BS EN 14369-2015 Products used for treatment of water intended for human consumption Iron-coated granular activated alumina《人类用水处理用制品 覆铁粒状活性铝》.pdf

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1、BSI Standards PublicationBS EN 14369:2015Products used for treatment of water intended for humanconsumption - Iron-coated granular activated aluminaBS EN 14369:2015 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 14369:2015. It supersedes BS EN 14369:2003 which

2、is withdrawn. The UK participation in its preparation was entrusted to TechnicalCommittee CII/59, Chemicals for drinking water treatment.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprov

3、isions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2015. Published by BSI Standards Limited 2015ISBN 978 0 580 87329 4ICS 13.060.20; 71.100.80Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard w

4、as published under the authority of theStandards Policy and Strategy Committee on 30 April 2015.Amendments/corrigenda issued since publicationDate T e x t a f f e c t e dBS EN 14369:2015EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 14369 April 2015 ICS 71.100.80 Supersedes EN 14369:2003Englis

5、h Version Products used for treatment of water intended for human consumption - Iron-coated granular activated alumina Produits utiliss pour le traitement de leau destine la consommation humaine - Alumine active en grains revtue de fer Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauc

6、h - Eisenumlagertes granuliertes aktiviertes Aluminiumoxid This European Standard was approved by CEN on 12 March 2015. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without

7、 any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other lan

8、guage made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denma

9、rk, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE

10、FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 14369:2015 EBS EN 14369:2015EN

11、14369:2015 (E) 2 Contents page Foreword 4 Introduction . 5 1 Scope 6 2 Normative references 6 3 Terms, definitions and symbols . 6 4 Description . 6 4.1 Identification . 6 4.1.1 Chemical name . 6 4.1.2 Synonym or common name 6 4.1.3 Chemical formula . 6 4.1.4 CAS Registry number 6 4.1.5 EINECS refer

12、ence 7 4.2 Commercial form . 7 5 Physical properties 7 5.1 Appearance 7 5.2 Particle size distribution . 7 5.3 Bulk density packed 7 6 Chemical properties 7 7 Specific properties. 8 8 Test methods 8 8.1 Sampling . 8 8.2 Analysis 8 8.2.1 Particle size distribution . 8 8.2.2 Bulk density packed 8 8.2.

13、3 Surface area . 8 9 Labelling, transportation and storage . 8 9.1 Means of delivery . 8 9.2 Labelling according to the EU legislation . 9 9.3 Transportation regulations and labelling 9 9.4 Marking . 9 9.5 Storage 9 9.5.1 Long term chemical stability 9 9.5.2 Storage incompatibilities 9 Annex A (info

14、rmative) General information on iron-coated granular activated alumina 10 A.1 Origin 10 A.1.1 Raw materials . 10 A.1.2 Manufacturing process . 10 A.2 Typical properties 10 A.2.1 Chemical composition 10 A.2.2 Physical properties 10 A.2.2.1 Particle size range . 10 BS EN 14369:2015EN 14369:2015 (E) 3

15、A.2.2.2 Density 11 A.2.2.3 Adsorption properties . 11 A.3 Hydraulic characteristics 11 A.3.1 Headloss in filtration . 11 A.3.2 Expansion during upflow washing 11 A.4 Use 11 A.4.1 Function 11 A.4.2 Treatment dose 11 A.4.3 Method of use 12 A.5 Rules for safe handling and use 12 A.6 Emergency procedure

16、s . 12 A.6.1 First aid . 12 A.6.2 Spillage . 12 A.6.3 Fire 12 Bibliography 13 BS EN 14369:2015EN 14369:2015 (E) 4 Foreword This document (EN 14369:2015) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be give

17、n the status of a national standard, either by publication of an identical text or by endorsement, at the latest by October 2015, and conflicting national standards shall be withdrawn at the latest by October 2015. Attention is drawn to the possibility that some of the elements of this document may

