EN 12878-2014 en Pigments for the colouring of building materials based on cement and or lime - Specifications and methods of test《混凝土和 或石灰基建筑材料着色用颜料 规格和试验方法》.pdf

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1、BSI Standards PublicationBS EN 12878:2014Pigments for the colouringof building materials basedon cement and/or lime Specifications and methods oftestBS EN 12878:2014 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 12878:2014. It supersedes BS EN 12878:2005 which

2、 is withdrawn.The UK participation in its preparation was entrusted to Technical Committee STI/1, Pigments.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users

3、are responsible for its correct application. The British Standards Institution 2014.Published by BSI Standards Limited 2014ISBN 978 0 580 77305 1ICS 87.060.10; 91.100.10Compliance with a British Standard cannot confer immunity from legal obligations.This British Standard was published under the auth

4、ority of the Standards Policy and Strategy Committee on 30 April 2014.Amendments/corrigenda issued since publicationDate T e x t a f f e c t e dBS EN 12878:2014EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 12878 April 2014 ICS 87.060.10; 91.100.10 Supersedes EN 12878:2005English Version Pigme

5、nts for the colouring of building materials based on cement and/or lime - Specifications and methods of test Pigments de coloration des matriaux de construction base de ciment et/ou de chaux - Spcifications et mthodes dessai Pigmente zum Einfrben von zement- und/oder kalkgebundenen Baustoffen - Anfo

6、rderungen und Prfverfahren This European Standard was approved by CEN on 4 January 2014. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lis

7、ts and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under

8、 the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yu

9、goslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROP

10、EN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2014 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 12878:2014 EBS EN 12878:2014EN 12878:2014 (E) 2 Contents Page

11、Foreword 4 1 Scope 5 2 Normative references 5 3 Terms and definitions .6 4 Requirements .7 4.1 Effects on concrete properties .7 4.1.1 General 7 4.1.2 Setting time 7 4.1.3 Compressive strength .7 4.2 Composition .7 4.2.1 General 7 4.2.2 Constitution of pigments 8 4.2.3 Water soluble substances 8 4.2

12、.4 Soluble chloride .8 4.2.5 Total chlorine .8 4.3 Loss on ignition .8 4.4 Emission of radioactivity 9 4.5 Release of dangerous substances .9 4.6 Relative colour strength 9 4.7 Residue on sieve9 4.8 pH value 9 4.9 Alkali stability .9 4.10 Resistance to weathering .9 4.11 Thermal stability 9 4.12 Col

13、our comparison against standard pigment .9 5 Test methods . 10 5.1 Effect on concrete properties 10 5.1.1 Setting time . 10 5.1.2 Compressive strength 10 5.2 Composition 10 5.2.1 General . 10 5.2.2 Composition of the pigments 10 5.2.3 Water soluble substances . 10 5.2.4 Soluble chloride 10 5.2.5 Tot

14、al chlorine 10 5.3 Loss on ignition 11 5.4 Emission of radioactivity . 11 5.5 Release of dangerous substances 11 5.6 Relative colour strength . 11 5.6.1 General remarks 11 5.6.2 Relative colour strength in barytes or white Portland cement CEM I (dry mix) . 12 5.6.3 Determination of relative colour s

15、trength in barytes (wet mix) . 13 5.6.4 Determination of relative colour strength in white Portland cement mortar (wet mix) . 13 5.7 Residue on sieve. 14 5.8 pH value . 14 5.9 Alkali stability 15 5.9.1 General remarks 15 BS EN 12878:2014EN 12878:2014 (E) 3 5.9.2 Preparation of test pieces. 15 5.9.3

16、Test procedure . 15 5.10 Resistance to weathering . 15 5.11 Thermal stability 16 5.12 Colour comparison against the standard pigment 16 5.12.1 General . 16 5.12.2 Equipment and test materials 16 5.12.3 Mortar formulation: . 17 5.12.4 Test procedure . 17 5.12.5 Evaluation of test . 17 6 Assessment an

