KS K 0734-2012 Test method for determination of arylamines content in polyester textiles《聚酯纤维制品中芳基胺含量测定方法》.pdf

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1、 KSKSKSKSKSKSKSK KSKSKS KSKSK KSKS KSK KS KS K 0734 KS K 0734:2012 2012 11 12 http:/www.kats.go.krKS K 0734:2012 : ( ) ( ) () FITI ( ) : (http:/www.standard.go.kr) ： ：2002 11 9 ：2012 11 12 2012-0604 ： ： ( 02-509-7278) (http:/www.kats.go.kr). 10 5 , . KS K 0734:2012 Test method for determination of a

2、rylamines content in polyester textiles 1 . 2 . . ( ) . KS M ISO 3696, KS M ISO 6353 2, 2： 1 KS M ISO 6353 3, 3： 2 3 , , (Na2S2O4) (Gas chromatography mass spectrometry) . (Thin layer chromatography) . 4 4.1 4.1.1 (Gas chromatoraphy mass spectroscopy) 40, 250, 20/min, , 1 mL/min, 270, 1 L . HP 5MS(

3、40 m, 0.25 mm) . 4.1.2 (Thin layer chromatography) 4.2 KS K 0734:2012 2 4.2.1 , KS M ISO 3696 4.2.2 3- (t-C5H12O), 4.2.3 n- (C6H14), 4.2.4 (CH3OH), KS M ISO 6353 2(R 18) . 4.2.5 (Na2S2O4) , 60 g (Na2S2O4) 400 mL . . 4.2.6 (C6H8O7) , 90.164 g (Na2HO4P) 48.718 g (C6H8O7) 5 L . 4.2.7 (Na2SO4), KS M ISO

4、 6353 2(R 35) . 4.2.8 4.2.9 , KS M ISO 6353 3(R 95) . 4.2.10 a) (5 000 mg/L) 1 0.25 g . . 50 mL . b) (100 mg/L) 100 mL 24 4.2.10 a) 2 mL 3- (4.2.2) . 4 . c) (4 mg/L) 100 mL 100 mg/kg 4.2.10 b) 4 mL 3- . . d) (6 mg/L) 100 mL 100 mg/kg 4.2.10 b) 6 mL 3- . . e) (9 mg/L) 100 mL 100 mg/kg 4.2.10 b) 9 mL

5、3- . . 4.2.11 60(20 cm20 cm), 4.2.12 (CH6COOH), KS M ISO 6353 2(R1) . 4.2.13 (NaNO2), 4.2.14 (C6H12O2), 4.2.15 (C6H6CH6), KS M ISO 6353 2(R 39) . 4.2.16 1- (C10H8O), 4.2.17 / (30： 70), 60 mL KS K 0734:2012 3 140 mL . 4.2.18 , 100 mL 1- . 4.2.19 (200 mg/kg), 100 mL 4 mL 3- . 4 . 5 5.1 5 mm5 mm , (2.0

6、0.2) g 50 mL . 5.2 (2.00.2) g 250 mL . 6 6.1 (4-Aminoazobenzene ) a) 5. 25 mL 25 min 25 mL 45 min . b) . c) , . d) 2 mL . e) 70 (4.2.6) 30 mL 30 min . f) 70 30 min . g) 6 mL (4.2.5) (302) min . h) 2 min 50 mL . . . i) 20 mL 3- . j) 15 20 s . k) 3 (4.2.7) . , 3- . l) 3- . 6.2 4-Aminoazobenzene a) 5.

7、25 mL 55 min . KS K 0734:2012 4 b) . c) , . d) 2 mL . e) 2 % NaOH 9 mL (200 mg/mL) 1 mL (402) 30 min . f) 3 min NaCl 7 g , 5 mL 3- 45 min 5 /s . 3- . 1 CAS a1 4- (4-Aminodiphenyl) 92 67 1 2 (Benzidine) 92 87 5 3 4- (4-Chloro-o-toluidine) 95 69 2 4 2- (2-Naphthylamine) 91 59 8 5 (o-Aminoazotoluene) 9

8、7 56 3 6 2- 4- (4-Amino-4-nitrotoluene) 99 55 8 7 - (4-Chloroaniline) 106 47 8 8 2,4- (4- 1,3- ) 2,4-Diaminoanisole(4-Methoxy-1,3-Phenylenediamin) 615 05 4 9 4,4- (4,4-Diaminobiphenylmethane) 101 77 9 10 3,3- (3,3-Dichlorobenzidin) 91 94 1 11 3,3- (3,3-Dimethoxybenzidin) 119 90 4 12 3,3- (3,3-Dimeth

9、ylbenzidin) 119 93 7 13 3,3- 4,4- (3,3-Dimethyl-4,4-Diaminobiphenylmethane) 838 88 0 14 - (2- 5- ) p-Kresidin(2-Methoxy-5-Methylaniline) 120 71 8 15 4,4- (2- ) 4,4-Methylene-Bis-(2-Chloroaniline) 101 14 4 16 4,4- (4,4-Oxydianiline) 101 80 4 17 4,4- (4,4-Thiodianiline) 139 65 1 18 - (o-Toluidine) 95

10、53 4 19 2,4- (2,4-Toluylenediamine) 95 80 7 20 2,4,5- (2,4,5-Trimethylaniline) 137 17 7 21 - (o-Anisdine) 90 04 0 22 2,4- (2,4-Xylidine) 95 68 1 23 2,6- (2,6-Xylidine) 87 62 7 24b4- (4-Aminoazobenzene) 60 09 3 aCAS (Chemical Abstract Service) b6.1 (4-Aminoazobenzene ) Aniline 1,4-diphenylenediamine

11、, 6.2 4-Aminoazobenzene . KS K 0734:2012 5 6.3 6.3.1 a) 4.2.10 c) e) 1 L . b) . c) (o-toluidine), 2- (2-naphthylamine) (p-chloroaniline) . 6.4 a) 2 6 mm . 10 mm ( 16 mm) . b) 200 mg/kg (4.2.19) 6 L . c) 200 600 L . d) 2 . e) 1 160 mm (4.2.17) . f) NOx1) 10 (4.2.18) . g) . . 7 (mg/kg)WVA A ： GC (mg/L

12、) V ： 6. 3- (mL) W ： (g) 8 8.1 (mg/kg) 8.2 1) 20 mL 2 NOx . 153787 1 92 3(13) (02)26240114 (02)262401489 http:/ KS K 0734:2012 KSKSKS SKSKS KSKS SKS KS SKS KSKS SKSKS KSKSKS Test method for determination of arylamines content in polyester textiles ICS 59.020 Korean Agency for Technology and Standards http:/www.kats.go.kr