BS ISO 16110-2-2010 Hydrogen generators using fuel processing technologies - Test methods for performance《利用燃料处理技术的氢气发生器 性能用试验方法》.pdf

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1、BS ISO16110-2:2010ICS 27.075; 71.020; 71.100.20NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBRITISH STANDARDHydrogen generatorsusing fuel processingtechnologiesPart 2: Test methods for performanceThis British Standardwas published under theauthority of the StandardsPolicy an

2、d StrategyCommittee on 31 March2010 BSI 2010ISBN 978 0 580 57270 8Amendments/corrigenda issued since publicationDate CommentsBS ISO 16110-2:2010National forewordThis British Standard is the UK implementation of ISO 16110-2:2010.The UK participation in its preparation was entrusted to TechnicalCommit

3、tee PVE/3/8, Gas containers - Hydrogen technologies.A list of organizations represented on this committee can be obtained onrequest to its secretary.This publication does not purport to include all the necessary provisionsof a contract. Users are responsible for its correct application.Compliance wi

4、th a British Standard cannot confer immunityfrom legal obligations.BS ISO 16110-2:2010Reference numberISO 16110-2:2010(E)ISO 2010INTERNATIONAL STANDARD ISO16110-2First edition2010-02-15Hydrogen generators using fuel processing technologies Part 2: Test methods for performance Gnrateurs dhydrogne fai

5、sant appel aux technologies du traitement du carburant Partie 2: Mthodes dessai de rendement BS ISO 16110-2:2010ISO 16110-2:2010(E) PDF disclaimer This PDF file may contain embedded typefaces. In accordance with Adobes licensing policy, this file may be printed or viewed but shall not be edited unle

6、ss the typefaces which are embedded are licensed to and installed on the computer performing the editing. In downloading this file, parties accept therein the responsibility of not infringing Adobes licensing policy. The ISO Central Secretariat accepts no liability in this area. Adobe is a trademark

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8、 the unlikely event that a problem relating to it is found, please inform the Central Secretariat at the address given below. COPYRIGHT PROTECTED DOCUMENT ISO 2010 All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized in any form or by any means,

9、electronic or mechanical, including photocopying and microfilm, without permission in writing from either ISO at the address below or ISOs member body in the country of the requester. ISO copyright office Case postale 56 CH-1211 Geneva 20 Tel. + 41 22 749 01 11 Fax + 41 22 749 09 47 E-mail copyright

10、iso.org Web www.iso.org Published in Switzerland ii ISO 2010 All rights reservedBS ISO 16110-2:2010ISO 16110-2:2010(E) ISO 2010 All rights reserved iiiContents Page Foreword iv Introduction.v 1 Scope1 2 Normative references1 3 Terms, definitions and symbols 2 3.1 Terms and definitions .2 3.2 Symbols

11、3 4 Test conditions 3 4.1 Test boundary3 5 Measurement technique .5 5.1 General .5 5.2 Operational parameters 5 5.3 Environmental aspects .6 5.4 Ambient conditions .8 6 Test plan.8 6.1 General .8 6.2 Test operating modes .8 6.3 Measurement, test frequency and duration10 6.4 Uncertainty analysis11 7

12、Test procedure.11 7.1 Safe operation of the hydrogen generator and test equipment .11 7.2 Execution of the test plan.11 8 Calculations .12 8.1 Electrical power input .12 8.2 Calculation of flow rates.13 8.3 Calculation of fuel, steam and hydrogen energy .15 8.4 Calculation of efficiency .20 9 Test r

13、eports21 9.1 General .21 9.2 Summary report.21 9.3 Detailed report .22 9.4 Full report.22 Annex A (normative) Symbols and abbreviated terms .23 Annex B (informative) Guidance for uncertainty analysis26 Annex C (normative) Calculation of fuel heating value 29 Annex D (informative) Definition of hydro

14、gen generator efficiency33 Annex E (informative) Reference gas .35 Bibliography38 BS ISO 16110-2:2010ISO 16110-2:2010(E) iv ISO 2010 All rights reservedForeword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The wo

15、rk of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governm

16、ental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The

17、main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote.

