BS EN 19694-5-2016 Stationary source emissions Determination of greenhouse gas (GHG) emissions in energy-intensive industries Lime industry《固定源排放 高耗能行业温室气体 (GHG) 排放的测定 石灰工业》.pdf

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1、BS EN 19694-5:2016Stationary source emissions Determination of greenhousegas (GHG) emissions in energy-intensive industriesPart 5: Lime industryBSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06BS EN 19694-5:2016 BRITISH STANDARDNational forewordThis British Standard i

2、s the UK implementation of EN 19694-5:2016.The UK participation in its preparation was entrusted to TechnicalCommittee EH/2/1, Stationary source emission.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all

3、the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2016.Published by BSI Standards Limited 2016ISBN 978 0 580 87116 0ICS 13.040.40Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Stand

4、ard was published under the authority of theStandards Policy and Strategy Committee on 31 July 2016.Amendments/corrigenda issued since publicationDate T e x t a f f e c t e dBS EN 19694-5:2016EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 19694-5 July 2016 ICS 13.040.40 English Version Station

5、ary source emissions - Determination of greenhouse gas (GHG) emissions in energy-intensive industries - Part 5: Lime industry missions de sources fixes - Dtermination des missions de gaz effet de serre (GES) dans les industries nergo-intensives - Partie 5: Industrie de la chaux Emissionen aus statio

6、nren Quellen - Bestimmung von Treibhausgasen (THG) aus energieintensiven Industrien - Teil 5: Kalkindustrie This European Standard was approved by CEN on 5 May 2016. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Stan

7、dard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (Englis

8、h, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bu

9、lgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland,

10、Turkey andUnited Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2016 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members

11、. Ref. No. EN 19694-5:2016 EBS EN 19694-5:2016EN 19694-5:2016 (E) 2 Contents Page European foreword . 4 1 Scope 5 2 Normative references 6 3 Terms and definitions . 6 4 Symbols and abbreviations . 8 5 Introduction . 10 5.1 Overview of the lime manufacturing process 10 5.2 Direct greenhouse gas emiss

12、ions from calcination of kiln stone (process emissions) 11 5.3 Direct greenhouse gas emissions from fuels for kiln operation (combustion emissions) . 11 5.4 Energy indirect greenhouse gas emissions 12 6 System boundaries 12 6.1 Appropriate boundaries to distinguish . 12 6.2 Organizational boundaries

13、 . 12 6.3 Operational boundaries . 13 6.4 Sources and greenhouse gases to be included. 14 6.5 Internal lime transfers . 14 6.6 Assessment period . 14 7 Principles 14 8 Determination of greenhouse gas emissions: general requirements . 15 8.1 Monitoring Plan and other requirements for identifying, cal

14、culating and reporting of greenhouse gas emissions 15 8.2 Stack-measurement-based method or mass-balance-based method . 15 9 Direct greenhouse gas emissions) and their determination 15 9.1 Sources of direct greenhouse gas emissions and the applicability of determination methods . 15 9.2 Direct CO2gr

15、eenhouse gas emissions from the calcination of kiln stone (process emissions) using the mass-balance-based method . 16 9.3 Direct greenhouse gas emissions from kiln fuels (combustion emissions) using the mass-balance-based method 26 9.4 Direct greenhouse gas emissions from non-kiln fuels (combustion

16、 emissions) using the mass-balance-based method 30 10 Energy indirect greenhouse gas emissions and their determination . 33 10.1 Overview of the sources of energy indirect greenhouse gas emissions . 33 10.2 Determination of the quantity of externally generated electricity used (activity data) 33 10.

