ASTM D5205-1996(2003) Standard Classification System for Polyetherimide (PEI) Materials《聚醚酰亚胺(PEI)材料的标准分类体系》.pdf

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1、Designation: D 5205 96 (Reapproved 2003)Standard Classification System forPolyetherimide (PEI) Materials1This standard is issued under the fixed designation D 5205; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last r

2、evision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope1.1 This classification system covers unfilled

3、, filled, andreinforced polyetherimide materials suitable for injectionmolding and extrusion.1.2 This classification system is not intended for the selec-tion of materials, but only as a means to call out plasticmaterials to be used for the manufacture of parts. The selectionof these materials is to

4、 be made by personnel with expertise inthe plastics field where the environment, inherent properties ofthe materials, performance of the parts, part design, manufac-turing process, and economics are considered.1.3 The properties included in this classification system arethose required to identify th

5、e compositions covered. There maybe other requirements necessary to identify particular charac-teristics important to specific applications. These may bespecified by using suffixes as described in Section 5.1.4 The values stated in SI units are to be regarded as thestandard.1.5 The following precaut

6、ionary caveat pertains only to thetest methods portion, Section 12, of this classification system:This standard does not purport to address all of the safetyconcerns, if any, associated with its use. It is the responsibilityof the user of this standard to establish appropriate safety andhealth pract

7、ices and determine the applicability of regulatorylimitations prior to use. Specific precautionary statements aregiven in Note 4.2. Referenced Documents2.1 ASTM Standards:D 149 Test Methods for Dielectric Breakdown Voltage andDielectric Strength of Electrical Insulating Materials atCommercial Power

8、Frequencies2D 150 Test Methods for A-C Loss Characteristics andPermittivity (Dielectric Constant) of Solid Electrical Insu-lation2D 257 Test Methods for D-C Resistance or Conductance ofInsulating Materials2D 618 Practice for Conditioning Plastics for Testing3D 638 Test Method for Tensile Properties

9、of Plastics3D 648 Test Method for Deflection Temperature of PlasticsUnder Flexural Load in the Edgewise Position3D 790 Test Methods for Flexural Properties of Unreinforcedand Reinforced Plastics and Electrical Insulating Materi-als3D 792 Test Method for Specific Gravity (Relative Density)and Density

10、 of Plastics by Displacement3D 883 Terminology Relating to Plastics3D 1238 Test Method for Melt Flow Rates of Thermoplasticsby Extrusion Plastometer3D 1600 Terminology for Abbreviated Terms Relating toPlastics3D 1897 Practice for Injection Molding Test Specimens ofThermoplastic Molding and Extrusion

11、 Materials4D 2584 Test Method for Ignition Loss of Cured ReinforcedResins5D 2863 Test Method for Measuring the Minimum OxygenConcentration to Support Candle-Like Combustion ofPlastics (Oxygen Index)5D 3892 Practice for Packaging/Packing of Plastics5D 4000 Classification System for Specifying Plastic

12、 Mate-rials5E29 Practice for Using Significant Digits in Test Data toDetermine Conformance with Specifications6E 662 Test Method for Specific Optical Density of SmokeGenerated by Solid Materials72.2 Military Standards:8MIL-P-46184 Plastic Molding and Extrusion Materials,Polyetherimide (PEI).MIL-M-24

13、519 Molding Plastics, Electrical, Thermoplastic1This classification system is under the jurisdiction ofASTM Committee D20 onPlastics and is the direct responsibility of Subcommittee D20.15 on ThermoplasticMaterials.Current edition approved Aug. 10, 2003. Published October 2003. Originallyapproved in

14、 1991. Last previous edition approved in 1996 as D 5205 96.2Annual Book of ASTM Standards, Vol 10.01.3Annual Book of ASTM Standards, Vol 08.01.4DiscontinuedSee 1991 Annual Book of ASTM Standards, Vol 08.02.5Annual Book of ASTM Standards, Vol 08.02.6Annual Book of ASTM Standards, Vol 14.02.7Annual Bo

