EN ISO 17895-2005 en Paints and varnishes - Determination of the volatile organic compound content of low-VOC emulsion paints (in-can VOC)《色漆和清漆 低VOC乳化涂料的挥发性有机化合物含量测定(罐内VOC) ISO 17.pdf

《EN ISO 17895-2005 en Paints and varnishes - Determination of the volatile organic compound content of low-VOC emulsion paints (in-can VOC)《色漆和清漆 低VOC乳化涂料的挥发性有机化合物含量测定(罐内VOC) ISO 17.pdf》由会员分享，可在线阅读，更多相关《EN ISO 17895-2005 en Paints and varnishes - Determination of the volatile organic compound content of low-VOC emulsion paints (in-can VOC)《色漆和清漆 低VOC乳化涂料的挥发性有机化合物含量测定(罐内VOC) ISO 17.pdf（22页珍藏版）》请在麦多课文档分享上搜索。

1、BRITISH STANDARD BS EN ISO 17895:2005 Paints and varnishes Determination of the volatile organic compound content of low-VOC emulsion paints (in-can VOC) The European Standard EN ISO 17895:2005 has the status of a British Standard ICS 87.040 BS EN ISO 17895:2005 This British Standard was published u

2、nder the authority of the Standards Policy and Strategy Committee on 21 April 2005 BSI 21 April 2005 ISBN 0 580 45889 X National foreword This British Standard is the official English language version of EN ISO 17895:2005. It is identical with ISO 17895:2005. The UK participation in its preparation

3、was entrusted to Technical Committee STI/10, Test methods for paints, which has the responsibility to: A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references The British Standards which implement international or European publications refe

4、rred to in this document may be found in the BSI Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Search” facility of the BSI Electronic Catalogue or of British Standards Online. This publication does not purport to include all the necessary provi

5、sions of a contract. Users are responsible for its correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation,

6、 or proposals for change, and keep the UK interests informed; monitor related international and European developments and promulgate them in the UK. Summary of pages This document comprises a front cover, an inside front cover, the EN ISO title page, the EN ISO foreword page, the ISO title page, pag

7、es ii to v, a blank page, pages 1 to 11 and a back cover. The BSI copyright notice displayed in this document indicates when the document was last issued. Amendments issued since publication Amd. No. Date CommentsEUROPEANSTANDARD NORMEEUROPENNE EUROPISCHENORM ENISO17895 March2005 ICS87.040 Englishve

8、rsion PaintsandvarnishesDeterminationofthevolatileorganic compoundcontentoflowVOCemulsionpaints(incanVOC) (ISO17895:2005) PeinturesetvernisDterminationducontenuen compossorganiquesvolatilesdansdespeinturesen mulsionfaibleteneurenCOV(COVenrcipient)(ISO 17895:2005) BeschichtungsstoffeBestimmungdesGeha

9、ltesan flchtigenorganischenVerbindungenin wasserverdnnbarenDispersionsfarben(IncanVOC)(ISO 17895:2005) ThisEuropeanStandardwasapprovedbyCENon3March2005. CENmembersareboundtocomplywiththeCEN/CENELECInternalRegulationswhichstipulatetheconditionsforgivingthisEurope an Standardthestatusofanationalstanda

10、rdwithoutanyalteration.Uptodatelistsandbibliographicalreferencesconcernings uchnational standardsmaybeobtainedonapplicationtotheCentralSecretariatortoanyCENmember. ThisEuropeanStandardexistsinthreeofficialversions(English,French,German).Aversioninanyotherlanguagemadebytra nslation undertheresponsibi

11、lityofaCENmemberintoitsownlanguageandnotifiedtotheCentralSecretariathasthesamestatusast heofficial versions. CENmembersarethenationalstandardsbodiesofAustria,Belgium,Cyprus,CzechRepublic,Denmark,Estonia,Finland,France, Germany,Greece,Hungary,Iceland,Ireland,Italy,Latvia,Lithuania,Luxembourg,Malta,Ne

12、therlands,Norway,Poland,Portugal, Slovakia, Slovenia,Spain,Sweden,SwitzerlandandUnitedKingdom. EUROPEANCOMMITTEEFORSTANDARDIZATION COMITEUROPENDENORMALISATION EUROPISCHESKOMITEEFRNORMUNG ManagementCentre:ruedeStassart,36B1050Brussels 2005CEN Allrightsofexploitationinanyformandbyanymeansreserved worl

