ASTM D2354-2010(2018) Standard Test Method for Minimum Film Formation Temperature (MFFT) of Emulsion Vehicles.pdf

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1、Designation: D2354 10 (Reapproved 2018)Standard Test Method forMinimum Film Formation Temperature (MFFT) of EmulsionVehicles1This standard is issued under the fixed designation D2354; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision,

2、 the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method covers the determination of the mini-mum temperature at which emulsion vehicles coalesce

3、 to formcontinuous films. The term “emulsion” in this test methodincludes latex vehicles.1.2 This test method is limited to emulsions having mini-mum film formation temperatures below 90C.1.3 The values stated in inch-pound units are to be regardedas standard. The values given in parentheses are mat

4、hematicalconversions to SI units that are provided for information onlyand are not considered standard.1.4 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety, heal

5、th, and environmental practices and deter-mine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accor-dance with internationally recognized principles on standard-ization established in the Decision on Principles for theDevelopment of Internat

6、ional Standards, Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade (TBT) Committee.2. Summary of Test Method2.1 In this test method the minimum film formation tem-perature (MFFT) is determined by visual observation ofcracking or whitening in films that hav

7、e dried over a substratehaving a controlled temperature gradient.3. Significance and Use3.1 The satisfactory film integrity of emulsion coatingsrequires that as the aqueous phase evaporates the resinousportion of the vehicle coalesces into a continuous film. Lowtemperature impairs the fluidity of th

8、e resin particle andthereby their ability to coalesce. Vehicles that can withstandlow temperatures are therefore required, and MFFT is animportant quality feature of emulsion vehicles.4. Apparatus4.1 Minimum Film Formation Temperature BarAn MFFTunit2such as is illustrated in Fig. 1. The bar represen

9、ted in Fig.1 is designed to be used with thermocouples. The thermo-couple leads used with the assembly are iron-constantan withan external resistance of 10 . Also included is a pyrometer(not shown in Fig. 1).NOTE 1Thermometers can be used as an alternative way of measuringtemperature.3It is noted th

10、at larger holes (532 in.) (4 mm) will have to bedrilled in the bar to accommodate the thermometers. If thermometers areselected, all holes are drilled on the same side of the bar, as opposed to thesystem of alternate placement of holes when using thermocouples.NOTE 2Aself-contained unit eliminating

11、the need for any accessories,such as for sub-ambient cooling or temperature measurement, andrequiring only an electrical outlet, piped water, and an air or nitrogensupply has been developed by ICI Paints Division.44.2 Dry Air or Dry Nitrogen Supply, with a regulating valveand flow meter.4.3 Film Cas

12、ter, having a 6-mil (150-m) clearance.5. Reagents and Materials5.1 Dry Ice.5.2 Isopropanol, anhydrous.1This test method is under the jurisdiction of ASTM Committee D01 on Paintand Related Coatings, Materials, and Applications and is the direct responsibility ofSubcommittee D01.33 on Polymers and Res

13、ins.Current edition approved Sept. 1, 2018. Published September 2018. Originallyapproved in 1965. Last previous edition approved in 2010 as D2354 101. DOI:10.1520/D2354-10R18.2The sole source of supply of the MFFT bar, Model CS 188, known to thecommittee at this time is Dek-Tron Scientific Instrumen

14、t Corp., 244 East 3rd Street,Plainfield, NJ 07060. If you are aware of alternative suppliers, please provide thisinformation to ASTM International. Your comments will receive careful consider-ation at a meeting of the responsible technical committee,1which you may attend.3The sole source of supply o

15、f the thermometer, Prince No. A-011044 known tothe committee at this time is Princo Instruments Inc., 1020 Industrial Hwy.,Southampton, PA 18966. If you are aware of alternative suppliers, please providethis information to ASTM International. Your comments will receive carefulconsideration at a meet

16、ing of the responsible technical committee,1which you mayattend.4The sole source of supply of the MFFTBAR units, Models MFFT-60, andMFFT-90, known to the committee at this time is Rhopoint House, Enviro 21 Park,Queensway Avenue South, Queensway, St. Leonards-on-Sea, East Sussex, TN389AG, UK. For the

