DIN EN 16192-2012 Characterization of waste - Analysis of eluates German version EN 16192 2011《废物特性描述 洗出液的分析 德文版本EN 16192-2011》.pdf

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1、February 2012 Translation by DIN-Sprachendienst.English price group 15No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).I

2、CS 13.030.99!$yrt“1867981www.din.deDDIN EN 16192Characterization of waste Analysis of eluatesEnglish translation of DIN EN 16192:2012-02Charakterisierung von Abfllen Analyse von EluatenEnglische bersetzung von DIN EN 16192:2012-02Caractrisation des dchets Analyse des luatsTraduction anglaise de DIN

3、EN 16192:2012-02SupersedesDIN EN 12506:2003-09 andDIN EN 13370:2003-09www.beuth.deDocument comprises 36 pagesIn case of doubt, the German-language original shall be considered authoritative.01.12 DIN EN 16192:2012-02 2 A comma is used as the decimal marker. National foreword This standard has been p

4、repared by Technical Committee CEN/TC 292 “Characterization of waste” (Secretariat: NEN, Netherlands). The responsible German body involved in its preparation was the Normenausschuss Wasserwesen (Water Practice Standards Committee), Working Committee NA 119-01-02-02 UA Chemische und physikalische Ve

5、rfahren. The DIN Standards corresponding to the International Standards referred to in this document are as follows: ISO 5725-1 DIN ISO 5725-1 ISO 5725-2 DIN ISO 5725-2 ISO 5725-3 DIN ISO 5725-3 ISO 5725-4 DIN ISO 5725-4 ISO 5725-5 DIN ISO 5725-5 ISO 5725-6 DIN ISO 5725-6 ISO 6439 DIN 38409-16 ISO 6

6、703-2 DIN 38405-13 ISO 8288 DIN 38406-21 ISO 9297 DIN 38405-1 ISO 9965 DIN 38405-23 ISO 10359-1 DIN 38405-4 ISO 11083 DIN 38405-24 Amendments This standard differs from DIN EN 12506:2003-09 and DIN EN 13370:2003-09 as follows: a) normative references have been updated; b) the standard has been edito

7、rially revised; c) additional validation data have been included; d) the analysis has been extended to include the determination of Sb and Se. Previous editions DIN EN 12506: 2003-09 DIN V ENV 12506: 2000-03 DIN EN 13370: 2003-09 DIN V ENV 13370: 2001-10 DIN EN 16192:2012-02 3 National Annex NA (inf

8、ormative) Bibliography DIN 38405-1, German standard methods for the examination of water, waste water and sludge Anions (group D) Determination of chloride ions (D 1) DIN 38405-4, German standard methods for the examination of water, waste water and sludge Anions (group D) Determination of fluoride

9、(D 4) DIN 38405-13, German standard methods for the examination of water, waste water and sludge Anions (group D) Part 13: Determination of cyanides (D 13) DIN 38405-23, German standard methods for the examination of water, waste water and sludge Anions (Group D) Part 23: Determination of selenium b

10、y atomic absorption spectrometry (D 23) DIN 38405-24, German standard methods for the examination of water, waste water and sludge Anions (group D) Photometric determination of chromium(VI) using 1,5-diphenylcarbonohydrazide (D 24) DIN 38406-21, German standard methods for the examination of water,

11、waste water and sludge Cations (group E), determination of nine heavy metals (Ag, Bi, Cd, Co, Cu, Ni, Pb, Tl, Zn) (E21) DIN 38409-16, German standard methods for the examination of water, waste water and sludge General measures of effects and substances (group H) Determination of the phenol index (H

12、 16) DIN ISO 5725-1, Accuracy (trueness and precision) of measurement methods and results Part 1: General principles and definitions DIN ISO 5725-1 Corrigendum 1, Corrigenda to DIN ISO 5725-1:1997-11 DIN ISO 5725-2, Accuracy (trueness and precision) of measurement methods and results Part 2: Basic m

13、ethod for the determination of repeatability and reproducibility of a standard measurement method DIN ISO 5725-3, Accuracy (trueness and precision) of measurement methods and results Part 3: Intermediate measures of the precision of a standard measurement method) DIN ISO 5725-4, Accuracy (trueness a

