DIN EN 16738-2016 Emission safety of combustible air fresheners - Test methods German version EN 16738 2015《可燃空气清新剂的散发安全性 试验方法 德文版本EN 16738-2015》.pdf

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1、April 2016 English price group 11No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 13.040.20!%Q1“2469714www.din.deDIN

2、 EN 16738Emission safety of combustible air fresheners Test methods;English version EN 16738:2015,English translation of DIN EN 16738:2016-04Emissionssicherheit brennbarer Lufterfrischer Testverfahren;Englische Fassung EN 16738:2015,Englische bersetzung von DIN EN 16738:2016-04Scurit des missions de

3、s dsodorisants combustion Mthodes dessais;Version anglaise EN 16738:2015,Traduction anglaise de DIN EN 16738:2016-04SupersedesDIN EN 16738:2016-02www.beuth.deDTranslation by DIN-Sprachendienst.In case of doubt, the German-language original shall be considered authoritative.Document comprises 17 page

4、s 04.16 DIN EN 16738:2016-04 2 A comma is used as the decimal marker. National foreword International technical rules pertaining to indoor air This document (EN 16738:2015) has been prepared by Technical Committee CEN/TC 421 “Project Committee - Emission safety of combustible air fresheners” (Secret

5、ariat: UNI, Italy). The requirements for emission test chambers and their operation specified here correlate closely with those given in DIN EN ISO 16000-9. National technical rules pertaining to indoor air General conditions and other aspects to be taken into consideration when planning indoor air

6、measurements are described for individual substances and substance groups in the VDI 4300 series. Many of these served as the sole basis for parts of the DIN ISO 16000 series (e.g. DIN EN ISO 16000-1, DIN EN ISO 16000-2 and DIN EN ISO 16000-5). The specific procedures (sampling, analysis) are descri

7、bed in the VDI 4301 series for individual substances and substance groups. Methods which can be used for both indoor and ambient air measurements are described in further VDI Guidelines. Thus, the following technical rules for indoor air measurements are available: DIN ISO 16000: International Stand

8、ards that have been adopted at national level, VDI 4300: Guidelines that have been prepared at national level. Amendments Compared with DIN EN 16738:2016-02, the following correction has been made: a) in the National foreword, the second sentence has been deleted. Previous editions DIN EN 16738: 201

9、6-02 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 16738 November 2015 ICS 13.040.20 English Version Emission safety of combustible air fresheners - Test methods Scurit des missions des dsodorisants combustion - Mthodes dessais Emissionssicherheit brennbarer Lufterfrischer - Testverfahren Thi

10、s European Standard was approved by CEN on 17 October 2015. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical refere

11、nces concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN

12、member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,

13、 France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCH

14、ES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 16738:2015 EEN 16738:2015 (E) 2 Contents Page European foreword . 3 1 Scope 4 2 Normative r

15、eferences 4 3 Terms and definitions . 5 4 Test methods 6 4.1 Principles . 6 4.2 Apparatus . 7 4.3 General test conditions . 7 4.3.1 General 7 4.3.2 Test chamber volume 7 4.3.3 Number of test specimens at the same time in the test chamber 7 4.3.4 Positioning of test specimens in the test chamber 8 4.

16、3.5 Air supply quality and background concentration . 9 4.3.6 Test specimen preparation and ignition 9 4.3.7 Temperature inside the test chamber during the test . 10 4.3.8 Relative air humidity inside the test chamber during the test 10 4.3.9 Oxygen concentration inside the test chamber during the t

17、est 10 4.3.10 Control of the burning process 10 4.3.11 Burn rates . 11 4.3.12 Sampling and analysis of VOC (benzene, naphthalene) . 11 4.3.13 Sampling and analysis of formaldehyde 11 4.3.14 Sampling and analysis of NO2(nitrogen dioxide) . 12 4.3.15 Sampling and analysis of SO2(sulfur dioxide) . 12 4

18、.3.16 Sampling analysis of CO . 12 4.4 Procedures of testing 12 4.5 Calculation of results 12 5 Test report 13 Annex A (informative) Description of sorbent types 14 Bibliography . 15 DIN EN 16738:2016-04EN 16738:2015 (E) 3 European foreword This document (EN 16738:2015) has been prepared by Technica

19、l Committee CEN/TC 421 “Project Committee - Emission safety of combustible air fresheners”, the secretariat of which is held by UNI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2016, and c

20、onflicting national standards shall be withdrawn at the latest by May 2016. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According

21、to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Gree

22、ce, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 16738:2016-04EN 16738:2015 (E) 4 1 Scope This European standard specifies a test method fo

23、r the determination of emissions resulting from the use of combustible air fresheners into indoor air by means of chamber operation according to EN ISO 16000-9. This standard defines specific testing conditions for the measurement of the emissions from combustible air fresheners which minimize the e

24、ffect of the testing on the combustion process. This standard provides a measurement method for the determination of the following non-exhaustive list of target substances emitted directly from the burning process: VOC; Benzene; Naphthalene; Formaldehyde. The measurement method can allow the determi

25、nation of other substances. This standard provides additional information on the optional measurement of the following substances: SO2; NOx; CO. This standard is not suitable for the quantitative determination of particulate matter. This standard does not apply to non-combustible air fresheners and

26、loose incenses. Any scented candle with burning time shorter than 2,5 h is outside the scope of the standard. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edi

27、tion cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 717-1, Wood-based panels - Determination of formaldehyde release - Part 1: Formaldehyde emission by the chamber method EN 14211, Ambient air - Standard method for the meas