15、ok of ASTM Standards, Vol 04.07.8Available from Standardization Documents Order Desk, Bldg. 4 Section D,Available from Standardization Documents Order Desk, Bldg. 4 Section D, 700Robbins Ave., Philadelphia, PA 19111-5094, Attn: NPODS.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700,

16、 West Conshohocken, PA 19428-2959, United States.2.3 Underwriters Laboratories Standards:9UL 94 Tests for Flammability of Plastic Materials for Partsin Devices and Appliances3. Terminology3.1 DefinitionsThe terminology used in this classificationsystem is in accordance with Terminologies D 883 and D

17、 1600.3.2 Abbreviations:AbbreviationThe polyetherimide mate-rials will be designated “PEI” as specified in TerminologyD 1600.4. Classification4.1 Unfilled polyetherimide materials are classified intogroups according to their composition. These groups aresubdivided into classes and grades as shown in

18、 Table PEI.NOTE 1An example of this classification system is given as follows.The designation PEI 0114 indicates the following:PEI = polyetherimide as found in Terminology D 1600,01 = polyetherimide (group),1 = general purpose (class), and4 = requirements given in Table PEI (grade).4.1.1 To facilita

19、te incorporation of future or special materi-als the “other” category (0) for group, class, and grade is shownin Table PEI. The basic properties of these materials can beobtained from Tables A or B as they apply.4.2 Reinforced, pigmented, filled, and lubricated versions ofpolyetherimide materials ar

20、e classified in accordance withTables PEI and A or B. Table PEI is used to specify theunreinforced material and Table A or B is used to specify theproperty requirements after the addition of reinforcements,pigments, fillers, or lubricants at the nominal level indicated(see 4.2.1).4.2.1 A single lett

21、er shall be used to indicate the majorcategory of the reinforcement, along with two numbers thatindicate the percentage of additive(s) by mass, with thetolerances as tabulated as follows:Category Material Tolerance(Based on the Total Mass)C Carbon and graphite fiber-reinforced62 percentage pointsG G

22、lass-reinforced15 % glass content 63 percentage pointsL Lubricants (such as PTFE, graph-ite, silicone, and molybdenum dis-ulfide)Variable. To be specified by user.M Mineral-reinforced 62 percentage pointsR Reinforced-combination/mixturesof reinforcements or other fillers/reinforcements63 percentage

23、points based onthe total reinforcementNOTE 2If necessary, additional requirements may be specified usingsuffixes as described in Section 5. Special agreements on tolerances maybe required when levels are below 5 %. Ash content of filled or reinforcedmaterials may be determined using Test Method D 25

24、84 where applicable.4.2.2 Specific requirements for reinforced, filled, or lubri-cated polyetherimide materials shall be shown by a six-character designation. The designation will consist of the letter“A” or “B” and the five digits comprising the cell numbers forthe property requirements in the orde

25、r as they appear in TablesPEI or A.4.2.2.1 Although the values listed are necessary to includethe range of properties available in existing materials, usersshould not infer that every possible combination of theproperties exists or can be obtained.4.2.3 When the grade of the basic materials is not s

26、hown, oris not important, the use of “O”-grade classification shall beused for reinforced materials in this system.NOTE 3An example of this classification for a polyetherimide mate-rial is given as follows. The designation PEI0110G10A48266 wouldindicate the following material requirements:PEI 0110 =

27、 general-purpose polyetherimide from Table PEI,G10 = glass reinforced at nominal 10 % level,A = Table A property requirements,4 = 110-MPa tensile strength, min,8 = 13790-MPa flexural modulus, min,2 = 4 g/10 min; melt flow, min,6 = 205-MPa flexural strength, min, and6 = 230C deflection temperature, m

28、in.If no properties are specified, the designation would bePEI0110G10A00000.5. Suffixes5.1 When requirements not covered by the basic cell tablesneed to be specified, suffixes shall be used. The followingsuffixes shall be used when appropriate. Additional suffixesmay also be defined according to Cla

29、ssification System D 4000when needed.5.1.1 E = Electrical requirements as designated by thefollowing digits:First Digit0 = specimen to be specified by user1 = specimens as appropriate for test methods as defined in Table 1Second Digit0 = to be specified by user1 = meets requirements of Table 1, Colu

