CEN TR 17055-2017 Workplace exposure - Measurement of chemical agents complying with the requirements given in EN 482 and either one of EN 838 EN 1076 EN 13205 EN 13890 and EN 1393.pdf

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1、PD CEN/TR 17055:2017Workplace exposure Measurement of chemicalagents complying with therequirements given in EN 482and either one of EN 838, EN1076, EN 13205, EN 13890and EN 13936 Choice ofproceduresBSI Standards PublicationPD CEN/TR 17055:2017 PUBLISHED DOCUMENTNational forewordThis Published Docum

2、ent is the UK implementation of CEN/TR 17055:2017.The UK participation in its preparation was entrusted to Technical Committee EH/2/2, Work Place Atmospheres .A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to includ

3、e all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2017. Published by BSI Standards Limited 2017ISBN 978 0 580 94047 7 ICS 13.040.30 Compliance with a British Standard cannot confer immunity from legal obligations.This B

4、ritish Standard was published under the authority of the Standards Policy and Strategy Committee on 31 March 2017.Amendments/corrigenda issued since publicationDate Text affectedg23g8g6g11g17g12g6g4g15g3g21g8g19g18g21g23g3g21g4g19g19g18g21g23g3g23g8g6g11g17g12g20g24g8g3g23g8g6g11g17g12g22g6g11g8g21g

5、3g5g8g21g12g6g11g23g3CEN/TR 17055 g9g135g132g148g151g131g148g155g3g884g882g883g889g3g12g6g22g3g883g885g484g882g886g882g484g885g882g3g8g144g137g142g139g149g138g3g25g135g148g149g139g145g144g3g26g145g148g141g146g142g131g133g135g3g135g154g146g145g149g151g148g135g3g486g3g16g135g131g149g151g148g135g143g13

6、5g144g150g3g145g136g3g133g138g135g143g139g133g131g142g3g131g137g135g144g150g149g3g133g145g143g146g142g155g139g144g137g3g153g139g150g138g3g150g138g135g3g148g135g147g151g139g148g135g143g135g144g150g149g3g137g139g152g135g144g3g139g144g3g8g17g3g886g890g884g3g131g144g134g3g135g139g150g138g135g148g3g145g1

7、44g135g3g145g136g3g8g17g3g890g885g890g481g3g8g17g3g883g882g889g888g481g3g8g17g3g883g885g884g882g887g481g3g8g17g3g883g885g890g891g882g3g131g144g134g3g8g17g3g883g885g891g885g888g3g486g3g6g138g145g139g133g135g3g145g136g3g146g148g145g133g135g134g151g148g135g149g3g8g154g146g145g149g139g150g139g145g144g3g

8、149g151g148g3g142g135g149g3g142g139g135g151g154g3g134g135g3g150g148g131g152g131g139g142g3g486g3g16g135g149g151g148g131g137g135g3g134g135g149g3g131g137g135g144g150g149g3g133g138g139g143g139g147g151g135g149g3g133g145g144g136g145g148g143g177g143g135g144g150g3g131g151g154g3g135g154g139g137g135g144g133g1

9、35g149g3g149g146g177g133g139g136g139g177g135g149g3g134g131g144g149g3g142g821g8g17g3g886g890g884g3g135g150g3g134g131g144g149g3g142g821g151g144g135g3g134g135g149g3g144g145g148g143g135g149g3g8g17g3g890g885g890g481g3g8g17g3g883g882g889g888g481g3g8g17g3g883g885g884g882g887g481g3g8g17g3g883g885g890g891g88

10、2g3g135g150g3g8g17g3g883g885g891g885g888g3g486g3g6g138g145g139g154g3g134g135g149g3g143g145g134g135g149g3g145g146g177g148g131g150g145g139g148g135g149g3g8g154g146g145g149g139g150g139g145g144g3g131g143g3g4g148g132g135g139g150g149g146g142g131g150g156g3g486g3g16g135g149g149g151g144g137g3g152g145g144g3g13

11、3g138g135g143g139g149g133g138g135g144g3g4g148g132g135g139g150g149g149g150g145g136g136g135g144g481g3g153g135g142g133g138g135g3g134g139g135g3g4g144g136g145g148g134g135g148g151g144g137g135g144g3g144g131g133g138g3g8g17g3g886g890g884g3g149g145g153g139g135g3g144g131g133g138g3g135g139g144g135g148g3g152g145

