ASTM D6210-2008 317 Standard Specification for Fully-Formulated Glycol Base Engine Coolant for Heavy-Duty Engines《全配方乙二醇型重负荷发动机冷却液的标准规范》.pdf

《ASTM D6210-2008 317 Standard Specification for Fully-Formulated Glycol Base Engine Coolant for Heavy-Duty Engines《全配方乙二醇型重负荷发动机冷却液的标准规范》.pdf》由会员分享，可在线阅读，更多相关《ASTM D6210-2008 317 Standard Specification for Fully-Formulated Glycol Base Engine Coolant for Heavy-Duty Engines《全配方乙二醇型重负荷发动机冷却液的标准规范》.pdf（4页珍藏版）》请在麦多课文档分享上搜索。

1、Designation: D 6210 08Standard Specification forFully-Formulated Glycol Base Engine Coolant for Heavy-Duty Engines1, 2This standard is issued under the fixed designation D 6210; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the y

2、ear of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope*1.1 This specification covers the requirements for fully-formulated glycol base coolants for cooling systems of he

3、avy-duty engines. When concentrates are used at 40 to 60 % glycolconcentration by volume in water of suitable quality, (seeAppendix X1), or when prediluted glycol base engine coolants(50 volume % minimum) are used without further dilution,they will function effectively during both winter and summer

4、toprovide protection against corrosion, cavitation, freezing, andboiling.1.2 This specification is intended to cover the requirementsfor engine coolants prepared from virgin or recycled ethyleneor propylene glycol.NOTE 1Committee D15 has not substantially studied the impact ofusing recycled glycols

5、from sources such as: glycol bottoms polyester manufacturing waste aircraft and runway deicers medical wasteto prepare engine coolants. However, several serious cases of very poor perfor-mance have been reported and substantiated in heavy duty fleets when recycledglycols from sources such as above h

6、ave been used to prepare engine coolants.Efforts are underway to more clearly define the purity requirements for glycolsused to prepare engine coolants meeting this specification, whether from recycledengine coolants or other sources.1.3 The coolants governed by this specification are catego-rized a

7、s follows:Coolant Type DescriptionI-FF Ethylene glycol base concentrateII-FF Propylene glycol base concentrateIII-FF Ethylene glycol predilute (50 vol %)IV-FF Propylene glycol predilute (50 vol %)1.4 Coolant concentrates meeting this specification do notrequire any addition of Supplemental Coolant A

8、dditive (SCA)until the first maintenance interval when a maintenance dose ofSCA is required to continue protection in certain heavy dutyengine cooling systems, particularly those of the wet cylinderliner-in-block design. The SCA additions are defined by andare the primary responsibility of the engin

9、e manufacturer orvehicle manufacturer. If they provide no instructions, followthe SCA suppliers instructions.1.5 The values stated in SI units are to be regarded asstandard. The values given in parentheses are for informationonly.1.6 This standard does not purport to address all of thesafety concern

10、s, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:3D 1126 Test Method for Hardness in WaterD

11、1293 Test Methods for pH of WaterD 3306 Specification for Glycol Base Engine Coolant forAutomobile and Light-Duty ServiceD 4327 Test Method for Anions in Water by ChemicallySuppressed Ion ChromatographyD 5828 Test Method for Compatibility of SupplementalCoolant Additives (SCAs) and Engine Coolant Co

12、ncen-trates2.2 Other Standards:4Federal Method 2540B Total Dissolved Solids Dried at103105C3. General Requirements3.1 Concentrated and prediluted coolants shall meet all ofthe physical, chemical and performance requirements of Speci-fication D 3306., Tables 1, 2, and 3.3.2 The coolant concentrate mi

13、xed with water or the predi-luted coolant, when maintained with maintenance doses of1This specification is under the jurisdiction ofASTM Committee D15 on EngineCoolants and is the direct responsibility of Subcommittee D15.07 on Specifications.Current edition approved Oct. 1, 2008. Published November

14、 2008. Originallyapproved in 1998. Last previous edition approved in 2006 as D 6210 - 06.2A research report is available from ASTM International Headquarters. RequestRR:D151023.3For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. F

15、or Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.4Standard Method for the Examination of Water and Wastewater, AmericanPublic Health Association, et al, 1015 15th Street, N.W. Washington, DC 200051*A Summary of Changes section appear

16、s at the end of this standard.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.SCAin accordance with the engine manufacturers recommen-dations, and those on the product label, shall be suitable for usein a properly maintained cooling s

17、ystem in normal service fora minimum of two years (see Appendix X1).4. Additional Requirements4.1 The coolant concentrate or prediluted coolant addition-ally shall provide protection in operating engines againstcavitation corrosion (also termed liner pitting) and againstscaling of internal engine ho

