ASTM B183-1979(2004)e1 Standard Practice for Preparation of Low-Carbon Steel for Electroplating《电镀用低碳钢的制备》.pdf

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1、Designation: B 183 79 (Reapproved 2004)e1Standard Practice forPreparation of Low-Carbon Steel for Electroplating1This standard is issued under the fixed designation B 183; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of

2、 last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.e1NOTEWarning note updated in 5.5 in May 2004.1

3、. Scope1.1 This practice is intended as an aid to electroplaters insetting up a suitable cleaning cycle preparatory to electroplat-ing of low-carbon steel (Note 1) containing less than 0.35mass % of carbon and to indicate some of the precautions thatmust be taken to maintain this cycle in good opera

4、tingcondition.NOTE 1The preparation of high-carbon steel for electroplating iscovered in Practice B 242.1.2 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and

5、health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2B 242 Practice for Preparation of High-Carbon Steel forElectroplatingB 322 Guide for Cleaning Metals Prior to Electroplating3. Nature of Cleaning3.1 The preparation of

6、low-carbon steel for electroplatinginvolves three basic steps in the following order:3.1.1 Removal of oil, grease, and caked-on dirt,3.1.2 Removal of scale and oxide films by “pickling,” and3.1.3 Removal of any smut left on the surface after step3.1.2 and activation of the steel.3.2 Removal from the

7、 steel of fabricating lubricants andfinishing compounds may have to be undertaken by “preclean-ing” before the articles reach the electroplating room. Theremainder of the operations should immediately precede theelectroplating. In some instances separate removal of smut maynot be necessary as in the

8、 case of parts which are barrel-electroplated and tumbled.4. Cleaning Solutions and Apparatus4.1 All solutions should be subject to chemical control,including determinations of the free acid and iron contents ofthe pickling solutions and acid dips, and such tests of thecleaning solutions as recommen

9、ded by the manufacturer.4.2 Based on tests and experience, all solutions should bediscarded before they have lost their effectiveness.4.3 To conserve cleaning and pickling solutions and toensure continuous operation when heavy production is in-volved, doubling of facilities in the same line of opera

10、tion maybe desirable. This arrangement will result in a high degree ofcontamination of the first of two solutions of the same kindwhile the second ones will be sufficiently clean to continue touse. It will also reduce the degree of contamination ofsubsequent solutions, for example, by oil and grease

11、.4.4 As an alternative to the procedure described in 4.3, thecleaner and pickle tanks may be provided with a large damoverflow and a pump having its intake placed about half-waydown the overflow dam between the accumulated grease andoil on top and the settled-out solid dirt at the bottom, andhaving

12、its outlet placed near the bottom of the tank at the endopposite to the dam overflow.4.5 Separate tank electrodes, removable from the tank forinspection and cleaning, should be used. Contact hooks for theelectrodes should be of the inverted V-type for round tank barsand should be of sufficient size

13、to carry the required current.4.6 Rinse tanks should be arranged with a dam overflow,and any water inlet other than a spray should be placed so asto ensure thorough circulation of the water and a large workingsurface free from grease accumulation. An adequate flow ofwater is essential.1This practice

14、 is under the jurisdiction of ASTM Committee B08 on Metallicand Inorganic Coatings and is the direct responsibility of Subcommittee B08.02 onPre Treatment.Current edition approved April 1, 2004. Published May 2004. Originallyapproved in 1943. Last previous edition approved in 1997 as B 183 79 (1997)

15、.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box

16、 C700, West Conshohocken, PA 19428-2959, United States.4.7 Heating coils should be placed on the work-piece side ofthe tank in order to assure a working surface free from greaseaccumulation.5. Procedure for Racked Parts5.1 The cycle described in 5.2 to 5.6 should be used for thepreparation of racked

17、 parts subsequently electroplated in stilltanks, agitated tanks, semi- and full-automatic equipment,except in those cases described in Section 6.5.2 PrecleaningIn general, it is necessary to removefabricating lubricants, buffing compounds, and other soils byprecleaning. This precleaning may be accom

18、plished withalkaline soak cleaners, cleaners designed to remove buffingcompounds (including the use of ultrasonic cleaners), alkalinespray cleaners, and the use of chlorinated solvents such astrichloroethylene and perchloroethylene in vapor-type degreas-ing equipment, or by use of cold chlorinated s

19、olvents if vaporequipment is not available. Precleaning normally should beaccomplished as soon as possible after fabrication becausemany stamping lubricants and buffing compounds becomemuch more difficult to remove if allowed to age on the steelsurface and can chemically attack the substrate causing

20、 etch-ing.5.3 ElectrocleaningThe part to be cleaned should beanodically (reverse) electrocleaned in a solution of a suitablycompounded, free-rinsing, high-conductivity steel electro-cleaner, at a concentration of about 45 to 90 g/L. The currentdensity should preferably be between 5 and 6 A/dm2and th

21、etank voltage about 6 V. The temperature should be between 60and 90C. The time of cleaning following an effective pre-cleaning operation is usually between 1 and 4 min. If propri-etary cleaners are used, the recommendations of the manufac-turer should be followed.5.4 Water RinseImmerse the part to b

22、e cleaned in clean,overflowing water for a minimum of 15 s. If possible, airagitation of the water rinse should be provided. If the water isvery cold, below 10C, slight warming is beneficial. A freshwater spray on the part as it enters and leaves the rinse tankhelps ensure complete rinsing.5.5 Acid

23、PicklingPickle the part in a solution of 150 to500 mL of concentrated, 31 mass %, hydrochloric acid (density1.16 g/mL) diluted to 1 L, 100 mL of concentrated, 93 mass %,sulfuric acid (density 1.83 g/L) diluted to 1 L, or a solution ofproprietary acid salts at room temperature, for a sufficientlength

