BS ISO 12219-1-2012 Indoor air of road vehicles Whole vehicle test chamber Specification and method for the determination of volatile organic compounds in cabin interiors《室内空气和道路车辆.pdf

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1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS ISO 12219-1:2012Interior air of road vehiclesPart 1: Whole vehicle test chamber Specification and method for thedetermination of volatile organiccompounds in cabin interiorsBS

2、 ISO 12219-1:2012 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of ISO 12219-1:2012.The UK participation in its preparation was entrusted to TechnicalCommittee EH/2/3, Ambient atmospheres.A list of organizations represented on this committee can beobtained on reques

3、t to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2012. Published by BSI StandardsLimited 2012ISBN 978 0 580 66607 0ICS 13.040.20; 43.020Compliance with a Brit

4、ish Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 31 July 2012.Amendments issued since publicationDate Text affectedBS ISO 12219-1:2012 ISO 2012Interior air of road vehicles Part 1: Whole

5、 vehicle test chamber Specification and method for the determination of volatile organic compounds in cabin interiorsAir intrieur des vhicules routiers Partie 1: Enceinte dessai pour un vhicule complet Spcification et mthode de dtermination des composs organiques volatils dans les habitacles dautomo

6、bilesINTERNATIONAL STANDARDISO12219-1First edition2012-07-15Reference numberISO 12219-1:2012(E)BS ISO 12219-1:2012ISO 12219-1:2012(E)ii ISO 2012 All rights reservedCOPYRIGHT PROTECTED DOCUMENT ISO 2012All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or u

7、tilized in any form or by any means, electronic or mechanical, including photocopying and microfilm, without permission in writing from either ISO at the address below or ISOs member body in the country of the requester.ISO copyright officeCase postale 56 CH-1211 Geneva 20Tel. + 41 22 749 01 11Fax +

8、 41 22 749 09 47E-mail copyrightiso.orgWeb www.iso.orgPublished in SwitzerlandBS ISO 12219-1:2012ISO 12219-1:2012(E) ISO 2012 All rights reserved iiiContents PageForeword ivIntroduction v1 Scope 12 Normative references . 23 Terms and definitions . 24 Apparatus and materials . 35 Principle . 46 Requi

9、rements of the whole vehicle test chamber, test vehicle and measurement procedures 56.1 Requirements for the whole vehicle test chamber . 56.2 Requirements for the test vehicle . 76.3 Requirements for VOC and carbonyl compound air sampling and measurement methods 76.4 Blank measurements 87 Standard

10、test procedure 97.1 General . 97.2 Pre-arrangements and preconditioning of the whole vehicle test chamber and the vehicle and performing the field blanks . 97.3 Detailed description of the test procedure .108 Calculation, presentation of results, and precision and uncertainty 129 Performance charact

11、eristics 1210 Quality assurance/quality control .12Annex A (informative) Whole vehicle test chamber 13Annex B (informative) Temperature measuring points for parking mode .14Annex C (informative) Test report 15Annex D (informative) Very volatile organic compounds, volatile organic compounds, and semi

12、-volatile organic compounds 20Annex E (normative) Overview of the number of samples to be taken .21Bibliography .22BS ISO 12219-1:2012ISO 12219-1:2012(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The wo

13、rk of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governm

14、ental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.The ma

15、in task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote.Att

16、ention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights.ISO 12219-1 was prepared by Technical Committee ISO/TC 146, Air quality, Subcommittee SC 6, Indoor air, i

17、n collaboration with Technical Committee ISO/TC 22, Road vehicles.ISO 12219 consists of the following parts, under the general title Interior air of road vehicles: Part 1: Whole vehicle test chamber Specification and method for the determination of volatile organic compounds in cabin interiors Part

18、2: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Bag method Part 3 Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Micro-scale chamber met

19、hod Part 4: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Small chamber methodThe following part is under preparation: Part 5: Screening method for the determination of the emissions of volatile organic compounds from

