KS M 2800-1-2007 Determination of aromatic hydrocarbon types in oil spill dispersant-High performance liquid chromatography method with refractive index detection《油溢出分散芳香族烃测定方法 高性能.pdf

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1、 KS M 28001 KSKSKSKS SKSKSKS KSKSKS SKSKS KSKS SKS KS RI KS M 28001 ：2007 (2012 ) 2007 11 30 http:/www.kats.go.krKS M 28001：2007 : ( ) ( ) () () () ( ) : (http:/www.standard.go.kr) ： ：2002 12 10 ：2007 11 30 : 2012 12 18 ： 20120723 ： ( 02-509-7270) (http:/www.kats.go.kr). 10 5 , . KS M 28001：2007 (20

2、12 ) RI Determination of aromatic hydrocarbon types in oil spill dispersant High performance liquid chromatography method with refractive index detection 1 150400 , , . . 4 40% , 020% , 06 % 4 65% . , . . , . KS M IP 391, Petroleum productDetermination of aromatic hydrocarbon types in middle distill

3、atesHigh performance liquid chromatography method with refractive index detection . 2 . 2.1 MAHs 2.2 MAHs , DAHs 2.3 DAHs MAHs , PAHs KS M 28001：2007 2.4 PAHs DAHs 2.5 MAHs, DAHs PAHs . . a) ( ), b) MAHs , , ( ), , , c) DAHs , , , , , d) PAHs , , , , , 3 . . (HPLC) . , . . MAH, DAH, PAH . DAHs , PAH

4、s . RI . . MAHs, DAHs PAHs . MAHs, DAHs PAHs . 4 4.1 99 % . 4.2 n (HPLC) 4.3 o(1,2) 98 % 2 KS M 28001：2007 4.4 1 97 % 4.5 98 % 4.6 95 % 4.7 9 95 % 4.8 35 % 4.9 95 % 4.10 n (HPLC) 1 . . 2 . 90 % . . 5 5.1 6. 1 % 0.5 % 0.51.5 mL/ min . 5.2 1 % 10 L 1 . ( ) 5.2 . . 6 . 2 10 L ( 3 20 L ) ( 2), RI (6.6 7

5、.4) (6.7) . 5.3 , 0.45 m . . 3 KS M 28001：2007 5.4 6.7 3 m, 5 m 10 m ( / ) 150300 mm 4 5 mm . (30 mm4.6 mm ) . 5.5 2040 (1 ) , ( ) . RI . . 5.6 (210 4 ) kPa , ( ) . 5.7 RI a) 1.31.6 RI . b) 6.6 . c) . d) . RI , . ( ), . (make-up flow) , . 10 1 . 5.8 , 1 Hz RI . . . 5.9 100 mL 10 mL B 4 KS M 28001：20

6、07 5.10 0.0 001 g 5.11 500 mL B 5.12 100 mL B 6 6.1 10 mL , 500 mL , 35 % 10 mL . 100 mL, 100 mL . 3 10 () . 100 mL 2 . . , . HPLC RI . HPLC (5.1), (5.2), (5.4), (5.6), RI (5.7) (5.8) . (5.5 ) . ( 1). . . . 6.2 1 mL/min , RI (5.7) . ( RI ) . 6.7 ( 0.81.2 mL/min ). 6.3 (1.00.1) g (4.1), (0.50.05) g o

7、(4.3), (0.050.005) g (4.6) (0.05 0.005) g 9 (4.7) 100 mL , (4.2) (SCS) . 9 (4.2) ( ) o . SCS 1 . 5 KS M 28001：2007 RI RI 1 6.4 SCS(6.3) 10 L . 0.5 % . RI / . 1 . 6.5 SCS ( 2). 6.6 9 . 6.7 o 5.0 . 6.8 9 . 9.2 . (7.) (8.) . 6.644 mAU o 175 5.30 150 125 100 10.737 9.959 9 75 50 25 0 15 min 10 5 2 (SCS)

8、 6 KS M 28001：2007 7 RI . 7.1 1 (A, B, C, D) 0.000 1 g 100 mL (4.2) . (100 mL ) . 6 . 1 g/100 mL o g/100mL 1 g/100 mL g/100 mL A B C D 5.0 2.0 0.5 0.1 4.0 1.0 0.25 0.05 4.0 1.0 0.25 0.02 0.4 0.2 0.05 0.01 7.2 (6.4), A 10 L . PAH (6.8) . ( 3) . 7.3 B, C D 7.2 . D (0.02 g/100 mL) D 7.2 . 7.4 (o , 1 )

9、(g/mL) . 0.01 g/100mL 0.999 . . 7 KS M 28001：2007 8.277 mAU 1 1750 1500 6.910 1250 o 1000 5.458 750 500 11.510 250 0 0 2.5 5 7.5 10 12.5 15 min 3 A 1.20000 1.00000 0.80000 0.60000 0.40000 0.20000 0.0000 0.0000 7.553 NA 8.408 1R 9.462 2R 27.903 3R 20.0000 30.0000 40.0000 10.0000 4 8 8.1 10 mL 0.91.1

10、g 0.001 g , (4.2) . . 10 . (2 g/10mL) (0.5 g/10mL) . 8.2 (7.) (6.4), (8.1) 10 L . 8 KS M 28001：2007 PAHs , (6.8) . , ( .) . 8.3 MAHs, DAHs, PAHs . 8.4 ( 5 A) ( 5 D) . 8.5 MAHs ( 5 C) (8.4) . 8.6 MAHs DAHs ( 5 C) . 8.7 PAHs ( 5 E) PAHs . . 8.8 B C ( 5) MAHs . 8.9 C D ( 5) DAHs . 8.10 E F ( 5) PAHs .

11、, . 7.553 NA 5 9 9.1 o R . 1.20000 1.00000 0.80000 0.60000 0.40000 0.20000 0.00000 0.0000 8.408 1R 27.903 3R 9.462 2R A F E D C B 20.0000 10.0000 30.0000 40.0000 9 KS M 28001：2007 ) ( 699 . 1 ) ( 2 2 1 1 2 y y t t R t 1 ： () t 2 ：o () y 1 ： () y 2 ：o () 9.2 B . Bt A 0.4(t B t A ) t A ： () t B ：9 ()

12、9.3 MAHs, DAHs, PAHs C % . M V I AS C ) ( A ： MAH DAH PAH S ：MAH DAH PAH (g/100 mL) I ：MAH DAH PAH M ： (g)(8.1) V ： (mL)(8.1) 9.4 (MAHs, DAHs PAHs) % . 10 MAH, DAH, PAH 0.1% . 11 11.1 2 20 1 . 10 KS M 28001：2007 11 11.2 2 20 1 . 2 % 440 020 06 465 0.026(X14.7) 0.10(X2.6) 0.12(X0.6) 0.036(X1.5) 0.063

13、(X17.3) 0.32(X1.8) 0.64(X0.3) 0.116(X6.3) X 12 . a) b) (, KS M 28001) c) (10. ) d) e) RI 153787 1 145 3(16) (02)26240114 (02)26240148 http:/ KS M 28001 ：2007KSKSKS SKSKS KSKS SKS KS SKS KSKS SKSKS KSKSKS Determination of aromatic hydrocarbon types in oil spill dispersant High performance liquid chromatography method with refractive index detection ICS 71.100.00 Korean Agency for Technology and Standards http:/www.kats.go.kr