DIN EN ISO 10304-1-2009 Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 1 Determination of bromide chloride fluoride nitrate nitrite phosp.pdf

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1、July 2009DEUTSCHE NORM English price group 12No part of this standard may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 13.060.50!$Xlu“1537382www

2、.din.deDDIN EN ISO 10304-1Water quality Determination of dissolved anions by liquid chromatography of ions Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite,phosphate and sulfate (ISO 10304-1:2007)English version of DIN EN ISO 10304-1:2009-07Wasserbeschaffenheit Bestimmung von g

3、elsten Anionen mittels Flssigkeits-Ionenchromatographie Teil 1: Bestimmung von Bromid, Chlorid, Fluorid, Nitrat, Nitrit, Phosphat und Sulfat(ISO 10304-1:2007)Englische Fassung DIN EN ISO 10304-1:2009-07SupersedesDIN EN ISO 10304-1:1995-04andDIN EN ISO 10304-2:1996-11www.beuth.deDocument comprises 23

4、 pagesDIN EN ISO 10304-1:2009-07 2 National foreword This standard has been prepared by Technical Committee ISO/TC 147 “Water quality” in collaboration with Technical Committee CEN/TC 230 “Water analysis” (Secretariat: DIN, Germany). The responsible German body involved in its preparation was the No

5、rmenausschuss Wasserwesen (Water Practice Standards Committee), Technical Committees NA 119-01-03-01-12 AK Ionenchromatographische Verfahren and NA 119-01-03 AA Wasseruntersuchung. DIN EN ISO 10304 consists of the following parts, under the general title Water quality Determination of dissolved anio

6、ns by liquid chromatography of ions: Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate Part 3: Determination of chromate, iodide, sulfite, thiocyanate and thiosulfate Part 4: Determination of chlorate, chloride and chlorite in water with low contamination

7、This standard is part of the series Deutsche Einheitsverfahren zur Wasser-, Abwasser- und Schlamm-untersuchung Anionen (Gruppe D) (German standard methods for the examination of water, waste water and sludge Anions (group D) and describes method D 20. Designation of method D 20 “Determination of dis

8、solved anions by liquid chromatography of ions Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate”: Method DIN EN ISO 10304-1 D 20 This standard has been published to implement the Water Framework Directive (WFD), Directive 2000/60/EC of the European Parlia

9、ment and of the Council of 23 October 2000 establishing a framework for Community action in the field of water policy1). As a result of national implementation in Germany, the following action has been taken: The English version of ISO 10304-1, subclause 5.10.1, first paragraph, second sentence, con

10、tained a wording error. This error has been corrected in the German version of DIN EN ISO 10304-1, and correspondingly in the English version. Former text: “In order to minimise the growth of bacteria or algae, prepare eluents freshly after 3 days”. Translation of new German text: Care is to be take

11、n to prevent any subsequent intake of gases (e.g. by using helium as a barrier). Likewise, the explanations of symbols l and n in the key of Table A.2, which were erroneously interchanged in ISO 10304, have been corrected in the German and English versions of DIN EN ISO 10304-1. The same applies to

12、an entry in Table A.5 (M 21 River water, o in %), which has been corrected from 2 9 to 2,9. In connection with clause 7 (Sampling and sample pre-treatment), acids shall not be used for the purpose of preserving samples. The DIN Standards corresponding to the International Standards referred to in th

13、is document are as follows: ISO 3696 DIN ISO 3696 ISO 5667-1 DIN EN ISO 5667-1 1) Registered in the DITR database of DIN Software GmbH, obtainable from: Beuth Verlag GmbH, 10772 Berlin. 3 ISO 5667-3 DIN EN ISO 5667-3 ISO 5725-2 DIN ISO 5725-2 ISO 8466-1 DIN 38402-51 ISO 8466-2 DIN ISO 8466-2 Expert

14、assistance and specialized laboratories will be required to perform the analysis described in this standard. Existing safety regulations are to be taken into account. Depending on the objective of the analysis, a check shall be made on a case-by-case basis as to whether and to what extent additional

