ASTM D4907-2010(2015) Standard Test Method for Nitrocellulose in Finish on Leather《皮革精制中硝化纤维素的标准试验方法》.pdf

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1、Designation: D4907 10 (Reapproved 2015)Standard Test Method forNitrocellulose in Finish on Leather1This standard is issued under the fixed designation D4907; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision

2、. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method is intended for use in identifyingnitrocellulose in the finish on all types of leathers. This testmethod does not

3、apply to wet blue.1.2 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard

4、 to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Significance and Use2.1 This test method is used to identify nitrocellulose infinishes on all types of leathers.3. Apparatus3.1 Borosilicate Glass Watch Glass, 100 mm dia

5、meter.3.2 Reagent Bottles, two, (4 fl oz each) equipped with glassjoint dropping pipet.4. Reagents4.1 Indicator solution prepared by dissolving 0.1 g diphe-nylamine in solution containing 100 mL of sulfuric acid and 30mL of distilled water.4.2 Blank solution comprising 100 mL of sulfuric acid and30

6、mL of distilled water.4.3 Acetone, C.P.4.4 Hazards StatementAll reagents and chemicals shouldbe handled with care. Before using any chemical, read andfollow all safety precautions and instructions on the manufac-turers label or MSDS (Material Safety Data Sheet).5. Test Specimen5.1 The test specimen

7、shall be approximately 1 cm2of thefinished leather.6. Procedure6.1 Place the test specimen in the watch glass with the finishside up. Apply one or 2 mL of indicator solution on the finishand allow to run over the side of the leather on to the watchglass. After 3 min, if the indicator solution does n

8、ot develop adark blue color, then nitrocellulose is not present in the finish.If the indicator solution develops a dark blue color after contactwith the finish, it indicates the presence of nitrocellulose or hasdeveloped color from colored finish components, or both.6.2 Repeat the above procedure ex

9、cept that the blanksolution is employed instead of the indicator solution. If a darkblue color does not develop, whereas it does when the indicatorsolution is applied, then nitrocellulose is present in the finishand colored finishing materials do not interfere.6.3 If colored finish material develops

10、 a dark blue color inthe presence of the blank solution, then place the specimenfinish side up in a watch glass and pour acetone on thespecimen, until completely covered, for dissolving any nitro-cellulose present in the specimen. After allowing the specimento soak in acetone for approximately 2 min

11、, remove thespecimen from the watch glass and the evaporate acetone in thewatch glass on the steam oven to dryness. When cooled toroom temperature, place a few drops of indicator solution onone side of the watch glass near the rim and allow the drops torun downward. At another location on the watch

12、glass, place afew drops of blank solution near the rim and allow to rundownward. If nitrocellulose is present in the finish, a dark bluecolor will develop as the indicator solution runs downward intothe watch glass whereas the blank solution will not show anycolor development.7. Report7.1 The indica

13、tor method for testing the presence of nitro-cellulose in finish on the leather shall be reported as positive ornegative.8. Precision and Bias8.1 This test method is adopted from the procedures of theAmerican Leather Chemists Association where it has been in1This test method is under the jurisdictio

14、n of ASTM Committee D31 on Leatherand is the direct responsibility of Subcommittee D31.06 on Chemical Analysis Thistest method was developed in cooperation with the American Leather ChemistsAssn. (Method K 5-1956).Current edition approved Dec. 1, 2015. Published December 2015. Originallyapproved in

15、1989. Last previous edition approved in 2010 as D4907 10. DOI:10.1520/D4907-10R15.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1use and where it was approved for publication before theinclusion of precision and bias statements were

16、mandated. Theoriginal interlaboratory test data is no longer available. Theuser is cautioned to verify by the use of reference materials, ifavailable, that the precision and bias of this method is adequatefor the contemplated use.9. Keywords9.1 finish; leather; nitrocelluloseASTM International takes

17、 no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own resp

18、onsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addresse

19、d to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the

20、address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ 10 (2015)2