BS ISO 10115-2013 Essential oil of tarragon (Artemisia dracunculus L )《龙嵩叶精油(狭叶青蒿Artemisia dracunculus L )》.pdf

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1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationEssential oil of tarragon(Artemisia dracunculus L.)BS ISO 10115:2013National forewordThis British Standard is the UK implementation of ISO 10115:2013.The UK participation in its

2、preparation was entrusted to Technical CommitteeAW/54, Essential oils.A list of organizations represented on this committee can be obtained onrequest to its secretary.This publication does not purport to include all the necessary provisions of acontract. Users are responsible for its correct applica

3、tion. The British Standards Institution 2013Published by BSI Standards Limited 2013ISBN 978 0 580 75062 5ICS 71.100.60Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of the StandardsPolicy and Strategy Committee

4、on 31 March 2013.Amendments issued since publicationAmd. No. Date Text affectedBRITISH STANDARDBS ISO 10115:2013 ISO 2013Essential oil of tarragon (Artemisia dracunculus L.)Huile essentielle destragon (Artemisia dracunculus L.)INTERNATIONAL STANDARDISO10115Second edition2013-02-01Reference numberISO

5、 10115:2013(E)BS ISO 10115:2013ISO 10115:2013(E)ii ISO 2013 All rights reservedCOPYRIGHT PROTECTED DOCUMENT ISO 2013All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including ph

6、otocopying, or posting on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below or ISOs member body in the country of the requester.ISO copyright officeCase postale 56 CH-1211 Geneva 20Tel. + 41 22 749 01 11Fax + 41 22 749 09

7、47E-mail copyrightiso.orgWeb www.iso.orgPublished in SwitzerlandBS ISO 10115:2013ISO 10115:2013(E) ISO 2013 All rights reserved iiiContents PageForeword iv1 Scope . 12 Normative references 13 Terms and definitions . 14 Specifications . 14.1 Appearance 14.2 Colour 14.3 Odour . 24.4 Relative density d

8、202024.5 Refractive index at 20 C . 24.6 Optical rotation at 20 C 24.7 Miscibility in ethanol 90 % (volume fraction) at 20 C 24.8 Acid value. 24.9 Chromatographic profile 24.10 Flashpoint 25 Sampling 36 Test methods . 36.1 Relative density d202036.2 Refractive index at 20 C . 36.3 Optical rotation a

9、t 20 C 36.4 Miscibility in 90 % (volume fraction) ethanol at 20 C 36.5 Acid value. 36.6 Chromatographic profile 37 Packaging, labelling, marking and storage . 3Annex A (informative) Typical chromatograms of the analysis by gas chromatography of the essential oil of tarragon (Artemisia dracunculus L.

10、) . 4Annex B (informative) Flashpoint . 7Bibliography 8BS ISO 10115:2013ISO 10115:2013(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out

11、through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO coll

12、aborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.The main task of technical committees is to prepare International Stan

13、dards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote.Attention is drawn to the possibility that some of the elements of

14、this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights.ISO 10115 was prepared by Technical Committee ISO/TC 54, Essential oils.This second edition cancels and replaces the first edition (ISO 10115:1997) which has been techni

15、cally revised.iv ISO 2013 All rights reservedBS ISO 10115:2013INTERNATIONAL STANDARD ISO 10115:2013(E)Essential oil of tarragon (Artemisia dracunculus L.)1 ScopeThis International Standard specifies certain characteristics of the essential oil of tarragon (Artemisia dracunculus L.), intended to faci

16、litate the assessment of its quality.2 Normative referencesThe following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments)

17、 applies.ISO/TR 210, Essential oils General rules for packaging, conditioning and storageISO/TR 211, Essential oils General rules for labelling and marking of containersISO 212, Essential oils SamplingISO 279, Essential oils Determination of relative density at 20 degrees C Reference methodISO 280,

18、Essential oils Determination of refractive indexISO 592, Essential oils Determination of optical rotationISO 875, Essential oils Evaluation of miscibility in ethanolISO 11024 (all parts), Essential oils General guidance on chromatographic profilesISO 1242, Essential oils Determination of acid value3

19、 Terms and definitionsFor the purposes of this document, the following terms and definitions apply.3.1essential oil of tarragonessential oil obtained by steam distillation of the leaves of tarragon (Artemisia dracunculus L.), of the Asteraceae familyNote 1 to entry: For information on the CAS number

20、, see ISO/TR 210922.4 Specifications4.1 AppearanceMobile, clear liquid.4.2 ColourColourless to pale yellow. ISO 2013 All rights reserved 1BS ISO 10115:2013ISO 10115:2013(E)4.3 OdourCharacteristic, with a hint of aniseed.4.4 Relative density d2020Minimum: 0,918.Maximum: 0,950.4.5 Refractive index at

21、20 CMinimum: 1,508.Maximum: 1,518.4.6 Optical rotation at 20 CBetween + 2 and + 6.4.7 Miscibility in ethanol 90 % (volume fraction) at 20 CIn order to obtain a clear solution with 1 volume of essential oil, no more than 4 volumes of ethanol 90 % (volume fraction) ethanol shall be required.4.8 Acid v

22、alueMaximum: 1.4.9 Chromatographic profileCarry out the analysis of the essential oil by gas chromatography. On the obtained chromatogram, identify the representative and characteristic components listed in Table 1 below. The percentage of each of these components, indicated by the integrator, shall

23、 be within the limits figuring in Table 1. This whole constitutes the “chromatographic profile” of the essential oil.Table 1 Chromatographic profileComponentMinimum Maximum% %-Pinene 0,5 2,0Limonene 2,0 7,0(Z)-Ocimene 5,0 13,0(E)-Ocimene 6,0 12,0Estragole 68,0 84,0Methyleugenol n.d.a 1,0NOTE The chr