24、 of time to remove all oxides, rust, or scale. (WarningThe acid should be added to the approximate amount of waterrequired and then after thorough mixing, diluted to exactvolume.)5.6 Alkaline DescalingIn place of acid pickling (5.5) it issometimes found that alkaline descaling may be more practi-cal

25、. Such solutions are operated at about 40C and averagecurrent density of 2 to 5 A/dm2. A typical bath compositionmay be as follows:Sodium hydroxideSodium cyanideChelating agent180g/L120 g/L(EDTA-NTA gluconates) 80 g/LWhen using this method it must be followed by a water rinse(5.4), an acid dip (5.5)

26、, and water rinse (5.4).5.7 Water RinseRinse the part again, as described in 5.4but in a separate tank.6. Variations in Procedure for Racked Parts6.1 Consideration should be given to separate precleaningbetween manufacturing operations; for example, between gear-cutting and deburring operations, and

27、 between drawing orstamping and buffing operations.6.2 Vapor phase degreasing with chlorinated solvents is anexcellent way to remove mineral oil form recesses such asoverlapping joints that cannot be cleaned by any other method.6.3 Plants with limited facilities sometimes omit preclean-ing especiall

28、y with work that is not too heavily soiled. This ispermissible; however, electrocleaning time may have to beincreased and it is almost always necessary to change electro-cleaners more frequently. Likewise, close control is necessaryto ensure proper electrocleaner concentration at all times.6.4 While

29、 pickling in strong hydrochloric acid or acid saltsin accordance with 5.5 is suitable for most oxide conditions,including heavy annealing scale, welding marks, or wheelburns, it may sometimes be preferable to use hot sulfuric acid(about 100 mL of concentrated, 93 mass %, sulfuric acid(density 1.83 g

30、/mL) diluted to 1 L) containing a suitableinhibitor to protect the steel from over pickling (see Warningin 5.5). The acid temperature may vary between 50 and 70C.When inhibitors are used, a second alkaline cleaning operation,preferably electrocleaning, should follow pickling to removeany adsorbed in

31、hibitor.6.5 Heavy scale may be removed more rapidly by makingthe part to be pickled either anodic or cathodic in a 50 to 100mL of concentrated, 93 mass %, sulfuric acid (density 1.83g/mL) diluted to 1 L or proprietary acid salt solution at atemperature of 50 to 65C and an average current density ofa

32、bout 4 A/dm2(see Warning in 5.5). Anodic pickling avoidshydrogen embrittlement. Cathodic pickling provides a brightersurface provided the acid is not contaminated with heavymetals such as copper, tin or lead.6.6 In addition to acid pickling, scale may be removed byshot-blasting, tumbling, or sandbla

33、sting. These methods avoidhydrogen embrittlement but may work-harden the surface.6.7 When there is a lapse of time between the final rinsingoperation (5.6) of the preparatory cleaning process and elec-troplating, arrangements should be made for temporary storageof parts. Those which are to be electr

34、oplated in a cyanidesolution may be stored in a solution of 15 to 30 g/L of sodiumcyanide and an equal amount of sodium hydroxide at roomtemperature. Those which are to be electroplated in an alkalinesolution such as alkaline tin, should be stored in a solutioncontaining 8 g/L of sodium hydroxide at

35、 room temperature.Storage time for parts to be nickel electroplated should beminimized but, if necessary, they may be held in clean coldwater for a very short time (3 or 4 min, depending on waterquality).7. Procedure for Parts in Bulk7.1 The cycle described in 7.2 to 7.5 should be used forcleaning p

36、art to be electroplated in barrels, hand-operated orautomatic, except in those cases described in Section 8.B 183 79 (2004)e127.2 Alkaline CleaningClean the parts by tumbling with orwithout current, in a solution of 30 to 60 g/L of a suitablealkaline cleaner at 60 to 90C. Anodic electrocleaning at a

37、bout2 to 4 A/dm2may supplement tumbling for more effectivecleaning.7.3 Water RinseRinse the parts in clean, overflowingwater. Air agitation of the rinse water is beneficial. If the wateris very cold, rinsing is improved by some warming.7.4 Acid PicklingPickle in a solution of 150 to 500 mL ofconcent

38、rated, 31 mass %, hydrochloric acid (density 1.16g/mL) diluted to 1 L at room temperature. Other suitablepickling solutions are proprietary acid salts and 50 to 150 mLof concentrated, 93 mass %, sulfuric acid (density 1.83 g/mL)diluted to 1 L (see Warning in 5.5).7.5 Water RinseRinse the parts again

39、 as described in 7.3,using a separate tank.8. Variations in Procedure for Bulk Parts8.1 Two water rinses after both cleaning and acid picklingare beneficial in many barrel electroplating operations. Thisserves to ensure more complete rinsing and thus preventcarry-over of cleaners or acids into subse

40、quent tanks.8.2 Heavily scaled parts such as heat-treated nuts and boltsmay require pickling in strong inhibited sulfuric acid (see 6.4).Tumble-pickling is preferred to immersion-pickling in bulkbecause the tumbling action increases the rate of scale andoxide removal.8.3 StorageIf parts must be stor

41、ed after cleaning andpickling prior to electroplating, the procedure described in 6.7should be followed.NOTE 2Additional information on procedures for cleaning of low-carbon steel prior to electroplating may be found in Practice B 322.ASTM International takes no position respecting the validity of a

42、ny patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to re

43、vision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. You

44、r comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copy

45、righted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).B 183 79 (2004)e13