17、3 Determination of the emission factor for externally generated electricity 35 11 Other indirect greenhouse gas emissions from imported kiln stone and transport of kiln stone by third parties 35 11.1 Other indirect indirect greenhouse gas emissions, third party and of site transportation . 35 11.2 G

18、reenhouse gas emissions from manufacture of imported kiln stone . 35 11.3 GHG from transport of kiln stone by third parties . 36 BS EN 19694-5:2016EN 19694-5:2016 (E) 3 12 Reporting and performance assessment . 37 12.1 Reporting data to include 37 12.2 Performance assessment . 37 13 Uncertainty of G

19、HG inventories . 39 13.1 General principles 39 13.2 Assessment of uncertainty for the mass-balance- base method . 39 13.3 Assessment of uncertainty for the stack-measurement-based method . 43 14 Verification / certification . 43 Annex A (informative) Objective and outcome of the site trails . 44 Ann

20、ex B (normative) Minimum content of the monitoring plan 47 Annex C (informative) Details about the calculation of process emissions from lime kilns using the mass balance-based-method . 50 Annex D (informative) Example of an uncertainty calculation . 56 Bibliography . 58 BS EN 19694-5:2016EN 19694-5

21、:2016 (E) 4 European foreword This document (EN 19694-5:2016) has been prepared by Technical Committee CEN/TC 264 “Air quality”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsem

22、ent, at the latest by January 2017, and conflicting national standards shall be withdrawn at the latest by January 2017. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identify

23、ing any or all such patent rights. This document has been prepared under a mandate M/478 given to CEN by the European Commission and the European Free Trade Association. This part of EN 19694 deals with sector-specific aspects for the determination of greenhouse gas (GHG) emissions from lime manufac

24、ture. This European Standard can be used to measure, report and compare the GHG emissions of a lime manufacturing plant. Data for individual plants, sites or works may be combined to measure, report and compare GHG emissions for an organization, corporation or group. EN 19694, Stationary source emis

25、sions Determination of greenhouse gas (GHG) emissions in energy intensive industries is a series of standards that consists of the following parts: Part 1: General aspects Part 2: Iron and steel industry Part 3: Cement industry Part 4: Aluminium industry Part 5: Lime industry Part 6: Ferroalloy indu

26、stry According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France

27、, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 19694-5:2016EN 19694-5:2016 (E) 5 1 Scope This European Standard provides a

28、harmonized methodology for calculating GHG emissions from the lime industry. It includes the manufacture of lime, and any downstream lime products manufactured at the plant, such as ground or hydrated lime. This standard allows for reporting of GHG emissions for various purposes and on different bas

29、is, such as plant basis, company basis (by country or by region) or international organization basis. Since lime is defined as the generic name for quicklime, dolime and sintered dolime, plants manufacturing at least one of these products shall be covered by this standard. This European Standard add

30、resses all of the following direct and indirect sources of GHG included as defined in ISO 14064-1: direct greenhouse gas emissions from greenhouse gas sources that are owned or controlled by the company, such as emissions resulting from the following sources: calcination of carbonates and combustion

31、 of organic carbon contained in the kiln stone; combustion of kiln fuels (fossil kiln fuels, alternative fossil fuels, mixed fuels with biogenic carbon content, biomass fuels and bio fuels) related to lime production and/or drying of raw materials; combustion of non-kiln fuels (fossil kiln fuels, mi

32、xed fuels with biogenic carbon content, biomass fuels and bio fuels) related to equipment and on-site vehicles, heating/cooling and other on-site uses; combustion of fuels for on-site power generation. indirect greenhouse gas emissions from the generation of imported electricity, heat or steam consu

33、med by the organization; other indirect greenhouse gas emissions, other than energy indirect GHG emissions, which is a consequence of an organizations activities, but arises from greenhouse gas sources that are owned or controlled by other organizations such as from imported kiln stone. This Europea

34、n Standard is to be used in conjunction with EN 19694-1, which contains generic, overall requirements, definitions and rules applicable to the determination of GHG emissions for all energy-intensive sectors, provides common methodological issues and defines the details for applying the rules. The ap

35、plication of this standard to the sector-specific standards ensures accuracy, precision and reproducibility of the results and is for this reason a normative reference standard. Together these standards provide a harmonized method for: a) measuring, testing and quantifying methods for GHG emissions;

36、 b) assessing the level of GHG emissions performance of production processes over time, at production sites; c) establishment and provision of reliable, accurate and quality information for reporting and verification purposes. GHG emissions offset mechanisms, including but not limited to voluntary o