12、g144g3g8g17g3g890g885g890g481g3g8g17g3g883g882g889g888g481g3g8g17g3g883g885g884g882g887g481g3g8g17g3g883g885g890g891g882g3g151g144g134g3g8g17g3g883g885g891g885g888g3g135g148g136g242g142g142g135g144g3g486g3g4g151g149g153g131g138g142g3g152g145g144g3g25g135g148g136g131g138g148g135g144g23g138g139g149g3g

13、23g135g133g138g144g139g133g131g142g3g21g135g146g145g148g150g3g153g131g149g3g131g146g146g148g145g152g135g134g3g132g155g3g6g8g17g3g145g144g3g891g3g13g131g144g151g131g148g155g3g884g882g883g889g484g3g12g150g3g138g131g149g3g132g135g135g144g3g134g148g131g153g144g3g151g146g3g132g155g3g150g138g135g3g23g135g

14、133g138g144g139g133g131g142g3g6g145g143g143g139g150g150g135g135g3g6g8g17g512g23g6g3g883g885g889g484g3g6g8g17g3g143g135g143g132g135g148g149g3g131g148g135g3g150g138g135g3g144g131g150g139g145g144g131g142g3g149g150g131g144g134g131g148g134g149g3g132g145g134g139g135g149g3g145g136g3g4g151g149g150g148g139g1

15、31g481g3g5g135g142g137g139g151g143g481g3g5g151g142g137g131g148g139g131g481g3g6g148g145g131g150g139g131g481g3g6g155g146g148g151g149g481g3g6g156g135g133g138g3g21g135g146g151g132g142g139g133g481g3g7g135g144g143g131g148g141g481g3g8g149g150g145g144g139g131g481g3g9g139g144g142g131g144g134g481g3g9g145g148g

16、143g135g148g3g28g151g137g145g149g142g131g152g3g21g135g146g151g132g142g139g133g3g145g136g3g16g131g133g135g134g145g144g139g131g481g3g9g148g131g144g133g135g481g3g10g135g148g143g131g144g155g481g3g10g148g135g135g133g135g481g3g11g151g144g137g131g148g155g481g3g12g133g135g142g131g144g134g481g3g12g148g135g14

17、2g131g144g134g481g3g12g150g131g142g155g481g3g15g131g150g152g139g131g481g3g15g139g150g138g151g131g144g139g131g481g3g15g151g154g135g143g132g145g151g148g137g481g3g16g131g142g150g131g481g3g17g135g150g138g135g148g142g131g144g134g149g481g3g17g145g148g153g131g155g481g3g19g145g142g131g144g134g481g3g19g145g1

18、48g150g151g137g131g142g481g3g21g145g143g131g144g139g131g481g3g22g135g148g132g139g131g481g3g22g142g145g152g131g141g139g131g481g3g22g142g145g152g135g144g139g131g481g3g22g146g131g139g144g481g3g22g153g135g134g135g144g481g3g22g153g139g150g156g135g148g142g131g144g134g481g3g23g151g148g141g135g155g3g131g144

19、g134g3g24g144g139g150g135g134g3g14g139g144g137g134g145g143g484g3g8g24g21g18g19g8g4g17g3g6g18g16g16g12g23g23g8g8g3g9g18g21g3g22g23g4g17g7g4g21g7g12g29g4g23g12g18g17g3g6g18g16g12g23g50g3g8g24g21g18g19g50g8g17g3g7g8g3g17g18g21g16g4g15g12g22g4g23g12g18g17g3g8g24g21g18g19g34g12g22g6g11g8g22g3g14g18g16g12

20、g23g8g8g3g9g111g21g3g17g18g21g16g24g17g10g3g3CEN-CENELECg3Management Centre: Avenue Marnix 17, B-1000 Brussels g825g3g884g882g883g889g3g6g8g17g3 g4g142g142g3g148g139g137g138g150g149g3g145g136g3g135g154g146g142g145g139g150g131g150g139g145g144g3g139g144g3g131g144g155g3g136g145g148g143g3g131g144g134g3g

21、132g155g3g131g144g155g3g143g135g131g144g149g3g148g135g149g135g148g152g135g134g3g153g145g148g142g134g153g139g134g135g3g136g145g148g3g6g8g17g3g144g131g150g139g145g144g131g142g3g16g135g143g132g135g148g149g484g3g21g135g136g484g3g17g145g484g3g6g8g17g512g23g21g3g883g889g882g887g887g483g884g882g883g889g3g8

22、CEN/TR 17055:2017 (E) 2 Contents Page European foreword . 3 Introduction 4 1 Scope 5 2 Measuring procedures 5 2.1 General 5 2.2 Selection of chemical agents . 5 3 Method lists . 6 3.1 General 6 3.2 Origin of the measuring procedure 6 3.3 Structure of the method lists 9 4 Evaluation of measuring proc

