BS EN 15072-2013 Chemicals used for treatment of swimming pool water Sodium dichloroisocyanurate anhydrous《游泳池水处理用化学品 无水二氯异氰脲酸钠》.pdf

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1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 15072:2013Chemicals used for treatmentof swimming pool water Sodium dichloroisocyanurate,anhydrousBS EN 15072:2013 BRITISH STANDARDNational forewordThis British Standard is

2、 the UK implementation of EN 15072:2013. Itsupersedes BS EN 15072:2006+A1:2008 which is withdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee CII/59, Chemicals for drinking water treatment.A list of organizations represented on this committee can beobtained on request

3、 to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2013. Published by BSI StandardsLimited 2013ISBN 978 0 580 80017 7ICS 13.060.25; 71.100.80Compliance with a Br

4、itish Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 30 June 2013.Amendments issued since publicationDate Text affectedBS EN 15072:2013EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN

5、15072 May 2013 ICS 71.100.80 Supersedes EN 15072:2006+A1:2008English Version Chemicals used for treatment of swimming pool water - Sodium dichloroisocyanurate, anhydrous Produits chimiques utiliss pour le traitement de leau des piscines - Dichloroisocyanurate de sodium, anhydre Produkte zur Aufberei

6、tung von Schwimm- und Badebeckenwasser - Natriumdichlorisocyanurat, wasserfreiThis European Standard was approved by CEN on 28 March 2013. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a nation

7、al standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A versi

8、on in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Cz

9、ech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom.

10、EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2013 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15072:2013: EBS EN 15072

11、:2013EN 15072:2013 (E) 2 Contents Page Foreword 3 Introduction .4 1 Scope 5 2 Normative reference 5 3 Description .5 3.1 Identification .5 3.2 Commercial form .6 3.3 Physical properties 6 3.4 Chemical properties 7 4 Purity criteria 7 4.1 General 7 4.2 Composition of commercial product .7 4.3 Impurit

12、ies and main by-products .7 4.4 Toxic substances .7 5 Test methods 8 6 Labelling - Transportation - Storage 8 6.1 Means of delivery .8 6.2 Labelling according to the EU legislation 8 6.3 Transportation regulations and labelling . 10 6.4 Marking 10 6.5 Storage . 10 Annex A (informative) General infor

13、mation on sodium dichloroisocyanurate, anhydrous . 12 A.1 Origin . 12 A.2 Use . 12 Annex B (normative) General rules relating to safety 14 B.1 Rules for safe handling and use . 14 B.2 Emergency procedures 14 Bibliography . 15 BS EN 15072:2013EN 15072:2013 (E) 3 Foreword This document (EN 15072:2013)

14、 has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by November 2013, and conflicting natio

15、nal standards shall be withdrawn at the latest by November 2013. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document superse

16、des EN 15072:2006+A1:2008. Significant technical differences between this edition and EN 15072:2006+A1:2008 are as follows: Replacement of warning and safety precautions notes by labelling according to Regulation (EC) No 1272/2008. According to the CEN-CENELEC Internal Regulations, the national stan

17、dards organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, L

18、uxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 15072:2013EN 15072:2013 (E) 4 Introduction In respect of potential adverse effects on the quality of water intended for swimming pools caused by the

19、product covered by this European Standard, the following statements apply: a) This European Standard provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA. b) It should be noted that, while awaiting the adoption of verifiable

20、European criteria, existing national regulations concerning the use and/or the characteristics of this product remain in force. NOTE 1 Conformity with this European Standard does not confer or imply acceptance or approval of the products in any of the Member States of the EU or EFTA. The use of the

21、products covered by this European Standard is subject to regulation or control by National Authorities. NOTE 2 This product is a biocide and needs to comply with the relevant legislation in force. In the European Union, at the time of publication, this legislation is Directive 1998/8/EC 1. BS EN 150

22、72:2013EN 15072:2013 (E) 5 1 Scope This European Standard is applicable to sodium dichloroisocyanurate, anhydrous used directly or used to prepare commercial formulations for disinfecting swimming pool water. It describes the characteristics of sodium dichloroisocyanurate, anhydrous and specifies th

