ASTM E481-2016 8131 Standard Test Method for Measuring Neutron Fluence Rates by Radioactivation of Cobalt and Silver《用钴和银的放射性测量中子注量率的标准试验方法》.pdf

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1、Designation: E481 16Standard Test Method forMeasuring Neutron Fluence Rates by Radioactivation ofCobalt and Silver1This standard is issued under the fixed designation E481; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year o

2、f last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method covers a suitable means of obtainingthe thermal neutron fluence rate, or fluence, in well moderated

3、nuclear reactor environments where the use of cadmium, as athermal neutron shield as described in Test Method E262,isundesirable because of potential spectrum perturbations or oftemperatures above the melting point of cadmium.1.2 This test method describes a means of measuring aWestcott neutron flue

4、nce rate (Note 1) by activation of cobalt-and silver-foil monitors (See Terminology E170). The reaction59Co(n, )60Co results in a well-defined gamma emitter havinga half-life of 1925.28 days (1).2The reaction109Ag(n,)110mAgresults in a nuclide with a complex decay scheme which is wellknown and havin

5、g a half-life of 249.76 days (1). Both cobaltand silver are available either in very pure form or alloyed withother metals such as aluminum.Areference source of cobalt inaluminum alloy to serve as a neutron fluence rate monitor wirestandard is available from the National Institute of Standardsand Te

6、chnology (NIST) as Standard Reference Material 953.3The competing activities from neutron activation of otherisotopes are eliminated, for the most part, by waiting for theshort-lived products to die out before counting. With suitabletechniques, thermal neutron fluence rate in the range from 109cm2s1

7、to31015cm2s1can be measured. For thismethod to be applicable, the reactor must be well moderatedand be well represented by a Maxwellian low-energy distribu-tion and an (1/E) epithermal distribution. These conditions areusually met in positions surrounded by hydrogenous moderatorwithout nearby strong

8、ly absorbing materials. Otherwise, thetrue spectrum must be calculated to obtain effective activationcross sections over all energies.NOTE 1Westcott fluence rate 5v0*0nv!dv.1.3 The values stated in SI units are to be regarded as thestandard.1.4 This standard does not purport to address all of thesaf

9、ety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:4E170 Terminology Relating to Ra

10、diation Measurements andDosimetryE177 Practice for Use of the Terms Precision and Bias inASTM Test MethodsE181 Test Methods for Detector Calibration and Analysis ofRadionuclidesE261 Practice for Determining Neutron Fluence, FluenceRate, and Spectra by Radioactivation TechniquesE262 Test Method for D

11、etermining Thermal Neutron Reac-tion Rates and Thermal Neutron Fluence Rates by Radio-activation Techniques3. Significance and Use3.1 This test method uses one monitor (cobalt) with a nearly1/v absorption cross-section curve and a second monitor(silver) with a large resonance peak so that its resona

12、nceintegral is large compared to the thermal cross section. Thepertinent data for these two reactions are given in Table 1. Theequations are based on the Westcott formalism (2, 3) andPractice E261) and determine a Westcott 2200 m/s neutronfluence rate nv0and the Westcott epithermal index parameterr=

13、T/T0. References (4, 5, and 6) contain a general discussionof the two-reaction test method. In this test method, theabsolute activities of both cobalt and silver monitors aredetermined. This differs from the test method in the referenceswherein only one absolute activity is determined.3.2 The advant

14、ages of this test method are the elimination ofthree difficulties associated with the use of cadmium: (1) the1This test method is under the jurisdiction ofASTM Committee E10 on NuclearTechnology and Applications and is the direct responsibility of SubcommitteeE10.05 on Nuclear Radiation Metrology.Cu

15、rrent edition approved Oct. 1, 2016. Published October 2016. Originallyapproved in 1973. Last previous edition approved in 2015 as E481 15. DOI:10.1520/E0481-16.2The boldface numbers in parentheses refer to references listed at the end of thistest method.3Standard Reference Material 953 is available

16、 from National Institute ofStandards and Technology, U.S. Dept. of Commerce, Washington, DC 20234.4For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Docu

17、ment Summary page onthe ASTM website.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1perturbation of the field by the cadmium; (2) the inexactcadmium cut-off energy; (3) the low melting temperature ofcadmium. In addition, the reactivi

18、ty changes accompanying therapid insertion and removal of cadmium may prohibit the useof the cadmium-ratio method. However, the self-shieldingcorrections remain important unless the concentrations ofcobalt and silver are small. Studies indicate that the accuracy ofthe two-reaction method for determi

19、nation of thermal neutronfluence is comparable to the cadmium-ratio method (14).3.3 The long half-lives of the two monitors permit thedetermination of fluence for long-term monitoring.4. Apparatus4.1 NaI(Tl) or Germanium Gamma-Ray Spectrometer (us-ing a multichannel analyzer)For the NaI(Tl) techniqu