18、be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 14369:2003. The main technical difference between this edition and EN 14369:2003 is the updating of 9.2 in line with current legislation. Accor

19、ding to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany,

20、 Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 14369:2015EN 14369:2015 (E) 5 Introduction In respect of potential adverse effects on

21、the quality of water intended for human consumption caused by the product covered by this European Standard: a) this European Standard provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA; b) it should be noted that, while aw

22、aiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of this product remain in force. NOTE Conformity with this standard does not confer or imply acceptance or approval of the product in any of the Member States of the EU or

23、 EFTA. The use of the product covered by this European Standard is subject to regulation or control by National Authorities. BS EN 14369:2015EN 14369:2015 (E) 6 1 Scope This European Standard is applicable to iron-coated granular activated alumina used for treatment of water intended for human consu

24、mption. It describes the characteristics of iron-coated granular activated alumina and specifies the requirements and the corresponding test methods for iron-coated granular activated alumina. It gives information on its use in water treatment. 2 Normative references The following documents, in whol

25、e or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 12901:1999, Products used for treatm

26、ent of water intended for human consumption Inorganic supporting and filtering materials Definitions EN 12902, Products used for treatment of water intended for human consumption Inorganic supporting and filtering materials Methods of test ISO 9277, Determination of the specific surface area of soli

27、ds by gas adsorption BET method 3 Terms, definitions and symbols For the purposes of this document, the terms, definitions and symbols given in EN 12901:1999 apply. 4 Description 4.1 Identification 4.1.1 Chemical name Aluminium oxide (partially hydroxylated) coated with iron. 4.1.2 Synonym or common

28、 name None. 4.1.3 Chemical formula Al2O(3-x)(OH)2x+ Fe(OH)3x ranges from almost zero to 0,80. 4.1.4 CAS Registry number1)Activated alumina: 1344-28-1. Iron(III) sulfate: 10028-22-5. 1)Chemical Abstracts Service Registry Number. BS EN 14369:2015EN 14369:2015 (E) 7 4.1.5 EINECS reference2)Activated al

29、umina: 215-691-6. Iron(III) sulfate: 233-072-9. 4.2 Commercial form Iron-coated activated alumina is a granular product consisting of irregularly shaped (non-moulded) particles; the product is available in different particle sizes. 5 Physical properties 5.1 Appearance The product consists of brown p

30、articles of irregular shape. The product shall be generally homogeneous and shall be visibly free of extraneous matter. 5.2 Particle size distribution The particle size distribution shall be described by either; a) effective size (d10) with a maximum deviation of 5 %; uniformity coefficient (U) less

31、 than 1,5; minimum size (d1) with a maximum deviation of 5 %. or b) particle size range and mass fraction of oversize and undersize particles; see A.2.2.1. The proportion of oversize plus undersize particles shall not exceed a mass fraction of 15 % and not more than a mass fraction of 5 % shall be u

32、ndersized. NOTE 1 The particle size can decrease during transportation and handling. NOTE 2 Other values can be necessary for certain applications. 5.3 Bulk density packed The bulk density (packed) shall be greater than 600 kg/m3. 6 Chemical properties This European Standard specifies the minimum pu

33、rity requirements for iron-coated granular activated alumina used for the treatment of water intended for human consumption. Limits are given for impurities commonly present in the product. Depending on the raw material and the manufacturing process other impurities may be present and, if so, this s

34、hall be notified to the user and when necessary to relevant authorities. 2)European Inventory of Existing Commercial Chemical Substances. BS EN 14369:2015EN 14369:2015 (E) 8 Users of this product should satisfy themselves that it is of appropriate purity for treatment of water intended for human con

35、sumption, taking into account raw water quality, contents of other impurities and additives used in the products not stated in the product standard, and other relevant factors. Limits have been given for impurities and chemical parameters where these are likely to be present in significant quantitie

