EN ISO TR 16178-2012 en Footwear - Critical substances potentially present in footwear and footwear components《鞋类 鞋类与其组件中潜在的重要物质》.pdf

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1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationPD CEN ISO/TR 16178:2012Footwear Critical substancespotentially present in footwearand footwear components(ISO/TR 16178:2012)PD CEN ISO/TR 16178:2012 PUBLISHED DOCUMENTNational f

2、orewordThis Published Document is the UK implementation of CEN ISO/TR 16178:2012. It supersedes PD CEN ISO/TR 16178:2010 which is withdrawn.The UK participation in its preparation was entrusted to Technical Committee TCI/69, Footwear, leather and coated fabrics.A list of organizations represented on

3、 this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2012. Published by BSI Standards Limited 2012ISBN 978 0 580 76485

4、1 ICS 61.060 Compliance with a British Standard cannot confer immunity from legal obligations.This Published Document was published under the authority of the Standards Policy and Strategy Committee on 30 September 2012.Amendments issued since publicationDate Text affectedTECHNICAL REPORT RAPPORT TE

5、CHNIQUE TECHNISCHER BERICHT CEN ISO/TR 16178 September 2012 ICS 61.060 Supersedes CEN ISO/TR 16178:2010English Version Footwear - Critical substances potentially present in footwear and footwear components (ISO/TR 16178:2012) Chaussures - Substances critiques potentiellement prsentes dans la chaussu

6、re et les composants de chaussures (ISO/TR 16178:2012) Schuhe - Mglicherweise in Schuhen und Schuhbestandteilen vorhandene kritische Substanzen (ISO/TR 16178:2012) This Technical Report was approved by CEN on 30 July 2012. It has been drawn up by the Technical Committee CEN/TC 309. CEN members are t

7、he national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Roman

8、ia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2012 CEN All rights of exploitation in any form and by any means re

9、served worldwide for CEN national Members. Ref. No. CEN ISO/TR 16178:2012: EPD CEN ISO/TR 16178:2012CEN ISO/TR 16178:2012 (E) 3 Foreword This document (CEN ISO/TR 16178:2012) has been prepared by Technical Committee CEN/TC 309 “Footwear“, the secretariat of which is held by AENOR, in collaboration w

10、ith Technical Committee ISO/TC 216 “Footwear“. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes CEN ISO/TR 161

11、78:2010. PD CEN ISO/TR 16178:2012ISO/TR 16178:2012(E) ISO 2012 All rights reserved iiiContents PageForeword iv1 Scope 12 Terms and definitions . 13 Presence of chemicals in footwear materials 2Annex A (informative) Materials used in the footwear industry . 7Annex B (informative) Critical substances

12、potentially present in footwear and footwear components 13Bibliography .40PD CEN ISO/TR 16178:2012ISO/TR 16178:2012(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Stand

13、ards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also ta

14、ke part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.The main task of technical committees is

15、to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote.In exceptional circumstances, when a t

16、echnical committee has collected data of a different kind from that which is normally published as an International Standard (“state of the art”, for example), it may decide by a simple majority vote of its participating members to publish a Technical Report. A Technical Report is entirely informati

17、ve in nature and does not have to be reviewed until the data it provides are considered to be no longer valid or useful.Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all s

18、uch patent rights.ISO/TR 16178 was prepared by Technical Committee ISO/TC 216, Footwear.ISO/TR 16178 was prepared by the European Committee for Standardization (CEN) Technical Committee CEN/TC 309, Footwear, in collaboration with ISO Technical Committee TC 216, Footwear, in accordance with the Agree

19、ment on technical cooperation between ISO and CEN (Vienna agreement).This second edition cancels and replaces the first edition (ISO/TR 16178:2010), which has been technically revised.iv ISO 2012 All rights reservedPD CEN ISO/TR 16178:2012TECHNICAL REPORT ISO/TR 16178:2012(E)Footwear Critical substa

20、nces potentially present in footwear and footwear components1 ScopeThis Technical Report establishes a list of critical chemical substances potentially present in footwear and footwear components.This Technical Report describes the critical chemical substances, their potential risks, the materials i

21、n which they can be found and the test method(s) which can be used to quantify them. It does not include requirements; it is the responsibility of the user of this Technical Report to fix his/her level of acceptance, for instance using a defined concentration or detection limit or quantification lim

22、it.NOTE The proposed test methods indicate the state of the art. Some substances do not include a test method, as no test method is available at the time of publication of this Technical Report. If possible, it is intended to include a test method in a revision of this Technical Report.This Technica

23、l Report applies to any kind of footwear and footwear components.2 Terms and definitionsFor the purposes of this document, the following terms and definitions apply.2.1allergensubstance that is capable of inducing an allergic reaction2.2allergyimmunologically mediated response to certain specific su

