BS EN 15482-2012 Chemicals used for treatment of water intended for human consumption Sodium permanganate《用于处理人类生活用水的化学品 高锰酸钠》.pdf

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1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 15482:2012Chemicals used for treatmentof water intended for humanconsumption SodiumpermanganateCopyright European Committee for Standardization Provided by IHS under licens

2、e with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15482:2012 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 15482:2012. It supersedes BS EN 15482:2007 which is withdrawn.The UK participation in its preparation wa

3、s entrusted to Technical Committee CII/59, Chemicals for drinking water treatment.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its c

4、orrect application. The British Standards Institution 2013. Published by BSI Standards Limited 2013ISBN 978 0 580 77700 4 ICS 13.060.20; 71.100.80 Compliance with a British Standard cannot confer immunity from legal obligations.This British Standard was published under the authority of the Standards

5、 Policy and Strategy Committee on 28 February 2013.Amendments issued since publicationDate T e x t a f f e c t e dCopyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15482:2012

6、EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 15482 November 2012 ICS 71.100.80 Supersedes EN 15482:2007English Version Chemicals used for treatment of water intended for human consumption - Sodium permanganate Produits chimiques utiliss pour le traitement de leau destine la consommation huma

7、ine - Permanganate de sodium Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch - Natriumpermanganat This European Standard was approved by CEN on 16 September 2012. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving thi

8、s European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official v

9、ersions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austr

10、ia, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden

11、, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2012 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Mem

12、bers. Ref. No. EN 15482:2012: ECopyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15482:2012EN 15482:2012 (E) 2 Contents Page Foreword 3Introduction .41 Scope 52 Normative ref

13、erences 53 Description .53.1 Identification .53.2 Commercial forms .63.3 Physical properties 63.4 Chemical properties 74 Purity criteria 84.1 General 84.2 Composition of commercial product .84.3 Impurities and main by-products .84.4 Chemical parameters 85 Test methods 95.1 Sampling .95.2 Analysis .

14、106 Labelling - Transportation - Storage . 136.1 Means of delivery 136.2 Labelling according to the EU legislation . 146.3 Transportation regulations and labelling . 146.4 Marking 146.5 Storage . 14Annex A (informative) General information on sodium permanganate 16A.1 Origin . 16A.1.1 Raw materials

15、16A.1.2 Manufacturing process 16A.2 Use . 16A.2.1 Function . 16A.2.2 Form in which the product is used . 16A.2.3 Treatment dose . 16A.2.4 Means of application 16A.2.5 Secondary effects . 17A.2.6 Removal of excess product . 17Annex B (normative) General rules relating to safety 18B.1 Rules for safe h

16、andling and use . 18B.2 Emergency procedures 18B.2.1 First aid 18B.2.2 Spillage 18B.2.3 Fire . 18Bibliography . 19Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15482:2012

17、EN 15482:2012 (E) 3 Foreword This document (EN 15482:2012) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsem

18、ent, at the latest by May 2013, and conflicting national standards shall be withdrawn at the latest by May 2013. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any

19、or all such patent rights. This document supersedes EN 15482:2007. Significant technical differences between this edition and EN 15482:2007 are as follows: a) Modification of Table 2 to show consistent limits for chemical parameters. b) Modification of 6.2 on labelling, deletion of the reference to

20、EU Directive 80/778/EEC of 15 July 1980 in order to take account of the latest Directive in force. This document is largely based on EN 12672:2008 3. According to the CEN/CENELEC Internal Regulations, the national standards organisations of the following countries are bound to implement this Europea

21、n Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Sloven

22、ia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15482:2012EN 15482:2012 (E) 4 Introduction In respect of the

23、potential adverse effects on the quality of water intended for human consumption caused by the product covered by this European Standard: a) this European Standard provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA; b) it s

24、hould be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of this product remain in force. NOTE Conformity with this European Standard does not confer or imply acceptance or approval of the product in

25、 any of the Member States of the EU or EFTA. The use of the product covered by this European Standard is subject to regulation or control by National Authorities. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permit

26、ted without license from IHS-,-,-BS EN 15482:2012EN 15482:2012 (E) 5 1 Scope This European Standard is applicable to sodium permanganate used for the treatment of water intended for human consumption. It describes the characteristics of sodium permanganate and specifies the requirements and the corr

27、esponding test methods for sodium permanganate. It provides information on its use in water treatment. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition ci

28、ted applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 1233, Water quality Determination of chromium Atomic absorption spectrometric methods EN ISO 3696, Water for analytical laboratory use Specification and test methods (ISO 3696) E

29、N ISO 11885, Water quality Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) (ISO 11885) EN ISO 11969, Water quality Determination of arsenic Atomic absorption spectrometric method (hydride technique (ISO 11969) EN ISO 12846, Water quality Deter

30、mination of mercury Method using atomic absorption spectrometry (AAS) with and without enrichment (ISO 12846) ISO 3165, Sampling of chemical products for industrial use Safety in sampling ISO 3856-2, Paints and varnishes Determination of “soluble“ metal content Part 2: Determination of antimony cont