37、ffset schemes or nationally or internationally recognized offset mechanisms, shall not be used at any point in the GHG assessment according to this standard. BS EN 19694-5:2016EN 19694-5:2016 (E) 6 2 Normative references The following documents, in whole or in part, are normatively referenced in thi

38、s document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 459-2, Building lime Part 2: Test methods EN 932-1, Tests for general properties of

39、 aggregates Part 1: Methods for sampling EN 12485, Chemicals used for treatment of water intended for human consumption Calcium carbonate, high-calcium lime, half-burnt dolomite, magnesium oxide and calcium magnesium carbonate Test methods EN 13639, Determination of total organic carbon in limestone

40、 EN 15442, Solid recovered fuels Methods for sampling EN 19694-1:2016, Stationary source emissions Determination of greenhouse gas (GHG) emissions in energy-intensive industries Part 1: General aspects ISO 5069-1, Brown coals and lignites Principles of sampling Part 1: Sampling for determination of

41、moisture content and for general analysis ISO 13909 (all parts), Hard coal and coke Mechanical sampling ISO 18283, Hard coal and coke Manual sampling ISO 14064-1, Greenhouse gases Part 1: Specification with guidance at the organization level for quantification and reporting of greenhouse gas emissio

42、ns and removals 3 Terms and definitions For the purposes of this document, the terms and definitions given in EN 19694-1 and the following apply. 3.1 activity data information on material flow, consumption of fuel, input material or production output Note 1 to entry: Expressed as energy GJ or as mas

43、s or volume t or m3N in the case of fuels and mass or volume in the case of raw materials or products t or m3N. 3.2 dolime product resulting from the calcination of kiln stone consisting of calcium carbonate and magnesium carbonate 3.3 downstream lime product downstream lime products including Run-O

44、f-Kiln lime (ROK), Lime Kiln Dust (LKD) and products made from them at the plant including ground lime and hydrated lime BS EN 19694-5:2016EN 19694-5:2016 (E) 7 3.4 free CaO and MgO calcium oxide or magnesium oxide that has been produced in the kiln during the decarbonation of calcium carbonate or m

45、agnesium carbonate Note 1 to entry: The terminology free CaO and MgO as used in this standard may differ from the terminology applied in other standards. 3.5 kiln battery group of kilns at the same plant and of the same design EXAMPLE Parallel Flow Regenerative Kilns, Annular Shaft Kilns, Mixed Feed

46、 Shaft Kilns, Preheater Rotary Kilns or Long Rotary Kilns 3.6 kiln stone limestone that is fed into the kiln 3.7 lime LI generic name for quicklime, dolime or sintered dolime 3.8 lime kiln dust LKD partly calcined kiln stone material which is extracted by the kiln particulate abatement system 3.9 li

47、mestone LS sedimentary rock consisting of calcium carbonate (CaCO3), magnesium carbonate (MgCO3), mineral and other minor impurities, including in some cases a small fraction of organic carbon 3.10 non kiln stone aggregates all stones extracted from a quarry except that used as kiln stone 3.11 quick

48、lime product resulting from the calcination of limestone consisting primarily of calcium carbonate 3.12 residual CO2CO2that remains in the product leaving the kiln which is bound with CaO in the form of CaCO3and possibly with MgO in form of MgCO33.13 run-of-kiln lime ROK direct output from the kiln

49、BS EN 19694-5:2016EN 19694-5:2016 (E) 8 3.14 sintered dolime dolime heated to temperatures below its melting temperature, so as to increase its density 4 Symbols and abbreviations 2CO stackmmass of CO2emitted through the stack t x arithmetic mean of the measured values CaCO3 LI-ROKweight fraction of calcium carbonate in the dry ROK lime produced by the kiln CaCO3 LKDweight fraction of calcium carbonate in the dry LKD CaCO3 LSweight fraction of calcium carbonate in the dry limestone fed into the kiln CaO fr free Ca