BS EN 71-9-2005+A1-2007 Safety of toys - Organic chemical compounds - Requirements《玩具安全 有机化合物 要求》.pdf

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1、Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHSg49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g

2、48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58-,-,-The European Standard EN 71-9:2005, incorporating amendment A1:2007, has the status of a British StandardICS 97.200.50Safety of toys Part 9: Organic chemical compounds RequirementsBRITISH STANDARDBS EN 71-9:2005 +A1:2007BS EN 71-9

3、:2005+A1:2007Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHSThis British Standard was published under the authority of the Standards Policy and Strategy Committee on 25 February 2005

4、 BSI 2007ISBN 978 0 580 59840 1Amendments issued since publicationAmd. No. Date Comments17278 31 August 2007 Implementation of CEN amendment A1:2007request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct

5、application.Compliance with a British Standard cannot confer immunity from legal obligations.National forewordThis British Standard is the UK implementation of EN 71-9:2005+A1:2007. The start and finish of text introduced or altered by amendment is indicated in the text by tags. Tags indicating chan

6、ges to CEN text carry the number of the CEN amendment. For example, text altered by CEN amendment A1 is indicated by !“.The UK participation in its preparation was entrusted by Technical Committee CW/15, Safety of toys, to Subcommittee CW/15/-/4, Chemical requirements.A list of organizations represe

7、nted on this subcommittee can be obtained on -,-,-EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 71-9:2005+A1 July 2007 ICS 97.200.50 Supersedes EN 71-9:2005English Version Safety of toys - Part 9: Organic chemical compounds - Requirements Scurit des jouets - Partie 9: Composs organiques chimi

8、ques - Exigences Sicherheit von Spielzeug - Teil 9: Organisch-chemische Verbindungen - Anforderungen This European Standard was approved by CEN on 15 November 2004 and includes Amendment 1 approved by CEN on 26 May 2007. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which

9、 stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Sta

10、ndard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national s

11、tandards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United

12、 Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 71-9:2005+A1

13、:2007: ECopyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-EN 71-9:2005+A1:2007 (E) 2 Contents Page Foreword3 Introduction .4 1 Scope 6 2 Normative references 6 3 Terms and definiti

14、ons .6 4 Requirements.7 4.1 Limits (see A.4) 7 4.2 Liquids in toys (see A.5) .8 4.3 Formaldehyde (see A.6) 8 4.4 Methods of analysis (see A.7) 8 Annex A (informative) Rationale 13 A.1 General13 A.2 Accessible liquid (see 3.2)13 A.3 Polymeric (see 3.6) 13 A.4 Limits (see 4.1).13 A.5 Liquids in toys (

15、see 4.2) 14 A.6 Formaldehyde (see 4.3).14 A.7 Methods of analysis (see 4.4).14 A.8 Colourants and primary aromatic amines (see Table 1, Table 2 B and Table 2 C).14 A.9 Applicable limit tables (see Table 1)15 A.10 Limit tables (see Tables 2 A to 2 I).15 A.11 Toys containing cosmetic components 16 Ann

16、ex B (informative) Conformity assessment .17 Annex ZA (informative) Clauses of this European Standard addressing essential requirements or other provisions of EU Directives18 Bibliography 19 Tables of 4.4 Table 1 Applicable limit tables Table 2 A Flame retardants Table 2 B Colourants Table 2 C Prima

17、ry aromatic amines Table 2 D Monomers (migration) Table 2 E Solvents (migration) Table 2 F Solvents (inhalation) Table 2 G a) and b) Wood preservatives Table 2 H Preservatives (other than wood preservatives) Table 2 I Plasticisers (migration) Copyright European Committee for Standardization Provided

18、 by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-EN 71-9:2005+A1:2007 (E) 3 Foreword This document (EN 71-9:2005+A1:2007) has been prepared by Technical Committee CEN/TC 52 “Safety of toys”, the secretariat of which is held by DS. This

19、document shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by January 2008 and conflicting national standards shall be withdrawn at the latest by January 2008. This document includes Amendment 1 approved by CEN on 2007-05-26

20、. This document supersedes EN 71-9:2005. The start and finish of text introduced or altered by amendment is indicated in the text by tags ! “. This document has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association, and supports essential requi

21、rements of EU Directive(s). For relationship with EU Directive(s), see informative Annex ZA, which is an integral part of this document. This standard constitutes part 9 of the European Standard on Safety of Toys. This part should be read in conjunction with parts 10 and 11. This !standard“ defines

22、contact routes and specifies limits for the migration or content of certain chemical compounds in toys. This !standard“ contains three annexes: - Annex A (informative) Rationale - Annex B (informative) Conformity assessment - Annex ZA (informative) Clauses of this European Standard addressing essent

23、ial requirements or other provisions of EU Directives. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, Fran

24、ce, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Copyright European Committee for Standardization Provided by IHS under license with CENNot f

25、or ResaleNo reproduction or networking permitted without license from IHS-,-,-EN 71-9:2005+A1:2007 (E) 4 Introduction The !standard“ EN 71 for safety of toys consists of the following parts. Part 1: Mechanical and physical properties Part 2: Flammability Part 3: Migration of certain elements Part 4:

26、 Experimental sets for chemistry and related activities Part 5: Chemical toys (sets) other than experimental sets Part 6: Graphical symbols for age warning labelling Part 7: Finger paints Requirements and test methods Part 8: Swings, slides and similar activity toys for indoor and outdoor family dom

27、estic use Part 9: Organic chemical compounds Requirements Part 10: Organic chemical compounds Sample preparation and extraction Part 11: Organic chemical compounds Methods of analysis The !standards“ EN 71-9, !EN 71-10“ and !EN 71-11“ were mandated by the European Commission (M/229) to address the r

