ASTM D5260-2004 Standard Classification for Chemical Resistance of Poly(Vinyl Chloride) (PVC) Homopolymer and Copolymer Compounds and Chlorinated Poly(Vinyl Chloride) (CPVC) Compou.pdf

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1、Designation: D 5260 04Standard Classification forChemical Resistance of Poly(Vinyl Chloride) (PVC)Homopolymer and Copolymer Compounds and ChlorinatedPoly(Vinyl Chloride) (CPVC) Compounds1This standard is issued under the fixed designation D 5260; the number immediately following the designation indi

2、cates the year oforiginal adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.1. Scope*1.1 This classification covers the method fo

3、r determiningand classifying the resistance of poly(vinyl chloride) (PVC)homopolymer and copolymer compounds, and chlorinatedpoly(vinyl chloride) (CPVC) compounds in chemicals bysimple immersion testing of unstressed specimens.1.2 This classification is applicable to any PVC or CPVCcompound as defin

4、ed in Specifications D 1784, D 3915,D 4216, D 4396, or D 4551.1.3 The values stated in SI units are to be regarded asstandard.1.4 The text of this standard references notes and footnoteswhich provide explanatory material. These notes and footnotes(excluding those in tables and figures) shall not be

5、consideredas requirements of this standard.1.5 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulato

6、ry limitations prior to use.NOTE 1There are no ISO standards covering the subject matter of thisclassification.2. Referenced Documents2.1 ASTM Standards:2D 543 Test Method for Resistance of Plastics to ChemicalReagentsD 883 Terminology Relating to PlasticsD 1600 Terminology for Abbreviated Terms Rel

7、ating toPlasticsD 1784 Specification for Rigid Poly(Vinyl Chloride) (PVC)Compounds and Chlorinated Poly(Vinyl Chloride)(CPVC) CompoundsD 3915 Specification for Poly(Vinyl Chloride) (PVC) andRelated Plastic Pipe and Fittings Compounds for PressureApplicationsD 4216 Specification for Rigid Poly(Vinyl

8、Chloride) (PVC)and Related Plastic Building Products CompoundsD 4396 Specification for Rigid Poly(Vinyl Chloride) (PVC)and Related Plastic Compounds for Nonpressure PipingProductsD 4551 Specification for Poly(Vinyl Chloride) (PVC) Plas-tic Flexible Concealed Water-Containment Membrane3. Terminology3

9、.1 Definitions and Abbreviations:3.1.1 Definitions are in accordance with Terminology D 883and abbreviations with Terminology D 1600 unless otherwiseindicated.4. Significance and Use4.1 Reference this chemical resistance classification for anyPVC/CPVC material compound specification wherein a levelo

10、f resistance to specific chemicals is required for satisfactoryproduct performance.4.2 Listing of a chemical in the annex does not implyPVC/CPVC compatibility or resistance to the chemical. Someof the chemicals listed could be deleterious to a specificcompound, causing radical changes in the physica

11、l properties.Resistance to these chemicals is not intended to be a practicalrequirement in a specification.4.3 For resistance to mixtures of chemicals, it is suggestedthat the blend be tested rather than accepting the resistance ofthe individual chemicals because of a possible solvencyenhancement of

12、 the combined chemicals.4.4 The specimens tested in this classification are un-stressed. When service conditions include stress or otherfactors, or both, test chemical resistance of the PVC/CPVCcompound under actual service conditions.1This classification is under the jurisdiction of ASTM Committee

13、D20 onPlastics and is the direct responsibility of Subcommittee D20.15 on ThermoplasticMaterials.Current edition approved February 1, 2004. Published March 2004. Originallyapproved in 1992. Last previous edition approved in 1997 as D 5260 - 97.2For referenced ASTM standards, visit the ASTM website,

14、www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.1*A Summary of Changes section appears at the end of this standard.Copyright ASTM International, 100 Barr Harbor Driv

15、e, PO Box C700, West Conshohocken, PA 19428-2959, United States.5. Basis of Classification5.1 The chemical resistance of a PVC or CPVC compoundis composed of the cell classifications specified from Table 1.For example, the resistance of PVC to 25 % acetic acid atambient temperature would be written

16、as a cell classification ofA05231:ClassChemical (acetic acid from annex) A05Concentration of 25 % 2Temperature of 23C 3Resistance 1NOTE 2The cell-type format provides the means of classifyingchemical resistance. This type of format is subject to possible misappli-cation in classifying a chemical res