18、Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 16110-2 was prepared by Technical Committee ISO/TC 197, Hydrogen technologies. ISO 16110 consists

19、 of the following parts, under the general title Hydrogen generators using fuel processing technologies: Part 1: Safety Part 2: Test methods for performance BS ISO 16110-2:2010ISO 16110-2:2010(E) ISO 2010 All rights reserved vIntroduction This part of ISO 16110 describes how to measure and document

20、the performance of stationary hydrogen generators for residential, commercial and industrial applications. The following hydrogen generation types have been considered: hydrogen generators using fuel processing technologies. BS ISO 16110-2:2010BS ISO 16110-2:2010INTERNATIONAL STANDARD ISO 16110-2:20

21、10(E) ISO 2010 All rights reserved 1Hydrogen generators using fuel processing technologies Part 2: Test methods for performance 1 Scope This part of ISO 16110 provides test procedures for determining the performance of packaged, self-contained or factory matched hydrogen generation systems with a ca

22、pacity less than 400 m3/h at 0 C and 101,325 kPa, herein referred to as hydrogen generators, that convert a fuel to a hydrogen-rich stream of composition and conditions suitable for the type of device using the hydrogen (e.g. a fuel cell power system, or a hydrogen compression, storage and delivery

23、system). 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 3744, Acousti

24、cs Determination of sound power levels of noise sources using sound pressure Engineering method in an essentially free field over a reflecting plane ISO 4677 (all parts), Atmospheres for conditioning and testing Determination of relative humidity ISO 5167 (all parts), Measurement of fluid flow by me

25、ans of pressure differential devices inserted in circular cross-section conduits running full ISO 6060, Water quality Determination of the chemical oxygen demand ISO 6326 (all parts), Natural gas Determination of sulfur compounds ISO 6974 (all parts), Natural gas Determination of composition with de

26、fined uncertainty by gas chromatography ISO 6975, Natural gas Extended analysis Gas-chromatographic method ISO 7934, Stationary source emissions Determination of the mass concentration of sulfur dioxide Hydrogen peroxide/barium perchlorate/Thorin method ISO 9096, Stationary source emissions Manual d

27、etermination of mass concentration of particulate matter ISO 10101 (all parts), Natural gas Determination of water by the Karl Fischer method ISO 10523, Water quality Determination of pH ISO 10707, Water quality Evaluation in an aqueous medium of the “ultimate” aerobic biodegradability of organic co

28、mpounds Method by analysis of biochemical oxygen demand (closed bottle test) ISO 11042 (all parts), Gas turbines Exhaust gas emission BS ISO 16110-2:2010ISO 16110-2:2010(E) 2 ISO 2010 All rights reservedISO 11541, Natural gas Determination of water content at high pressure ISO 11564, Stationary sour

29、ce emissions Determination of the mass concentration of nitrogen oxides Naphthylethylenediamine photometric method ISO 14687-1, Hydrogen fuel Product specification Part 1: All applications except proton exchange membrane (PEM) fuel cell for road vehicles ISO 14687-2, Hydrogen fuel Product specificat

30、ion Part 2: Proton exchange membrane (PEM) fuel cell applications for road vehicles ISO 16622, Meteorology Sonic anemometers/thermometers Acceptance test methods for mean wind measurements IEC 61010-1, Safety requirements for electrical equipment for measurement, control, and laboratory use Part 1:

31、General requirements IEC 61672-1, Electroacoustics Sound level meters Part 1: Specifications 3 Terms, definitions and symbols 3.1 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1.1 audible noise level sound pressure level produced by the hydroge

32、n generator measured at a specified distance NOTE Audible noise level is expressed as decibels (dBA) and measured as described in this part of ISO 16110. 3.1.2 background noise level sound pressure level of ambient noise at the measurement point 3.1.3 cold state condition of a hydrogen generator at

33、ambient temperature with no substantial fuel or power input 3.1.4 discharge water water that is released by the hydrogen generator NOTE Discharge water does not constitute part of a thermal recovery system. It is comprised of the water treatment waste and the process condensate shown in Figure 1. 3.