23、e requirements and the corresponding test methods for sodium dichloroisocyanurate, anhydrous. It gives information on its use for treating swimming pool water and determines the rules relating to safe handling and use (see Annex B). 2 Normative reference The following documents, in whole or in part,

24、 are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 12931, Chemicals used for treatment of water inte

25、nded for human consumption Chemicals for emergency use Sodium dichloroisocyanurate, anhydrous 3 Description 3.1 Identification 3.1.1 Chemical name 1-sodium - 3,5-dichloro - 1,3,5-triazine - 2,4,6-trione. 3.1.2 Synonym or common name Sodium dichloroisocyanurate. 3.1.3 Relative molecular mass 219,98.

26、3.1.4 Empirical formula C3N3O3Cl2Na. 3.1.5 Chemical formula BS EN 15072:2013EN 15072:2013 (E) 6 3.1.6 CAS Registry Number 1)2893-78-9. 3.1.7 EINECS reference 2)2-207-67-7. 3.2 Commercial form The product is available in various granular forms. 3.3 Physical properties 3.3.1 Appearance and odour The p

27、roduct is a white granular solid with chlorinous odour. 3.3.2 Density The bulk density is approximately 0,9 g/cm3. 3.3.3 Solubility in water The solubility in water is 250 g/l at 25 C. 3.3.4 Vapour pressure Not applicable. 3.3.5 Boiling point at 100 kPa 3)Not applicable, the product decomposes befor

28、e fusion. 3.3.6 Melting point Not applicable. 3.3.7 Specific heat (1 090 40) J/kg.K at 20 C. 3.3.8 Viscosity, (dynamic) Not applicable. 3.3.9 Critical temperature Not applicable. 1) Chemical Abstracts Service Registry Number. 2) European Inventory of Existing Commercial Chemical Substances. 3) 100 k

29、Pa = 1 bar. BS EN 15072:2013EN 15072:2013 (E) 7 3.3.10 Critical pressure Not applicable. 3.3.11 Physical hardness Not applicable. 3.4 Chemical properties The product is a strong oxidant. It is corrosive and hygroscopic; sodium dichloroisocyanurate decomposes into hydrochloric acid and cyanuric acid.

30、 When dissolved in an excess of water, it liberates chlorine by hydrolysis. 4 Purity criteria 4.1 General Limits have been given for impurities and toxic substances where these are likely to be present in significant quantities from the current production process and raw materials. If a change in th

31、e production process or raw materials leads to significant quantities of other impurities or by-products being present, the user shall be notified. 4.2 Composition of commercial product The product shall contain at least 62 percent by mass (% (m/m) of available chlorine. 4.3 Impurities and main by-p

32、roducts The water content shall be less than 3 % (m/m) of the product. The sodium chloride content shall be less than 0,05 % (m/m) of the product. 4.4 Toxic substances NOTE For the purpose of this standard, “toxic substances“ are those defined in the EU Directive 80/778/EEC of 15 July, 1980 1. The c

33、ontent of toxic substances shall conform to the requirements specified in Table 1. BS EN 15072:2013EN 15072:2013 (E) 8 Table 1 Toxic substances Element Limit mg/kg of product Type 1 Type 2 Arsenic (As) max. 10 10 Cadmium (Cd) max. 1 1 Chromium (Cr) max. 6 10 Mercury (Hg) max. 0,02 0,02 Nickel (Ni) m

34、ax. 3 5 Lead (Pb) max. 4 15 Antimony (Sb) max. 5 5 Selenium (Se) max. 1 1 NOTE Cyanide, which does not exist in a strong oxidising medium such as sodium dichloroisocyanurate, is not a relevant toxic substance (see 2). Pesticides and polycyclic aromatic hydrocarbons are not by-products of the manufac

35、turing process. 5 Test methods The sampling and the analytical methods are those described in EN 12931. 6 Labelling - Transportation - Storage 6.1 Means of delivery The product shall be delivered in fibre or polyethylene drums or semi-bulk containers. To ensure the purity of the product, the means o

36、f delivery shall not have previously been used for any different product or it shall have been specially cleaned and prepared before use. 6.2 Labelling according to the EU legislation 4)The following labelling requirements shall apply to sodium dichloroisocyanurate anhydrous at the date of the publi