17、 name of a local distributor search their website at ww-. Interested parties are invited to submit informationregarding the identification of acceptable alternatives to the Committee onStandards, ASTM International. Your comments will receive careful considerationat a meeting of the responsible tech

18、nical committee,1which you may attend.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United StatesThis international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on

19、Principles for theDevelopment of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.16. Procedure6.1 Set up the MFFT bar in a level position with the lowertemperature leg of the bar immersed in a dry ice-isopropanolb

20、ath. It is important that the surface of the bar be smooth andplane to ensure uniform film thicknesses. Use a12-gal (2-L)container for this purpose. (The container can be insulated withany suitable material to reduce heat loss.) Adjust the height ofthe dry ice-isopropanol bath as needed to bring the

21、 temperatureof the bar to approximately 0C at the lowest temperature-measuring stage of the unit. Lower or higher temperatures canbe obtained, if needed, by adjusting the bath height. The bathheight needed to obtain 0C will vary depending on the heatconductivity of the metal used in the construction

22、 of the bar.Expose the higher temperature end of the bar at approximately25C by either conducting the test in a constant-temperatureroom at this temperature or by thermostatting the leg.6.2 Immediately after imposing the temperature gradient onthe bar, place the cover over it and adjust the flow of

23、dry air (ornitrogen) at a rate of 4 L/min from the low-temperature end tothe high-temperature end of the bar. Allowing the air to retainmoisture by warming up prevents water condensation at thecold temperature end that would interfere with film drying.Approximately 45 min is needed for the temperatu

24、re gradientto reach equilibrium once the bar is placed in operation. The airmanifold holes must be clean and free of frost before startinga test.NOTE 3A mixture of ethylene glycol and surfactant applied to the airoutlet alleviates the frosting condition temporarily.6.3 Once a constant-temperature gr

25、adient is established,remove the cover and cast the films using the 3-mil (75 m)applicator (Note 3). Cast films from the low to the high-temperature end of the bar because the extension at thehigh-temperature end is designed to permit overflow to fall intoa container below the bar. After the film is

26、 cast and the coverput in place, approximately 1 to 2 h are required for the film todry. Check the air flow and isopropanol bath height before anytests are started and then maintain them at their respectivelevels until the test is completed.NOTE 4If desired, a12-mil (13-m) polyethylene terephthalate

27、 sheetof 5-in. (125-mm) width can be placed on the bar surface before castingthe film. Tests show that there are no differences between minimumfilming temperatures determined with and without the sheet. The polyeth-ylene terephthalate film permits not only easier clean-up of the apparatus,but also a

28、 semi-permanent record of the test. Special care must beexercised to ensure good contact of the sheet with the bar.Accomplish thisby either of the following techniques:(1) Wipe the sheet with a dry cloth to develop a static charge beforeplacement on the bar.(2) Coat the sheet with silicone oil befor

29、e placement on the bar6.4 After the film has dried, observe for discontinuity asevidenced by whitening or cracking or both. Record the lowesttemperature on the bar at which the film is still continuous asthe minimum film formation temperature.7. Report7.1 Report the following information:7.1.1 MFFT

30、in degrees Celsius, andNOTE 11 in. = 25.4 mm.FIG. 1 Minimum Film Formation Temperature BarD2354 10 (2018)27.1.2 Description of the discontinuity indicating degree ofwhitening and cracking.8. Precision and Bias8.1 PrecisionInformation for a formal precision statementhas not yet been obtained, but it

31、is reported that MFFT valuesobtained by this test method can be expected to fall within62C of their mean.8.2 BiasNo information can be presented on the bias ofthe procedure of this test method, because no material havingan accepted reference value is available.9. Keywords9.1 emulsion vehicles; film

32、formation; minimum film for-mation temperature; MFFTASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rig

33、hts, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for

34、 revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing

35、 you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may

36、 be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ 10 (2018)3