ASTM F2669-2012 Standard Performance Specification for Protective Clothing Worn by Operators Applying Pesticides《杀虫剂施药人员穿的防护服的标准性能规范》.pdf

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1、Designation: F2669 12Standard Performance Specification forProtective Clothing Worn by Operators Applying Pesticides1This standard is issued under the fixed designation F2669; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the yea

2、r of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This specification establishes minimum performance,classification, and labeling requirements for protective cloth

3、ingworn by operators applying pesticide products, primarily fieldstrength, in liquid form.1.2 Protective clothing items covered by this specificationinclude, but are not necessarily limited to, liquid-tight orspray-tight garments, coveralls, jackets, shirts, and pants.1.3 This specification addresse

4、s protection provided byprotective accessories, with the exception of those used for theprotection of the head, hands, and feet.1.4 This specification does not address protection againstbiocides, fumigants, or highly volatile liquids.1.5 The values given in SI units are to be regarded as thestandard

5、.1.6 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced

6、Documents2.1 ASTM Standards:2D1424 Test Method for Tearing Strength of Fabrics byFalling-Pendulum (Elmendorf-Type) ApparatusD5034 Test Method for Breaking Strength and Elongationof Textile Fabrics (Grab Test)D5035 Test Method for Breaking Force and Elongation ofTextile Fabrics (Strip Method)F739 Tes

7、t Method for Permeation of Liquids and Gasesthrough Protective Clothing Materials under Conditions ofContinuous ContactF903 Test Method for Resistance of Materials Used inProtective Clothing to Penetration by LiquidsF2130 Test Method for Measuring Repellency, Retention,and Penetration of Liquid Pest

8、icide Formulation ThroughProtective Clothing Materials2.2 ISO Standards:3ISO 13688 ISO Protective ClothingGeneral Require-mentsISO 17491-4 Protective ClothingTest Methods for Cloth-ing Providing Protection Against ChemicalsPart 4:Determination of Resistance to Penetration by a Spray ofLiquid (Spray

9、Test)ISO 27065 Protective ClothingPerformance Require-ments for Work and Protective Clothing for Horticulturaland Agricultural Pesticide Workers3. Terminology3.1 Definitions:3.1.1 decontamination, nreduction, removal, or neutral-ization of a contaminant or contaminants from protectiveclothing to the

10、 extent necessary to safely permit the protectiveclothing to be doffed (taken off), or reused, or discarded.3.1.2 finish, nchemical or mechanical modification orboth of the fabric for a specific performance result.3.1.3 garment, nsingle item of clothing (for example, ashirt).3.1.4 penetration, nfor

11、chemical protective clothing, themovement of substances through voids in protective clothingmaterials or items on a non-molecular level.3.1.4.1 DiscussionVoids include gaps, pores, holes, andimperfections in closures, seams, interfaces, and protectiveclothing materials. Penetration does not require

12、a change ofstate; solid chemicals move through voids in the materials assolids, liquids as liquids, and gases as gases. Penetration is adistinctly different mechanism from permeation.3.1.5 permeation, nfor chemical protective clothing, themovement of chemicals through protective clothing materialite

13、ms by the processes of (1) absorption of the chemical intothe contact surface of the material, (2) diffusion of the absorbedmolecules throughout the material, and (3) desorption of thechemical from the opposite surface of the material.3.1.5.1 DiscussionPermeation is a distinctly differentmechanism f

14、rom penetration.3.1.6 protective clothing, nan item of clothing that isspecifically designed and constructed for the intended purpose1This specification is under the jurisdiction of ASTM Committee F23 onPersonal Protective Clothing and Equipment and is the direct responsibility ofSubcommittee F23.30

15、 on Chemicals.Current edition approved Aug. 1, 2012. Published September 2012. Originallyapproved in 2009. Last previous edition approved in 2009 as F2669 - 09. DOI:10.1520/F2669-12.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.o

16、rg. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3Available from American National Standards Institute (ANSI), 25 W. 43rd St.,4th Floor, New York, NY 10036, http:/www.ansi.org.1Copyright ASTM International, 100 Barr Harbor Drive

17、, PO Box C700, West Conshohocken, PA 19428-2959, United States.of isolating all or part of the body from a potential hazard; or,isolating the external environment from contamination by thewearer of the clothing.3.1.6.1 DiscussionFor the purpose of this specification,protective clothing materials inc