20、vehicle interior parts and materials Static chamber methodiv ISO 2012 All rights reservedBS ISO 12219-1:2012ISO 12219-1:2012(E)IntroductionVolatile organic compounds (VOCs) are widely used in industry and can be emitted by many everyday products and materials. They have attracted attention in recent

21、 years because of their impact on indoor air quality. After homes and workplaces, people spend a lot of time in their vehicles. It is important to determine the material emissions of interior parts and to reduce them to an acceptable level, if required. Therefore it is necessary to obtain comprehens

22、ive and reliable information about the types of organic compounds in the interior air of vehicles and also their concentrations.This part of ISO 12219 outlines a method of measuring the types and levels of VOCs in vehicle cabin air under controlled conditions. It describes requirements for a whole v

23、ehicle test chamber and a test protocol. Measurements are carried out according to ISO 16000-6 (VOCs) and ISO 16000-3 (carbonyl compounds).There are several national test methods available for measuring in-vehicle air quality, e.g. References 23. However, this part of ISO 12219 requires a fixed heat

24、ing radiation system whereas the methods of References 23 define a fixed temperature programme.Before setting a fixed radiation density for heating the test vehicle, several validation measurements were performed (Reference 1).ISO 16000-3, ISO 16000-5,6ISO 16000-6, ISO 16000-9,7ISO 16000-10,8ISO 160

25、00-11,9ISO 16000-24,10ISO 16000-25,11as well as ISO 16017-1 and ISO 16017-212also focus on volatile organic compound (VOC) measurements. ISO 2012 All rights reserved vBS ISO 12219-1:2012BS ISO 12219-1:2012Interior air of road vehiclesPart 1: Whole vehicle test chamber Specification and method for th

26、e determination of volatile organic compounds in cabin interiorsWARNING It is the responsibility of the user of this part of ISO 12219 to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use. National regulations for precautions

27、shall be followed.1 ScopeThis part of ISO 12219 describes and specifies the whole vehicle test chamber, the vapour sampling assembly and the operating conditions for the determination of volatile organic compounds (VOCs), and carbonyl compounds in vehicle cabin air. There are three measurements perf

28、ormed: one (for VOCs and carbonyl compounds) during the simulation of ambient conditions (ambient mode) at standard conditions of 23 C with no air exchange; a second only for the measurement of formaldehyde at elevated temperatures (parking mode); and a third for VOCs and carbonyl compounds simulati

29、ng driving after the vehicle has been parked in the sun starting at elevated temperatures (driving mode). For the simulation of the mean sun irradiation, a fixed irradiation in the whole vehicle test chamber is employed.The VOC method is valid for measurement of non-polar and slightly polar VOCs in

30、a concentration range of sub-micrograms per cubic metre up to several milligrams per cubic metre. Using the principles described in this method, some semi-volatile organic compounds (SVOC) can also be analysed. Compatible compounds are those which can be trapped and released from the Tenax TA1)sorbe

31、nt tubes described in ISO 16000-6, which includes VOCs ranging in volatility from n-C6to n-C16.The sampling and analysis procedure for formaldehyde and other carbonyl compounds is performed by collecting air on to cartridges coated with 2,4-dinitrophenylhydrazine (DNPH) and subsequent analysis by hi

32、gh performance liquid chromatography (HPLC) with detection by ultraviolet absorption. Formaldehyde and other carbonyl compounds can be determined in the approximate concentration range 1 g/m3to 1 mg/m3.The method is valid for passenger cars, as defined in ISO 3833.This part of ISO 12219 describes:a)

33、 transport and storage of the test vehicles until the start of the test;b) conditioning for the surroundings of the test vehicle and the test vehicle itself as well as the whole vehicle test chamber;c) conditioning of the test vehicle prior to measurements;d) simulation of ambient air conditions (am

34、bient mode);e) formaldehyde sampling at elevated temperatures (parking mode);f) simulation of driving after the test vehicle has been parked in the sun (driving mode).Buses, motor caravans, and trucks, in accordance with the descriptions given in ISO 3833, are excluded.1) Tenax TAis the trade name o

