ASTM D3021-2001(2012) Standard Specification for Phthalocyanine Green Pigments《酞菁绿颜料的标准规格》.pdf

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1、Designation: D3021 01 (Reapproved 2012)Standard Specification forPhthalocyanine Green Pigments1This standard is issued under the fixed designation D3021; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A

2、number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This specification covers chlorinated and chlorinated-brominated copper phthalocyanine green pigments in drypowder form, for use in pai

3、nts, printing inks, and relatedproducts. A variety of commercial types are available to meetthe requirements of different end uses.1.2 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.2. Referenced Documents2.1 ASTM Standards:2D2

4、80 Test Methods for Hygroscopic Moisture (and OtherMatter Volatile Under the Test Conditions) in PigmentsD281 Test Method for Oil Absorption of Pigments bySpatula Rub-outD387 Test Method for Color and Strength of ChromaticPigments with a Mechanical MullerD1135 Test Methods for Chemical Analysis of B

5、lue Pig-ments3. Composition and Properties3.1 The pigments shall consist of the product known com-mercially as phthalocyanine green, with or without phthalo-cyanine blue or other ingredients incorporated during manu-facture to improve or alter the properties of the pigment, butfree of any other colo

6、ring matter either organic or inorganic.The pigment shall conform to the following requirements:Moisture and other volatile matter, max, % 3.0Coloring matter other than phthalocyanines none3.2 Mass Color and Character of TintThe mass color, andthe character of the tint formed by mixture with a white

7、pigment, and the strength, shall be within mutually agreed-upon limits of a standard acceptable to both the purchaser andthe seller.3.3 Oil AbsorptionThe oil absorption shall be between 90and 110 % of that of a reference sample mutually agreed uponbetween the purchaser and the seller.3.4 Reaction in

8、 Identification TestsThe pigment shallshow the same reaction in identification tests (5.5-5.8)asareference sample mutually agreed upon between the purchaserand the seller.4. Sampling4.1 Two samples shall be taken at random from differentpackages from each lot, batch, days pack, or other unit ofprodu

9、ction in a shipment. When no markings distinguishingbetween units of production appear, samples shall be takenfrom different packages in the ratio of two samples for each4545 kg or (10 000 lb), except that for shipments of less than1000 lb, two samples shall be taken. At the option of thepurchaser,

10、each sample may be tested or samples from thesame production may be blended in equal quantities to form acomposite sample.5. Test Methods5.1 Tests shall be conducted in accordance with the appro-priate ASTM test methods. Test procedures not covered byASTM test methods shall be mutually agreed upon b

11、etween thepurchaser and the seller.5.2 Moisture and Other Volatile MatterMethod A of TestMethods D280.5.3 Mass Color and Tinting StrengthTest Method D387.5.4 Oil AbsorptionTest Method D281.5.5 Identification:5.5.1 To about 50 mg of the sample in a 50-mL beaker, add30 mL of H2SO4(sp gr 1.84). Stir oc

12、casionally for 15 min,heating if necessary. A dark greenish yellow to a dark reddishcolor forms, depending on the degree of bromination. Pour thesolution into 250 mL of water and stir. The phthalocyaninegreen will immediately precipitate as a flocculent mass.5.5.2 Filter off the precipitate, washing

13、 once or twice withwater. Scrape a small amount of the precipitate off the filter,place on a clean platinum wire moistened with HCl, and1This specification is under the jurisdiction of ASTM Committee D01 on Paintand Related Coatings, Materials, and Applications and is the direct responsibility ofSub

14、committee D01.31 on Pigment Specifications.Current edition approved June 1, 2012. Published August 2012. Originallyapproved in 1972. Last previous edition approved in 2006 as D3021 01 (2006).DOI: 10.1520/D3021-01R12.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM

15、 Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1subject it to the low flame of

16、a bunsen burner.As the precipitateburns, a light blue-green flame should be clearly evident,indicating organically combined copper.NOTE 1Characteristic spectrophotometric absorption spectra in thenear infrared range (700 to 900 nm) are exhibited by dilute solutions ofcopper phthalocyanine pigments (

17、2 to 50 mg/L) in H2SO4(sp gr 1.84).The absorption maxima are so sharp and well defined that they may beused for positive qualitative identification of the various phthalocyaninepigments. Phthalocyanine green has maxima at approximately 820 and860 nm for bromine-free types; for the chlorinated-bromin

18、ated types, themaxima appear at approximately 830 to 840 nm, and 875 to 885 nm.5.6 Basic Dye DerivativesTest Method D1135.5.7 Other Organic Coloring MatterTest Method D1135.5.8 Chrome Green and Iron BlueTest Method D1135.6. Keywords6.1 chlorinated brominated copper phthalocyanine green;chlorinated c

19、opper phthalocyanine green; phthalocyaninegreen; pigmentASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent

20、 rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either

21、 for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hea

22、ring you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard

23、 may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).D3021 01 (2012)2