18、lude those materials used inthe construction of the suit or clothing that serve as the primarybarrier for the wearer. Protective clothing materials do notinclude materials used in the construction of integral visors,gloves, and footwear.3.1.7 seam, njunction between two or more pieces ofmaterial cre

19、ated by sewing, welding, or another method.3.1.8 test chemical, nsolid, liquid, or gas, or mixturethereof, used to evaluate the performance of a protectiveclothing material.3.1.8.1 DiscussionFor the purpose of this specification,the test chemical selected is limited to a liquid chemical.3.1.9 toxici

20、ty, npropensity of a substance to produceadverse biochemical or physiological effects.4. Classification and Test Requirements4.1 All protective clothing complying with this specificationshall fulfill the requirements of ISO 13688 and shall be testedand classified by the level of protection based on

21、the material,seam, and garment requirements included in Sections 5-7.Information on tests to be conducted for each level of protec-tion is included in Table 1.4.2 Level 1 garments shall be made of materials and withseams that demonstrate a minimum liquid penetration resis-tance when tested in accord

22、ance with tests specified in Table 1.The mechanical strength performance requirements are thesame for all levels of garments, and the garments shall pass apractical performance test.4.3 Level 2 garments shall be made of materials and withseams that demonstrate a higher level of liquid penetrationres

23、istance than Level 1 garments. The mechanical strengthperformance requirements are the same for all levels. Thegarments shall pass a practical performance test before beingsubmitted to a low-level spray test of the whole garment.4.4 If, for a particular pesticide, additional testing is re-quired to

24、fully characterize the material (this shall be decidedon the basis of the risk assessment provided for the registrationof the specific pesticide), the material shall also be tested forpermeation resistance using the pesticide in question. Whentested with specific pesticide formulations, information

25、regard-ing the test liquid shall be included in the information providedwith the garment. The mechanical strength performance re-quirements are the same for all levels. The garments shall passa practical performance test before being submitted to ahigh-level spray test of the whole garment, which is

26、 moresevere than the test for Level 2 garments. Level 3 protectiveclothing includes accessories such as aprons, protectivesleeves, and material placed below knapsack/backpack spray-ers, which is used for extra protection during spraying, mixing,and loading. Whole body testing is not required for acc

27、essoriesworn over whole body garments.5. Performance Requirements of Protective ClothingMaterials5.1 PreconditioningAll protective clothing materials ormaterial assemblies shall undergo 30 cycles of cleaning inaccordance with the manufacturers instructions before testing,if the manufacturers instruc

28、tions indicate that the garment canbe cleaned. However, garments that, in accordance with themanufacturers instructions, can be cleaned fewer than 30times shall undergo only as many cycles of cleaning asindicated by the manufacturers instructions. After the lastcleaning cycle, materials to be tested

29、 for penetration shall beair dried and shall not be ironed before testing.NOTE 1Garments do not need to be dried between wash cycles.5.1.1 If the manufacturer requires special cleaning or main-tenance conditions, this information shall be included as part ofa warning label in accordance with Section

30、 8.NOTE 2The purpose of the warning label is to inform the user ofspecial requirements that, if not followed, have the potential to impact theprotective properties of the garment. Examples of special conditionsinclude, but are not limited to, use of a specific detergent or use of heatsuch as tumble

31、dry or ironing to reactivate the repellent finish.TABLE 1 Testing Requirements for Level 1, 2, and 3 GarmentsSpecific Performance TestLevel1A23Material Requirements Liquid penetration resistance (Test Method F2130)xBxBResistance to penetration by liquid under pressure (Test Method F903)xResistance t

32、o permeation (Test Method F739CBreaking strength (Test Method D5035Tearing strength (Test Method D1424Seam requirements Liquid penetration resistance (Test Method F2130BxBResistance to penetration by liquid under pressure (Test Method F903)xResistance to permeation (Test Method F739CBreaking strengt

33、h (Test Method D5034)xWhole garment requirements Practical performance test xxxLow-level spray test (ISO 17491-4, Method A) xHigh-level spray test (ISO 17491-4, Method B) xALevel 1 is equivalent to Level 1b of ISO 27065.BThe minimum performance requirement for Level 2 is considerably more severe tha