13、dwideforCENnationalMembers. Ref.No.ENISO17895:2005:E I NESO 71:5982005 (E) 2 Foreword This document (EN ISO 17895:2005) has been prepared by Technical Committee ISO/TC 35 “Paints and varnishes“ in collaboration with Technical Committee CEN/TC 139 “Paints and varnishes“, the secretariat of which is h

14、eld by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by September 2005, and conflicting national standards shall be withdrawn at the latest by September 2005. According to the CEN/CENELEC Inte

15、rnal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Nethe

16、rlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Endorsement notice The text of ISO 17895:2005 has been approved by CEN as EN ISO 17895:2005 without any modifications. ENISO17895:2005 Reference number ISO 17895:2005(E) OSI 5002INTERNATIONAL STANDAR

17、D ISO 17895 First edition 2005-03-15 Paints and varnishes Determination of the volatile organic compound content of low-VOC emulsion paints (in-can VOC) Peintures et vernis Dtermination du contenu en composs organiques volatiles dans des peintures en mulsion faible teneur en COV (COV en rcipient) EN

18、ISO17895:2005IS:59871 O5002(E) DPlcsid Fremia ihTs PDF file may ctnoian emdebt dedyfepcaes. In ccaocnadrw eith Aebods licensilop gnic,y this file mairp eb ynted iv roweb detu slahl ton ide ebtlnu deess the typefaces whice era hml era deddebicsnede to i dnanstlaled t noeh computfrep reormign tide eht

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21、the serddaig sleb nevwo. ISO 5002 All irthgs erse.devr lnUeto sswrehise specified, on trap fo this lbupictaion maeb y cudorperro de tuilizi den yna form ro na ybm ynae,s lecetrinoc ro mecinahcal, inclidung tohpcoiypodna gn micrfoilm, wittuoh repmissii non writign from ietI rehSa Ot tsserdda eh ebolw

22、 or ISOs memreb i ydobn the cnuotrfo y ttseuqer ehe.r ISO cirypothg fofice saCe tsopale 65 eneG 1121-HC 02 av leT. 4 + 10 947 22 1 11 xaF0 947 22 14 + 9 74 E-mail coirypthgiso.o gr We bwww.is.o gro Pulbisdehi n Switlrez dnaii ISO 5002 Allr ithgsr esedevrENISO17895:2005IS:59871 O5002(E) I SO 5002 All

23、 irthgs ersedevr iiiContents Page Foreword iv Introduction v 1 Scope 1 2 Normative references . 1 3 Terms and definitions. 1 4 Principle . 2 5 Apparatus. 3 6 Reagents and materials 3 7 Sampling 4 8 Procedure. 4 9 Evaluation 7 10 Precision 8 11 Test report 9 Annex A (informative) Gas chromatogram of

24、the reference compound mixture and tetradecane 10 Bibliography . 11 ENISO17895:2005IS:59871 O5002(E) iv I SO 5002 All irthgs ersedevrForeword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing Int

25、ernational Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison w

26、ith ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of techni

27、cal committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn

28、to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 17895 was prepared by Technical Committee ISO/TC 35, Paints and varnishes. ENISO17895:2005IS:59871 O5002(E) I SO 500

29、2 All irthgs ersedevr vIntroduction The requirements imposed today by authorities, for health and environmental reasons, include the assessment of the content of residual monomers and organic saturated volatiles, sometimes down to minute traces. This International Standard is one of a series of stan

30、dards dealing with the VOC content of paints, varnishes and related products: ISO 11890-1 (see the Bibliography) specifies a method for determining VOC contents greater than 15 % (by mass), ISO 11890-2 is applicable to VOC contents between 0,1 % and 15 % (by mass). This International Standard descri

31、bes a method for determining VOC contents between 0,01 % and 0,1 % (by mass). In contrast to ISO 11890-1 and ISO 11890-2, this standard is applicable to volatile organic compounds with boiling points up to 250 C. ENISO17895:2005blank 5002:59871OSINEINTENRATIONAL TSANDADR IS:59871 O5002(E)I SO 5002 A