20、e andthe germanium technique, see Test Methods E181.4.2 Precision Balance.4.3 Digital Computer.5. Materials and Manufacture5.1 The two monitors required for this test method arecobalt and silver. Although these two materials are availablecommercially in very pure form, they have been used (15)alloye

21、d with aluminum (1 % cobalt and 1 % silver) tominimize the self-shielding effect and to permit insertion intoa high thermal-neutron fluence rate (1015cm2s1) facility (6,16). Typical alloys contain 0.1 % silver or cobalt in aluminum)see 6.1 and 8.1).5.2 The uncertainties and nonuniformity of alloy co

22、ncentra-tions must be established by one or more different testmethods. These might include chemical and activationanalysis, or spectrometry. The purity of the aluminum matrixshould also be established.5.3 Whenever possible, the alloys should be tested forinterfering impurities by neutron activation

23、.5.4 The method of encapsulating the monitors for irradia-tion depends upon the characteristics of the facility in whichthe measurements are to be made. The monitors have essen-tially the same chemical characteristics as pure aluminum;therefore, an environment in which aluminum would not beadversely

24、 affected would be generally satisfactory for thealloys. However, the low mechanical strength of the monitorsrequires in many instances that it be encapsulated or shieldedfrom physical disturbances by some type of container. Alumi-num cans or tubing are satisfactory for many cases of interest,but fo

25、r hostile environments, stainless steel or vanadium maybe preferable. Perturbation due to the presence of the containermust be accounted for, especially in the case of stainless steel.The container should be constructed in such a manner that itwill not create a significant flux perturbation and that

26、 it may beopened easily, especially if the monitors must be removedremotely.6. Westcott Neutron Fluence Convention6.1 The Westcott neutron fluence convention is designedprimarily for calculations involving reactions rather than thoseinvolving scattering or diffusion. It states that the reaction rate

27、per atom present, R, is equal to the product of an effective crosssection, , with the Westcott neutron fluence w= nv0, wheren = the neutron density, including both thermal and epithermalneutrons, cm3, and v0= 2200 m/s.Thus:R 5 w 5 nv0 (1)The true equation for reaction rate is given by the equation:R

28、 5 *0nv!vv!dv (2)where:n(v) = neutron density per unit velocity,v = neutron velocity, and(v) = cross section for neutrons of velocity v.TABLE 1 Recommended ConstantsSymbol ParameterCobalt (60Co) Silver (110mAg)ValueAReference ValueAReferencet1/2Half-life 1925.28 (14) days (1) 249.76 (4) days (1)A Ab

29、undance of parent isotope 100 % (59Co) (1) 48.161 (8) % (109Ag) (1)aAbsorption 2200 m/s cross section for target59Co and109Ag37.233b0.16%B,C91.0b1% (7)02200 m/s cross section for formation of60Co and110mAg 37.233b0.16%B,C4.12 (10) (8)S0Correction factor which describes the departure of thecross sect

30、ion from the 1/v law in the epithermalregion1.8059Co(n,)60CoD18.1(7)109Ag(n,)110mAg(8)I0Resonance Integral 75.421b0.77%59Co(n,)60Co(9)E67.9 (31) b109Ag(n,)110mAg(8)2Effective absorption cross section for product nuclide(reactor spectrum)2b (10) 82 b (11)GthThermal neutron self-shielding factor Table

31、 3 (12) 14/3Ra(4)GresResonance neutron self-shielding factor Table 3 (12) Fig. 1Fg Correction factor which describes the departure of thecross section from 1/v law in thermal region1.0 (2) See Table 4 (2)AThe numbers in parenthesis following given values are the uncertainty in the last digit(s) of t

32、he value; 0.729 (8) means 0.729 0.008, 70.8(1) means 70.8 0.1.BA 2200 m/s cross section (E = 0.0253 eV, T = 20C) was taken from the sources indicated in Ref (9).CCross section uncertainty data is taken from Ref (7), the cross section comes from the other reference.DCalculated using Eq 10.ECross sect

33、ion uncertainty comes from covariance data provided in the cross section source. The other reference indicates the source of the cross section.FIn Fig. 1, =4ErkT/A2= 0.2 corresponds to the value for109Ag for T = 293 K, r=N0r, max. r, max=29999 barn at 5.19 eV (13) .E481 162Therefore, the effective c

34、ross section is defined by theequation: 5 *0nv!vv!dv/nv0(3)The neutron spectrum assumed by Westcott has the form:n(v)=n(1 f)Pm(v)+nfPe(v), where Pmand Peare theMaxwellian and epithermal density distribution functions nor-malized so that: *0Pmv!dv5*0Pev!dv51. The quantity f is thefraction of the tota

