GMKOREA EDS-M-4311-2008 PHENYL MALEIMIDE ACRYLONITRILE-BUTADIENE-STYRENE COPOLYMER (VERSION 6).pdf

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1、GM DAEWOO Auto & Technology EDS Engineering, GM DAEWOO Auto & Technology Standards PHENYL MALEIMIDE ACRYLONITRILE-BUTADIENE-STYRENE COPOLYMER EDS-M-4311 ISSUED DATE: 1996. 08. 16 REVISED DATE: 2008. 03. 26 VERSION: 6 EDS-M-4311PHENYL MALEIMIDE ACRYLONITRILE-BUTADIENE-STYRENE COPOLYMER PAGE: 1/4 ISSU

2、ED DATE: 1996. 08. 16 REVISED DATE: 2008. 03. 26 VERSION: 6 GM DAEWOO Auto & Technology 1. PURPOSE This specification defines general requirements for raw materials of PMI-ABS:Phenylmaleimide Acrylonitrile Butadiene Styrene applied to interior and exterior parts of a vehicle. 2. SCOPE This specifica

3、tion shall be applied to raw materials of PMI-ABS:Phenylmaleimide Acrylonitrile Butadiene Styrene used in all passenger cars by GM DAEWOO Auto & Technology Company(hereinafter referred to as the “GMDAT“). 3. DEFINITION OF TERMS 3.1. PMI-ABS types: As Acrylonitrile Butadiene Styrene of Phenylmaleimid

4、e group, this ABS has been improved in aspect of heat resistance by adding and replacing of Phenylmaleimide in previous -Methyl Styrene. 4. MATERIAL INDICATION Material indication: ABS Detailed contents shall conform to the indication method of synthetic resin materials for vehicles.(Spec. No: GMW31

5、16) 5. APPLICATION 5.1. Group 1: Ultrahigh heat resistance raw materials which have heat deflection temperature of 120 or higher. 5.1.1. Type 1: Raw materials which the heat resistance has especially been improved by adding of PMI heat-resistance material Ex) Door Garnish, Speaker Grille 5.1.2. Type

6、 2: Raw materials which the heat resistance has especially been improved by adding of PMI heat-resistance material & the toughness and mechanical properties have especially been improved by blending a small quantity of Polycarbonate. Ex) Back Panel-Deposit Box 5.2. Group 2: Super heat and impact res

7、istance raw materials which have heat deflection temperature of 110 or higher. 5.2.1. Type 1: Raw materials which the heat and impact resistance have been improved by adding of PMI heat-resistance material Ex) Defroster Grille 5.2.2. Type 2: Raw materials which the heat resistance has been improved

8、by adding of PMI heat-resistance material and the impact-resistance properties has been improved by blending a small quantity of Polycarbonate. Ex) Cup holder, Defroster Grille EDS-M-4311PHENYL MALEIMIDE ACRYLONITRILE-BUTADIENE-STYRENE COPOLYMER PAGE: 2/4 ISSUED DATE: 1996. 08. 16 REVISED DATE: 2008

9、. 03. 26 VERSION: 6 GM DAEWOO Auto & Technology 5.3. Group 3: High heat and impact resistance raw materials which have heat deflection temperature of 100 or higher. 5.3.1. Type 1: Raw materials which the heat resistance has been improved by adding of PMI heat-resistance material and the impact-resis

10、tance properties has been improved by using base material with High-rubber ABS. Ex) I/P Center Molding 5.3.2. Type 2: Raw materials which the heat resistance has been improved by adding of PMI heat-resistance material and the impact-resistance and mechanical properties have been improved by adjustin

11、g of Polycarbonate content. Ex) I/P Center Molding, I/P LWR type Notice to Use Parts which were molded using this specification material can be damaged as contacted by foam, rubber, seal, PVC products with plasticizer such as DOP, DOA, etc., because contacted parts can be chemically cracked by plast

12、icizers migration. So the use of product must be avoided in case of contact. But, if the contact is necessary, surface treatment methods such as painting with clear coat, coated gold, etc must be used to prevent chemical crack by plasticizers migration. # Phthalic Acid Ester plasticizer: DOP(Di-Octy

13、l Phathalate), DBP(Di -Butyl Phathalate), etc # Aliphatic Acid Ester plasticizer: DOA(Di 2-ethyl- hexyl Adipate), etc 6. REQUIREMENTS 6.1. Mechanical properties Group 1 Group 2 Group 3 Type 1 Type 2 Type 1 Type 2 Type 1 Type 2Rockwell hardness EDS-T-7517 R Scale 100 110 100 110 100 110 Tensile stren

