ASTM D4066-2001a Standard Classification System for Nylon Injection and Extrusion Materials (PA)《尼龙注入及挤压材料的标准分类系统》.pdf

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1、Designation: D 4066 01aStandard Classification System forNylon Injection and Extrusion Materials (PA)1This standard is issued under the fixed designation D 4066; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revi

2、sion. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope *1.1 This classification system covers nylon mat

3、erials suit-able for injection molding and extrusion. Some of thesecompositions are also suitable for compression molding andapplication from solution.1.2 The properties included in this classification system arethose required to identify the compositions covered. There maybe other requirements nece

4、ssary to identify particular charac-teristics important to specialized applications. These may bespecified by using the suffixes as given in Section 5.1.3 This classification system and subsequent line call-out(specification) are intended to provide a means of calling outplastic materials used in th

5、e fabrication of end items or parts.It is not intended for the selection of materials. Materialselection should be made by those having expertise in theplastic field after careful consideration of the design and theperformance required of the part, the environment to which itwill be exposed, the fab

6、rication process to be employed, thecosts involved, and the inherent properties of the material otherthan those covered by this classification system.1.4 The values stated in SI units are to be regarded as thestandard.1.5 The following precautionary caveat pertains only to thetest methods portion, S

7、ection 11, of this classification system.This standard does not purport to address all of the safetyconcerns, if any, associated with its use. It is the responsibilityof the user of this standard to establish appropriate safety andhealth practices and determine the applicability of regulatorylimitat

8、ions prior to use.NOTE 1This classification system is similar to ISO 1874-1/-2 1993,although the technical content is significantly different.NOTE 2This classification system is being revised to include interna-tional 4-mm specimens and test procedures as the standard for compli-ance. The 3.2-mm spe

9、cimens; test methods; and Tables PA, A, and B areincluded in Appendix X3 as a reference for those wishing to use them. Itis recommended that the material manufacturer be consulted on allcall-outs against this classification system.2. Referenced Documents2.1 ASTM Standards:D 149 Test Method for Diele

10、ctric Breakdown Voltage andDielectric Strength of Electrical Insulating Materials atCommercial Power Frequencies2D 150 Test Methods for A-C Loss Characteristics andPermittivity (Dielectric Constant) of Solid Electrical Insu-lation2D 256 Test Methods for Determining the Izod PendulumImpact Resistance

11、 of Plastics3D 257 Test Methods for D-C Resistance or Conductance ofInsulating Materials2D 618 Practice for Conditioning Plastics for Testing3D 638 Test Method for Tensile Properties of Plastics3D 648 Test Method for Deflection Temperature of PlasticsUnder Flexural Load in the Edgewise Position3D 78

12、9 Test Methods for Determination of Relative Viscos-ity, and Moisture Content of Polyamide (PA)3D 790 Test Methods for Flexural Properties of Unreinforcedand Reinforced Plastics and Electrical Insulating Materi-als3D 792 Test Methods for Density and Specific Gravity (Rela-tive Density) of Plastics b

13、y Displacement3D 883 Terminology Relating to Plastics3D 1600 Terminology for Abbreviated Terms Relating toPlastics3D 1898 Practice for Sampling of Plastics4D 1999 Guide for Selection of Specimens and Test Param-eters for International Commerce5D 3418 Test Method for Transition Temperatures of Poly-m

14、ers by Differential Scanning Calorimetry6D 3641 Practice for Injection Molding Test Specimens ofThermoplastic Molding and Extrusion Materials6D 3892 Practice for Packaging/Packing of Plastics61This classification system is under the jurisdiction of ASTM Committee D20 onPlastics and is the direct res

15、ponsibility of Subcommittee D20.15 on ThermoplasticMaterials (Section D20.15.09).Current edition approved August 10, 2001. Published October 2001. Originallypublished as D 4066 82. Last previous edition D 4066 01.2Annual Book of ASTM Standards, Vol 10.01.3Annual Book of ASTM Standards, Vol 08.01.4Di

16、scontinued; see 1997 Annual Book of ASTM Standards, Vol 08.01.5Discontinued; see 1999 Annual Book of ASTM Standards, Vol 08.01.6Annual Book of ASTM Standards, Vol 08.02.1*A Summary of Changes section appears at the end of this standard.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700