24、omatographic profile is normative, contrary to typical chromatograms given for information in Annex A.aNot detectable.4.10 FlashpointInformation concerning the flashpoint is given in Annex B.2 ISO 2013 All rights reservedBS ISO 10115:2013ISO 10115:2013(E)5 SamplingSampling shall be performed in acco

25、rdance with ISO 212.Minimum volume of the test sample: 25 ml.NOTE This volume allows each of the tests specified in this International Standard to be carried out at least once.6 Test methods6.1 Relative density d2020Determine the relative density in accordance with ISO 279.6.2 Refractive index at 20

26、 CDetermine the refractive index in accordance with ISO 280.6.3 Optical rotation at 20 CDetermine the optical rotation in accordance with ISO 592.6.4 Miscibility in 90 % (volume fraction) ethanol at 20 CDetermine the miscibility in accordance with ISO 875.6.5 Acid valueDetermine the acid value in ac

27、cordance with ISO 1242.6.6 Chromatographic profileDetermine the chromatographic profile in accordance with ISO 11024.7 Packaging, labelling, marking and storageThese items shall be in accordance with ISO/TR 210 and ISO/TR 211. ISO 2013 All rights reserved 3BS ISO 10115:2013ISO 10115:2013(E)Annex A (

28、informative) Typical chromatograms of the analysis by gas chromatography of the essential oil of tarragon (Artemisia dracunculus L.)4 ISO 2013 All rights reservedBS ISO 10115:2013ISO 10115:2013(E)minPeak identification Operating conditions1 -Pinene Fused silica capillary column (HP-101) length 50 m,

29、 internal diameter 0,2 mm2 Limonene 100 % dimethylpolysiloxane3 (Z)-Ocimene Film thickness: 0,2 m4 (E)-Ocimene Oven temperature: programming temperature isothermal at 65 C for 5 min, then from 65 C to 95 C at the rate of 2 C/min, then isothermal at 95 C for 5 min, then from 95 C to 160 C at the rate

30、 of 2,5 C/min, then from 160 C to 200 C at the rate of 3 C/min, then isothermal at 20 C for 26 min5 Estragole Injector temperature: 230 C6 Eugenol Detector temperature: 250 C (flame ionization detector)7 Methyleugenol Carrier gas: hydrogenVolume injected: 0,2 lCarrier gas flow rate: 1,2 ml/min (cons

31、tant flow rate)Split ratio: 1/100NOTE HP-101 is an example of a suitable product available commercially. This information is given for the convenience of users of this International Standard and does not constitute an endorsement by ISO of this product.Figure A.1 Typical chromatogram taken on an apo

32、lar column ISO 2013 All rights reserved 5BS ISO 10115:2013ISO 10115:2013(E)minPeak identification Operating conditions1 -Pinene Fused silica capillary column (HP-20) length 50 m, internal diameter 0,2 mm2 Limonene Polyethyleneglycol, MW 200003 (Z)-Ocimene Film thickness: 0,1 m4 (E)-Ocimene Oven temp

33、erature: programming temperature isothermal at 65 C for 5 min, then from 65 C to 95 C at the rate of 2 C/min, then isothermal at 95 C for 5 min, then from 95 C to 160 C at the rate of 2,5 C/min, then from 160 C to 200 C at the rate of 3 C/min, then isothermal at 200 C for 26 min5 Estragole Injector

34、temperature: 230 C6 Eugenol Detector temperature: 250 C (flame ionization detector)7 Methyleugenol Carrier gas: hydrogenVolume injected: 0,2 lCarrier gas flow rate: 1,2 ml/min (constant flow rate)Split ratio: 1/100NOTE HP-20 is an example of a suitable product available commercially. This informatio

35、n is given for the convenience of users of this International Standard and does not constitute an endorsement by ISO of this product.Figure A.2 Typical chromatogram taken on a polar column6 ISO 2013 All rights reservedBS ISO 10115:2013ISO 10115:2013(E)Annex B (informative) FlashpointB.1 General info

36、rmationFor safety reasons, transporters, insurance companies, safety department officials, etc., insist on knowing the flashpoint of essential oils which, in most cases, are inflammable products.A comparative study of the appropriate methods of analysis (see ISO/TR 110181) found that it was difficul

37、t to standardize a single method, because: there is a very large number of essential oils and their chemical composition varies considerably; the sample volume recommended for use with certain appliances is incompatible with the high price of the essential oils; users cannot be under obligation to p

38、urchase one type of appliance rather than another from the moment that several appliances which can meet the desired objective exist.Consequently, it was decided to give a mean value for the flashpoint annexed to each research study, and solely by way of indication, in order to meet the request of t

39、he relevant departments.As far as possible, the method by which this value was obtained will be specified.For all additional information, see ISO/TR 110181.B.2 Flashpoint of the essential oil of tarragon (Artemisia dracunculus L.)The mean value is + 70 C.NOTE Value obtained using a Setaflash equipme

40、nt1).1) Equipment available commercially. This information is given for the convenience of users of this International Standard and does not constitute an endorsement by ISO of this product. ISO 2013 All rights reserved 7BS ISO 10115:2013ISO 10115:2013(E)Bibliography1 ISO/TR 11018:1997, Essential oi

41、ls General guidance on the determination of flashpoint2 ISO/TR 21092, Essential oils Characterization3 ISO 3218, Essential oils Principles of nomenclature8 ISO 2013 All rights reservedBS ISO 10115:2013This page deliberately left blankBSI is the independent national body responsible for preparing Bri

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