28、urement of the concentration of nitrogen dioxide and nitrogen monoxide by chemiluminescence EN 14212, Ambient air - Standard method for the measurement of the concentration of sulphur dioxide by ultraviolet fluorescence EN 14626, Ambient air - Standard method for the measurement of the concentration

29、 of carbon monoxide by non-dispersive infrared spectroscopy EN 14789, Stationary source emissions - Determination of volume concentration of oxygen (O2) - Reference method - Paramagnetism DIN EN 16738:2016-04EN 16738:2015 (E) 5 EN 14792, Stationary source emissions - Determination of mass concentrat

30、ion of nitrogen oxides (NOx) - Reference method: Chemiluminescence EN 15058, Stationary source emissions - Determination of the mass concentration of carbon monoxide (CO) - Reference method: Non-dispersive infrared spectrometry EN 15426, Candles - Specification for sooting behaviour EN ISO 16000-9,

31、Indoor air - Part 9: Determination of the emission of volatile organic compounds from building products and furnishing - Emission test chamber method (ISO 16000-9) EN ISO 16017-1, Indoor, ambient and workplace air - Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorpti

32、on/capillary gas chromatography - Part 1: Pumped sampling (ISO 16017-1) ISO 16000-3, Indoor air Part 3: Determination of formaldehyde and other carbonyl compounds in indoor air and test chamber air Active sampling method ISO 16000-6, Indoor air Part 6: Determination of volatile organic compounds in

33、indoor and test chamber air by active sampling on Tenax TA sorbent, thermal desorption and gas chromatography using MS or MS-FID 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 combustible air freshener product constituted by a fragranced com

34、bustible material which by action of combustion releases in the air smelling substances which it contains (e.g.: scented candle, incense, catalytic lamp, etc.) 3.2 candle one or more combustible wicks supported by a material that constitutes a fuel, which is solid, semisolid or quasi-rigid at room t

35、emperature (20 C to 27 C), the combined function of which is to sustain a light-producing flame Note 1 to entry: It can also contain additives, which are used for colour, odour, stability, or to modify the burning characteristics; including candles with decoration attached to or contained within the

36、m. 3.2.1 scented candle candle in the fuel of which a fragrance intended to be released is added 3.3 indoor air air within an enclosed space, e.g. dwelling or public building 3.4 scented oil lamp (for indoor use) container in which scented oil is burned at the wick DIN EN 16738:2016-04EN 16738:2015

37、(E) 6 3.5 incense dried plants (herbs or wood) which are pulverized and mixed with resins Note 1 to entry: The sticks in incense sticks may be of sandalwood, bamboo or similar material that has the ability to burn together with the wrapped plant ingredients. Some incense mixtures are composed of dri

38、ed and finely chopped herbs, woods and roots, others from resins and balsams as small pellets or granules. Incense may be mixtures but may also consist of one single type of incense based on single plants or plant parts. Besides, natural or synthetic essential oils can be added. Four common types of

39、 incense exist: loose incense (granulate or powder), cones, incense sticks with and without solid stick. 3.6 catalytic lamp system based on the catalytic combustion of a combustible liquid by using a catalytic burner composed of porous material which is made of synthetic or mineral materials Note 1

40、to entry: The product requires also a wick that feeds the burner from the liquid container by capillarity, a cap designed to stop operation of the catalytic lamp and openwork mounting for protection and ventilation. The catalytic lamp diffuses perfume and combustibles in the air. It perfumes and des

41、troys smells, at the same time. 3.6.1 catalytic burner burner composed of a porous material made from synthetic or mineral material and a specific catalyst in the catalytic oxidation of solvent which favours the production of carbon dioxide and water 3.7 unit specific emission rate SERUproduct speci

42、fic rate describing the mass of a volatile organic compound emitted per unit (U) of combustible air freshener per unit of time at a given time from the start of the test 3.8 burn rate BR mass of material burned per unit of time under test conditions 3.9 background of the test chamber emission level

43、of the test chamber operated with all the equipment except the specimen 3.10 test specimen sample intended for emission testing in an emission test chamber 4 Test methods 4.1 Principles The principle of the test is to determine the unit specific emission rate (SERu) of emissions resulting from the u

44、se of combustible air fresheners. The test is performed under controlled conditions in an emission test chamber according to EN ISO 16000-9. The air in the emission test chamber is fully mixed and measurements of a substance concentration in the air at the test chamber outlet are representative of t

45、he emission test chamber concentrations for that substance. DIN EN 16738:2016-04EN 16738:2015 (E) 7 Unit specific emission rates, SERU, at a given time, t, are calculated from the emission test chamber air concentrations, C, the air change rate, n, and number of test specimens at the same time in th

46、e test chamber, N. With knowledge of the concentration in the outlet air, the air flow through the emission test chamber and the number of the test specimens, the unit specific emission rates of emissions from the product under test can be determined. 4.2 Apparatus Dynamic environmental emission tes

47、t chamber according to EN ISO 16000-9, and a suitable number of wire mesh cylinders type 2 according to EN 15426. 4.3 General test conditions 4.3.1 General Combustible air fresheners are ignited and burned in the test chamber using the parameters specified in Table 1 until a state of equilibration i

48、s reached. Dynamic emission test chamber according to EN ISO 16000-9 using inlet air at 23 C and 50 % relative humidity with 2 air changes per hour. If the burn rates data outside the chamber are not available the data can be provided by a burning test run outside the test chamber and for candles it

49、 will be according to EN 15426 for the minimum testing time in the test chamber. The test protocol and test conditions of the chamber experiment are defined in such a way that standardized (well controlled) burning processes inside the chamber are guaranteed. Parameters to be controlled are: air mixing inside the chamber; avoidance of disturbance of the flame, burning in draught free conditions and no flickering; composition of the stand on which the can