31、ent Flame atomic absorption spectrometric method and Rhodamine B spectrophotometric method ISO 6206, Chemical products for industrial use Sampling Vocabulary ISO 8288, Water quality Determination of cobalt, nickel, copper, zinc, cadmium and lead Flame atomic absorption spectrometric methods ISO 9965

32、, Water quality Determination of selenium Atomic absorption spectrometric method (hydride technique) 3 Description 3.1 Identification 3.1.1 Chemical name Sodium permanganate 3.1.2 Synonym or common name Permanganate acid sodium salt 3.1.3 Relative molecular mass Copyright European Committee for Stan

33、dardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15482:2012EN 15482:2012 (E) 6 141,93 3.1.4 Empirical formula NaMnO43.1.5 Chemical formula NaMnO43.1.6 CAS Registry Number 1)10101-50-5 3.1.7 EINECS reference 2)2

34、33-251-1 3.2 Commercial forms The sodium permanganate is usually available as a concentrated solution with a concentration within the range of mass fraction of 20 % to 40 %. The density of sodium permanganate solutions is given in Table 1. Table 1 Solution concentration Mass fraction in % Densityg/m

35、l at 22 C 10 1,07615 1,116 20 1,16425 1,21630 1,266 35 1,31640 1,3743.3 Physical properties 3.3.1 Appearance Sodium permanganate solution is a dark purple coloured solution. 3.3.2 Density The density of 40,00 % sodium permanganate solution is 1,37 g/cm3at 20 C. 1) Chemicals Abstracts Service Registr

36、y Number. 2) European Inventory of Existing Commercial Chemical Substances. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15482:2012EN 15482:2012 (E) 7 3.3.3 Solubility (

37、in water) Sodium permanganate solution is soluble up to 40 % and miscible with water in all proportions. 3.3.4 Vapour pressure Not determined for sodium permanganate solution, however, very similar to water. 3.3.5 Boiling point at 100 kPa3)Greater than 101 C. 3.3.6 Melting point Not applicable. 3.3.

38、7 Specific heat Not determined. 3.3.8 Viscosity (dynamic) Less than 0,005 Pas for concentrations of 40 % or less 3.3.9 Critical temperature Not determined. 3.3.10 Critical pressure Not determined. 3.3.11 Physical hardness Not applicable. 3.4 Chemical properties Sodium permanganate is a very strong o

39、xidising agent. It is soluble in water and dissolves in various organic solvents (methanol, ethanol). NOTE The reaction with organics can be violent and is not recommended. It decomposes at a high temperature and also in the presence of concentrated acids, hydrogen peroxide and organic compounds in

40、general. It hydrolyses very slowly in contact with air, reducing to manganese dioxide (MnO2), a solid, brown to black colour product. 3) 100 kPa = 1 bar. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted witho

41、ut license from IHS-,-,-BS EN 15482:2012EN 15482:2012 (E) 8 4 Purity criteria 4.1 General This European Standard specifies the minimum purity requirements for sodium permanganate used for the treatment of water intended for human consumption. Limits are given for impurities commonly present in the p

42、roduct. Depending on the raw material and the manufacturing process other impurities may be present and, if so, the user and when necessary relevant authorities shall be notified. Users of this product should check the national regulations to clarify whether it is of appropriate purity for treatment

43、 of water intended for human consumption, taking into account raw water quality, required dosage, contents of other impurities and additives used in the product not stated in this product standard. Limits have been given for impurities and chemical parameters where these are likely to be present in

44、significant quantities from the current production process and raw materials. If the production process or raw materials leads to significant quantities of impurities, by-products or additives being present, the user shall be notified. 4.2 Composition of commercial product The sodium permanganate is

45、 usually available in a concentrated solution with a concentration within the range of mass fraction of 20 % to 40 %. The concentration of sodium permanganate solution shall be equal to or greater than the manufacturer specified value. 4.3 Impurities and main by-products The content of manganese dio

46、xide (insoluble matter) shall be no more than a mass fraction of 0,055 %. NOTE The product can contain fluoride or hexafluorosilicate. At typical levels of dosing, the added fluoride would be less than 40 g/l. 4.4 Chemical parameters The content of chemical parameters shall conform to the requiremen

47、ts specified in Table 2. Table 2 Chemical parameters Parameter Limit mg/kg of NaMnO4(mass fraction 100 %) Arsenic (As) max. 20 Cadmium (Cd) max. 50 Chromium (Cr) max. 50 Mercury (Hg) max. 10 Nickel (Ni) max. 50 Lead (Pb) max. 50 Antimony (Sb) max. 50 Selenium (Se) max. 50 Copyright European Committe

48、e for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15482:2012EN 15482:2012 (E) 9 5 Test methods 5.1 Sampling 5.1.1 General Observe the general recommendations of ISO 3165 and take account those of ISO 6206. 5.1.2 Sampling from drums and bottles 5.1.2.1 General 5.1.2.1.1 Mix the contents of e