ASTM D5260-2004(2010) Standard Classification for Chemical Resistance of Poly(Vinyl Chloride) (PVC) Homopolymer and Copolymer Compounds and Chlorinated Poly(Vinyl Chloride) (CPVC) .pdf

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1、Designation: D5260 04 (Reapproved 2010)Standard Classification forChemical Resistance of Poly(Vinyl Chloride) (PVC)Homopolymer and Copolymer Compounds and ChlorinatedPoly(Vinyl Chloride) (CPVC) Compounds1This standard is issued under the fixed designation D5260; the number immediately following the

2、designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This classification covers

3、 the method for determiningand classifying the resistance of poly(vinyl chloride) (PVC)homopolymer and copolymer compounds, and chlorinatedpoly(vinyl chloride) (CPVC) compounds in chemicals bysimple immersion testing of unstressed specimens.1.2 This classification is applicable to any PVC or CPVCcom

4、pound as defined in Specifications D1784, D3915, D4216,D4396,orD4551.1.3 The values stated in SI units are to be regarded asstandard.1.4 The text of this standard references notes and footnoteswhich provide explanatory material. These notes and footnotes(excluding those in tables and figures) shall

5、not be consideredas requirements of this standard.1.5 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of r

6、egulatory limitations prior to use.NOTE 1There are no ISO standards covering the subject matter of thisclassification.2. Referenced Documents2.1 ASTM Standards:2D543 Practices for Evaluating the Resistance of Plastics toChemical ReagentsD883 Terminology Relating to PlasticsD1600 Terminology for Abbr

7、eviated Terms Relating toPlasticsD1784 Specification for Rigid Poly(Vinyl Chloride) (PVC)Compounds and Chlorinated Poly(Vinyl Chloride)(CPVC) CompoundsD3915 Specification for Rigid Poly(Vinyl Chloride) (PVC)and Chlorinated Poly(Vinyl Chloride) (CPVC) Com-pounds for Plastic Pipe and Fittings Used in

8、PressureApplicationsD4216 Specification for Rigid Poly(Vinyl Chloride) (PVC)and Related PVC and Chlorinated Poly(Vinyl Chloride)(CPVC) Building Products CompoundsD4396 Specification for Rigid Poly(Vinyl Chloride) (PVC)and Chlorinated Poly(Vinyl Chloride) (CPVC) Com-pounds for Plastic Pipe and Fittin

9、gs Used in NonpressureApplicationsD4551 Specification for Poly(Vinyl Chloride) (PVC) PlasticFlexible Concealed Water-Containment Membrane3. Terminology3.1 Definitions and Abbreviations:3.1.1 Definitions are in accordance with Terminology D883and abbreviations with Terminology D1600 unless otherwisei

10、ndicated.4. Significance and Use4.1 Reference this chemical resistance classification for anyPVC/CPVC material compound specification wherein a levelof resistance to specific chemicals is required for satisfactoryproduct performance.4.2 Listing of a chemical in the annex does not implyPVC/CPVC compa

11、tibility or resistance to the chemical. Someof the chemicals listed could be deleterious to a specific1This classification is under the jurisdiction of ASTM Committee D20 onPlastics and is the direct responsibility of Subcommittee D20.15 on ThermoplasticMaterials.Current edition approved Aug. 1, 201

12、0. Published November 2010. Originallyapproved in 1992. Last previous edition approved in 2004 as D5260 - 04. DOI:10.1520/D5260-04R10.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume info

13、rmation, refer to the standards Document Summary page onthe ASTM website.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United Spound, causing radical changes in the physical properties.Resistance to these chemicals is not intended to be a practi

14、calrequirement in a specification.4.3 For resistance to mixtures of chemicals, it is suggestedthat the blend be tested rather than accepting the resistance ofthe individual chemicals because of a possible solvencyenhancement of the combined chemicals.4.4 The specimens tested in this classification a

15、re un-stressed. When service conditions include stress or otherfactors, or both, test chemical resistance of the PVC/CPVCcompound under actual service conditions.5. Basis of Classification5.1 The chemical resistance of a PVC or CPVC compoundis composed of the cell classifications specified from Tabl

16、e 1.For example, the resistance of PVC to 25 % acetic acid atambient temperature would be written as a cell classification ofA05231:ClassChemical (acetic acid from annex) A05Concentration of 25 % 2Temperature of 23C 3Resistance 1NOTE 2The cell-type format provides the means of classifyingchemical re