23、edures 10 4.1 General . 10 4.2 Rating 10 4.3 Downgrade of a rating 13 4.4 Expanded uncertainty 14 Annex A (informative) Selection of chemical agents related to 2.2 15 Annex B (informative) Examples of method lists 19 Bibliography . 28 1%$ to evaluate and rate a given measuring procedure (from an acc

24、epted source) for a given chemical agent not yet selected in the database GESTIS Analytical methods 2. 2 Measuring procedures 2.1 General Measuring procedures (“analytical methods”) for chemical agents in workplace atmospheres are available from many sources. In Europe, for example in France, German

25、y, Spain and UK “official” measuring procedures for workplace atmospheres are published. Furthermore, a number of International Standards have been promulgated the use in this field, but the most important sources of measuring procedures from countries outside Europe are those published by OSHA and

26、NIOSH. 2.2 Selection of chemical agents Further surveys show that there are about 2000 different chemical agents, mixtures and preparations with existing limit values in Europe 3. Beyond, many so called “derived no-effect levels” (DNELs) have been published by the European Chemical Agency (ECHA) sin

27、ce 2010 4. It is far beyond the application range of the database to select measuring procedures for all chemical agents with a limit value. In any case for many chemical agents no measuring procedure exists. Furthermore, due to the very specific problems of fibre measurements and measurements of na

28、noparticles, no procedures for these chemical agents are listed. The selection of chemical agents is based mainly on the number of measurements carried out in France and Germany. Both countries have similar databases for measurements in workplace atmospheres, and in both countries several hundred th

29、ousand measurements have been performed since the early 1970s 5, 6. These databases give a very good overview about chemical agents of high priority. The chemical agents for the method lists are mainly selected from that group of chemical agents which remained more or less unchanged since 2006, and

30、a few other criteria: high number of measurements; high profile substances (e.g. diesel fume); EU limit value and a reasonable number of measurements; limit values in most countries of the EU. PD CEN/TR 17055:2017g6g8g17g512g23g21g3g883g889g882g887g887g483g884g882g883g889g3g525g8g5264PD CEN/TR 17055

31、:2017CEN/TR 17055:2017 (E) 6 The following substances or groups of chemical agents were selected: a) aerosols inhalable and respirable dust; crystalline silica; diesel fume; metal working fluids/oil mist.b) metals Ag, As, Ba-soluble, Be, Cd, Co, Cr, Cr (VI), Cu, Hg, Mn, Ni, Ni-soluble, Pb, Sb, Sn.c)

32、 Organic substances Acetonitrile, Acrylates, Alcohols, Aldehydes, Aliphatic amines, Aliphatic ester alcohols, Aliphaticethers, Alkanolamines, N-Alkyl-2-pyrrolidons, Amides, Chlorinated aromatic hydrocarbons, Cresols, Cyclic ethers, hydrocarbons (aliphatic, aromatic, cyclic), Esters, Glycol esters, H

33、alogenated hydrocarbons (aliphatic), Isocyanates, Ketones (aliphatic and cyclic), Organic acids, Oxiranes, Phenol d) Gases CO, CO2, NH3, N2O, NO, NO2, PH3, SO2,halogense) Inorganic acids and alkaline substances Hydrogen cyanide and Cyanides, Hydrogen fluoride and fluorides, Hydroxides, Particulatein

34、organic acids and anhydrides, Volatile inorganic acids A list of the chemical agents selected for the database GESTIS Analytical methods 2 is given in Annex A. 3 Method lists 3.1 General After selection of chemical agents and related substance groups the basic requirements given in 3.2 are specified

35、. 3.2 Origin of the measuring procedure The following criteria are taken into account for the compilation of the measuring procedures: a) The measuring procedure is examined by an independent group and has already been published inanother set of (measuring) procedures for measurements in workplace a

36、tmospheres.b) The measuring procedure has been designed for personal exposure measurement and requires theuse of a personal sampler.c) Measuring procedures either using static (area) sampling only or developed for ambient air areexcluded from further considerations.PD CEN/TR 17055:2017g6g8g17g512g23

37、g21g3g883g889g882g887g887g483g884g882g883g889g3g525g8g5265PD CEN/TR 17055:2017CEN/TR 17055:2017 (E) 7 The accepted sources are listed in Table 1. Table 1 Accepted sources of methods for workplace air measurements Abbreviation Language Source Web address EN English (French/ German) European Organizat