15、 conditions will have to be specified. German standard methods for the examination of water, waste water and sludge Standard methods published as DIN Standards are obtainable from Beuth Verlag GmbH, either individually or grouped in volumes. The standard methods included in the loose-leaf publicatio

16、n entitled Deutsche Einheitsverfahren zur Wasser-, Abwasser- und Schlammuntersuchung will continue to be published jointly by Wiley-VCH Verlag and Beuth Verlag GmbH. All standard methods relevant to the Abwasserverordnung (Waste Water Regulation) (AbwV1) included in the new Regulation on Section 7a

17、of the Gesetz zur Ordnung des Wasserhaushaltes (German Water Management Act1) concerning Anforderungen an das Einleiten von Abwasser in Gewsser together with the Abwasserverordnung and the Gesetz zur Ordnung des Wasserhaushalts have been published by Beuth-Verlag GmbH as a loose-leaf collection Anal

18、ysenverfahren in der Abwasserverordnung Rechtsvorschriften und Normen (Supplements). Standards or draft standards bearing the group title “German standard methods for the examination of water, waste water and sludge” are classified under the following categories (main titles): General information (g

19、roup A) (DIN 38402) Sensory analysis (group B) (DIN 38403) Physical and physicochemical parameters (group C) (DIN 38404) Anions (group D) (DIN 38405) Cations (group E) (DIN 38406) Substance group analysis (group F) (DIN 38407) Gaseous constituents (group G) (DIN 38408) Parameters characterizingeffec

20、ts and substances (group H) (DIN 38409) Biological-ecological methods of analysis (group M) (DIN 38410) Microbiological methods (group K) (DIN 38411) Test methods using water organisms (group L) (DIN 38412) Individual constituents (group P) (DIN 38413) Sludge and sediments (group S) (DIN 38414) Bio-

21、assays with microorganisms (group T) (DIN 38415) In addition to the methods described in the DIN 38402 to DIN 38415 series of standards, there are a number of European and International Standards available as DIN EN, DIN EN ISO and DIN ISO Standards, which also form part of the collection of German

22、standard methods. Information on Parts of these series of standards that have already been published can be obtained from the offices of the Normenausschuss Wasserwesen, telephone +49 30 2601-2448, or from Beuth Verlag GmbH, Burggrafenstr. 6, 10787 Berlin. DIN EN ISO 10304-1:2009-07 For , see page 2

23、. 1)DIN EN ISO 10304-1:2009-07 4 Amendments This standard differs from DIN EN ISO 10304-1:1995-04 and DIN EN ISO 10304-2:1996-11 as follows: a) The standards ISO 10304-1:1992-11 and ISO 10304-2:1995-04 have been combined in one standard. b) The scope has been extended to include the matrix types lea

24、chate and marine water. c) The working range has been expanded to lower concentrations. d) The anions may be separated by means of isocratic or gradient elution. e) Hydroxide eluent has been added as a further example for eluents. f) Examples relating to the conductivity if no suppressor device is u

25、sed have been omitted. g) The samples are to be stabilized as specified in ISO 5667-3. h) The standard has been editorially revised. Previous editions DIN 38405-19: 1988-02 DIN 38405-20: 1991-09 DIN EN ISO 10304-1: 1995-04 DIN EN ISO 10304-2: 1996-11 National Annex NA (informative) Bibliography DIN

26、38402-51, German standard methods for the examination of water, waste water and sludge General information (group A) Calibration of analytical methods, evaluation of analytical results and linear calibration functions used to determine the performance characteristics of analytical methods (A 51) DIN

27、 ISO 3696, Water for analytical laboratory use Specification and test methods DIN ISO 5725-2, Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method DIN ISO 8466-2, Water qu

28、ality Calibration and evaluation of analytical methods and estimation of performance characteristics Part 2: Calibration strategy for non-linear second-order calibration functions DIN EN ISO 5667-1, Water quality Sampling Part 1: Guidance on the design of sampling programmes and sampling techniques

29、DIN EN ISO 5667-3, Water quality Sampling Part 3: Guidance on the preservation and handling of water samples EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 10304-1 March 2009 ICS 13.060.50 Supersedes EN ISO 10304-1:1995, EN ISO 10304-2:1996 English Version Water quality - Determination of

