ASTM D3643-2015 Standard Test Method for Acid Number of Certain Alkali-Soluble Resins《某些碱溶性树脂酸值的标准试验方法》.pdf

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1、Designation: D3643 15Standard Test Method forAcid Number of Certain Alkali-Soluble Resins1This standard is issued under the fixed designation D3643; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A numbe

2、r in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method covers the measurement of the freeacidity present in certain alkali-soluble resins.1.2 This test method is not suitable for

3、 styrene-maleicanhydride resins.1.3 The resin manufacturer should specify whether or notthis test method may be used for his product(s).1.4 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.1.5 This standard does not purport to ad

4、dress all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D362 Specifi

5、cation for Industrial Grade Toluene (Withdrawn1989)3D1152 Specification for Methanol (Methyl Alcohol)D1193 Specification for Reagent WaterD3644 Test Method for Acid Number of Styrene-MaleicAnhydride Resins3. Terminology3.1 Definitions:3.1.1 acid numberthe number of milligrams of potassiumhydroxide (

6、KOH) required to neutralize the alkali-reactivegroups in1gofmaterial under the conditions of test.4. Significance and Use4.1 This test method is not appropriate for alkali-solubleresins whose acid functionality is due to incorporated anhy-drides. Variations in manufacture, storage, and possible con-

7、tamination of anhydride functional resins may cause partialhydrolysis, or esterification, which will invalidate data fromthis test method. Anhydride functional resins should be char-acterized by Test Method D3644.4.2 This test method is used to measure a property of acidfunctionalized resins. Acid n

8、umber determines the utility ofresins as well as being a significant quality control measure.5. Reagents and Materials5.1 Purity of ReagentsReagent grade chemicals shall beused in all tests. Unless otherwise indicated, it is intended thatall reagents shall conform to the specifications of the Commit

9、-tee on Analytical Reagents of the American Chemical Society,where such specifications are available.4Other grades may beused, provided it is first ascertained that the reagent is ofsufficiently high purity to permit its use without lessening theaccuracy of the determination.5.2 Purity of WaterUnles

10、s otherwise indicated, referencesto water shall be understood to mean reagent water conformingto Specification D1193.5.3 Neutral Solvent MixtureMix equal parts of denaturedalcohol and industrial toluene conforming respectively to therequirements described for SDA. 3A (200 proof) and Specifi-cation D

11、362. Neutralize the mixture using 0.1 N KOH solutionand phenolphthalein indicator solution, until the faint pinkcolor persists for 1 min.5.4 Phenolphthalein Indicator Solution (10 g/L)Dissolve1.0 g of phenolphthalein in 100 mL of denatured alcohol (SDA3A, 200 proof).5.5 Potassium Hydroxide, Methyl A

12、lcohol Solution (1mL = 5.6 mg KOH)Dissolve 6.6 g of potassium hydroxide1This test method is under the jurisdiction ofASTM Committee D21 on Polishesand is the direct responsibility of Subcommittee D21.02 on Raw Materials.Current edition approved Nov. 1, 2015. Published November 2015. Originallyapprov

13、ed in 1978. Last previous edition approved in 2010 as D3643 10. DOI:10.1520/D3643-15.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary

14、page onthe ASTM website.3The last approved version of this historical standard is referenced onwww.astm.org.4Reagent Chemicals, American Chemical Society Specifications, AmericanChemical Society, Washington, DC. For suggestions on the testing of reagents notlisted by the American Chemical Society, s

15、ee Analar Standards for LaboratoryChemicals, BDH Ltd., Poole, Dorset, U.K., and the United States Pharmacopeiaand National Formulary, U.S. Pharmacopeial Convention, Inc. (USPC), Rockville,MD.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United St

16、ates1(KOH) in 1 L of methyl alcohol conforming to the require-ments described in Specification D1152. Standardize againstNational Institute of Standards and Technology standardsample of acid potassium phthalate No. 84, using phenolphtha-lein as the indicator. Do not adjust the concentration of theso

17、lution, but calculate the milligrams of KOH per L ofsolution.6. Procedure6.1 Weigh or transfer into a 250-mL Erlenmeyer flask 0.5 gof crushed resin to the nearest 0.001 g.6.2 Add 100 mL of neutral solvent. Mix until all material isdissolved. Add 3 to 5 drops of phenolphthalein indicatorsolution and

18、titrate to the end point, a faint pink color whichpersists for 1 min.6.3 Run a blank titration in the procedure of 6.1 and 6.2without including test material.6.4 For each test material run three sample titrations and oneBlank titration.7. Calculation7.1 Calculate the acid number as follows:Acid numb

19、er 5 A2B!3N356.1!/CA = millilitres of alkali solution required for titration of thesample,B = millilitres of alkali solution required for titration of theBlank sample,N = normality of the alkali solution, andC = grams of resin used.8. Report8.1 Report the acid number of resin tested, to the nearestw

20、hole number.9. Precision and Bias9.1 PrecisionDuplicate results by the same operator shallnot be considered suspect unless they differ by more than 65units.9.2 BiasThis test has no bias because the values producedare defined only in terms of this test method.10. Keywords10.1 acid number; alkali-solu

21、ble resins; free acid; polish;resins; titrationASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights,

22、and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revi

23、sion of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you

24、shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be o

25、btained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ 152