17、, West Conshohocken, PA 19428-2959, United States.D 4000 Classification System for Specifying Plastic Mate-rials6D 5630 Test Method for Ash Content in Thermoplastics7D 6260 Test Method for Gravimetric Determination of Car-bon Black in Nylon Materials PA7E 29 Practice for Using Significant Digits in

18、Test Data toDetermine Conformance with Specifications82.2 Military and Federal Specifications and Standards:9L-P-410 Plastic, Polyamide (Nylon) Rigid: Rods, Tubes,Flats, Molded and Cast PartsVV-I-530 Insulating Oil, Electrical (for Transformers,Switches, and Circuit Breakers)2.3 ISO Standards:10ISO

19、75-1:1993 PlasticsDetermination of Temperature ofDeflection Under LoadPart 1: General Test MethodsISO 75-2:1993 PlasticsDetermination of Temperature ofDeflection Under LoadPart 2: Plastic and EboniteISO 178:1993 PlasticsDetermination of Flexural Proper-tiesISO 180:1993 PlasticsDetermination of Izod

20、ImpactStrengthISO/DIS 294-1:1995 PlasticsInjection Moulding of TestSpecimens of Thermoplastic MaterialsPart 1: GeneralPrinciples, Multipurpose-Test Specimens (ISO MouldType A) and Bars (ISO Mould Type B)ISO 307 Determination of Viscosity Number of PolyamidesIn Dilute SolutionsISO 527-1:1993 Plastics

21、Determination of TensilePropertiesPart 1: General PrinciplesISO 527-2:1993 PlasticsDetermination of TensilePropertiesPart 2: Testing ConditionsISO 960:1969 PlasticsDetermination of the Water Con-tent in PolyamidesISO 1183:1987 PlasticsMethods for Determining theDensity and Relative Density of Non-Ce

22、llular PlasticsISO 1874-1:1992 PlasticsPolyamide (PA) Homopoly-mers and Copolymers for Moulding and Extrusion Part 1:DesignationISO/DIS 1874-2.2:1995 PlasticsPolyamide (PA) Ho-mopolymers for Moulding and ExtrusionPart 2: Prepa-ration of Test Specimens and Determination of PropertiesISO 3146: Plastic

23、sDetermination of Melting Behaviour(Melting Temperature or Melting Range) of Semi-Crystalline PolymersISO 3167 Plastics, Multipurpose Test SpecimensISO 3451-4:1994 PlasticsDetermination of AshPart 4:Polyamides3. Terminology3.1 The terminology used in this classification system is inaccordance with T

24、erminologies D 883 and D 1600.4. Classification4.1 Nylon materials are classified into groups according totheir composition. These groups are subdivided into classesand grades as shown in the Basic Property Table (Table PA).NOTE 3An example of this classification system for unreinforcednylon is give

25、n as follows: The designation PA0123 indicates the follow-ing:PA = polyamide (nylon) as found in Terminology D 1600,01 (group) = 66 nylon,2 (class) = heat stabilized, and3 (grade) = with a minimum viscosity number of 210 and therequirements given in Table PA.NOTE 4An example of this classification s

26、ystem for reinforced nylonis given as follows: The designation PA012G35 indicates the following:PA = polyamide (nylon) as found in Terminology D 1600,01 (group) = 66 nylon,2 (class) = heat stabilized, andG35 (grade) = nominal 35 % glass with the requirements given inTable PA.4.1.1 Grades of reinforc

27、ed or filled versions, or both, of thebasic materials are identified by a single letter that indicates thereinforcement or filler used and two digits, in multiples of 5,that indicate the nominal quantity in percent by weight. Thus,a letter designation G for glass reinforced and 35 for percent orrein

28、forcement, G35, specifies a material with a nominal glasslevel of 35 %. The reinforcement letter designations andassociated tolerance levels are shown as follows:Symbol MaterialTolerance(Based on the Total Mass)C carbon- and graphite-fiber-reinforced 62%G glass-reinforced 62%L lubricants (such as PT

29、FE, graphite,silicone, and molybdenum disulfide)Depends upon material andprocessto be specified.M mineral-reinforced 62%R combinations of reinforcements orfillers, or both63%NOTE 5This part of the classification system uses percent of rein-forcements or additives, or both, in the call-out of the mod

30、ified basicmaterial. The types and percentages of reinforcements and additivesshould be shown on the suppliers technical data sheet unless they areproprietary in nature. If necessary, additional control of these reinforce-ments and additives can be accomplished by use of the suffix part of thesystem