34、n for Level 1 (see 5.2).CIf, for a particular pesticide, additional testing is required to fully characterize the material (this shall be decided on the basis of the risk assessment provided for theregistration of the specific pesticide), the material shall also be tested for permeation resistance u

35、sing the pesticide in question. When tested with specific pesticideformulations, information regarding the test liquid shall be included in the information provided with the garment.F2669 1225.2 Material Penetration Resistance:5.2.1 Penetration testing for Level 1 and Level 2 garmentsshall be conduc

36、ted in accordance with Test Method F2130,Method A, using 0.2 mL of test chemical. The average of threepercent penetration values shall be used to classify the mate-rial. If the average of three readings is within 10 % of thethreshold, the test shall be repeated for an additional set ofthree readings

37、, and the average of six readings shall be used toclassify the material. If more than one type of material is usedto construct the garment, three specimens of each material shallbe tested. Prowl 3.3, an emulsifiable concentrate with 37.4 %pendimethalin, diluted with distilled water to 5 % activeingr

38、edient (a.i.) shall be used. It is acceptable to substitute thetest chemical as long as it has been verified that the sameperformance rating for materials and seams is achieved.5.2.2 If the garment consists of a combination of separatelayers of materials, all layers shall be tested together with the

39、outer fabric exposed to the test chemical. For single-layergarments constructed from different types of materials, eachmaterial shall be tested separately and the penetration classifi-cation based on the lowest performing level.5.2.3 Materials classified as Level 1 shall have an averagepenetration v

40、alue #40 %. If the material fails to meet therequirement, Test Method F2130, Method B, an analyticmethod, can be used to verify the results obtained for MethodA.5.2.4 Materials classified as Level 2 shall have an averagepenetration value of 5 % or less. If the material fails to meet therequirement,

41、Test Method F2130, Method B, an analyticmethod, can be used to verify the results obtained for MethodA.NOTE 3It is possible that some materials, such as those with amicroporous membrane, will allow water and not the a.i. to penetratethrough the fabric. If bright yellow, the color of pendimethalin, i

42、s notvisible on the collector layer, proceed with analytical testing using MethodB.NOTE 4The pipette test is an accelerated laboratory test that differ-entiates the penetration performance of materials. The maximum allow-able penetration of 40 % is derived from the pipette data analysis of cottonand

43、 cotton/polyester garment materials typically used for operator expo-sure studies. Therefore, it is not possible to substitute laboratory data fromthe pipette method for field penetration data. For this reason, the 40 %limit shall not be used to calculate default protection factors used forexposure

44、mitigation in operator exposure and risk assessment.5.2.5 The results shall be reported in the manufacturersproduct technical information (see Section 8).5.3 Material Resistance to Penetration by Liquid underPressure:5.3.1 Resistance to penetration by liquid under pressure forLevel 3 garments shall

45、be tested in accordance with TestMethod F903. Three specimens shall be tested for eachmaterial. Use Prowl 3.3, an emulsifiable concentrate with37.4 % pendimethalin, diluted with distilled water to 5 % a.iTest the specimens at 0-kPa pressure for 1 min. Then increasethe pressure at increments of 1 kPa

46、 every minute until failureis observed or a maximum of 15 kPa is reached. A materialmeets the requirements if all three specimens pass the test at apressure 14 kPa. It is acceptable to substitute the test chemicalas long as it has been verified that the same performance ratingfor materials and seams

47、 is achieved.5.3.2 If the garment consists of a combination of separatelayers of materials, all layers shall be tested together with theouter fabric exposed to the test chemical. For single-layergarments constructed from different types of materials, eachmaterial shall be tested separately and the p

48、enetration classifi-cation based on the lowest performing level.5.3.3 The results shall be reported in the manufacturersproduct technical information (see Section 8).5.4 Material Resistance to Permeation (Alternative to Liq-uid Pressure Test):5.4.1 If, for a particular pesticide, additional testing

49、isrequired to fully characterize the material (this shall be decidedon the basis of the risk assessment provided for the registrationof the specific pesticide), the material shall also be tested inaccordance with Test Method F739. The average of the threepermeation readings shall be used to determine the normalizedbreakthrough time (see Note 5). The test liquid shall be thespecific pesticide formulation diluted with water in accordancewith the manufacturers instructions. Materials classified forLevel 3 garments shall have a normalized breakthrough time30