:2004 is applicable Degradation test EN 13832-1: 2006, 4.2 1 pair 2 discs yes Permeation test EN 13832-1: 2006, 4.3 1 pair 2 discs yes 4.2 Degradation test 4.2.1 Principle The basic physical properties of th

39、e footwear component (upper and sole) are checked before and after contact with chemicals. 4.2.2 Apparatus 4.2.2.1 Degradation cell The apparatus shall be suitable for holding the test piece. A suitable apparatus is illustrated in Figure 1 and comprises a base-plate (5) and an open-ended cylindrical

40、 chamber (4) that is held tightly against the test piece (6) by the wing nuts (1) mounted on the bolts (2). NOTE A hole of diameter approximately 50 mm may be made in the base-plate for the examination of the surface not in contact with the liquid. During the test, the opening in the top of the cham

41、ber shall be closed by a close-fitting plug (3). 4.2.2.2 Miscellaneous a) wash flask, for example a Becher glass b) absorbent paper or lint free textile fabric EN 13832-1:2006 (E) 7 Dimensions in millimetres 321 1245620 150100Key 1 Wing nut 2 Bolt 3 Close-fitting plug to seal the hole in top of the

42、chamber 4 Open-ended cylindrical chamber 5 Base plate 6 Test piece Figure 1 Example of vessel for degradation resistance of footwear components 4.2.3 Preparation of samples If it is impossible to take the sample from the footwear, it may be taken from raw material representative of the shoe. The tes

43、t piece for the upper shall consist of a disc of diameter (120 10) mm, taken from the footwear (see Figure 2) or from the material intended for use in constructing the footwear. The lining shall be removed. NOTE During removal of the lining as small an amount as possible of polymeric material should

44、 be removed. For the sole, a disc of diameter (120 10) mm shall be taken from the fore part of the sole. Discs with a thickness of (2,5 0,1) mm shall be prepared according to the following steps: a) Remove the sole tread by splitting. b) Obtain the thickness of (2,5 0,1) mm by removing the interior

45、material. Except for the necessary handling during preparation, the surface in contact with the chemical shall be tested without any mechanical treatment. If there is seam in the sample upper, it shall be tested. EN 13832-1:2006 (E) 8 11Figure 2a) - Knee length rubber boot Figure 2b) - Shoe or low b

46、oot 1Key 1 Area for taking samples Figure 2 c) - Sole or insole Figure 2 Area for sampling of footwear 4.2.4 Procedure 4.2.4.1 Preliminary measurements For footwear in rubber material, measure the elongation at break according to EN ISO 20344:2004, 6.4 before degradation. Before chemical degradation

47、 the tests given in Table 2 shall be performed. EN 13832-1:2006 (E) 9 Table 2 Tests for basic properties of the sole and the upper before degradation Sole Upper 1sttest 2ndtest 1sttest 2ndtest Tear resistance EN ISO 20344: 2004, 8.2 Hardness EN ISO 868 Tear resistance EN ISO 20344: 2004, 6.3 Elongat

48、ion at break EN ISO 20344: 2004, 6.4 (not applicable for leather upper) In addition, perform these measurements on all the test pieces. a) For the upper: weigh the test piece to the nearest milligram (mass Mu1). b) For the sole: weigh the test piece to the nearest milligram (mass Ms1) and measure th

49、e hardness in accordance with EN ISO 868. 4.2.4.2 Degradation Place the test piece in the apparatus as indicated in Figure 1. The outer part shall be in contact with the chemical. Fill the chamber of the apparatus with the liquid chemical chosen for the test to a depth of approximately 15 mm and insert the plug (3). Maintain the apparatus for (23 1) h either at a temperature of (23 2) C or at another temperature. In the latter case, report the temperature in the test report Remove the liqui