35、l density, n, in the epithermal distribution.The epithermal distribution is assumed proportional to 1/E perunit energy interval. This distribution is terminated by a cut-offfunction at a suitable lower limit of energy. Based on the abovespectrum, one obtains the following relation for the effectivec

36、ross section: 5 0g1rs! (4)where:0= cross section of 2200 m/s neutrons,g = a measure of the departure of the cross section from 1/vdependence in the thermal region,s =S0=T/T0, a factor which describes the departure of thecross section from the 1/v law in the epithermal region,including resonance effe

37、cts, andr = a measure of the proportion of epithermal neutrons inthe reactor spectrum.More specifically:r 5 f=n/4 (5)where:f = fraction of the total density in the epithermaldistribution, andn= a factor chosen to give the proper normalization to theepithermal density distribution. A suitable factor

38、forwater moderated systems is 5 (2).6.2 Limitation of the Westcott ConventionSufficient con-ditions for the applications of the Westcott convention are that:(a/(s,0.1 (6)and:T/Tm,1.07 (7)where:a= macroscopic absorption cross section averaged over allmaterials affecting spectrum, = average logarithmi

39、c energy decrement per collision,s= macroscopic scattering cross section averaged over allmaterials affecting spectrum,T = neutron temperature, K, andTm= temperature of the moderator, K.If as a result of neutron captures (for example, in the fuel)the quantity a/sbecomes too great or if the neutronte

40、mperature T is too great relative to the moderator temperatureTm, the Maxwell spectrum hypothesis fails and the truespectrum must be calculated and the effective cross sectiondetermined with this spectrum.6.3 The conventional 2200 m/s thermal neutron-fluencerate, 0, and the epithermal fluence-rate p

41、arameter, e,asdefined in Test Method E262, can be obtained from theWestcott neutron-fluence rate, w, and the Westcott epithermalindex, r =T/T0, by means of equations Eq 8 and Eq 9:05S1 24 r=nDw(8)e52=r TT0w(9)6.4 In Eq 8, it is necessary to estimate the neutrontemperature, T, in order to obtain the

42、value of r from the indexr=T/T0. Provided inequality (Eq 7) is satisfied, only slighterror is introduced by assuming T=Tm, the moderatortemperature.6.5 Although the Ag109(n,)Ag110mS0value in Table 1 is ameasured value, S0can be calculated by the following equa-tion:S052=I“0052=SI002 2g E0ECdD (10)wh

43、ere:I“0= resonance integral excess over the 1/v cross sectionvalue, cm2,0= 2200 m/s cross-section value, cm2,I0=resonance integral, *ECdE!EdEE0= 0.0253 eV, andECd= 0.55 eV.7. Procedure7.1 Decide on the size and shape of the monitors to beirradiated, taking into consideration the size and shape of th

44、eirradiation space. The mass and exposure time are parameterswhich can be varied to obtain a desired disintegration rate fora given neutron fluence rate level. To facilitate the convergenceof the two activity equations for the fluence rate and theepithermal index, the concentration of the alloys sho

45、uld bechosen so that the ratio of the disintegration rates is on theorder of one.7.2 Weigh the samples to a precision of 61.0 % (1S %) asdefined in Practice E177.7.3 Irradiate the samples for the predetermined time period.Record the power level and any changes in power during theirradiation, the tim

46、e at the beginning and end of the irradiation,and the relative position of the monitors in the irradiationfacility.7.4 A waiting period is necessary between termination ofthe exposure and start of counting when using Co-Al andAg-Al monitors. This allows the 0.62356 days (17) half-life24Na which is f

47、ormed by fast-neutron reactions on27Al or bythermal-neutron captures by23Na impurities to decay belowlevels at which its radiations may cause interferences. It issometimes advisable to count the samples periodically andfollow the decay of the portions of the activities due to the24Na. The length of

48、the waiting period can be reduced by theuse of a germanium detector.E481 1637.5 With the gamma-ray spectrometer, analyze the silversample for110mAg and the cobalt sample for60Co. Obtain thenet count rate in each full-energy gamma-ray peak of interest,that is, 657.7623 keV or 884.684 keV for110mAg, 1

49、332.501keV for60Co (see Test Methods E181). See Table 2 for gammaradiations of110mAg.8. Calculation8.1 Calculate the activities of110mAg and60Co in disinte-grations per second.8.2 AWestcott 2200 m/s neutron fluence rate, nv0,orwandtheWestcott epithermal index parameter, r =T/T0are related tothe measured activities of the silver and cobalt monitors by thefollowing equation:A 5 N0BFG1wti(11)where:A = measured activity at the end of the exposure time,disintegrations/