30、dissolved anions by liquid chromatography of ions - Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate (ISO 10304-1:2007) Qualit de leau - Dosage des anions dissous par chromatographie des ions en phase liquide - Partie 1: Dosage du bromure, chlorure, fluor

31、ure, nitrate, nitrite, phosphate et sulfate (ISO 10304-1:2007) Wasserbeschaffenheit - Bestimmung von gelsten Anionen mittels Flssigkeits-Ionenchromatographie - Teil 1: Bestimmung von Bromid, Chlorid, Fluorid, Nitrat, Nitrit, Phosphat und Sulfat (ISO 10304-1:2007) This European Standard was approved

32、by CEN on 1 March 2009. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standa

33、rds may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to

34、 the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Net

35、herlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2009 CEN All rights of exploitatio

36、n in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 10304-1:2009: EContents Page Foreword .3 Introduction.4 1 Scope5 2 Normative references5 3 Interferences 6 4 Principle .6 5 Reagents 6 6 Apparatus.8 7 Sampling and sample pre-treatment .11 8 Procedure.12 9 Ca

37、lculation .13 10 Expression of results13 11 Test report13 Annex A (informative) Performance data .14 Annex B (informative) Checked interferences .18 Bibliography19 2 DIN EN ISO 10304-1:2009-07EN ISO 10304-1:2009 (E)Foreword 3 The text of ISO 10304-1:2007 has been prepared by Technical Committee ISO/

38、TC 147 “Water quality” of the International Organization for Standardization (ISO) and has been taken over as EN ISO 10304-1:2009 by Technical Committee CEN/TC 230 “Water analysis” the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, eithe

39、r by publication of an identical text or by endorsement, at the latest by September 2009, and conflicting national standards shall be withdrawn at the latest by September 2009. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN a

40、nd/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN ISO 10304-1:1995, EN ISO 10304-2:1996. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this

41、 European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the U

42、nited Kingdom. Endorsement notice The text of ISO 10304-1:2007 has been approved by CEN as a EN ISO 10304-1:2009 without any modification. EN ISO 10304-1:2009 (E) DIN EN ISO 10304-1:2009-07Introduction The user should be aware that particular problems could require the specification of additional co

43、nditions not provided for in this part of ISO 10304. 4 DIN EN ISO 10304-1:2009-07EN ISO 10304-1:2009 (E)WARNING Persons using this International Standard should be familiar with normal laboratory practice. This standard does not purport to address all of the safety problems, if any, associated with

44、its use. It is the responsibility of the user to establish appropriate safety and health practices and to ensure compliance with any national regulatory conditions. IMPORTANT It is absolutely essential that tests conducted according to this International Standard be carried out by suitably trained s

45、taff. 1 Scope This part of ISO 10304 specifies a method for the determination of dissolved bromide, chloride, fluoride, nitrate, nitrite, orthophosphate and sulfate in water, e.g. drinking water, ground water, surface water, waste water, leachates and marine water by liquid chromatography of ions. T

46、he lower limit of application is 0,05 mg/l for bromide and for nitrite, and 0,1 mg/l for chloride, fluoride, nitrate, orthophosphate, and sulfate. The lower limit of application depends on the matrix and the interferences encountered. The working range may be expanded to lower concentrations (e.g. 0

47、,01 mg/l) if an appropriate pre-treatment of the sample (e.g. conditions for trace analyses, pre-concentration technique) is applied, and/or if an ultraviolet (UV) detector (for bromide, nitrate and nitrite) is used. 2 Normative references The following referenced documents are indispensable for the

48、 application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 3696, Water for analytical laboratory use Specification and test methods ISO 5667-3, Water quality Sampli

49、ng Part 3: Guidance on the preservation and handling of water samples ISO 8466-1, Water quality Calibration and evaluation of analytical methods and estimation of performance characteristics Part 1: Statistical evaluation of the linear calibration function ISO 8466-2, Water quality Calibration and evaluation of analytical methods and estimation of performance characteristics Part 2: Calibration strategy for non-linear second-order calibration functions 5 EN ISO 10304-1:2009 (E) DIN EN ISO 10304-1:2009