14、nd precision) of measurement methods and results Part 4: Basic methods for the determination of the trueness of a standard measurement method DIN ISO 5725-5, Accuracy (trueness and precision) of measurement methods and results Part 5: Alternative methods for the determination of the precision of a s

15、tandard measurement method DIN ISO 5725-6, Accuracy (trueness and precision) of measurement methods and results Part 6: Use in practice of accuracy values DIN EN 16192:2012-02 4 This page is intentionally blank EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 16192 November 2011 ICS 13.030.99 Su

16、persedes EN 12506:2003, EN 13370:2003English Version Characterization of waste - Analysis of eluates Caractrisation des dchets - Analyse des luats Charakterisierung von Abfllen - Analyse von Eluaten This European Standard was approved by CEN on 15 October 2011. CEN members are bound to comply with t

17、he CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Manageme

18、nt Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status

19、 as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,

20、Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2011 CEN All rights of exploitation in any form and by any means reser

21、ved worldwide for CEN national Members. Ref. No. EN 16192:2011: EEN 16192:2011 (E) 2 Contents Page Foreword 3Introduction .41 Scope 52 Normative references 53 Terms and definitions .64 Sample pretreatment .75 Blank determination 76 Interference 87 Selection of the suitable test method 88 Expression

22、of results . 119 Test report . 11Annex A (informative) Validation of EN 12506:2003 and EN 13370:2003 . 12A.1 General . 12A.2 Interlaboratory study 12A.3 Selection of laboratories 12A.4 Selection of samples 12A.5 Validation scope . 13A.6 Results and statistics . 16A.7 Conclusion 24Annex B (informativ

23、e) Additional validation data . 25B.1 Round robin test for the determination of Ba, Cd, Cr, Mo, Sb and Se in eluates 25B.1.1 General . 25B.1.2 Round robin samples . 25B.1.3 Results of the round robin test . 25B.1.4 Conclusion from the round robin test 29B.2 Round robin tests in the framework of acce

24、ptability of waste at landfills . 29Bibliography . 31DIN EN 16192:2012-02 EN 16192:2011 (E) 3 Foreword This document (EN 16192:2011) has been prepared by Technical Committee CEN/TC 292 “Characterization of waste”, the secretariat of which is held by NEN. This European Standard shall be given the sta

25、tus of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2012, and conflicting national standards shall be withdrawn at the latest by May 2012. Attention is drawn to the possibility that some of the elements of this document may be the subject of

26、 patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 12506:2003 and EN 13370:2003. Details of significant technical changes between this European Standard and the previous edition are: This European Standard, EN 1

27、6192, is now a single document (instead of two) for the analysis of eluates specifying methods for the determination of the parameters pH, ammonium, AOX, As, Ba, Cd, Cl-, easily liberatable CN-, Co, Cr, Cr(VI), Cu, DOC/TOC, electrical conductivity, F-, Hg, Mo, Ni, NO2-, Pb, phenol index, total S, Sb

28、, Se, SO42-, TDS, V and Zn in aqueous eluates for the characterization of waste. In Clause 7 the parameters, previously described in two documents, are now all integrated in Table 1. In Table 1 for all parameters EN and ISO standards are updated, removed if withdrawn and new relevant standards are a

29、dded, i.e.: addition of the parameters Sb and Se together with the related analytical methods; revision of the standards EN ISO 11885 (ICP-OES) and EN ISO 10304-1 (IC); addition of the ICP-MS method (EN ISO 17294-1:2006 and EN ISO 17294-2:2004); addition of the AAS with graphite furnace technique (E

30、N ISO 15586:2003); addition of the flow analysis techniques for Cl-(EN ISO 15682:2001), Cr(VI) (EN ISO 23913:2009) and SO42-(ISO 22743:2006); addition of the parameter TDS (total dissolved solids) together with the related analytical method; addition of the parameter DOC (dissolved organic carbon) t

31、o the parameter TOC (total organic carbon); revision of the standards EN ISO 11732 (ammonium by flow analyser); replacement of EN 1485 (AOX) by EN ISO 9562:2004; revision and addition of new standards for Hg determination EN 1483 and EN ISO 17852. In Annex B (informative) additional validation data

32、are added obtained from a round robin test for the determination of Ba, Cd, Cr, Mo, Sb and Se in eluates and from round robin tests in the framework of acceptability of waste at landfills, both organized in Belgium. According to the CEN/CENELEC Internal Regulations, the national standards organizati