17、istance that is unobtainable withcommercially available materials. Consult the manufacturer regarding thisclassification.6. Performance Requirements6.1 The chemical resistance shall be for a compound thatmeets the physical property and processing requirements of theapplication.7. Sampling7.1 A batch

18、 or lot shall be considered as a unit of manufac-ture and is permitted to consist of a blend of two or moreproduction runs of material.7.2 Sample using a statistically acceptable procedure.8. Test Methods8.1 Determine the chemical resistance of a compound fol-lowing the procedure of Test Method D 54

19、3 except theexposure period shall be for 30 days. Note the chemical,concentration, test temperature, and resistance in accordancewith 8.1.1-8.1.4. This data is compiled in Table 1 and com-prises the six digits of the chemical resistance cell.8.1.1 The test chemical is designated from the alphanumeri

20、-cal list of chemicals in the annex. This alphanumeric designa-tion is the first three digits of the chemical resistance cell.8.1.2 The concentration of the chemical from row two ofTable 1 is designated as the fourth digit of the chemicalresistance cell.8.1.3 The test temperature from row three of T

21、able 1 isdesignated as the fifth number of the chemical resistance cell.8.1.4 The resistance of a compound from row four of Table1 is designated as the sixth number of the chemical resistancecell. Grade a compound for its resistance to the testing of8.1.1-8.1.3 as follows:Resistant MarginallyResista

22、ntNon-ResistantLinear Swelling 0 % 5 %Change in Weight 10 %Change in Shore Hardness no change 5 units9. Inspection9.1 Inspection of the product shall be agreed upon betweenthe purchaser and the supplier as part of the purchase contract.10. Rejection and Rehearing10.1 Product that fails to conform to

23、 the requirements of thisclassification shall not be certified as meeting the requirementsof this classification. Report rejection to the producer orsupplier promptly and in writing. In case of dissatisfaction withthe results of the test, the producer or supplier is permitted tomake claim for a rehe

24、aring.11. Keywords11.1 chemical resistance; chlorinated poly(vinyl chloride)polymers; poly(vinyl chloride) copolymers; poly(vinyl chlo-ride) polymersTABLE 1 Chemical Resistance of a CompoundDesignationOrder NumberProperty and UnitCell Limits0 12345671 to 3 chemical unspecified use number of chemical

25、 from annex4 concentration, % unspecified 0 to 19 20 to 39 40 to 59 60 to 79 80 to 99 1005 temperature, C unspecified 1006 resistance unspecified R MR NRD5260042ANNEX(Mandatory Information)A1. ALPHANUMERICAL LIST OF CHEMICALSAcetaldehyde A01 Ammonia Biflouride A19Acetamide A02 Ammonium Carbonate A20

26、Acetate Solvent A03 Ammonium Casenite A21Acetic Acid, Glacial A04 Ammonium Chloride A22Acetic Acid A05 Ammonium Hydroxide A23Acetic Anhydride A06 Ammonium Nitrate A24Acetone A07 Ammonium Oxalate A25Acetylene A08 Ammonium Persulfate A26Acrylonitrile A09 Ammonium Phosphate, Dibasic A27Aluminum Chlorid

27、e A10 Ammonium Phosphate, Monobasic A28Aluminum Fluoride A11 Ammonium Phosphate, Tribasic A29Aluminum Hydroxide A12 Ammonium Sulfate A30Aluminum Potassium Sulfate A13 Ammonium Thio-Sulfate A31Aluminum Sulfate A14 Amyl Acetate A32Amines A15 Amyl Alcohol A33Ammonia, Anhydrous A16 Amyl Chloride A34Ammo

28、nia, Liquid A17 Aniline A35Ammonia, Nitrate A18 Aqua Regia (80 % HCl/20 % H2SO4) A36Arsenic Acid A37Barium Carbonate B01 Benzyl Alcohol B14Barium Chloride B02 Borax (Sodium Borate) B15Barium Cyanide B03 Boric Acid B16Barium Hydroxide B04 Brewey Slop B17Barium Nitrate B05 Bromine B18Barium Sulfate B0

29、6 Butadiene B19Barium Sulfide B07 Butane B20Beer B08 Butter B21Beet Sugar Liquids B09 Buttermilk B22Benzaldehyde B10 Butyl Acetate B23Benzene B11 Butyl Alcohol B24Benzoic Acid B12 Butylene B25Benzol B13 Butyric Acid B26Calcium Bisulfide C01 Chlorobenzene (mono) C20Calcium Carbonate C02 Chloroform C2