37、cation of this European Standard. 4) See 3. BS EN 15072:2013EN 15072:2013 (E) 9 Figure 1 GHS 03 Figure 2 GHS 07 Figure 3 GHS 09 Signal word: Danger Classification and hazard statement: H272 May intensify fire; oxidiser H 302 Harmful if swallowed H400 Very toxic to aquatic life BS EN 15072:2013EN 150

38、72:2013 (E) 10 The regulation 3, and its amendments for the purposes of its adaptation to technical and scientific progress, contains a list of substances classified by the EU. Substances not listed in this regulation should be classified on the basis of their intrinsic properties according to the c

39、riteria in the regulation by the person responsible for the marketing of the substance. 6.3 Transportation regulations and labelling Sodium dichloroisocyanurate, anhydrous is listed as UN Number 5)2465 and is classified as follows: RID 6): class 5.1, classification code O2, packing group II; ADR 7):

40、 class 5.1, classification code O2, packing group II; IMDG 8): class 5.1; IATA 9): class 5.1. 6.4 Marking The marking shall include the following: name “sodium dichloroisocyanurate, anhydrous”, trade name and type; net mass; name and the address of supplier and/or manufacturer; statement “this produ

41、ct conforms to EN 15072“. 6.5 Storage 6.5.1 General The product shall be stored in its original package, firmly closed in a cool and dry place, away from any sources of heat or incompatible materials. 6.5.2 Long term stability When stored in above conditions, the product is stable for at least three

42、 years. 6.5.3 Storage incompatibilities Store the product on its own if possible. Keep it away from: water; strong acids; 5) United Nations Number. 6) Regulations concerning International carriage of Dangerous goods by rail. 7) European Agreement concerning the international carriage of Dangerous go

43、ods by Road. 8) International maritime transport of Dangerous Goods. 9) International Air Transport Association. BS EN 15072:2013EN 15072:2013 (E) 11 nitrogenated products; organic solvents; hydrocarbons; peroxides; hypochlorites; oils, greases and organic materials; ammonium salts; basic products.

44、BS EN 15072:2013EN 15072:2013 (E) 12 Annex A (informative) General information on sodium dichloroisocyanurate, anhydrous A.1 Origin A.1.1 Raw materials Sodium dichloroisocyanurate, anhydrous is manufactured from isocyanuric acid (CNOH)3, sodium hydroxide (NaOH) and chlorine (Cl2). A.1.2 Manufacturin

45、g process Sodium dichloroisocyanurate, anhydrous is produced by chlorination of disodium cyanurate (Na2H(NCO)3) using chlorine (Cl2) and neutralisation with sodium hydroxide (NaOH). Disodium cyanurate is obtained by action of sodium hydroxide on isocyanuric acid. A.2 Use A.2.1 Function The product i

46、s used as a disinfectant of swimming pool water. It is an indirect source of free chlorine (HOCl) when dissolved in water via an organic carrier substance (sodium cyanurate, C3N3O3H2Na): C3N3O3Cl2Na + 2H2O - C3N3O3H2Na + 2HOCl (A.1) As the disinfectant (HOCl) is used up, more chlorine atoms are rele

47、ased from “sodium dichloroisocyanurate, anhydrous“ to form hypochlorous acid. This results in an enrichment of sodium isocyanurate in the pool water which cannot be removed by the water treatment process. Only dilution with fresh water keeps the sodium isocyanurate concentration at a satisfactory le

48、vel. If the sodium isocyanurate concentration becomes too high, unsatisfactory disinfection can result. The automatic amperometric monitoring of free chlorine residual is negatively affected by sodium isocyanurate. A.2.2 Form in which it is used The product is used in tablet and granular form. A.2.3

49、 Treatment dose The treatment dose is subject to national regulations, depending on the required free chlorine concentration in the pool water In order to have 2,5 mg/l free chlorine concentration, one should add 3,97g/m3of sodium dichloroisocyanurate, anhydrous. A.2.4 Means of application The product is dissolved either directly or using a dissolution device. BS EN 15072:2013EN 15072:2013 (E) 13 A.2.5 Secondary effects The secondary effects include the following: oxidation of iron, of manganese and ammonium