17、d verification of constancy of performance AVCP . 18 6.1 General . 18 6.2 Sampling. 18 6.3 Conformity criteria 18 6.4 Product type determination 18 6.5 Factory production control. 19 6.5.1 Concept 19 6.6 Internal quality control 22 6.6.1 Process control . 22 6.6.2 Measuring and testing 22 6.6.3 Hand

18、ling, storage, packaging and delivery 22 6.7 Frequency of inspections . 22 A.1 Reference to 5.6.2 “Relative colour strength in barites white Portland cement CEM I (dry mix)” and 5.6.3 “Determination of relative colour strength in barytes (wet mix)” 23 A.2 Reference to 5.9 “Alkali stability” 23 A.3 R

19、eference to 5.10 “Resistance to weathering” 23 Annex ZA (informative) Clauses of this European Standard addressing the provisions of the EU Construction Products Regulation 24 ZA.1 Scope and relevant characteristics . 24 ZA.2 Procedure for AVCP of pigments for use in the colouring of building materi

20、als based on cement and cement/lime combinations 25 ZA.2.1 Systems of Assessment and verification of constancy of performance (AVCP) . 25 ZA.2.2 Declaration of performance (DoP) . 26 ZA.2.2.1 General 26 ZA.2.2.2 Content 26 ZA.2.2.3 Example of DoP 27 ZA.3 CE marking and labelling 28 Bibliography 30 B

21、S EN 12878:2014EN 12878:2014 (E) 4 Foreword This document (EN 12878:2014) has been prepared by Technical Committee CEN/TC 298 “Pigments and extenders”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identi

22、cal text or by endorsement, at the latest by October 2014 and conflicting national standards shall be withdrawn at the latest by January 2016. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held re

23、sponsible for identifying any or all such patent rights. This document supersedes EN 12878:2005. This document has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association, and supports essential requirements of the Construction Production Regulat

24、ion (CPR). For relationship with the Construction Production Regulation, see informative Annex ZA, which is an integral part of this document. EN 12878:2005 has been technically revised as follows: a) requirements for Category B regarding water soluble substances in 4.2.3 modified to accommodate non

25、 powder preparations; b) test method for total chlorine content (5.2.5) changed; c) permission to use alternative test methods with proven correlation to standard methods added; d) light source amended; e) Annex ZA has been changed to consider the new Construction Production Regulation (CPR). Accord

26、ing to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany,

27、Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 12878:2014EN 12878:2014 (E) 5 1 Scope This European Standard specifies the requirements

28、 and the methods of test for pigments for use in the colouring of building materials based on cement and cement/lime combinations. Pigments covered by this European Standard may also be used in pure lime mortar. For this application, see EN 459-1 and EN 459-2. Pigments for this purpose may be single

29、 pigments, blends of pigments, or blends of pigments and extenders, in powder or granular form, or aqueous preparations. Pigments typically belong to one of the following classes of compounds: synthetic or natural oxides and hydroxides of iron; oxides of chromium, titanium and manganese; complex ino

30、rganic pigments, for example combinations of the above mentioned metal oxides and hydroxides with cobalt, aluminium, nickel and antimony oxides and hydroxides; ultramarine pigments; phthalocyanine blue and green; elemental carbon (shall be regarded as an inorganic pigment); blends of the above mater

31、ials (which may also include extenders). 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the

32、 referenced document (including any amendments) applies. EN 196-1:2005, Methods of testing cement - Part 1: Determination of strength EN 196-3, Methods of testing cement - Part 3: Determination of setting times and soundness EN 197-1, Cement - Part 1: Composition, specifications and conformity crite

33、ria for common cements EN 934-1:2008, Admixtures for concrete, mortar and grout - Part 1: Common requirements EN ISO 787-3, General methods of test for pigments and extenders - Part 3: Determination of matter soluble in water - Hot extraction method (ISO 787-3) EN ISO 787-7, General methods of test

34、for pigments and extenders - Part 7: Determination of residue on sieve - Water method - Manual procedure (ISO 787-7) EN ISO 787-9, General methods of test for pigments and extenders - Part 9: Determination of pH value of aqueous suspension (ISO 787-9) EN ISO 787-13, General methods of test for pigme