14、gth (kg/ ) EDS-T-7511 Test piece(133mm) Test speed(5mm/min) 430 450 430 430 380 400 Elongation (%) EDS-T-7511 Test piece(133mm) Test speed(5mm/min) 20 20 20 30 30 40 Flexural strength (kg/ ) EDS-T-7518 Test piece(12712.76.4mm)Test speed(2.8mm/min) 650 680 650 650 630 650 Flexural modulus (kg/ ) EDS-

15、T-7510 Test piece(12712.76.4mm)Test speed(2.8mm/min) 21,000 23,000 20,000 21,000 18,000 20,000EDS-M-4311PHENYL MALEIMIDE ACRYLONITRILE-BUTADIENE-STYRENE COPOLYMER PAGE: 3/4 ISSUED DATE: 1996. 08. 16 REVISED DATE: 2008. 03. 26 VERSION: 6 GM DAEWOO Auto & Technology Group 1 Group 2 Group 3 Type 1 Type

16、 2 Type 1 Type 2 Type 1 Type 2Impact strength, IZOD (kg cm/cm) EDS-T-7514 Test piece(63.512.73.2mm)Room temperature -30 10 3 10 3 15 3 20 3 25 3 35 3 6.2. Thermal properties Heat deflection temperature () EDS-T-7520 Test piece(12712.76.4mm)18.6kg/cm2120 120 110 110 100 100 6.3. General properties De

17、nsity (g/cm3) EDS-T-7406 1.06 0.011.04 0.011.06 0.01 1.04 0.01 1.06 0.011.04 0.01Melt flow index(g/10 min) EDS-T-7516 230, 21.6kg 8 10 15 20 30 30 Note) All the mechanical, thermal and general property values above indicate minimum values except having specified ranges. 7. TEST PIECE AND TEST 7.1. T

18、est piece Test pieces shall be prepared with injection molding. Unless otherwise specified in the requirements of clause 6, they shall be conditioned at 235K and a relative humidity of 50% for 24 hours or more. 7.2. Test Tests shall be performed at 235K and a relative humidity of 50%. 8. APPROVAL OF

19、 RAW MATERIALS 8.1. Approved raw materials Division Approved suppliers Approved raw materials Remark Type 1 CHEIL industries INC SR0360M Group 1 Type 2 KUMHO Petrochemical Co., Ltd. HGX-4500 Type 1 CHEIL industries INC, LG Chemical SR0350M, XR475 Group 2 Type 2 KUMHO Petrochemical Co., Ltd. HGX-4302

20、 Type 1 CHEIL industries INC, LG Chemical, KUMHO Petrochemical Co., Ltd. SR0321M, XR454, HGX-4303D Group 3 Type 2 KUMHO Petrochemical Co., Ltd. HGX-4303 EDS-M-4311PHENYL MALEIMIDE ACRYLONITRILE-BUTADIENE-STYRENE COPOLYMER PAGE: 4/4 ISSUED DATE: 1996. 08. 16 REVISED DATE: 2008. 03. 26 VERSION: 6 GM D

21、AEWOO Auto & Technology 8.2. Approval and quality assurance procedure All raw materials shall be approved and regularly inspected for its quality prior to and during mass production delivery according to approval and quality assurance procedure for chemical raw materials (Spec. No. EDS-M-0102). 9. A

22、UTOMOTIVE RESTRICTED HAZARDOUS SUBSTANCES Materials and components of parts must comply with GMW3059. 10. OTHERS 10.1. Coding system Material specification of raw materials shall be indicated in drawings as follows. EDS-M-4311 - Required property type (clause 5) Material group (clause 5) Material sp

23、ecification number 11. RELATED STANDARDS EDS-M-0102 Procedures for approval of chemical raw material and quality control EDS-T-7406 Determination of volume and density of elastomers EDS-T-7510 Testing of plastics determination of the modulus of elasticity by tensile, compression and flexural test ED

24、S-T-7511 Test method for the tensile property of plastics EDS-T-7514 Test method for determining the flexural strength of plastics EDS-T-7516 The test method for the melt flow index of thermoplastics EDS-T-7517 The test method for Rockwell hardness of plastics EDS-T-7518 The method for the flexural strength of plastics EDS-T-7520 Test for deflection temperature of plastics under load GMW 3059 Restricted and reportable substance for parts GMW 3116 Recyclability / recoverability guidelines