18、t surfaces. Hot surfaces typicallyare within the engine head, head spacer, upper cylinder liner, orliquid cooled exhaust manifold. ASTM has test methods underdevelopment for both cavitation corrosion and hot surfacescaling. Until these procedures are approved as ASTM stan-dards, the mandatory requir

19、ements of Annex A1 shall apply.4.2 Lack of compatibility between the coolant and SCAproducts chemistry may cause the solute to precipitate out ofsolution, with potential adverse effects in the vehicle or enginecooling system. A test procedure for compatibility (TestMethod D 5828) has been developed

20、and approved. Thecompatibility of SCA and coolant concentrate solutions meet-ing this specification shall be determined using D 5828 and theresults reported.4.3 Both the concentrated and prediluted coolants shallcontain less than 50 g/g sulfate ion.5. Keywords5.1 cavitation; fully-formulated heavy-d

21、uty engine coolant;supplemental coolant additive maintenance doseANNEX(Mandatory Information)A1. CHEMICAL REQUIREMENTS FOR FULLY FORMULATED HEAVY DUTY ENGINE COOLANTA1.1 Laboratory data or in-service experience demonstrat-ing a positive influence on reducing cavitation corrosion in anoperating engin

22、e is required.A1.1.1 In-service qualification tests may consist of single-or multiple-cylinder engine tests.At the option of the engine orvehicle manufacturer, such testing may be conducted in “looseengines” or in engines fully integrated into an application, suchas a vehicle, a power boat, or a sta

23、tionary power source. Onesuch test has been developed.5A1.2 Several chemical compositions have been testedextensively by producers and users and satisfactorily minimizecylinder liner cavitation in actual test engines. Coolants meet-ing either of the following compositions are regarded aspassing the

24、requirements of A1.1:A1.2.1 A minimum concentration of nitrite (as NO2)of1200 g/g (ppm) in the 50 volume % predilute coolant, orA1.2.2 A minimum combined concentration of nitrite (asNO2) plus molybdate (as MoO42) in the 50 volume %predilute coolant of 780 g/g (ppm). At least 300 g/g (ppm)each of NO2

25、and MoO42must be present.A1.2.3 The above concentrations are doubled for coolantconcentrates.A1.3 Chemical composition requirements for cavitationcorrosion protection will be removed from this specificationand replaced with anASTM test method when a test method isdeveloped and adopted.A1.4 Both conc

26、entrated and prediluted coolants under thisspecification must contain additives to minimize hot surfacescaling deposits. Certain additives (polyacrylate and othertypes) minimize the deposition of calcium and magnesiumcompounds on heat rejecting surfaces. No specific chemicalrequirements for hot surf

27、ace scaling and deposits resistancehave been established at this time. A test procedure is underdevelopment and will be incorporated into the specificationwhen a procedure is approved by ASTM.5“A Comparison of Engine Coolant in an Accelerated Heavy-Duty EngineCavitation Test,” SAE Technical Paper 96

28、0883, SAE International, 400 Common-wealth Drive, Warrendale, PA 150960001.D6210082APPENDIX(Nonmandatory Information)X1. COOLANT MAINTENANCE FOR HEAVY DUTY ENGINESX1.1 Engine CoolantCooling system fill for a heavy dutyengine consists of water and fully formulated heavy dutycoolant concentrate or ful

29、ly formulated prediluted heavy dutycoolant.X1.1.1 Water:X1.1.1.1 Water quality affects the efficiency of coolantadditives. When untreated, all water is corrosive. Water havinga high mineral content or corrosive materials is unfit forcooling system use.X1.1.1.2 When preparing coolant mixtures, the wa

30、tershould be of such quality that it does not contain excessivesolids, hardness salts, sulfates, or chlorides. In the absence ofspecific recommendations from the engine or vehicle manu-facture, see Table X1.1. Contact your local water department,the responsible government agency, or submit a water s

31、amplefor analysis if there is a question on water quality.X1.1.2 Coolant Concentrates:X1.1.2.1 The coolant concentration should be maintainedbetween 40 and 60 % glycol by volume, depending on theengine operating environment. Freeze protection will be pro-vided in accordance with Table X1.2.X1.1.3 Pr

32、ediluted Engine Coolants:X1.1.3.1 Prediluted glycol base engine coolants (50 volume% minimum) should be used without further dilution. Ifadditional freeze protection is required, coolant concentratemay be added to the prediluted engine coolant to increase thetotal glycol content in the cooling syste

33、m (see Table X1.2)X1.1.4 Supplemental Coolant Additive:X1.1.4.1 SCAs extend the life of the coolant by replenishingthe additives that deplete during normal operation. SCAs,however, do not extend the freeze protection provided by thecoolant concentrate.X1.1.4.2 Heavy-duty engine users experience has