17、sistance. This type of format is subject to possible misappli-cation in classifying a chemical resistance that is unobtainable withcommercially available materials. Consult the manufacturer regarding thisclassification.6. Performance Requirements6.1 The chemical resistance shall be for a compound th

18、atmeets the physical property and processing requirements of theapplication.7. Sampling7.1 A batch or lot shall be considered as a unit of manufac-ture and is permitted to consist of a blend of two or moreproduction runs of material.7.2 Sample using a statistically acceptable procedure.8. Test Metho

19、ds8.1 Determine the chemical resistance of a compound fol-lowing the procedure of Test Method D543 except the expo-sure period shall be for 30 days. Note the chemical, concen-tration, test temperature, and resistance in accordance with8.1.1-8.1.4. This data is compiled in Table 1 and comprises thesi

20、x digits of the chemical resistance cell.8.1.1 The test chemical is designated from the alphanumeri-cal list of chemicals in the annex. This alphanumeric designa-tion is the first three digits of the chemical resistance cell.8.1.2 The concentration of the chemical from row two ofTable 1 is designate

21、d as the fourth digit of the chemicalresistance cell.8.1.3 The test temperature from row three of Table 1 isdesignated as the fifth number of the chemical resistance cell.8.1.4 The resistance of a compound from row four of Table1 is designated as the sixth number of the chemical resistancecell. Grad

22、e a compound for its resistance to the testing of8.1.1-8.1.3 as follows:Resistant MarginallyResistantNon-ResistantLinear Swelling 0 % 5 %Change in Weight 10 %Change in Shore Hardness no change 5 units9. Inspection9.1 Inspection of the product shall be agreed upon betweenthe purchaser and the supplie

23、r as part of the purchase contract.10. Rejection and Rehearing10.1 Product that fails to conform to the requirements of thisclassification shall not be certified as meeting the requirementsof this classification. Report rejection to the producer orsupplier promptly and in writing. In case of dissati

24、sfaction withthe results of the test, the producer or supplier is permitted tomake claim for a rehearing.11. Keywords11.1 chemical resistance; chlorinated poly(vinyl chloride)polymers; poly(vinyl chloride) copolymers; poly(vinyl chlo-ride) polymersTABLE 1 Chemical Resistance of a CompoundDesignation

25、Order NumberProperty and UnitCell Limits0 12345671 to 3 chemical unspecified use number of chemical from annex4 concentration, % unspecified 0 to 19 20 to 39 40 to 59 60 to 79 80 to 99 1005 temperature, C unspecified 1006 resistance unspecified R MR NRD5260 04 (2010)2ANNEX(Mandatory Information)A1.

26、ALPHANUMERICAL LIST OF CHEMICALSAcetaldehyde A01 Ammonia Biflouride A19Acetamide A02 Ammonium Carbonate A20Acetate Solvent A03 Ammonium Casenite A21Acetic Acid, Glacial A04 Ammonium Chloride A22Acetic Acid A05 Ammonium Hydroxide A23Acetic Anhydride A06 Ammonium Nitrate A24Acetone A07 Ammonium Oxalat

27、e A25Acetylene A08 Ammonium Persulfate A26Acrylonitrile A09 Ammonium Phosphate, Dibasic A27Aluminum Chloride A10 Ammonium Phosphate, Monobasic A28Aluminum Fluoride A11 Ammonium Phosphate, Tribasic A29Aluminum Hydroxide A12 Ammonium Sulfate A30Aluminum Potassium Sulfate A13 Ammonium Thio-Sulfate A31A

28、luminum Sulfate A14 Amyl Acetate A32Amines A15 Amyl Alcohol A33Ammonia, Anhydrous A16 Amyl Chloride A34Ammonia, Liquid A17 Aniline A35Ammonia, Nitrate A18 Aqua Regia (80 % HCl/20 % H2SO4) A36Arsenic Acid A37Barium Carbonate B01 Benzyl Alcohol B14Barium Chloride B02 Borax (Sodium Borate) B15Barium Cy