34、1.5 hydrogen generator system that converts a fuel to a hydrogen-rich stream NOTE The hydrogen generator is composed of all or some of the following subsystems: a fuel processing system, a fluid management system, a thermal management system, and other subsystems as described in more detail in ISO 1

35、6110-1. 3.1.6 interface point measurement point of a hydrogen generator at which material and/or energy either enters or leaves BS ISO 16110-2:2010ISO 16110-2:2010(E) ISO 2010 All rights reserved 33.1.7 return gas tail gas unused reformed hydrogen-rich gas, which returns to the hydrogen generator an

36、d is used as a fuel NOTE Return gas generally includes hydrogen, carbon dioxide, water vapour and slipped hydrocarbon. 3.1.8 standby state state in which the hydrogen generator is at operating temperature and is in an operational mode from which it can be promptly switched to an operational mode wit

37、h net hydrogen output See Figure 2, item 2. 3.1.9 start-up time time from cold start to supply of hydrogen gas at the rated hydrogen pressure See Figure 2, item 1-3. 3.1.10 waste heat thermal energy released and not recovered 3.2 Symbols The symbols and their meanings are described in Annex A. 4 Tes

38、t conditions/Test boundary Hydrogen generators may have different subsystems depending on types of primary conversion processes and applications, and they have different streams of material and energy in and out of them. However, a common system diagram and boundary has been defined for evaluation o

39、f the hydrogen generator (see Figure 1). The following conditions shall be considered in order to determine the test boundary of the hydrogen generator: All energy recovery systems shall be included within the system boundary. Calculation of the heating value of the input fuel (such as natural gas,

40、propane gas, etc.) shall be based on the conditions of the input fuel at the boundary of the hydrogen generator. Calculation of the heating value of the output hydrogen containing gas stream shall be based on the conditions of the gas stream at the boundary of the hydrogen generator. Mechanical syst

41、ems required for hydrogen generator operation (i.e. ventilation or micro-turbines, expanders or compressors) shall be included inside the test boundary. The direct measurement of these mechanical systems inside the test boundary is not required; however, their effects shall be included in the hydrog

42、en generator operation. If mechanical (shaft) power and energy cross the test boundary, additional measurements and calculations may be necessary. NOTE This part of ISO 16110 does not take into account mechanical (shaft) power or mechanical energy inputs or outputs. BS ISO 16110-2:2010ISO 16110-2:20

43、10(E) 4 ISO 2010 All rights reserved1 system boundary of the hydrogen generator including subsystems and the interface is defined as a conceptual or functional one 2 inputs 3 outputs 2.1 steam (if imported) 3.1 water treatment waste 2.2 water 3.2 exhaust gas 2.3 treatment chemicals 3.3 process vents

44、 2.4 air/oxidant 3.4 recovered heat 2.5 fuel 3.5 process condensate 2.6 purge gas 3.6 solid waste 2.7 cooling fluid 3.7 hydrogen 2.8 instrument gas 3.8 cooling fluid 2.9 electrical power input 3.9 ventilation exhaust 2.10 atmospheric air 3.10 noise 3.11 waste heat 4 subsystems (the configurations de

45、pend on the kind of fuel, type of fuel cell or system) 4.1 water treatment and steam generation 4.2 air/oxidant processing system 4.3 feedstock compression and processing 4.4 fuel processing system 4.5 hydrogen purification (optional) 4.6 hydrogen metering and analysis 4.7 process utilities (cooling

46、 fluid, purge gas, instrument gas, electrical, etc.) 4.8 ventilation system ： The interface points in the boundary to be measured for calculation data. NOTE The fuel input can also consist of return gas. Figure 1 Typical hydrogen generator diagram BS ISO 16110-2:2010ISO 16110-2:2010(E) ISO 2010 All

47、rights reserved 55 Measurement technique 5.1 General The types of measuring instruments and measurement methods shall conform to the relevant International Standards and shall be selected to meet the measurement uncertainty targets in line with the uncertainty analysis of 6.4. If necessary, external

48、 equipment with required specification shall be added. 5.2 Operational parameters 5.2.1 Electrical power input The electrical power input to the hydrogen generator, the voltage, the current and the power factor shall be determined and measured in accordance with IEC 61010-1. 5.2.2 Input and output f

49、luid characteristics 5.2.2.1 General The composition, the heating value (only for fuels), the temperature, the pressure and the flow rate of the input and output fluids shall be determined as per 5.2.2.2 to 5.2.2.6. If there is fluctuation greater than 2 % in any measured value, the amplitude and the frequency of the fluctuation shall be measured and reported as part of the test results. 5.2.2.2 Composition of fluids The composition of each input and output fluid