INTERN TMS 6039-2008 Rubber (TSR) Molding Compounds《橡胶(TSR)模塑复合物》.pdf

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1、NAVISTAR, INC. TMS (TRUCK MATERIAL SPECIFICATION) NUMBER: TMS-6039 TITLE: Rubber (TSR) Molding Compounds CURRENT REV No: 0806 DATE: June 2008 WRITTEN/EDITED BY: Materials Engineering APPROVED BY: Materials Engineering SUPERSEDES: Rev J April 2008 PRINTED COPIES OF THIS DOCUMENT MUST BE VERIFIED FOR

2、CURRENT REVISION This specification may involve hazardous materials, equipment, and procedures. This specification does not purport to address all of the safety issues associated with its use. The user is responsible to consult appropriate safety and health practices and to determine the applicabili

3、ty of regulatory limits prior to use. Change Notice: Replaced “International Truck and Engine Corporation” with “Navistar, Inc.” per corporate directive; added Table 9 and new materials to Table 8; editorial changes. Reference: File 30-16 Keywords: Thermoset Rubber, Rubber compounds. 1.0 APPLICATION

4、 This specification covers thermoset rubber (TSR) molding compounds used in truck applications. These TSR compounds are generally molded or extruded and may contain recycled materials. For thermoplastic elastomers (TPR/TPE/TPU), see TMS-6040. Note: Mount properties are listed in Table 8 which is in

5、a restricted issue appendix, TMS-6039-R. Contact Materials Engineering (referenced in Section 8.0) for further information. 1.1 Restricted Chemical SubstancesEffective January 1, 2007, all product supplied to the requirements of this specification must comply with the requirements of the CEMS B-50 s

6、pecification. 2.0 SCOPE This specification covers the general requirements, identification, inspection, property and performance requirements, quality plan, and source approval and quality control requirements for these TSR compounds. 2.1 Rubber Compound Designation - Description The TSR compounds c

7、overed in this specification may include several different types of polymer base, such as EPDM, NR, CSM, NBR, etc. Within each of these basic polymer groups, several different blends and curing treatments are available, and unless otherwise specified, may be used to provide the specified hardness an

8、d other material properties required for the part. A specific polymer may be specified within the material designation for the part. Upon approval of the prototype and/or PPAP samples, no changes in the polymer base, blend, curing treatment, or other processing variables shall be made without the ap

9、proval of Materials Engineering and the Quality Department of the receiving plant. 2.1.1 TSR Prefix All rubber molding compounds provided to the requirements of this specification shall be designated with the TSR prefix. A specific polymer may or may not be specified in the material designation. The

10、se materials may contain recycled rubber (post-consumer recycled material, such as automotive tires) with prior Engineering approval. If industrial recyclate (pre-consumer recycled material) is included in the TSR compound, it shall be reported separately from the post-consumer recycled content. 2.2

11、 Suffix Designations This document is restricted and may not be sent outside Navistar, Inc. or reproduced without permission from Corporate Technical Standards. Additional requirements for parts made from the rubber molding compound may be specified by adding a suffix to the compound designation. Th

12、e suffix requirement is in addition to the normal durometer hardness and tensile requirements of the material designation and independent of the polymer base used Suppliers are required to assume all patent liability. 2008 by Navistar, Inc. JUNE 2008 Page 1 of 17 Copyright Navistar International Cor

13、poration Provided by IHS under license with INTERNNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-NUMBER: TITLE: REVISION: TMS-6039 Rubber (TSR) Molding Compounds 0806This document is restricted and may not be sent outside Navistar, Inc. or reproduced without permi

14、ssion from Corporate Technical Standards. for the part. The suffix designation follows and is separated from the TSR prefix by a “dash. In some cases more than one suffix requirement may be designated. An alternate method of assigning a sequential number to new compounds has been added to facilitate

15、 development of parts while parameters may yet change. 2.2.1 Suffix-H: This designates a heat- and weather-resistant TSR material. Unless otherwise specified on the Engineering drawing, product supplied shall meet the heat resistance and aged heat adhesion requirements as specified in Tables 4-9. Mi

16、nimal oil resistance is expected for this type of material. 2.2.2 Suffix-O: This suffix designates a TSR compound with good oil and/or diesel fuel resistance. Unless otherwise specified on the Engineering drawing, parts supplied will meet the oil and fuel resistance requirements specified in Tables

17、4-9. Typical polymers that may be used for this specification include: Acrylonitrile-butadiene (nitrile or NBR) and appropriate blends. 2.2.3 Suffix-H/O: This suffix designates a heat-resistant TSR material that also exhibits good oil and diesel fuel resistance. Unless otherwise specified on the Eng

18、ineering drawing, parts supplied will meet both the heat resistance and oil and fuel resistance requirements specified in Tables 4-9. Typical polymers that may be used for this specification include: Chloroprene (CR), Chlorinated Polyethylene(CPE or CM), Chloro-sulfonated Polyethylene (CSM), Epichlo

