ASTM D4651-2014 Standard Specification for Isobutane Thermophysical Property Tables《异丁烷热物理性能表的标准规格》.pdf
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1、Designation: D4651 14Standard Specification forIsobutane Thermophysical Property Tables1This standard is issued under the fixed designation D4651; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A number
2、in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 The thermophysical property tables for isobutane are foruse in the calculation of the pressure-volume-temperature(PVT), thermodynamic, and tra
3、nsport properties of isobutanefor process design and operations. Two tables provide proper-ties at the conditions of liquid-vapor equilibrium (saturationproperties), one for liquid and one for vapor, at temperaturesbetween 120 K and the critical point, 407.81 K. A third tableprovides properties at s
4、elected T, p points for the equilibriumphase at temperatures between 120 K and 570 K at pressures to20 MPa. The tables were developed using the National Instituteof Standards and Technology Standard Reference Databaseproduct REFPROP, version 9.1.1.2 The values stated in SI units are to be regarded a
5、sstandard. No other units of measurement are included in thisstandard.2. Applicability2.1 These tables apply directly only to pure isobutane. Theymay also be used in mathematical models and tables for thethermophysical properties of mixtures containing isobutane.3. Tables3.1 These tables were produc
6、ed by equations from a com-puter package, “NIST Standard Reference Database 23; Ref-erence Fluid Thermodynamic and Transport Properties Data-base (REFPROP): Version 9.1.”2A wide selection of units (SIunits, engineering units, chemical units) and additional prop-erties are available with this program
7、.3.2 These thermophysical property tables are:3.2.1 Thermophysical Properties of Isobutane Liquid atVapor-Liquid Equilibrium, in SI units. See Table 1.3.2.2 Thermophysical Properties of Isobutane Vapor atVapor-Liquid Equilibrium, in SI units. See Table 2.3.2.3 Thermophysical Properties of Isobutane
8、AlongIsobars, in SI units. See Table 3.3.3 The symbols are:T, temperature (K), molar density (molL-1)H, molar enthalpy (Jmol-1)S, molar entropy (JK-1mol-1)Cv, constant volume molar heat capacity (JK-1mol-1)Cp, constant pressure molar heat capacity (JK-1mol-1)c, speed of sound (ms-1), viscosity (Pas)
9、, thermal conductivity (mWm-1K-1)3.4 The tabulated thermophysical properties are:, molar density (molL-1)H, molar enthalpy (Jmol-1)S, molar entropy (JK-1mol-1)Cv, constant volume molar heat capacity (JK-1mol-1)Cp, constant pressure molar heat capacity (JK-1mol-1)c, speed of sound (ms-1), viscosity (
10、Pas), thermal conductivity (mWm-1K-1)4. Additional Information4.1 Reference state properties are required to calculate thethermodynamic properties enthalpy and entropy from an equa-tion of state formulation. The reference state properties usedare those specified by the International Institute of Ref
11、rigera-tion (IIR): enthalpy, H = 200 J/g, and entropy, S = 1 J/(gK), forthe saturated liquid at 273.15K (0C).4.2 The molar mass of isobutane is 58.122 g/mol.5. Keywords5.1 isobutane; isobutane gas tables; natural gas; thermody-namic properties of isobutane; transport properties of isobu-tane; 2-meth
12、ylpropane1This specification is under the jurisdiction of ASTM Committee D03 onGaseous Fuels and is the direct responsibility of Subcommittee D03.08 onThermophysical Properties.Current edition approved June 1, 2014. Published July 2014. Originally approvedin 1987. Last previous edition approved in 2