24、bstances NOTE 1 The specific substances are allergens.NOTE 2 Type-1 allergy (respiratory allergy) is mediated by IgE antibodies and can cause asthma, rhinitis and urticaria.NOTE 3 Type-4 allergy (dermal allergy) is mediated by T-cells and can cause dermatitis.2.3detection limitvalue from which a sub

25、stance is considered detectableNOTE This means that the signal associated to the substance is three times bigger than the background noise signal. The limit of detection is determined experimentally by the laboratory for each substance.2.4quantification limitvalue from which a substance is considere

26、d measurableNOTE It is the value where the uncertainty of measurement is equal to 50 % of the determined value.2.5absence of a chemicalstate in which a chemical is lacking from a material, where the test method is unable to detect itNOTE The amount of the chemical is smaller than the detection limit

27、 of the test method. ISO 2012 All rights reserved 1PD CEN ISO/TR 16178:2012ISO/TR 16178:2012(E)2.6critical substancechemical substance that can be found in footwear or footwear components and that can have an effect on the wearer and/or environmental impact due to its chemical reactivityNOTE 1 The e

28、ffects caused by critical substances vary. They can be carcinogenic or mutagenic effects, allergy, reaction to toxics, etc.NOTE 2 Legislations can change; this Technical Report gives the information available at the time of publication. It is the responsibility of the user of this Technical Report t

29、o ensure that no changes have occurred.2.6.1critical substances category 1substances with proven dangerous effect on the wearerNOTE These substances are restricted by regulation at European level.2.6.2critical substances category 2substances with dangerous effect on the wearerNOTE These substances a

30、re restricted by regulation at national level in some countries.2.6.3critical substances category 3substances with environmental impactNOTE These substances are mentioned in European Ecolabel.2.6.4critical substances category 4substances that are highly suspected to have an effect on the wearerNOTE

31、Possibly, these substances are not restricted by regulation at the time of publication of this Technical Report.2.6.5critical substances category 5substances that are suspected to have an effect on the wearerNOTE Possibly, these substances are not restricted by regulation at the time of publication

32、of this Technical Report.3 Presence of chemicals in footwear materialsA number of chemicals are present in footwear materials. Table 1 gives:a) materials in which they are supposed to be (for information, see Annex A);b) the list of the critical chemicals, (for information, see Annex B);c) test meth

33、ods which can be used to provoke and quantify them;d) the potential risk associated with and assessed by the use of the critical substances category scale (see 2.6).For composite materials, the tests should be conducted on the entire component.EXAMPLE 1 Coated textile (cotton plus PVC coating): the

34、test on PVC and the test on cellulosic natural fibres should be carried out.EXAMPLE 2 Mixed textile (PES plus cotton): the test on cellulosic natural textile and the test on PES textile should be carried out.2 ISO 2012 All rights reservedPD CEN ISO/TR 16178:2012ISO/TR 16178:2012(E)Table1Criticalchem

35、icalspotentiallypresentinfootwearandfootwearcomponentsSubstance(see AnnexB)TestmethodLeatherSyntheticmaterialNaturalmaterialMiscellaneousLe at h e rC oa t e d le a t h erL e a t h e r fi b r e b o a r dP VCE VAR u bb erP U T P U e l a s t h a nP E- PPP ol y es t e rP o ly a m i d eC h l o r i d e fi

36、 b r ePo l y a c r y l i cL a t exC e l l u l o s i c n a t u r a l t e x t i l eP r o t e i n i c n a t u r a l t e x t i l eW o o d - c o r kA d he s i v e sM e t al har d w ar eP r i n t s f o r t e x t i l eC e l l u l o s i c ma t e r ia lsAcrylonitrile555AZO - arylaminesISO17234-1111AZO - aryl

37、aminesWhen4-aminoazobenzeneissuspectedISO17234-2111AZO - arylaminesEN14362-1111111AZO - arylaminesEN14362-211AZO - arylaminesWhen4-aminoazobenzeneissuspectedEN14362-31111111CadmiumAll plastics (mainlyPVC)EN11221111111ChloroorganiccarriersDIN 542323ChromiumVIISO17075222Colophony5Dimethylformamide(DMF

38、)44Dimethylfumarate(DMFU)ISO/TS16186111111111111111111Disperses dyes and dyestuffsDIN54231222222FlameretardantOnly for product claimingFRproperties111111111111111111FormaldehydeISO17226-1 andISO17226-2222 ISO 2012 All rights reserved 3PD CEN ISO/TR 16178:2012ISO/TR 16178:2012(E)Table1(continued)Subs