30、1Calcium Chloride C03 Chlorosulfuric Acid C22Calcium Hydroxide C04 Chlorox (bleach) C23Calcium Hypochlorite C05 Chocolate Syrup C24Calcium Sulfate C06 Chromic Acid C25Calgon C07 Cider C26Cane Juice C08 Citric Acid C27Carbolic Acid(See Phenol) Coffee C28Carbon Bisulfide C09 Copper Chloride C29Carbon

31、Dioxide C10 Copper Cyanide C30Carbon Disulfide C11 Copper Fluorborate C31Carbon Monoxide C12 Copper Nitrate C32Carbon Tetrachloride C13 Copper Sulfate C33Carbonated Water C14 Cream C34Carbonic Acid C15 Cresols C35Catsup C16 Cresylic Acid C36Chloroacetic Acid C17 Cyclohexane C37Chlorinated Glue C18 C

32、yanic Acid C38Chlorine, Anhydrous Liquid C19D5260043Detergents D01 Diethylene Glycol D04Diethylene D02 Diphenyl Oxide D05Diacetone Alcohol D03 Dyes D06Epsom Salts.(See Magnesium Sulfate) Ethyl Chloride E06Ethane E01 Ethyl Sulfate E07Ethanolamine E02 Ethylene Chloride E08Ether E03 Ethylene Dichloride

33、 E09Ethyl Acetate E04 Ethylene Glycol E10Ethyl Alcohol E05 Ethylene Oxide E11Fatty Acids F01 Freon 22 F13Ferric Chloride F02 Freon 113 F14Ferric Nitrate F03 Freon T.F. F15Ferric Sulfate F04 Fruit Juice F16Ferrous Chloride F05 Fuel Oil #1 F17Ferrous Sulfate F06 Fuel Oil #2 F18Fluorboric Acid F07 Fuel

34、 Oil #3 F19Fluosilicic Acid F08 Fuel Oil #5A F20Formaldehyde F09 Fuel Oil #5B F21Formic Acid F10 Fuel Oil #6 F22Freon 11 F11 Furan Resin F23Freon 12 (wet) F12 Furfural F24Gasoline (unleaded) G01 Glycerine G06Gasoline (unleaded premium) G02 Glycolic Acid G07Gelatin G03 Gold Monocyanide G08Glucose G04

35、 Grape Juice G09Glue, P.V.A. G05 Grease G10Heptane H01 Hydrochloric Acid H09Hexane H02 Hydrocyanic Acid H10Hexyl Alcohol H03 Hydrofluoric Acid H11Honey H04 Hydrofluosilicic Acid H12Hydraulic Oil (Petroleum) H05 Hydrogen Peroxide H13Hydraulic Oil (Synthetic) H06 Hydrogen Sulfide, Aqueous H14Hydrazine

36、 H07 Hydroxyacetic Acid H15Hydrobromic Acid H08Ink I01 Isopropyl Acetate I05Iodine I02 Isopropyl Ether I06Isobutyl Alcohol I03 Isotane I07Isopropyl Alcohol I04JP 3 Jet Fuel J01 JP 5 Jet Fuel J03JP 4 Jet Fuel J02Kerosene K01Lacquers L01 Lead Sulfamate L06Lactic Acid L02 Ligroin L07Lard L03 Lime L08La

37、tex L04 Lubricants L09Lead Acetate L05Magnesium Carbonate M01 Methyl Acrylate M17D5260044Magnesium Chloride M02 Methyl Alcohol M18Magnesium Hydroxide M03 Methyl Bromide M19Magnesium Nitrate M04 Methyl Butyl Ketone M20Magnesium Oxide M05 Methyl Cellosolve M21Magnesium Sulfate M06 Methyl Chloride M22M

38、aleic Acid M07 Methyl Dichloride M23Maleic Anhydride M08 Methyl Ethyl Ketone M24Mash M09 Methyl Isobutyl Ketone M25Mayonnaise M10 Methyl Isopropyl Ketone M26Melamine M11 Methyl Methacrylate M27Mercuric Chloride M12 Methylamine M28Mercuric Cyanide M13 Methylene Chloride M29Mercury M14 Milk M30Methyl