28、isks presented by organic compounds in toys by taking into account the potential exposure and toxicological effects of those substances considered to present the greatest risk to health. This !standard“ gives requirements for organic compounds in certain toys and toy materials. In drafting the !stan

29、dard“, CEN/TC 52 considered the risks associated with more than 650 organic compounds. It was recognized that not all potentially hazardous organic compounds could be addressed. The Commission further restricted the Mandate to substances classified as dangerous under Council Directive 67/548/EEC. Th

30、is !standard“, therefore, supports but does not reduce the responsibility of toy manufacturers, importers and suppliers for ensuring that the use of other substances will not endanger the health whilst playing with toys as intended or in a reasonably foreseeable way. In addition, there should be no

31、exposure to children from toys, in amounts which may harm their health, of organic chemical substances which are classified by other relevant statutes as carcinogenic, mutagenic or toxic for reproduction and for which no requirements are specified in this !standard“. !Future editions of this standar

32、d may address additional organic compounds. Users of this standard are reminded that compliance with the standard can only provide presumption of conformity with the essential safety requirements of the Toys Safety Directive in respect of the substances addressed.“ This part should be read in conjun

33、ction with !EN 71-10“, which describes sample preparation and extraction procedures, and !EN 71-11“, which specifies methods of analysis. At the date of publication, the standard does not specify requirements for chemical compounds which are prohibited in toys by Council Directive 76/769/EEC of 27th

34、July 1976, as amended, on restrictions on the marketing and use of certain dangerous substances and preparations. This !standard“ takes into account the opinion of the Toxicology Section of the Scientific Advisory Committee published in 1992 (EUR 13976) which recommended that certain groups of chemi

35、cal compounds used in toys and toy materials need to be given special attention. In drafting this !standard“ CEN/TC 52 has considered organic chemicals that can be classified within the following groups: Solvents Preservatives Plasticisers (excluding phthalate plasticisers)1 Flame retardants Monomer

36、s Biocides (wood preservatives) 1Phthalate plasticisers were specifically excluded from the scope of mandate M/229. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-EN 71-9:2005+A

37、1:2007 (E) 5 Processing aids Colouring agents During the development of this !standard“, CEN/TC 52 has considered the requirements set out in Council Directive 82/711/EEC as amended and its supporting standards. Copyright European Committee for Standardization Provided by IHS under license with CENN

38、ot for ResaleNo reproduction or networking permitted without license from IHS-,-,-EN 71-9:2005+A1:2007 (E) 6 1 Scope This Part 9 of the !standard“ EN 71 for safety of toys specifies requirements for the migration or content of certain hazardous organic chemical compounds from/in certain toys and toy

39、 materials (see Table 1) by the following exposure routes: - mouthing - ingestion - skin contact - eye contact - inhalation when used as intended or in a foreseeable way, bearing in mind the normal behaviour of children and the function and design of the toy. This !standard“ does not contain require

40、ments for chemical toys, experimental sets or finger-paints, which are addressed by other parts of EN 71. Packaging materials used with toys are not within the scope of the !standard“ unless they form part of the toy or have intended play value. 2 Normative references The following referenced docume

41、nts are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. !EN 71-1:2005+A4:2007“, Safety of toys - Part 1: Mechanical and physical propert

42、ies EN 71-5, Safety of toys Part 5: Chemical toys (sets) other than experimental sets !EN 71-10, Safety of toys - Part 10: Organic chemical compounds - Sample preparation and extraction“ !EN 71-11, Safety of toys - Part 11: Organic chemical compounds - Methods of analysis“ EN 645, Paper and board in

43、tended to come into contact with foodstuffs Preparation of a cold water extract EN 717-3, Wood-based panels Determination of formaldehyde release Part 3: Formaldehyde release by the flask method EN 1541, Paper and board intended to come into contact with foodstuffs - Determination of formaldehyde in

44、 an aqueous extract EN ISO 787-9, General methods of test for pigments and extenders Part 9: Determination of pH value of aqueous suspension (ISO 787-9:1981) EN ISO 14184-1, Textiles Determination of formaldehyde Part 1: Free and hydrolysed formaldehyde (water extraction method) (ISO 14184-1:1998) 3

45、 Terms and definitions For the purposes of this document, the following terms and definitions apply. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-EN 71-9:2005+A1:2007 (E) 7 3.

46、1 accessible contact with the articulated probe when tested in accordance with the accessibility-of-a-part-or-component test in !EN 71-1:2005+A4:2007“ 3.2 (see A.2) accessible liquid liquid in or on a toy or accompanying a toy to which the child is likely to become exposed during normal or foreseeab

47、le use of the toy (e.g. liquid paints, bubble liquids, ink in pens, liquids provided with toys for squirting) 3.3 mouth-actuated toy toy which relies on an action of the mouth to operate and which therefore is designed to come into contact with the mouth during play (e.g. toy whistles, toy imitation

48、 novelty teeth). Inflatable toys are not considered mouth-actuated toys unless they rely on an action of the mouth after inflation 3.4 mouthed licked, sucked and chewed 3.5 paper material, marketed as either paper or paperboard, with a maximum mass per unit area of 400 g/m2!EN 71-1:2005+A4:2007“ 3.6 (see A.3) polymeric consisting of plastic, synthetic rubber, natural rubber, silicone polymer but not other natural polymers 3.7 resin-bonded wood wood-based material, for example, plywood, particle board, chipboard and medium-density fibreboard (MDF) 3.8 textile woven or knitted fabrics,