BS EN 15797-2010 Chemicals used for the treatment of swimming pool water - Iron based coagulants《游泳池水处理用化学品 铁基凝结剂》.pdf

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1、BS EN 15797:2010ICS 13.060.25; 71.100.80NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBRITISH STANDARDChemicals used for thetreatment of swimmingpool water Ironbased coagulantsThis British Standardwas published under theauthority of the StandardsPolicy and StrategyCommittee o

2、n 30 April2010 BSI 2010ISBN 978 0 580 61783 6Amendments/corrigenda issued since publicationDate CommentsBS EN 15797:2010National forewordThis British Standard is the UK implementation of EN 15797:2010.The UK participation in its preparation was entrusted to TechnicalCommittee CII/59, Chemicals for d

3、rinking water treatment.A list of organizations represented on this committee can be obtained onrequest to its secretary.This publication does not purport to include all the necessary provisionsof a contract. Users are responsible for its correct application.Compliance with a British Standard cannot

4、 confer immunityfrom legal obligations.BS EN 15797:2010EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 15797 January 2010 ICS 71.100.80 English Version Chemicals used for the treatment of swimming pool water - Iron based coagulants Produits chimiques utiliss pour le traitement de leau des pisci

5、nes - Coagulants base de fer Produkte zur Aufbereitung von Schwimm- und Badebackenwasser - Flockungsmittel auf Eisenbasis This European Standard was approved by CEN on 28 November 2009. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for givin

6、g this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official vers

7、ions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium

8、, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITT

9、EE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15797:2010: EBS EN 15797:2010EN 15797:20

10、10 (E) 2 Contents Page Foreword 3Introduction .41 Scope 52 Normative references 53 Description .54 Purity criteria 54.1 General 54.2 Composition of commercial product .54.3 Impurities and main by-products .64.4 Chemical parameters 65 Test methods 66 Labelling - Transportation - Storage 66.1 Means of

11、 delivery .66.2 Risk and safety labelling in accordance with the EU Directives 66.3 Transportation regulations and labelling 76.4 Marking .86.5 Storage 9Annex A (informative) General information on iron based coagulants . 10A.1 Origin . 10A.2 Use . 10Annex B (normative) General rules relating to saf

12、ety . 11B.1 Rules for safe handling and use . 11B.2 Emergency procedures 11Bibliography . 12BS EN 15797:2010EN 15797:2010 (E) 3 Foreword This document (EN 15797:2010) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard

13、 shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by July 2010, and conflicting national standards shall be withdrawn at the latest by July 2010. Attention is drawn to the possibility that some of the elements of this docum

14、ent may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: A

15、ustria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdo

16、m. BS EN 15797:2010EN 15797:2010 (E) 4 Introduction In respect of potential adverse effects on the quality of water for swimming pools, caused by the products covered by this European Standard: a) this document provides no information as to whether the products may be used without restriction in any

17、 of the Member States of the EU or EFTA; b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of these products remain in force. NOTE Conformity with the document does not confer or imply

18、acceptance or approval of the products in any of the Member States of the EU or EFTA. The use of these products covered by this document is subject to regulation or control by National Authorities. BS EN 15797:2010EN 15797:2010 (E) 5 1 Scope This European Standard is applicable to iron based coagula

19、nts (iron (III) chloride, iron (III) chloride sulfate and iron (III) sulfate liquid) used directly or for the production of formulations for treatment of water for swimming pools. It describes the characteristics of iron based coagulants and specifies the requirements and the corresponding test meth

20、ods for iron based coagulants. It gives information on their use in swimming pool water treatment. General information on iron based coagulants is given in Annex A. It also determines the rules relating to safe handling and use (see Annex B). 2 Normative references The following referenced documents

21、 are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 888, Chemicals used for treatment of water intended for human consumption Iron (

22、III) chloride EN 890, Chemicals used for treatment of water intended for human consumption Iron (III) sulfate liquid EN 891, Chemicals used for treatment of water intended for human consumption Iron (III) chloride sulfate 3 Description For the identification, the commercial form, the physical proper