29、anide B03 Boric Acid B16Barium Hydroxide B04 Brewey Slop B17Barium Nitrate B05 Bromine B18Barium Sulfate B06 Butadiene B19Barium Sulfide B07 Butane B20Beer B08 Butter B21Beet Sugar Liquids B09 Buttermilk B22Benzaldehyde B10 Butyl Acetate B23Benzene B11 Butyl Alcohol B24Benzoic Acid B12 Butylene B25B

30、enzol B13 Butyric Acid B26Calcium Bisulfide C01 Chlorobenzene (mono) C20Calcium Carbonate C02 Chloroform C21Calcium Chloride C03 Chlorosulfuric Acid C22Calcium Hydroxide C04 Chlorox (bleach) C23Calcium Hypochlorite C05 Chocolate Syrup C24Calcium Sulfate C06 Chromic Acid C25Calgon C07 Cider C26Cane J

31、uice C08 Citric Acid C27Carbolic Acid(See Phenol) Coffee C28Carbon Bisulfide C09 Copper Chloride C29Carbon Dioxide C10 Copper Cyanide C30Carbon Disulfide C11 Copper Fluorborate C31Carbon Monoxide C12 Copper Nitrate C32Carbon Tetrachloride C13 Copper Sulfate C33Carbonated Water C14 Cream C34Carbonic

32、Acid C15 Cresols C35Catsup C16 Cresylic Acid C36Chloroacetic Acid C17 Cyclohexane C37Chlorinated Glue C18 Cyanic Acid C38Chlorine, Anhydrous Liquid C19D5260 04 (2010)3Detergents D01 Diethylene Glycol D04Diethylene D02 Diphenyl Oxide D05Diacetone Alcohol D03 Dyes D06Epsom Salts.(See Magnesium Sulfate

33、) Ethyl Chloride E06Ethane E01 Ethyl Sulfate E07Ethanolamine E02 Ethylene Chloride E08Ether E03 Ethylene Dichloride E09Ethyl Acetate E04 Ethylene Glycol E10Ethyl Alcohol E05 Ethylene Oxide E11Fatty Acids F01 Freon 22 F13Ferric Chloride F02 Freon 113 F14Ferric Nitrate F03 Freon T.F. F15Ferric Sulfate

34、 F04 Fruit Juice F16Ferrous Chloride F05 Fuel Oil #1 F17Ferrous Sulfate F06 Fuel Oil #2 F18Fluorboric Acid F07 Fuel Oil #3 F19Fluosilicic Acid F08 Fuel Oil #5A F20Formaldehyde F09 Fuel Oil #5B F21Formic Acid F10 Fuel Oil #6 F22Freon 11 F11 Furan Resin F23Freon 12 (wet) F12 Furfural F24Gasoline (unle

35、aded) G01 Glycerine G06Gasoline (unleaded premium) G02 Glycolic Acid G07Gelatin G03 Gold Monocyanide G08Glucose G04 Grape Juice G09Glue, P.V.A. G05 Grease G10Heptane H01 Hydrochloric Acid H09Hexane H02 Hydrocyanic Acid H10Hexyl Alcohol H03 Hydrofluoric Acid H11Honey H04 Hydrofluosilicic Acid H12Hydr

36、aulic Oil (Petroleum) H05 Hydrogen Peroxide H13Hydraulic Oil (Synthetic) H06 Hydrogen Sulfide, Aqueous H14Hydrazine H07 Hydroxyacetic Acid H15Hydrobromic Acid H08Ink I01 Isopropyl Acetate I05Iodine I02 Isopropyl Ether I06Isobutyl Alcohol I03 Isotane I07Isopropyl Alcohol I04JP 3 Jet Fuel J01 JP 5 Jet

37、 Fuel J03JP 4 Jet Fuel J02Kerosene K01Lacquers L01 Lead Sulfamate L06Lactic Acid L02 Ligroin L07Lard L03 Lime L08Latex L04 Lubricants L09Lead Acetate L05Magnesium Carbonate M01 Methyl Acrylate M17D5260 04 (2010)4Magnesium Chloride M02 Methyl Alcohol M18Magnesium Hydroxide M03 Methyl Bromide M19Magne

38、sium Nitrate M04 Methyl Butyl Ketone M20Magnesium Oxide M05 Methyl Cellosolve M21Magnesium Sulfate M06 Methyl Chloride M22Maleic Acid M07 Methyl Dichloride M23Maleic Anhydride M08 Methyl Ethyl Ketone M24Mash M09 Methyl Isobutyl Ketone M25Mayonnaise M10 Methyl Isopropyl Ketone M26Melamine M11 Methyl