19、rohydrin copolymer (ECO), Acrylonitrile-butadiene (nitrile or NBR), Hydrogenated Nitrile (HNBR), and appropriate blends. 2.2.4 Suffix-H/C: This suffix designates a heat- and weather-resistant TSR material with good resistance to heavy-duty diesel coolants. Unless otherwise specified on the Engineeri

20、ng drawing, parts supplied will meet both the heat resistance and coolant resistance requirements specified in Tables 4-9. A typical polymer that may be used is EPDM. Minimal oil resistance is expected for this material. 2.2.5 Suffix-M: This suffix designates a common TSR class of materials except u

21、sed in mount or isolator applications. Dynamic property requirements for these parts are generally specified separately on the Engineering drawing. Typically, the TSR material is a Natural Rubber. Natural Rubber blends with IR and SBR may be considered with prior approval. Chloroprene can be conside

22、red in a similar fashion in applications requiring high heat and oil resistance but lower flex fatigue resistance. When highly damped materials are required, butyl compounds may be specified. 2.3 Specific TSR Compound Designations A lower case letter may be used at the end of the compound designatio

23、n to specify a specific blend or composition of TSR compound. The lower case letter is added at the end, after the tensile strength number, to indicate a specific compound. For example, as indicated in Table 3, TSR65-10a designates an 8021 molding compound supplied by NRI. The specific molding compo

24、und designated by the use of the lower case letter will be indicated in Tables 4-9 or will be shown on the engineering drawing. 2.4 Explanation Examples of Designation System The material designation on the drawing shall consist of the TSR material prefix, followed by any suffix requirements H, -O,

25、-C, or M, followed by the durometer and tensile strength specified. In some cases, a specific compound identifier (lower case letter) may be used to differentiate compound variations. A specific polymer base material may also be identified in the specification as well. 2.4.1 Designation on Drawings:

26、 Rubber per TMS 6039, TSR60-10 2.4.1.1 This designation identifies a basic TSR elastomer, without a specific polymer base identified, with a durometer hardness of 60 and a tensile strength of 10 MPa. 2.4.2 Designation on Drawings: EPDM per TMS-6039 TSR-H70-8a Suppliers are required to assume all pat

27、ent liability. 2008 by Navistar, Inc. JUNE 2008 Page 2 of 17 Copyright Navistar International Corporation Provided by IHS under license with INTERNNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-NUMBER: TITLE: REVISION: TMS-6039 Rubber (TSR) Molding Compounds 0806T

28、his document is restricted and may not be sent outside Navistar, Inc. or reproduced without permission from Corporate Technical Standards. 2.4.2.1 This designation requires an EPDM compound meeting the heat resistance requirement with a durometer of 70 and a tensile of 8 MPa. This is also a specific

29、 compound variation as designated by the lower case letter “a.” The specific material description is shown on the Engineering drawing. 2.4.3 Designation on Drawings: Natural Rubber per TMS-6039 TSR-M50-25b 2.4.3.1 This is an engine mount material made from Natural Rubber with a durometer of 50 and a

30、 tensile strength of 25 MPa. A specific compound, designated by the lower case letter “b”, will be shown on the drawing. The print also describes specific dynamic and static spring rates for this part. 2.4.4 Designation on Drawings: TSR-0020 per TMS-6039 2.4.4.1 An alternate designation, intended pr

31、imarily for parts still under development that may require material property modifications prior to final production release but after the print geometry has been determined. 3.0 REFERENCE DOCUMENTS Unless otherwise specified the latest issue of all referenced standards shall apply. The following sp

32、ecifications and standards are referenced in this specification. Quality System Standard ISO 9001 or TS-16949 CFR Title 29, Part 1910 ASTM D 1171 NAVISTAR Eng. Design Std. A-16 ASTM D 395 ASTM D 2137 NAVISTAR Manufacturing Std MS-D-13 ASTM D 412 ASTM D 2240 NAVISTAR TMS-9543 ASTM D 575 ASTM D 5992 N

33、AVISTAR CEMS B-50 ASTM D 624 ASTM B 117 4.0 GENERAL REQUIREMENTS All materials covered by this specification shall meet the requirements specified herein and shall be molded or extruded, using good industry practices. 4.1 FinishUnless otherwise specified on the engineering drawing, the finish for mo

34、lded parts shall be uniform as produced from polished steel tools. The mold will be polished to a surface finish of 800 nm or better. Extruded products shall have a smooth, clean surface, free from any foreign matter. Extruded finish will be equivalent to Rubber Manufacturers Association (RMA) F2 fo

35、r mold finish. 4.2 FlashUnless otherwise specified on the engineering drawing, the parts shall have a maximum flash allowance of 0.80 mm (RMA T.80mm). Mounts and other parts deemed non-cosmetic and so indicated on the engineering print may have a flash allowance of 2.35mm (RMA T2.35). 4.3 Dimensiona