39、Acetate M15 Mineral Oil M31Methyl Acetone M16 Molasses M32Mustard M33Naptha N01 Nickel Sulfate N04Napthalene N02 Nitric Acid N05Nickel Chloride N03 Nitrobenzene N06Oils: Oils:Anise O01 Olive O15Bay O02 Orange O16Bone O03 Palm O17Castor O04 Peanut O18Cinnamon O05 Peppermint O19Citric O06 Pine O20Clov

40、e O07 Rape Seed O21Coconut O08 Rosin O22Cod Liver O09 Sesame Seed O23Corn O10 Soybean O24Cotton Seed O11 Sperm O25Ginger O12 Oleic Acid O26Lemon O13 Oleum O27Linseed O14 Oxalic Acid O28Paraffin P01 Potash P23Pentane P02 Potassium Bicarbonate P24Perchloroethylene P03 Potassium Bromide P25Petrolatum P

41、04 Potassium Carbonate P26Phenol P05 Potassium Chlorate P27Phosphoric Acid P06 Potassium Chloride P28Photographic Developer P07 Potassium Chromate P29Plating Solution:Antimony P08 Potassium Cyanide P30Arsenic P09 Potassium Dichromate P31Brass P10 Potassium Hydroxide P32Bronze P11 Potassium Nitrate P

42、33Cadmium P12 Potassium Permanganate P34Chrome P13 Potassium Sulfate P35Copper P14 Propane (liquified) P36Gold P15 Propyl Alcohol P37Indium P16 Propylene Glycol P38Iron P17 Pyridene P39Lead P18 Pyrogallic Acid P40Nickel P19Silver P20Tin P21Zinc P22Rosins R01 Rust Inhibitors R03Rum R02Salad Dressing

43、S01 Sodium Polyphosphate, monobasic S26D5260045Sea Water S02 Sodium Polyphosphate, dibasic S27Shellac (bleached) S03 Sodium Polyphosphate, tribasic S28Shellac (orange) S04 Sodium Silicate S29Silicone S05 Sodium Sulfate S30Silver Bromide S06 Sodium Sulfide S31Silver Nitrate S07 Sodium Tetraborate S32

44、Soap Solutions S08 Sodium Thiosulfate S33Sodium Acetate S09 Sorgum S34Sodium Aluminate S10 Soy Sauce S35Sodium Bicarbonate S11 Stannic Chloride S36Sodium Bisulfate S12 Stannic Fluoborate S37Sodium Bisulfite S13 Starch S38Sodium Carbonate S14 Stearic Acid S39Sodium Chlorate S15 Stoddard Solvent S40So

45、dium Chloride S16 Styrene S41Sodium Chromate S17 Sugar (liquids) S42Sodium Cyanide S18 Sulfate Liquors S43Sodium Hydroxide S19 Sulfur Chloride S44Sodium Hypochlorite S20 Sulfur Dioxide S45Sodium Metaphosphate S21 Sulfur Trioxide S46Sodium Metasilicate S22 Sulfuric Acid S47Sodium Nitrate S23 Sulfurou

46、s Acid S48Sodium Perborate S24 Syrup S49Sodium Peroxide S25Tallow T01 Tomato Juice T08Tannic Acid T02 Trichloroethane T09Tanning Liquors T03 Trichloroethylene T10Tartaric Acid T04 Trichloropropane T11Tetrachloroethane T05 Tricresylphosphate T12Tetrahydrofuran T06 Triethylamine T13Toluene T07 Turpent

47、ine T14Urine U01Vegetable Juice V01 Vinegar V02Water, Distilled W01 Whey W06Water, Fresh W02 Whiskey W07Water, Mine, Acid W03 Wine W08Water, Salt W04 White Liquor (pulp mill) W09Weed Killers W05 White Water (pulp mill) W10Xylene X01Zinc Chloride Z01 Zinc Sulfate Z03Zinc Hydrosulfite Z02D5260046SUMMA

48、RY OF CHANGESThis section identifies the location of selected changes to this classification. For the convenience of the user,Committee D20 has highlighted those changes that impact the use of this classification. This section also includesdescriptions of the changes or reasons for the changes, or b

49、oth.D 5260 - 04:(1) Removed references to D 1898 and D 3679.(2) Revised for use of permissive language.D 5260 - 97:(1) Added ISO equivalency statement (Note 1).(2) Added explanation of notes and footnotes (1.4).ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at