34、shownthat compositions below those defined in Annex A1.2 may notprovide long term protection against cavitation corrosion (linerpitting). User experience and published information shows thepresence of nitrite in an SCA or fully-formulated heavy-dutycoolant is particularly effective in providing maxi

35、mum protec-tion.X1.1.4.3 New technology consisting of other chemistriesmay provide satisfactory protection. Such chemistries can beestablished by agreement between producers and users upondemonstration of performance. Such demonstrations can con-sist of comparative laboratory cavitation tests or com

36、parativedamage rating from testing in operating engines. One or bothof these options may be applied as determined in a specificagreement between parties. An engine test has been devel-oped.5X1.2 Coolant Maintenance Recommendations:X1.2.1 If any of the following recommendations differ,follow the engi

37、ne or vehicle manufacturers recommendations.X1.2.2 Use the coolant concentration recommended in thisspecification.X1.2.3 Drain and flush the cooling system as recommendedby the engine or vehicle manufacturer.X1.2.4 Use water that meets the requirement in Table X1.1.X1.2.5 Use accurate, reliable equi

38、pment, such as a refrac-tometer, to measure coolant concentrate levels for freezeprotections.X1.2.6 Use the SCA manufacturers recommended test kitwhen testing the coolant for proper additive concentration. Testkits shall indicate the degree of liner pitting protection presentin the coolant.X1.2.7 Ch

39、eck freezing point at two different levels whencoolant concentrate and water is premixed and stored in bulk ordrums to be sure mixing is complete before use.X1.2.8 Use coolant mixed at the desired proportions formake-up.X1.2.9 Use SCAs at the recommended maintenance dosageand intervals to control de

40、posits, corrosion, water pumpdamage, and liner pitting.X1.2.10 Periodically check bulk premixed coolant storagetanks for separation of chemicals and contamination.X1.2.11 DO NOT add undiluted coolant concentrate asmake-up coolant for coolant Types I-FF and II-FF.X1.2.12 DO NOT add plain water as mak

41、e-up coolant.X1.2.13 DO NOT exceed 60 % coolant concentrate in TypeI-FF and Type II-FF coolants. A coolant concentrate levelgreater than 68 % actually reduces freeze protection in ethyl-ene glycol base coolants. The maximum recommended coolantconcentrate level is 60 % which provides the freeze prote

42、ctionshown in X1.1.2.TABLE X1.1 Suggested Water Quality LimitsAProperty Specific Values Test MethodTotal solids, g/g (ppm (grains/gal)340 (20) max Fed Method 2540BBTotal hardness, g/g (ppm(grains/gal)170 (10) max D 1126Chloride (Cl), g/g (ppm (grains/gal)40 (2.4) max D 4327Sulfate (SO4), g/g (ppm (g

43、rains/gal)100 (5.9) max D 4327pH 5.5 to 9.0 D 1293AAdopted from a survey by the D 15 Water Quality Task Force.BFederal Method 2540B, “Total Dissolved Solids Dried at 103105C.”4TABLE X1.2 Freeze ProtectionApproximate Freeze Protection Temperature, C (F)Glycol Content, % Coolant Type I-FF Coolant Type

44、 II-FF40 24 (12) 21 (6)50 37 (34) 32 (26)60 52 (62) 48 (54)D6210083X1.2.14 DO NOT exceed the manufacturers recommendeddosage of SCA or the recommended concentration of coolantconcentrate. Over-concentration can result in plugged radia-tors, heater cores, and charge air coolers and can also causewate

45、r pump seal leaks.X1.2.15 DO NOT reuse coolant that has been drained froma vehicle.X1.2.16 DO NOT precharge the cooling system with SCAwhen using fully-formulated heavy-duty engine coolant.X1.2.17 DO NOT use soluble oil additives.X1.2.18 DO NOT use methyl alcohol or methoxypropanolbase coolant conce

46、ntrates.X1.2.19 DO NOT use anti-leak additives if engine coolingsystem is equipped with a coolant filter, as this may plug thefilter element. For all other cooling systems, follow therecommendations of the engine or vehicle manufacturer.SUMMARY OF CHANGESCommittee D15 has identified the location of

47、selected changes to this standard since the last issue (D 621006)that may impact the use of this standard.(1) Revised Section 3.1 to allow the use of recycled glycolwhich was the intent when the specification was created.Coolants meeting this specification must meet the physical,chemical, and perfor

48、mance requirements of D 3306. The 25g/g (ppm) chloride limit is retained.(2) The SCAcompatibility information previously inA1.5 hasbeen revised and placed in 4.2 along with a report requirementfor D 5828.(3) A change from ppm to g/g has been made in 4.3, A1.2.1,A1.2.2 and in Table X1.1.ASTM Internat

49、ional takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for rev