36、l Tolerances Part tolerances are shown in Table 1. Unless otherwise specified on the drawing, these tolerances are applicable and supersede the standard tolerances shown in the title block on the Engineering drawing. TABLE 1 STANDARD DIMENSIONAL TOLERANCE TABLE Dimension - inch Tolerance - inch Dime

37、nsion mm Tolerance -mm 0 -1.00 .015 0 -25 .40 1.00 -4.00 .025 25 -100 .50 4.00 -6.30 .032 100 -160 .80 6.30 distribution is limited to NAVISTAR employees and approved suppliers. Please contact Materials Engineering for further guidance. Suppliers are required to assume all patent liability. 2008 by

38、Navistar, Inc. JUNE 2008 Page 8 of 17 Copyright Navistar International Corporation Provided by IHS under license with INTERNNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-NUMBER: TITLE: REVISION: TMS-6039 Rubber (TSR) Molding Compounds 0806This document is restric

39、ted and may not be sent outside Navistar, Inc. or reproduced without permission from Corporate Technical Standards. TABLE 3a TSR GENERAL MATERIAL REQUIREMENTS Designation: TSR45-10a TSR60-10a TSR60-10b TSR65-10a TSR70-8a TSR70-10a TSR80-7b Material ID: TSR-0001 TSR-0002 TSR-0003 TSR-0004 TSR-0005 TS

40、R-0006 TSR-0007 Property Material EPDM NR* EPDM SBR/BR EPDM EPDM EPDM Hardness 45 60 60 65 67 70 80Tensile Strength 10 10 10 10 8 10 8 Elongation 400 350 350 300 200 250 200Tear Resistance 26 26 25 26 27 - 25 Compression Set 70 (125C) 50 (70C) 40 (70C) 50 (70C) 50 (70C) 70 (100C) 50 (70C) Low Temper

41、ature Pass Pass Pass Pass Pass Pass Pass Ozone Resistance 100% 85% 100 85% 100% 100% 100%Adhesion - 2.8 - (1)2.8 2.7(5) - - (1)Heat Resistance C A A A A B AHardness 10 15 10 15 15 10 15 Tensile Strength 20 30 25 30 30 20% 30 Elongation -40 -50 25 -50 -50 -40% 50 Adhesion - -10 -10 -10 - - 40% -10 Sa

42、lt Spray/Adhesion - -15 -15 -15 - - - (1)Pico Abrasion - (1)- (1)140 - - (1)- (1)Staining Pass Recycled Content - 15 to20% R(2) - - - - Approved Supplier NRI NRI NRI NRI Supergum NRI Griffith Compound I.D. 7440 8011 4097 8021 EX03704(3)03708(4)8043 Approval Report No. Comments Steering Shaft Compoun

43、d Rubber Grommet Compound Air Duct or Baffle CompoundRear Hood Mount Material Windshield Seals Same as TMS-6033 Type I SS Wheel Eyebrow Suppliers are required to assume all patent liability. 2008 by Navistar, Inc. JUNE 2008 Page 9 of 17 Copyright Navistar International Corporation Provided by IHS un

44、der license with INTERNNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-NUMBER: TITLE: REVISION: TMS-6039 Rubber (TSR) Molding Compounds 0806This document is restricted and may not be sent outside Navistar, Inc. or reproduced without permission from Corporate Techni

45、cal Standards. TABLE 3b (continued) TSR GENERAL MATERIAL REQUIREMENTS Designation: TSR70-14a TSR80-7a TSR95-5a TSR40-10a TSR80-8a Material ID: TSR-0008 TSR-0009 TSR-0010 TSR-0024 TSR-0057* Property Material EPDM EPDM EPDM EPDM EPDM Hardness 70 80 95 4080Tensile Strength 14 7 5 108 Elongation 200 100

46、 100 400200Tear Resistance 25 19 22 2225 Compression Set 35 (100C) 50 (70C) 50 (70C) 35 (70C) 50 (70C) Low Temperature Pass Pass Pass Pass Pass Ozone Resistance 100% 100% 100% 100% 100% Adhesion - (1)- 2.8 - (1)Heat Resistance A A B B A Hardness 10 15 15 15 15 Tensile Strength 25 30 30 30 30 Elongat

47、ion 25 -50 -50 -50 50 Adhesion -10 - -10 -10 Salt Spray/Adhesion - (1)- -15 -(1)Pico Abrasion - (1)- -(1)R(2) - (1)Staining Pass Pass Recycled Content - - 15 to 20% - Approved Supplier NRI Supergum NRI Griffith Compound I.D. 7520 EX03801 1101 Approval Report No. Comments Hood Latch Compound Windshie

48、ld Seal Lace Mud Guard and Radiator Seals Chassis Skirt Support 3618040C1Chassis skirt Close-out (1) dash (-) indicates no requirement (2) R = Value is to be reported by the supplier and/or included in the Qualification report. (3) = Seal S & H extrusions (4) = Seal molded corners * NR = Natural Rubber * - This was incorrectly TSR-0041 Suppliers