39、Methacrylate M27Mercuric Chloride M12 Methylamine M28Mercuric Cyanide M13 Methylene Chloride M29Mercury M14 Milk M30Methyl Acetate M15 Mineral Oil M31Methyl Acetone M16 Molasses M32Mustard M33Naptha N01 Nickel Sulfate N04Napthalene N02 Nitric Acid N05Nickel Chloride N03 Nitrobenzene N06Oils: Oils:An

40、ise O01 Olive O15Bay O02 Orange O16Bone O03 Palm O17Castor O04 Peanut O18Cinnamon O05 Peppermint O19Citric O06 Pine O20Clove O07 Rape Seed O21Coconut O08 Rosin O22Cod Liver O09 Sesame Seed O23Corn O10 Soybean O24Cotton Seed O11 Sperm O25Ginger O12 Oleic Acid O26Lemon O13 Oleum O27Linseed O14 Oxalic

41、Acid O28Paraffin P01 Potash P23Pentane P02 Potassium Bicarbonate P24Perchloroethylene P03 Potassium Bromide P25Petrolatum P04 Potassium Carbonate P26Phenol P05 Potassium Chlorate P27Phosphoric Acid P06 Potassium Chloride P28Photographic Developer P07 Potassium Chromate P29Plating Solution:Antimony P

42、08 Potassium Cyanide P30Arsenic P09 Potassium Dichromate P31Brass P10 Potassium Hydroxide P32Bronze P11 Potassium Nitrate P33Cadmium P12 Potassium Permanganate P34Chrome P13 Potassium Sulfate P35Copper P14 Propane (liquified) P36Gold P15 Propyl Alcohol P37Indium P16 Propylene Glycol P38Iron P17 Pyri

43、dene P39Lead P18 Pyrogallic Acid P40Nickel P19Silver P20Tin P21Zinc P22Rosins R01 Rust Inhibitors R03Rum R02Salad Dressing S01 Sodium Polyphosphate, monobasic S26D5260 04 (2010)5Sea Water S02 Sodium Polyphosphate, dibasic S27Shellac (bleached) S03 Sodium Polyphosphate, tribasic S28Shellac (orange) S

44、04 Sodium Silicate S29Silicone S05 Sodium Sulfate S30Silver Bromide S06 Sodium Sulfide S31Silver Nitrate S07 Sodium Tetraborate S32Soap Solutions S08 Sodium Thiosulfate S33Sodium Acetate S09 Sorgum S34Sodium Aluminate S10 Soy Sauce S35Sodium Bicarbonate S11 Stannic Chloride S36Sodium Bisulfate S12 S

45、tannic Fluoborate S37Sodium Bisulfite S13 Starch S38Sodium Carbonate S14 Stearic Acid S39Sodium Chlorate S15 Stoddard Solvent S40Sodium Chloride S16 Styrene S41Sodium Chromate S17 Sugar (liquids) S42Sodium Cyanide S18 Sulfate Liquors S43Sodium Hydroxide S19 Sulfur Chloride S44Sodium Hypochlorite S20

46、 Sulfur Dioxide S45Sodium Metaphosphate S21 Sulfur Trioxide S46Sodium Metasilicate S22 Sulfuric Acid S47Sodium Nitrate S23 Sulfurous Acid S48Sodium Perborate S24 Syrup S49Sodium Peroxide S25Tallow T01 Tomato Juice T08Tannic Acid T02 Trichloroethane T09Tanning Liquors T03 Trichloroethylene T10Tartari

47、c Acid T04 Trichloropropane T11Tetrachloroethane T05 Tricresylphosphate T12Tetrahydrofuran T06 Triethylamine T13Toluene T07 Turpentine T14Urine U01Vegetable Juice V01 Vinegar V02Water, Distilled W01 Whey W06Water, Fresh W02 Whiskey W07Water, Mine, Acid W03 Wine W08Water, Salt W04 White Liquor (pulp

48、mill) W09Weed Killers W05 White Water (pulp mill) W10Xylene X01Zinc Chloride Z01 Zinc Sulfate Z03Zinc Hydrosulfite Z02D5260 04 (2010)6ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standa

49、rd are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of therespon