36、s from the current production process and raw materials. If the production process or raw materials lead to significant quantities of impurities, by-products or additives being present, this shall be notified to the user. After filling, washing and commissioning of a filter system producing drinking

37、 water, iron-coated activated alumina should not increase the concentrations of chemical parameters (see 1). NOTE Water extractable substances, determined in accordance with the method for granular materials given in EN 12902, can be used to estimate the leaching of the chemicals specified in EN 129

38、02. 7 Specific properties The surface area shall be not less than 200 m2/g. 8 Test methods 8.1 Sampling Prepare the laboratory sample required by the relevant procedures described in EN 12902. 8.2 Analysis 8.2.1 Particle size distribution The particle size distribution shall be determined on samples

39、 taken at the point of manufacture using the method of test given in EN 12902. 8.2.2 Bulk density packed The bulk density packed shall be determined in accordance with EN 12902. 8.2.3 Surface area The surface area shall be determined by the BET method, degassing at a maximum of 200 C, in accordance

40、with ISO 9277. 9 Labelling, transportation and storage 9.1 Means of delivery Iron-coated granular activated alumina shall be delivered in bulk (dry or wet product), in semi-bulk containers or in drums of cardboard, plastics or steel or suitable bags of various sizes. In order that the purity of the

41、product is not affected, the means of delivery shall not have been used previously for any different product or it shall have been specially cleaned and prepared before use. BS EN 14369:2015EN 14369:2015 (E) 9 9.2 Labelling according to the EU legislation Iron-coated granular activated alumina is no

42、t listed within Annex VI of Regulation (EC) No 1272/2008 at the date of publication of this European Standard. The legislation 2 contains a list of substances classified by the EU. Substances not listed in this regulation should be classified on the basis of their intrinsic properties according to t

43、he criteria in the regulation by the person responsible for the marketing of the substance. 9.3 Transportation regulations and labelling Iron-coated granular activated alumina is not classified as dangerous for transportation by road, rail, sea or air. Iron-coated granular activated alumina is not l

44、isted under a UN number3). 9.4 Marking The marking shall include the following: name “Iron-coated Granular Activated Alumina”, trade name and grade; net mass; name and the address of the supplier and/or manufacturer; statement “This product conforms to EN 14369”. 9.5 Storage 9.5.1 Long term chemical

45、 stability The product is stable and can be stored for a period of at least two years. 9.5.2 Storage incompatibilities Keep away from moisture, strong acids or strong alkalis, solvents and odorous products. 3) United Nations number.BS EN 14369:2015EN 14369:2015 (E) 10 Annex A (informative) General i

46、nformation on iron-coated granular activated alumina A.1 Origin A.1.1 Raw materials Granular activated alumina is produced from aluminium hydroxide. Following manufacture of the high surface area granular activated alumina, conforming to EN 13753 (see 3), is coated with iron using iron(III) sulfate

47、conforming to EN 890 (see 4). A.1.2 Manufacturing process Activated alumina is prepared by the calcination of aluminium hydroxide. Granular activated alumina can be prepared by granulation of activated alumina powder or calcination of aluminium hydroxide granules. Iron-coated activated alumina is pr

48、epared by coating of granules of activated alumina with insoluble iron using a solution of iron(III) sulfate. A.2 Typical properties A.2.1 Chemical composition Activated alumina is a partially calcined aluminium trihydroxide with a combined water content of mass fraction between 5 % and 6 %. The cry

49、stal structure is predominantly gamma or chi alumina; small amounts of other forms can be present. The crystal structure can be determined by X-ray diffraction. The chemical composition depends on the origin of the raw material. Typical limits are given in Table A.1, the remainder being Al2O3. Table A.1 Typical chemical composition of iron-coated granular activated alumina Parameter Mass fraction of the product, % Water (loss on ignition) 17 Na2O 0,5 Fe2O3 6 SiO2 0,02 TiO2 0,002 A.2.2 Physical properties A.2.2.1 Particle size ran