32、ll irthgs ersedevr 1Paints and varnishes Determination of the volatile organic compound content of low-VOC emulsion paints (in-can VOC) 1 Scope This International Standard specifies a gas-chromatographic method of quantitatively determining the volatile organic compound (VOC) content (i.e. the conte

33、nt of organic compounds with boiling points up to 250 C) under standard conditions (101,325 kPa) of low VOC content emulsion paints (in-can VOC). The method is applicable to VOC contents between 0,01 % and 0,1 % (by mass). The main purpose of the method is to qualify low-VOC emulsion paints, not rou

34、tine quality control. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO

35、2811-1, Paints and varnishes Determination of density Part 1: Pyknometer method ISO 2811-2, Paints and varnishes Determination of density Part 2: Immersed body (plummet) method ISO 2811-3, Paints and varnishes Determination of density Part 3: Oscillation method ISO 2811-4, Paints and varnishes Deter

36、mination of density Part 4: Pressure cup method ISO 3696, Water for analytical laboratory use Specification and test methods ISO 15528, Paints, varnishes and raw materials for paints and varnishes Sampling 3 Terms and definitions For the purposes of this document, the following terms and definitions

37、 apply. 3.1 volatile organic compound VOC any organic liquid and/or solid that evaporates spontaneously at the prevailing temperature and pressure of the atmosphere with which it is in contact NOTE 1 As to current usage of the term VOC in the field of coating materials, see volatile organic compound

38、 content (VOC content). NOTE 2 Under U.S. government legislation, the term VOC is restricted solely to those compounds that are photochemically active in the atmosphere (see ASTM D 3960). Any other compound is then defined as being an exempt compound. ISO 4618 ENISO17895:2005IS:59871 O5002(E) 2 I SO

39、 5002 All irthgs ersedevr3.2 volatile organic compound content VOC content mass of the volatile organic compounds present in a coating material, as determined under specified conditions NOTE The properties and the amounts of compounds to be taken into account will depend on the field of application

40、of the coating material. For each field of application, the limiting values and the methods of determination or calculation are stipulated by regulations 1)or by agreement. ISO 4618 3.3 in-can VOC volatile organic compound present in a water-based emulsion paint 3.4 emulsion paint latex paint coatin

41、g material in which the organic binder is an aqueous dispersion ISO 4618 3.5 full evaporation method of transferring the VOCs in a liquid sample from the liquid to the vapour phase NOTE Although a headspace injector with septum-sealable vials is used for introduction of a test portion of the vapour

42、phase into the chromatographic column, the full evaporation method differs substantially from conventional headspace analysis in which equilibrium is established. Since the vial contains very small amounts of sample, virtually all the VOCs enter the vapour phase when heated to a certain temperature3

43、 . 3.6 stock reference compound mixture mixture prepared from pure substances for use in the standard addition method NOTE The concentration of the stock reference compound mixture is determined by the initial masses of the individual components in the sample and their degree of purity. 3.7 multiple

44、 standard addition method method of determining the VOC content in which a known amount of stock reference compound mixture is added to the sample 4 Principle The VOCs in a very small amount of thinned sample are fully evaporated in a headspace injector and then determined by gas-chromatographic ana

45、lysis, as follows: A few microlitres of the sample diluted with buffer solution are heated to 150 C in a septum-sealed vial and, when fully evaporated, some of the vapour phase is transferred to a non-polar capillary column. The peak areas of all the components with retention times less than that of

46、 tetradecane (boiling point 252,6 C) are integrated. Standard additions of a stock reference compound mixture (see 3.6) are employed at four 1) For the purposes of this International Standard, the applicable regulations are given in European Commission decision 96/13/EC dated 1996-01-06 which define

47、s all organic compounds having a boiling point (or initial boiling point) of not more than 250 C at normal pressure (101,325 kPa) as volatile organic compounds (VOCs). ENISO17895:2005IS:59871 O5002(E) I SO 5002 All irthgs ersedevr 3concentration levels to determine the VOC content. The result is bas

48、ed on the average response factor of the reference compound mixture. NOTE Determination of individual components in the sample, or of standards prepared separately from emulsions or emulsion paints which are as free of VOCs as possible, can be used to validate the analytical system. 5 Apparatus Ordinary laboratory apparatus and glassware, together with the following: 5.1 Gas chromatography system, consisting of a headspace injector, preferably with an automati