35、nts and extenders - Part 13: Determination of water-soluble sulfates, chlorides and nitrates (ISO 787-13) BS EN 12878:2014EN 12878:2014 (E) 6 EN ISO 15528, Paints, varnishes and raw materials for paints and varnishes - Sampling (ISO 15528) ISO 9277, Determination of the specific surface area of soli

36、ds by gas adsorption - BET method 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 pigment substance, generally in the form of fine particles, which is practically insoluble in the application medium and whose sole purpose is to colour cement-

37、 and/or lime-based building materials 3.2 single pigment pigment that is of singular (chemical) composition Note 1 to entry: Single pigments contain no substances other than those originating from the pigment manufacturing process. Note 2 to entry: Surface treatment of the primary pigment particles

38、is considered as a part of the pigment manufacturing process. 3.3 pigment blend blend of at least two single pigments, or at least one single pigment and an extender 3.4 aqueous pigment preparation preparation in which a pigment (single pigment or pigment blend) is dispersed in water, with or withou

39、t a dispersion or other agent EXAMPLES of agents are: dispersants; binding agents (resins); solvents; wetting agents; or combinations thereof. 3.5 pigment in granular form preparation in which a pigment (single pigment or pigment blend) is converted into granules, by the use of the binding agent whi

40、ch retains the integrity of the granule 3.6 reference sample; standard pigment sample of a single pigment or a blend (powder, or preparation) retained by the interested parties for comparison for the evaluation of the product properties (e.g. colour) BS EN 12878:2014EN 12878:2014 (E) 7 3.7 extender

41、inorganic substance, generally in the form of fine particles, which is practically insoluble in the application medium and has no inherent colour properties 4 Requirements 4.1 Effects on concrete properties 4.1.1 General Pigments for steel reinforced concrete shall additionally meet all Category B r

42、equirements given in 4.1.3, 4.2.3 to 4.2.5. The inorganic pigment dosage shall be 5,0 % solids, carbon black and organic pigment dosage of 2,0 % solids, by mass, based on the cement amount for testing according 5.1. If a higher dosage of pigment is recommended the tests shall be carried out with tha

43、t dosage. The dosage in percent by mass shall be specified by the manufacturer. 4.1.2 Setting time 4.1.2.1 Initial setting time The initial setting time of cement with the single pigment or a blend (both as powder, granulate or preparation), determined in accordance with 5.1.1, shall be not less tha

44、n 60 min. The maximum difference between the initial setting time of mixes with and without the single pigment or a blend (both as powder, granulate or preparation) shall be not greater than 60 min. 4.1.2.2 Final setting time The final setting time of cement with the single pigment or a blend (both

45、as powder, granulate or preparation), determined in accordance with 5.1.1, shall not be longer than 720 min. The maximum difference between the final setting time of mixes with and without the single pigment or a blend (both as powder, granulate or preparation) shall be not greater than 120 min. 4.1

46、.3 Compressive strength The 28 day compressive strength of mixes with the single pigment or a blend (both as powder, granulate or preparation), determined in accordance with 5.1.2, shall not be reduced in comparison with the mix without pigment more than Category A: the manufacturers declared value;

47、 Category B: 8 %. 4.2 Composition 4.2.1 General The stability of a pigment with respect to colour shall be linked to the intended end use conditions. BS EN 12878:2014EN 12878:2014 (E) 8 The solids content, as a percentage (%) of aqueous preparations, shall be declared by the manufacturer. 4.2.2 Cons

48、titution of pigments The main constituents of the pigments are determined in accordance with 5.2.1 and 5.2.2. 4.2.3 Water soluble substances The content of water soluble substances, determined in accordance with 5.2.3, shall not be greater than Category A: the manufacturers declared value Category B

49、: 0,5 % by mass for single pigments and pigment blends. Where additives such as dispersion agents, binding agents and/or grinding aids are used for powder and non-powder preparations, their total water soluble content shall be equal to or less than 5,0 % (8 % for carbon black) by mass, based on solids. The used additives shall conform to EN 934-1:2008, Annex A.1. For pigment blends in powder form, evidence of compliance may be calculated from data recorded for constituent single pigments. 4.2.4 Soluble chloride The soluble chloride conten