31、 (see Section 5).NOTE 6Materials containing reinforcements or fillers, or both, atnominal levels not in multiples of 5 are included in the nearest PA gradedesignation. For example, a material with a nominal material level of28 % is included with Grade M30.NOTE 7An example of this classification syst

32、em for a 33 % glass-reinforced nylon is given as follows. The designation PA011G35 indicatesthe following:PA = polyamide (nylon) as found in Terminology D 1600,01 (group) = 66 nylon,1 (class) = general purpose, andG35 (grade) = with requirements given in Table PA.NOTE 8Ash content of filled or reinf

33、orced materials may be deter-mined using Test Method D 5630.7Annual Book of ASTM Standards, Vol 08.03.8Annual Book of ASTM Standards, Vol 14.02.9Available from Standardization Documents Order Desk, Bldg. 4 Section D, 700Robbins Ave., Philadelphia, PA 19111-5094, Attn: NPODS.10Available from American

34、 National Standards Institute (ANSI), 25 W. 43rd St.,4th Floor, New York, NY 10036.D 4066 01a2TABLE PA Requirements for Nylons Dry-as-MoldedA,BGroup Description Class Description Grade DescriptionCViscosityNumber,ISO 307,min, mL/gDensity,ISO 1183,g/cm3TensileStrength,DISO527-1 and ISO527-2, min,MPaF

35、lexuralModulus, ISO178,min, MPaIzod ImpactResistance,ISO 180/1A,min, kJ/m2DeflectionTemperature at1.82 MPa,EISO 75-1 andISO 75-2 min,C01 66 Nylon 1 General-purpose 1 135 1.131.15 70 2 300 3.3 602 165 1.131.15 70 2 300 3.3 603 210 1.131.15 70 2 300 3.3 604 270 1.131.15 70 2 300 3.3 605 recycled 115 1

36、.131.15 70 2 300 3.3 606 recycled 135 1.131.15 70 2 300 3.3 600 otherG15 15 % glass . . . 1.201.26 100 4 000 3.0 215G20 20 % glass . . . 1.251.33 115 5 000 4.0 220G25 25 % glass . . . 1.291.37 140 6 000 5.0 225G35 35 % glass . . . 1.351.45 170 8 000 7.0 235G40 40 % glass . . . 1.421.52 175 9 000 8.0

37、 235G45 45 % glass . . . 1.451.55 180 10 000 9.0 240M40 40 % mineral . . . 1.451.55 80 5 000 2.0 1502 Heat-stabilized 1 135 1.131.15 70 2 300 3.0 602 165 1.131.15 70 2 300 3.0 603 210 1.131.15 70 2 300 3.0 604 270 1.131.15 70 2 300 3.0 605 recycled 115 1.131.15 70 2 300 3.0 606 recycled 135 1.131.15

38、 70 2 300 3.0 600 otherG15 15 % glass . . . 1.201.26 100 4 000 3.0 220G25 25 % glass . . . 1.291.37 140 6 000 5.0 225G30 30 % glass . . . 1.321.42 160 7 000 6.0 230G35 35 % glass . . . 1.351.45 170 8 000 7.0 235G40 40 % glass . . . 1.431.53 175 9 000 8.0 235G45 45 % glass . . . 1.451.55 180 10 000 9

39、.0 240M40 40 % mineral . . . 1.451.55 80 5 000 2.0 150R20 20 % filler . . . 1.231.31 70 3 200 1.5 . . .R40 40 % filler . . . 1.431.53 100 5 500 2.5 2003 Nucleated 1 135 1.131.15 80 2 500 2.8 602 165 1.131.15 80 2 500 2.8 603 210 1.131.15 80 2 500 2.8 604 270 1.131.15 80 2 500 2.8 605 recycled 115 1.

40、131.15 80 2 500 2.8 606 recycled 135 1.131.15 80 2 500 2.8 600 other4 Nucleated, heat-stabilized123 Requirements the same as corresponding grades under Group 01, Class 3.40 other5 Impact-modified 1 . . . 1.061.12 52 1 700 9.0 502 recycled . . . 1.061.12 50 1 600 8.0 500 otherG15 15 % glass . . . 1.1

41、51.23 85 3 000 6.0 210G35 35 % glass . . . 1.311.41 110 5 500 6.0 2256 Impact-modified,heat-stabilized1 . . . 1.081.12 52 1 700 9.0 502 recycled . . . 1.081.12 50 1 600 8.0 500 otherG15 15 % glass . . . 1.151.23 85 3 000 6.0 210G35 35 % glass . . . 1.311.41 110 5 500 6.0 225M40 40 % mineral . . . 1.