38、ion for Standardization (CEN), CEN-CENELEC Management Centre Avenue Marnix 17, B-1000 Brussels, Belgium European Standards Also available from National Standards Bodies, e.g. AFNOR, AENOR, BSI, DIN, SIS etc. http:/www.cen.eu/ with costs ISO English (French) International Organization for Standardiza

39、tion (ISO), ISO Central Secretariat Chemin de Blandonnet 8, Case Postale 401 CH-1214 Vernier, Geneva, Switzerland: International Standards Also available from National Standards Bodies, e.g. AFNOR, AENOR, BSI, DIN, SIS etc. http:/www.iso.org with costs DGUV I German Deutsche Gesetzliche Unfallversic

40、herung (DGUV): Von den Berufsgenossenschaften anerkannte Analysenverfahren zur Feststellung der Konzentration krebserzeugender Arbeitsstoffe in der Luft in Arbeitsbereichen 83 methods since 1983 (some methods are published in DFG (E) http:/publikationen.dguv.de/dguv/udt_dguv_main.aspx?QPX=TUlEPSZDSU

41、Q9MTAwNzI6U0cjR2VmYWhyc3RvZmZl for free IFA German Institut fr Arbeitsschutz der Deutschen Gesetzlichen Unfallversicherung IFA-Arbeitsmappe, Messung von Gefahrstoffen, Sankt Augustin. Erich Schmidt Verlag, Berlin, Loose leaf edition, 50 supplements since 1988 http:/bgia-arbeitsmappedigital.de/login.

42、html with costs DFG (D) German Deutsche Forschungsgemeinschaft (DFG): Analytische Methoden zur Prfung gesundheitsschdlicher Arbeitsstoffe Luftanalysen, Ed. H. Greim, Wiley-VCH, Weinheim, Germany Loose leaf edition, 18 supplements since 1976 http:/ for free PD CEN/TR 17055:2017g6g8g17g512g23g21g3g883

43、g889g882g887g887g483g884g882g883g889g3g525g8g5266PD CEN/TR 17055:2017CEN/TR 17055:2017 (E) 8 Abbreviation Language Source Web address DFG (E) English Deutsche Forschungsgemeinschaft (DFG): Analyses of Hazardous Substances in Air, Wiley-VCH. Weinheim, New York http:/ for free MDHS English Health and

44、Safety Laboratory (HSL), Harpur Hil, Buxton, Derbyshire SK17 9JN, UK: Methods for the Determination of Hazardous Substances (MDHS) 100 methods since 1979 http:/www.hse.gov.uk/pubns/mdhs/ for free Metropol French (English) Institut National de Recherche et de Scurit (INRS) MtroPol Mtrologie des pollu

45、ants (Recueil des mthodes de prlvement et danalyse de lair pour lvaluation de lexposition professionnelle aux agents chimiques) INRS, Paris CD edition with cost (new edition every 1 or 2 years) and Website (fre downloadable .PDF files) updated as needed. 124 methods (1998 to 2016) New database: 300

46、methods available from 2016 http:/www.inrs.fr/publications/bdd/metropol.html for free MTA Spanish Instituto Nacional de Seguridad e Higiene en el Trabajo (INSHT), c/ Torrelaguna 73, 28027 Madrid Mtodos de Toma de muestra y Anlisis (MTA) 80 methods since1987 http:/www.insht.es/portal/site/Insht/menui

47、tem.a82abc159115c8090128ca10060961ca/?vgnextoid=f6a8908b51593110VgnVCM100000dc0ca8c0RCRD for free NIOSH English National Institute for Occupational Safety and Health (NIOSH), 4676 Columbia Parkway, Cincinnati, OH 452261998, USA: http:/www.cdc.gov/niosh/docs/2003-154/ for free OSHA English Occupation

48、al Safety and Health Administration (OSHA), Salt Lake Technical Center, 8660 South Sandy Parkway, Sandy, UT 84070, USA: OSHA Sampling and Analytical Methods http:/www.osha.gov/dts/sltc/methods/ for free IRSST English French Institut de recherche Robert-Sauv en sant et en scurit de travail (IRSST) 50

49、5 Maisonneuve Blvd West, Montral, Qubec H3A 3C2, CANADA http:/www.irsst.qc.ca/laboratoires/outils-references/methodes-laboratoire for free NOTE For lack of space only the abbreviations of the method publisher are given in the first table column and in the method lists. PD CEN/TR 17055:2017g6g8g17g512g23g21g3g883g889g882g887g887g483g884g882g883g889g3g525g8g5267PD CEN/TR 17055:2017CEN/TR 17055:2017 (E)