35、f a product supplied by Buchem. This information is given for the convenience of users of this document and does not constitute an endorsement by ISO of the product named. Equivalent products may be used if they can be shown to lead to the same results.INTERNATIONAL STANDARD ISO 12219-1:2012(E) ISO

36、2012 All rights reserved 1BS ISO 12219-1:2012ISO 12219-1:2012(E)2 Normative referencesThe following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document

37、 (including any amendments) applies.ISO 3833:1977, Road vehicles Types Terms and definitionsISO 9060, Solar energy Specification and classification of instruments for measuring hemispherical solar and direct solar radiationISO 16000-3, Indoor air Part 3: Determination of formaldehyde and other carbo

38、nyl compounds in indoor air and test chamber air Active sampling methodISO 16000-6:2011, Indoor air Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TAsorbent, thermal desorption and gas chromatography using MS or MSFIDISO 16017-1, Indoor

39、, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 1: Pumped sampling3 Terms and definitionsFor the purpose of this document, the terms and definitions of ISO 16000-3, ISO 16000-6 and the following appl

40、y.3.1background concentrationanalyte concentration in the whole-vehicle test chamber when the test vehicle is inside3.2test vehiclenew or used vehicle to be testedNOTE 1 The test vehicle can be of any type specified in ISO 3833:1977, 3.1.1, only.NOTE 2 See also 4.5.3.3total volatile organic compound

41、sTVOCssum of volatile organic compounds sampled on Tenax TA1)and eluting between and including n-hexane and n-hexadecane, detected with a flame ionization detector (TVOCFID) or mass spectrometric detector (TVOCMS) and quantified converting the total area of the chromatogram in that analytical window

42、 to toluene equivalentsNOTE Adapted from ISO 16000-6:2011, 3.4.3.4carbonyl compoundcompound containing the functional group C(=O) determined according to a specified procedureNOTE For the purposes of this part of ISO 12219, the procedure is that specified in ISO 16000-3.3.5ambient modemode in which

43、sampling of VOCs and carbonyl compounds in the cabin of a test vehicle under standardized ambient temperature conditions is performed, defined by 23 CNOTE Engine off, radiators off, sampling time 30 min.2 ISO 2012 All rights reservedBS ISO 12219-1:2012ISO 12219-1:2012(E)3.6parking modemode in which

44、sampling of formaldehyde in the cabin of a test vehicle under standardized elevated temperatures is performedNOTE Sampling time 30 min.3.7driving modemode in which sampling of VOCs and carbonyl compounds in the cabin of a test vehicle under standardized conditions starting at elevated temperatures i

45、s performed, simulating a vehicle driven after being parked in the sunNOTE Sampling time 30 min.3.8sampling trainapparatus to collect the sample gas inside the test vehicle cabin (indoor) and in the whole vehicle test chamber, trapping the VOCs and carbonyl compounds in sorbent tubes under standardi

46、zed conditionsNOTE See ISO 16000-3 for formaldehyde and ISO 16000-6 for VOCs.4 Apparatus and materials4.1 General. The whole vehicle test chamber is big enough to house the test vehicle completely. An air-conditioning system is installed to allow standardized air conditions for a temperature of 23 C

47、 2 C, humidity of 50 % RH 10 % RH. A solar radiator system is installed to heat the test vehicle cabin with a fixed irradiation. The resulting temperature inside the cabin depends on the insulation and the window glass material (the minimum requirements are specified in 6.1) (see also Figure 1).4.2

48、Heating radiator. Infrared radiator, halogen radiator or other radiators (simulating sunlight) (wavelengths 300 nm shall be filtered out). The heating radiators used shall be powered to create a radiation density at the reference measurement point in the middle of the roof surface of the test vehicl

49、e of 350 W/m2to 450 W/m2(400 W/m2 50 W/m2).The heating area shall cover at least the area of the test vehicle cabin and an additional 0,5 m more to each side of the lower part of the glazing (footprint) (see Figure 1). Position the heating radiators on the roof with a shining angle of 90 to the heating area. There shall be no heating radiators shining from the side. The heating area shall be calibrated in squares of 25 cm 25 cm with a radiation density of 400 W/m2 50 W/m