42、451.55 75 4 500 4.0 . . .R35 35 % filler . . . 1.381.48 80 5 500 3.0 2007 Toughened 1 . . . 1.061.10 42 1 500 40 452 recycled . . . 1.051.11 40 1 300 35 450 otherG15 15 % glass . . . 1.151.23 70 2 800 9.0 180G35 35 % glass . . . 1.281.38 110 5 500 11 2208 Toughened, heat-stabilized1 . . . 1.061.10 4

43、2 1 500 40 452 recycled . . . 1.051.11 40 1 300 35 450 otherG15 15 % glass . . . 1.151.23 70 2 800 9.0 180D 4066 01a3TABLE PA Requirements for Nylons Dry-as-MoldedA,BGroup Description Class Description Grade DescriptionCViscosityNumber,ISO 307,min, mL/gDensity,ISO 1183,g/cm3TensileStrength,DISO527-1

44、 and ISO527-2, min,MPaFlexuralModulus, ISO178,min, MPaIzod ImpactResistance,ISO 180/1A,min, kJ/m2DeflectionTemperature at1.82 MPa,EISO 75-1 andISO 75-2 min,CG35 35 % glass . . . 1.281.38 110 5 500 11 220G45 45 % glass . . . 1.391.49 130 8 000 10 230M35 35 % mineral . . . 1.371.47 70 3 800 6.0 . . .9

45、 Weather-stabilizedF1 135 1.131.17 80 2 400 2.5 602 recycled 115 1.131.17 65 2 200 2.0 600 other0 Other 0 other02 6 Nylon 1 General-purpose 1 100 1.121.14 75 2 400 4 502 135 1.121.14 70 2 200 3 503 150 1.121.15 70 2 200 3 504 200 1.121.15 70 2 200 3 500 otherG15 15 % glass 1.201.28 110 4 200 4 170G2

46、5 25 % glass 1.281.36 135 5 000 6.5 180G30 30 % glass 1.321.40 150 7 000 7.5 180G35 35 % glass 1.381.44 155 7 500 8 180G00 otherM30 30 % mineral 1.301.40 70 3 200 2.4 50M40 40 % mineral 1.44-1.52 75 4 500 4 70M00 otherR40 40 % glass/mineral1.421.50 100 6 000 3 180R00 other2 Heat-Stabilized 1 100 1.1

47、21.14 75 2 400 4 502 135 1.121.14 70 2 200 3 503 150 1.121.15 70 2 200 3 504 200 1.121.15 70 2 200 3 507 recycled 135 1.12-1.14 70 2 000 3 500 otherG5 5 % glass 1.161.22 85 2 500 2.5 110G15 15 % glass 1.201.28 110 4 200 4 180G25 25 % glass 1.281.36 135 5 000 6.5 190G30 30 % glass 1.321.40 150 7 000

48、7.5 190G35 35 % glass 1.361.44 155 7 500 8 190G45 45 % glass 1.461.54 175 10 000 10 190G50 50 % glass 1.521.60 175 10 000 10 190G65 65 % glass 1.701.78 175 13 000 10 200G00 otherM30 30 % mineral 1.301.40 70 3 200 2.4 50M35 35 % mineral 1.391.47 70 3 500 3 60M40 40 % mineral 1.441.52 75 4 500 4 70M00

49、 otherR20 20 % glass/mineral1.251.33 80 3 200 2.5 120R40 40 % glass/mineral1.421.50 100 6 000 3 180R00 other3 Nucleated 1 100 1.121.14 70 2 300 2.5 502 135 1.121.14 70 2 300 2.5 503 150 1.121.15 75 2 300 2.5 504 200 1.121.15 80 2 300 2.5 500 other4 Nucleated and Heat-Stabilized1 100 1.121.14 70 2 300 2.5 502 135 1.121.14 70 2 300 2.5 503 150 1.121.15 75 2 300 2.5 504 200 1.121.15 80 2 300 2.5 507 recycled 135 1.121.14 70 2 100 2.5 500 other5 Impact-Modified 1