23、ties and the chemical properties see the relevant subclauses of EN 888, EN 890 and EN 891. 4 Purity criteria 4.1 General This document specifies the minimum purity requirements for iron based coagulants used for the treatment of water for swimming pools. Limits are given for impurities commonly pres

24、ent in the products. Depending on the raw material and the manufacturing process other impurities may be present and, if so, this shall be notified to the user and when necessary to relevant authorities. NOTE Users of these products should check the national regulations in order to clarify whether t

25、hey are of appropriate purity for treatment of water for swimming pools, taking into account water quality, required dosage, contents of other impurities and additives used in these products not stated in these product standards. Limits have been given for impurities and chemical parameters where th

26、ese are likely to be present in significant quantities from the current production process and raw materials. If the production process or raw materials lead to significant quantities of other impurities by-products or additives being present, this shall be notified to the user. 4.2 Composition of c

27、ommercial product The concentration of active matter in the product expressed as mass fraction in % of FeCl3, Fe2 (SO4)3 orFeClSO4 shall be within 3 % of the manufacturers declared values. BS EN 15797:2010EN 15797:2010 (E) 6 NOTE The concentration of iron active matter in commercial products varies.

28、 Typical values are given in Table 1. Table 1 Typical values for the concentration of iron active matter in commercial products Product Commercial form ConcentrationMass fraction in % Iron (III) chloride Solid 99 in FeCl3 Solid hexahydrate 59 in FeCl3Solution 40 in FeCl3Iron (III) sulfate Solution 3

29、0 in Fe2 (SO4)3Iron (III) chloride sulfate Solution 36,9 in FeClSO44.3 Impurities and main by-products The content of manganese, iron (II) and insoluble matters shall conform to the requirements specified in EN 888, EN 890 and EN 891. 4.4 Chemical parameters The content of arsenic, cadmium, chromium

30、, mercury, nickel, lead, antimony and selenium for each grade and type of products shall conform to the requirements specified in EN 888, EN 890 and EN 891. 5 Test methods The methods for sampling and analysis are those specified respectively in EN 888, EN 890 and EN 891. 6 Labelling - Transportatio

31、n - Storage 6.1 Means of delivery Solids: the products shall be delivered in suitable packages, paper or plastics bags Liquids: the products shall be delivered in containers of corrosion-resistant materials suitable for the purpose. NOTE The manufacturer can provide advice on suitable materials. In

32、order that the purity of the products is not affected, the means of delivery shall not have been used previously for any different product or it shall have been specially cleaned and prepared before use. 6.2 Risk and safety labelling in accordance with the EU Directives1)Iron (III) chloride is not s

33、ubject to labelling regulations. 1) See 1. BS EN 15797:2010EN 15797:2010 (E) 7 The following labelling requirements shall apply to the following iron based coagulants at the date of the publication of this document: Iron (III) sulfate liquid: a) symbols and indications of danger: C: Corrosive; b) na

34、ture of special risks attributed to dangerous substances: R 36/38: Irritating to eyes and skin; c) safety advice concerning dangerous substances: 1) S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice; 2) S 36/37/39: Wear suitable protective clothing, g

35、loves and eye/face protection. Iron (III) chloride sulfate: d) Symbols and indications of danger: C: Corrosive; e) Nature of special risks attributed to dangerous substances: 1) R 21/22: Harmful in contact with skin and if swallowed; 2) R 34: Causes burns; 3) R 36/38: Irritating to eyes and skin; f)

36、 Safety advice concerning dangerous substances: 1) S 24/25: Avoid contact with skin and eyes; 2) S 37/39: Wear suitable gloves and eye/face protection. NOTE Annex I of the Directive 67/548/EEC on Classification, packaging and labelling of dangerous substances and its amendments and adaptations in th