30、mn A2 = meets requirements of Table 1, Column B3 = meets requirements of Table 1, Column C4 = meets requirements of Table 1, Column D5 = meets requirements of Table 1, Column E5.1.2 F = Flammability requirements as designated by thefollowing digits:NOTE 4Precaution: By publication of this classifica

31、tion system andits use of flammability ratings, ASTM does not intend that their use in anyway reflects hazards presented under actual fire conditions.First Digit0 = to be specified by user,1 = product is tested according to UL94 at 3.05-mm minimum thickness,2 = product is tested according to UL94 at

32、 1.47-mm minimum thickness,3 = product is tested according to UL94 at 0.71-mm minimum thickness,4 = product is tested according to Test Method D 2863,5 = product is tested according to Test Method E 662.Second Digit0 = To be specified by user1 = 94V-0 flammability class2 = 94V-1 flammability class3

33、= 94V-2 flammability class4 = 94-5V flammability class5 = Oxygen index 44 % minimum6 = Specific optical density, flaming mode, D4 # 2, D max # 50.6. General Requirements6.1 The plastic compositions shall be uniform and shallconform to the requirements specified herein.9Available from Underwriters La

34、boratories Inc., 333 Pfingsten Road, North-brook, IL 60066.D 5205 96 (2003)2TABLE PEI Polyetherimide Materials Detail RequirementsNOTE 1The values listed were developed for “natural colors.” Pigments or other additives, or both, may alter these properties.Group Description Class DescriptionAGrade De

35、scriptionFlow-Rate,BTest MethodD 1238,g/10, minSpecificGravity, TestMethodD 792DeflectionATemperature(DTUL), min,Test MethodD 648,C, minTensileBStrength,Test MethodD 638,MPa, minFlexuralCStrength,TestMethodsD 790,MPa, minFlexuralEModulus,TestMethodsD 790,MPa, min01 Polyetheri- 1 General-Purpose1 30

36、1.251.30 190 83 138 29000 Other . . . . . .2 Impact-Modified1 30 1.221.28 180 69 103 22800 Other . . . . . .0 Other 0 Other . . . . . .02 PEI Chemical 1 General-Purpose1 30 1.251.30 196 90 124 27600 Other . . . . . .2 Impact-Modified1 30 1.221.28 184 69 90 20700 Other . . . . . .3 High-Heat 1 30 1.2

37、71.32 215 97 145 27600 Other . . . . . .4 High-Heat 1 30 1.231.30 200 69 103 20700 Other 0 Other . . . . . .03 PEI Heat- 1 General-Purpose1 30 1.271.31 210 90 131 27600 Other . . . . . .D 5205 96 (2003)3TABLE ContinuedGroup Description Class DescriptionAGrade DescriptionFlow-Rate,BTest MethodD 1238,

38、g/10, minSpecificGravity, TestMethodD 792DeflectionATemperature(DTUL), min,Test MethodD 648,C, minTensileBStrength,Test MethodD 638,MPa, minFlexuralCStrength,TestMethodsD 790,MPa, minFlexuralEModulus,TestMethodsD 790,MPa, min2 Impact-Modified1 30 1.221.28 196 69 110 20700 Other . . . . . .3 High-Hea

39、t 1 30 1.281.32 225 103 138 27600 Other . . . . . .4 High-Heat 1 30 1.241.28 210 69 97 20700 Other . . . . . .0 Other 0 Other . . . . . .04 PEIFlexible 1 General-Purpose1 30 1.161.20 N/A 34 52 6900 Other . . . . . .2 Semirigid 1 30 1.161.20 N/A 21 14 690 Other . . . . . .3 Nonrigid 1 30 1.101.20 N/A

40、 7 7 690 Other . . . . . .0 Other 0 Other . . . . . .ANo descriptions are listed unless needed to describe a special grade under the class. All other grades are listed by requirements.BConditionsMethod A, 6.7 kg, 2.0955-mm inside diameter orifice:Group-Class Test Temperatures, C011, 012, 021, 022 33