39、tance(see AnnexB)TestmethodLeatherSyntheticmaterialNaturalmaterialMiscellaneousLe at h e rC oa t e d le a t h erL e a t h e r fi b r e b o a r dP VCE VAR u bb erP U T P U e l a s t h a nP E- PPP ol y es t e rP o ly a m i d eC h l o r i d e fi b r ePo l y a c r y l i cL a t exC e l l u l o s i c n a

40、t u r a l t e x t i l eP r o t e i n i c n a t u r a l t e x t i l eW o o d - c o r kA d he s i v e sM e t al har d w ar eP r i n t s f o r t e x t i l eC e l l u l o s i c ma t e r ia lsFormaldehydeEN120 EN717-322FormaldehydeISO14184-1222222Heavy metalsExtractible(Sb As Pb Cd Cr Co Cu Ni Hg Zn)ISO1

41、7072-14444444444444444444ExtractibleFootwear for children lessthan 36months old(Sb As Pb Cd Cr Co Cu Ni Hg Zn Ba Se)ISO17072-12222222222222222222Total content(Sb As Pb Cd Cr Co Cu Ni Hg Zn)ISO17072-24444444444444444444Total content(As Cd Pb)EN14602:20043333333333333333333Mercaptobenzothiazole5Extrac

42、tible latex proteinsEN455-34N-ethylphenylamine54NickelSkin contactEN1811CR12471(withorwithoutEN12472)1NitrosaminesFootwear for children lessthan 36months oldEN1286824 ISO 2012 All rights reservedPD CEN ISO/TR 16178:2012ISO/TR 16178:2012(E)Table1(continued)Substance(see AnnexB)TestmethodLeatherSynthe

43、ticmaterialNaturalmaterialMiscellaneousLe at h e rC oa t e d le a t h erL e a t h e r fi b r e b o a r dP VCE VAR u bb erP U T P U e l a s t h a nP E- PPP ol y es t e rP o ly a m i d eC h l o r i d e fi b r ePo l y a c r y l i cL a t exC e l l u l o s i c n a t u r a l t e x t i l eP r o t e i n i c

44、 n a t u r a l t e x t i l eW o o d - c o r kA d he s i v e sM e t al har d w ar eP r i n t s f o r t e x t i l eC e l l u l o s i c ma t e r ia lsNitrosaminesEN128683OP, NP, OPEO, NPEO Alkylphenols andalkylphenolethoxylates)444333333Organotin compounds(TBT, TPT)ISO/TS161791111111111111111111Organot

45、in compounds(MBT, DBT, DOT),ISO/TS161794444444433334334444Ortho-phenylphenolISO133655555555555555Ozonedepletingsubstances333333PAH polycyclic aromatic hydrocarbons44444444PCP -TeCP TriCP - polychlorophenolsISO17070222PCP -TeCP TriCP - polychlorophenolsCEN/TR148232PCP -TeCP TriCP - polychlorophenolsX

46、PG08-01522Pesticides555335PFOS/PFOA(Perfluorooctanesulfonate/perfluorooctanoicacid)Only for product claimingFR properties and waterresistanceCEN/TS15968111111111pHISO4045444pHISO3071444444Phenol44444444PhthalatesISO/TS1618133333Footwear for children lessthan 36months oldISO/TS161812222222222222PCB -

47、 Polychlorinated biphenyls555333333Polychloropreneorneoprene55 ISO 2012 All rights reserved 5PD CEN ISO/TR 16178:2012ISO/TR 16178:2012(E)Table1(continued)Substance(see AnnexB)TestmethodLeatherSyntheticmaterialNaturalmaterialMiscellaneousLe at h e rC oa t e d le a t h erL e a t h e r fi b r e b o a r

48、 dP VCE VAR u bb erP U T P U e l a s t h a nP E- PPP ol y es t e rP o ly a m i d eC h l o r i d e fi b r ePo l y a c r y l i cL a t exC e l l u l o s i c n a t u r a l t e x t i l eP r o t e i n i c n a t u r a l t e x t i l eW o o d - c o r kA d he s i v e sM e t al har d w ar eP r i n t s f o r t

49、e x t i l eC e l l u l o s i c ma t e r ia lsPPDParaphenylenediamine5555555555PTBF Paratertiary butyl phenol formaldehyde5Short-chainedchloroparaffins(C10-C13)3333333333TCMTB(2-(thiocyanatomethylthio)-1,3-benzothiazole)ISO13365555Thiuramandthiocarbamate5VinylchloridemonomerISO6401446 ISO 2012 All rights reservedPD CEN ISO/TR 16178:2012ISO/TR 16178:2012(E)Annex A (informative) Materials used in the footwear industryA.1 LeatherLeather is a general term for hide or skin, with its