33、ons of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal

34、, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. DIN EN 16192:2012-02 EN 16192:2011 (E) 4 Introduction This European standard is intended to be used for the characterization of waste as defined in the Council Directive 75/442/EEC on waste, as amended by Council Directive

35、 91/156/EEC of 18th March 1991, and national regulations, whose final destination for disposal is landfill. In the Council Decision of 19 December 2002 establishing criteria and procedures for the acceptance of waste at landfills pursuant to Article 16 of and Annex II to Directive 1999/31/EC, the te

36、st methods are described for determining the acceptability of waste at landfills. In section 3 of the Annex of this Decision the European standards EN 12506 and EN 13370 are included which are replaced by this European Standard. This European Standard deals with the determination of chemical constit

37、uents, electrical conductivity, pH and total dissolved solids (TDS) in eluates which have been obtained by leaching of waste samples for example using EN 12457 “Characterization of waste - Leaching - Compliance test for leaching of granular waste materials and sludges” (Part 1 to Part 4). In princip

38、le, it may be used for the analysis of every kind of eluate as long as the performance characteristics of the applied analytical method fulfill the specific requirements. DIN EN 16192:2012-02 EN 16192:2011 (E) 5 1 Scope This European Standard specifies methods for the determination of the parameters

39、 pH, ammonium, AOX, As, Ba, Cd, Cl-, easily liberatable CN-, Co, Cr, Cr(VI), Cu, DOC/TOC, electrical conductivity, F-, Hg, Mo, Ni, NO2-, Pb, phenol index, total S, Sb, Se, SO42-, TDS, V and Zn in aqueous eluates for the characterization of waste. 2 Normative references The following referenced docum

40、ents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 1483:2007, Water quality Determination of mercury Method using atomic absorp

41、tion spectrometry EN 1484:1997, Water analysis Guidelines for the determination of total organic carbon (TOC) and dissolved organic carbon (DOC) EN 15216:2007, Characterization of waste Determination of total dissolved solids (TDS) in water and eluates EN 26777:1993, Water quality Determination of n

42、itrite Molecular absorption spectrometric method (ISO 6777:1984) EN 27888:1993, Water quality Determination of electrical conductivity (ISO 7888:1985) prEN ISO 5667-3, Water quality Sampling Part 3: Preservation and handling of water samples (ISO/DIS 5667-3:2010) EN ISO 9562:2004, Water quality Dete

43、rmination of adsorbable organically bound halogens (AOX) (ISO 9562:2004) EN ISO 10304-1:2009, Water quality Determination of dissolved anions by liquid chromatography of ions Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate (ISO 10304-1:2007) EN ISO 10304

44、-3:1997, Water quality Determination of dissolved anions by liquid chromatography of ions Part 3: Determination of chromate, iodide, sulfite, thiocyanate and thiosulfate (ISO 10304-3:1997) EN ISO 11732:2005, Water quality Determination of ammonium nitrogen Method by flow analysis (CFA and FIA) and s

45、pectrometric detection (ISO 11732:2005) EN ISO 11885:2009, Water quality Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) (ISO 11885:2007) EN ISO 11969:1996, Water quality Determination of arsenic Atomic absorption spectrometric method (hydride

46、 technique) (ISO 11969:1996) EN ISO 13395:1996, Water quality Determination of nitrite nitrogen and nitrate nitrogen and the sum of both by flow analysis (CFA and FIA) and spectrometric detection (ISO 13395:1996) EN ISO 14402:1999, Water quality Determination of the phenol index by flow analysis (FI

47、A and CFA) (ISO 14402:1999) EN ISO 14403:2002, Water quality Determination of total cyanide and free cyanide by continuous flow analysis (ISO 14403:2002) EN ISO 14911:1999, Water quality Determination of dissolved Li+, Na+, NH4+, K+, Mn2+, Ca2+, Mg2+, Sr2+and Ba2+using ion chromatography Method for

48、water and waste water (ISO 14911:1998) EN ISO 15586:2003, Water quality Determination of trace elements using atomic absorption spectrometry with graphite furnace (ISO 15586:2003) DIN EN 16192:2012-02 EN 16192:2011 (E) 6 EN ISO 15682:2001, Water quality Determination of chloride by flow analysis (CFA and FIA) and photometric and potentiometric detection (ISO 1568