37、e European Union contains a list of substances classified by the EU. Substances not listed in that Annex I should be classified on the basis of their intrinsic properties according to the criteria in the Directive by the person responsible for the marketing of the substance. 6.3 Transportation regul

38、ations and labelling 6.3.1 General The following classification requirements shall apply to the following iron based coagulants at the date of the publication of this document. BS EN 15797:2010EN 15797:2010 (E) 8 6.3.2 Iron (III) chloride Depending on the composition, the commercial product can be s

39、ubject to transportation regulations and, if so, at the date of the publication of this document the iron (III) chloride is listed as UN2)number 1773 and the solutions as UN number 2582. a) ADR3)/ RID4) 1) class 8, classification code C2; packing group III (E) for iron (III) chloride; 2) class 8, cl

40、assification code C1; packing group III (E) for solutions. b) IMDG5): class 8; c) IATA6): class 8. 6.3.3 Iron (III) sulfate liquid At the date of the publication of this document, the commercial product is subject to transportation regulations and is listed as UN number 1760. a) ADR3)/ RID4): class

41、8; classification code C9; packing group I (E); b) IMDG5): class 8, packing group I; c) IATA6): class 8, packing group I. 6.3.4 Iron (III) chloride sulfate: At the date of the publication of this document, the commercial product is subject to transportation regulations and is listed as UN number 258

42、2. a) ADR3) / RID4): class 8; classification code C1; packing group III (E); b) IMDG5): class 8; c) IATA6): class 8. 6.4 Marking The marking shall include the following information: a) the name: 1) “iron (III) chloride“; or 2) “iron (III) sulfate liquid“; or 2) United nations Number. 3) European Agr

43、eement concerning the international carriage of Dangerous goods by Road. 4) Regulations concerning International carriage of Dangerous goods by rail. 5) International Maritime Transport of Dangerous Goods Code. 6) International Air Transport Association. Dangerous Goods Regulations. BS EN 15797:2010

44、EN 15797:2010 (E) 9 3) “iron (III) chloride sulfate“; b) the trade name, commercial form, class, grade and type; c) the net mass; d) the name and the address of the supplier and/or manufacturer; e) the statement “This product conforms to EN 15797“. 6.5 Storage 6.5.1 Long term stability 6.5.1.1 Iron

45、(III) chloride Products are stable, but for solutions see 6.5.2.1. 6.5.1.2 Iron (III) sulfate liquid Storable in stainless steel (316 and 440), rubber and plastics containers or tanks. NOTE Some sedimentation of yellow iron (III) sulfate can occur. 6.5.1.3 Iron (III) chloride sulfate Unlimited stora

46、ge in plastics or rubber lined containers or tanks. NOTE Some sedimentation of yellow iron(III) chloride sulfate can occur. 6.5.2 Storage incompatibilities 6.5.2.1 Iron (III) chloride Solid products: keep barrels dry and tightly closed. Keep away from water, these products are hygroscopic. Solutions

47、: keep away from alkalis, these products react aggressively towards metals and strong oxidizing agents (chlorites, hypochlorites and sulfites). 6.5.2.2 Iron (III) sulfate liquid Iron (III) sulfate liquid is corrosive: avoid contact with metals (except stainless steel 316 and 440); avoid contact with

48、 alkalis; avoid contact with oxidizing agents especially chlorites and hypochlorites. 6.5.2.3 Iron (III) chloride sulfate Iron (III) chloride sulfate has a highly acid and corrosive character. Avoid any contact with metals. Keep away from alkaline agents. Avoid contact with agents capable of liberat

49、ing chlorine. BS EN 15797:2010EN 15797:2010 (E) 10 Annex A (informative) General information on iron based coagulants A.1 Origin A.1.1 Raw materials See EN 888, EN 890 and EN 891. A.1.2 Manufacturing process See EN 888, EN 890 and EN 891. A.2 Use A.2.1 Function The products are used as primary coagulants to enhance the removal of dissolved, colloidal and suspended material (including micro-organisms) by filtration. A.2.2 Form in which the product is used The products are