41、7023, 024, 031, 032, 033, 034 367041, 042, 043 295A,B,C,DASpecimens 6.4 mm tested at 1.82 MPa.BType 1 bar, speed 5.1 mm/min.CMethod I, Procedure A, speed = 2.5 mm/min, span-to-depth ratio 16/1 (tangent modulus).D“N/A” indicates the particular data so designated is considered “Not Applicable” to the

42、product being considered.D 5205 96 (2003)4TABLE A Detail Requirements Filled or Reinforced PEI, or BothNOTE 1Resin samples should be dried4hat160C in an air-circulating oven before molding specimens to be used in these tests and beforedetermining melt-flow rate.Designa-tionOrderProperty/ASTM TestMet

43、hodUnits 01 2345 6 7 891 Tensile strength, min, D638,AType Ibar, 0.2 in./minMPaBC25 55 80 110 135 165 190 220D2 Flexural modulus, min, D 790EMPaBC690 1720 3450 5170 6900 8620 10340 13790D3 Flow Rate, min, D1238Fg/10 minC1471013162024D4 Flexural strength, min, D 790EMPaBC30 65 100 135 170 205 240 275

44、D5 Deflection Temperature, min, D 648GGCC180 190 200 210 220 230 240 250DAType I bar, speed = 5.1 mm/min.BMPa 3 145 = psi.CUnspecified.DSpecific value (must be shown).EMethod 1, Procedure A; speed = 2.55 mm/min.FConditionsMethod A, 6.7 kg, 2.0955-mm inside diameter orifice:G6.4-mm thick specimen tes

45、ted at 1.82 MPa.Group-Class Test Temperatures, C011, 012, 021, 022 337023, 024, 031, 032, 033, 034 367041, 042, 043 295TABLE B Detail Requirements Unreinforced/Unfilled PEINOTE 1Resin samples should be dried4hat160C in an air-circulating oven before molding specimens to be used in these tests and be

46、foredetermining melt-flow rate.Designa-tionOrderProperty/ASTM TestMethodUnits 0 1 2 3 4 5 6 7 8 91 Tensile strength, min, D638AMPaBC14 25 40 55 65 80 95 110D2 Flexural modulus, min, D790EMPa 7 30 65 340 690 1380 2070 2760D3 Flow Rate, min, D1238Fg/10 minC2 6 10 14 18 22 26 30D4 Flexural strength, mi

47、n, D790EMPaBC7 30 65 90 110 130 150 170D5 Deflecting Temperature, min, D648GGCC170 180 190 200 210 220 230 240DAType I bar, speed = 5.1 mm/min.BMPa 3 145 = psi.CUnspecified.DSpecific value (must be shown).EMethod 1, Procedure A; speed = 2.55 mm/min.FConditionsMethod A, 6.7 kg, 2.0955-mm inside diame

48、ter orifice:G6.4-mm thick specimen tested at 1.82 MPa.Group-Class Test Temperatures, C011, 012, 021, 022 337023, 024, 031, 032, 033, 034 367041, 042, 043 295TABLE 1 Detail RequirementsNOTE 1Resin samples should be dried4hat160C in an air-circulating oven before molding specimens to be used in these

49、tests.Property ConditionAUnits A B C D EDielectric constant,Bmax 48/50 + D24/231 KHz, 50 % RH, 23C . 3.2 3.7 3.7 3.8 .1 MHz . . . . . 3.5Dissipation factor,Bmax 48/50 + D24/231 KHz, 50 % RH, 23C . 0.0015 0.0016 0.0017 0.0017 .2450 MH, 50 % RH, 23C . 0.003 . . . .1 MH, 50 % RH, 23C . . . . . 0.007Volume resistivity,Cmin 24/23/50 ohm-cm 1016101610161016.Dielectric strength,Dmin (1.6-mm thickness, inoil, S/T)48/50 + 96/23/50 KV/mm(V/mil)23.6 23.0 22.0 21.0 17.0Specific gravityE. . 1.27 1.34 1.42 1.51 .AIn accordance with Practice D 618.BSee T