13、008 as D4651 08. DOI: 10.1520/D4651-14.2Available from Standard Reference Data, National Institute of Standards andTechnology (NIST), 100 Bureau Drive, Stop 3460, Gaithersburg, MD 20899.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1
14、TABLE 1 Thermophysical Properties of Isobutane Liquid at Vapor-Liquid EquilibriumTP HSCvCpc K MPa moll-1Jmol-1Jmol-1K-1Jmol-1K-1Jmol-1K-1ms-1Pas mWm-1K-1120 1.0633E-07 12.636 -5912.6 -34.216 69.001 99.308 1945.4 6055.8 156.73122 1.6734E-07 12.603 -5713.6 -32.571 69.251 99.681 1928.5 5441.0 156.30124
15、 2.5915E-07 12.571 -5513.9 -30.948 69.501 100.06 1911.9 4910.8 155.85126 3.9524E-07 12.538 -5313.4 -29.344 69.752 100.43 1895.5 4450.9 155.38128 5.9407E-07 12.506 -5112.1 -27.759 70.004 100.81 1879.3 4049.9 154.89130 8.8064E-07 12.473 -4910.1 -26.193 70.255 101.18 1863.4 3698.4 154.39132 1.2883E-06
16、12.441 -4707.4 -24.646 70.505 101.56 1847.7 3389.0 153.86134 1.8611E-06 12.408 -4503.9 -23.116 70.754 101.93 1832.2 3115.4 153.32136 2.6564E-06 12.376 -4299.7 -21.603 71.003 102.30 1816.9 2872.5 152.76138 3.7483E-06 12.343 -4094.7 -20.107 71.250 102.68 1801.7 2656.0 152.19140 5.2314E-06 12.311 -3889
17、.0 -18.627 71.497 103.05 1786.8 2462.5 151.60142 7.2252E-06 12.278 -3682.5 -17.162 71.743 103.42 1772.0 2288.8 150.99144 9.8793E-06 12.245 -3475.3 -15.713 71.988 103.79 1757.4 2132.5 150.37146 1.3379E-05 12.213 -3267.4 -14.279 72.233 104.16 1742.9 1991.3 149.74148 1.7953E-05 12.180 -3058.7 -12.859 7
18、2.477 104.53 1728.6 1863.6 149.09150 2.3880E-05 12.147 -2849.3 -11.454 72.720 104.89 1714.4 1747.6 148.43152 3.1496E-05 12.115 -2639.1 -10.062 72.964 105.26 1700.3 1642.0 147.75154 4.1206E-05 12.082 -2428.2 -8.6838 73.207 105.63 1686.4 1545.6 147.07156 5.3493E-05 12.049 -2216.6 -7.3185 73.451 106.00
19、 1672.6 1457.5 146.37158 6.8925E-05 12.016 -2004.2 -5.9659 73.695 106.36 1658.9 1376.7 145.67160 8.8176E-05 11.984 -1791.1 -4.6257 73.940 106.73 1645.3 1302.4 144.95162 0.00011203 11.951 -1577.3 -3.2975 74.186 107.10 1631.8 1234.1 144.22164 0.00014139 11.918 -1362.8 -1.9812 74.432 107.47 1618.3 1171
20、.0 143.48166 0.00017732 11.885 -1147.5 -0.67634 74.679 107.83 1605.0 1112.6 142.74168 0.00022101 11.852 -931.41 0.61730 74.928 108.20 1591.8 1058.6 141.98170 0.00027386 11.819 -714.63 1.9000 75.178 108.57 1578.6 1008.4 141.22172 0.00033740 11.786 -497.11 3.1721 75.430 108.95 1565.6 961.80 140.45174
21、0.00041343 11.752 -278.84 4.4337 75.684 109.32 1552.6 918.37 139.67176 0.00050391 11.719 -59.816 5.6852 75.939 109.69 1539.6 877.85 138.88178 0.00061107 11.686 159.96 6.9268 76.197 110.07 1526.8 839.98 138.09180 0.00073738 11.653 380.48 8.1588 76.456 110.45 1514.0 804.54 137.30182 0.00088560 11.619
22、601.77 9.3813 76.718 110.83 1501.3 771.33 136.49184 0.0010588 11.586 823.82 10.595 76.983 111.21 1488.6 740.15 135.68186 0.0012602 11.552 1046.6 11.799 77.250 111.60 1476.0 710.84 134.87188 0.0014935 11.519 1270.2 12.995 77.519 111.98 1463.4 683.26 134.05190 0.0017628 11.485 1494.6 14.182 77.792 112
23、.37 1450.9 657.25 133.23192 0.0020724 11.451 1719.8 15.360 78.067 112.77 1438.5 632.72 132.40194 0.0024270 11.418 1945.7 16.531 78.345 113.16 1426.1 609.54 131.57196 0.0028316 11.384 2172.5 17.694 78.627 113.56 1413.7 587.61 130.73198 0.0032918 11.350 2400.0 18.849 78.911 113.96 1401.4 566.84 129.90
24、200 0.0038135 11.316 2628.4 19.996 79.199 114.37 1389.1 547.15 129.06202 0.0044031 11.282 2857.6 21.136 79.490 114.78 1376.9 528.46 128.21204 0.0050671 11.248 3087.6 22.269 79.785 115.19 1364.7 510.71 127.37206 0.0058130 11.213 3318.5 23.394 80.082 115.61 1352.6 493.83 126.52208 0.0066482 11.179 355
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