EN ISO 18064-2005 en Thermoplastic elastomers - Nomenclature and abbreviated terms《热塑性弹性体 术语和简化术语 (ISO 18064)-2003》.pdf

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1、BRITISH STANDARDBS EN ISO 18064:2005Incorporating Amendment No. 1 (renumbers BS ISO 18064:2003 as BS EN ISO 18064:2005)Thermoplastic elastomers Nomenclature and abbreviated termsThe European Standard EN ISO 18064:2005 has the status of a British StandardICS 01.040.83; 83.080.20g49g50g3g38g50g51g60g4

2、4g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58BS EN ISO 18064:2005This British Standard was published under the authority of the Standards Policy and Strategy Committee

3、 on 4 October 2003 BSI 21 December 2005ISBN 0 580 42708 0National forewordThis British Standard is the official English language version of EN ISO 18064:2005. It is identical with ISO 18064:2003.The UK participation in its preparation was entrusted to Technical Committee PRI/10, Plastics and rubbers

4、 terminology, which has the responsibility to: A list of organizations represented on this committee can be obtained on request to its secretary.Cross-referencesThe British Standards which implement international or European publications referred to in this document may be found in the BSI Catalogue

5、 under the section entitled “International Standards Correspondence Index”, or by using the “Search” facility of the BSI Electronic Catalogue or of British Standards Online.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct

6、application. Compliance with a British Standard does not of itself confer immunity from legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep UK interests informed; m

7、onitor related international and European developments and promulgate them in the UK.Summary of pagesThis document comprises a front cover, an inside front cover, the EN ISO title page, the EN ISO foreword page, the ISO title page, pages ii to v, a blank page, pages 1 to 5 and a back cover.The BSI c

8、opyright notice displayed in this document indicates when the document was last issued.Amendments issued since publicationAmd. No. Date Comments21 December 2005 Renumbers BS ISO 18064:2003 as BS EN ISO 18064:2005EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 18064February 2005ICS 01.040.83; 8

9、3.080.20English versionThermoplastic elastomers - Nomenclature and abbreviatedterms (ISO 18064:2003)lastomres thermoplastiques - Nomenclature et termesabrg (ISO 18064:2003)Thermoplastische Elastomere - Nomenklatur undKurzzeichen (ISO 18064:2003)This European Standard was approved by CEN on 3 Februar

10、y 2005.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained

11、 on application to the Central Secretariat or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the Central Secretaria

12、t has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, S

13、lovakia,Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2005 CEN All rights of exploitation in any form and by any means reservedworldwide

14、for CEN national Members.Ref. No. EN ISO 18064:2005: EForeword The text of ISO 18064:2003 has been prepared by Technical Committee ISO/TC 45 “Rubber and rubber products” of the International Organization for Standardization (ISO) and has been taken over as EN ISO 18064:2005 by Technical Committee CE

15、N/TC 249 “Plastics“, the secretariat of which is held by IBN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by August 2005, and conflicting national standards shall be withdrawn at the latest by Au

16、gust 2005. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy,

17、 Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Endorsement notice The text of ISO 18064:2003 has been approved by CEN as EN ISO 18064:2005 without any modifications. EN ISO 18064:2005Reference number IS

18、O 18064:2003(E)OSI 3002INTERNATIONAL STANDARD ISO 18064First edition 2003-09-01Thermoplastic elastomers Nomenclature and abbreviated terms lastomres thermoplastiques Nomenclature et termes abrgs EN ISO 18064:2005ii iiiContents Page Foreword iv Introduction v 1 Scope 1 2 Normative references . 1 3 Ge

19、neric terms and definitions . 1 3.1 TPE . 1 3.2 TP 1 4 Nomenclature system. 2 5 Categories of thermoplastic elastomer 2 5.1 TPA . 2 5.2 TPC . 2 5.3 TPO . 2 5.4 TPS . 2 5.5 TPU . 2 5.6 TPV . 2 5.7 TPZ 2 6 Materials in each TPE category . 3 6.1 Polyamide TPEs (TPAs) 3 6.2 Copolyester TPEs (TPCs). 3 6.

20、3 Olefinic TPEs (TPOs) 3 6.4 Styrenic TPEs (TPSs) 3 6.5 Urethane TPEs (TPUs) 4 6.6 Dynamically vulcanized TPEs (TPVs) . 4 6.7 Miscellaneous material (TPZ). 4 Annex A (informative) Formerly used abbreviated terms 5 EN ISO 18064:2005iv Foreword ISO (the International Organization for Standardization)

21、is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be repres

22、ented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are

23、drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International

24、 Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 18064 was prepa

25、red by Technical Committee ISO/TC 45, Rubber and rubber products. EN ISO 18064:2005vIntroduction Thermoplastic elastomers combine many of the attributes and features of both vulcanized thermoset rubber and thermoplastic materials. It is, therefore, important that any system of classification and nom

26、enclature for this rapidly expanding polymer sector should be acceptable to both the rubber and plastics industries. Neither of the existing standards for the nomenclature and abbreviated terms for rubber (ISO 1629) and for plastics (ISO 1043-1) is suitable for this purpose. The system in this Inter

27、national Standard has been devised to avoid any conflict of interests or ambiguity, permit the use of existing terms in the construction of abbreviations for thermoplastic elastomers, and allow for future developments or expansion. This International Standard uses established abbreviated terms. Its

28、aim is both to prevent the occurrence of more than one abbreviated term for a given thermoplastic elastomer term, and to prevent the interpretation of more than one meaning for a given abbreviated term. For this reason, this International Standard makes appropriate use of the terms and symbols liste

29、d in ISO 1043-1 and ISO 1629. EN ISO 18064:2005blank1Thermoplastic elastomers Nomenclature and abbreviated terms 1 Scope This International Standard establishes a nomenclature system for thermoplastic elastomers based on the chemical composition of the polymer or polymers involved. It defines symbol

30、s and abbreviated terms used to identify thermoplastic elastomers in industry, commerce and government. It is not intended to conflict with, but to supplement, existing trade names and trademarks. NOTE 1 The name of the thermoplastic elastomer should be used in technical papers and presentations fol

31、lowed by the abbreviated term used to designate the elastomer in this International Standard. NOTE 2 Annex A gives thermoplastic-elastomer abbreviated terms that have been used in the past in materials standards, technical bulletins, textbooks, patents and trade literature. 2 Normative references Th

32、e following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 1043-1, Plastics Symbols and abbreviated terms

33、Part 1: Basic polymers and their special characteristics ISO 1629, Rubber and latices Nomenclature 3 Generic terms and definitions 3.1 TPE Thermoplastic elastomer, consisting of a polymer or blend of polymers that has properties at its service temperature similar to those of vulcanized rubber but ca

34、n be processed and reprocessed at elevated temperature like a thermoplastic. NOTE Thermoplastic rubber is a commonly used term for thermoplastic elastomer. 3.2 TP Prefix used to identify that the abbreviated term is for a thermoplastic elastomer. EN ISO 18064:20052 4 Nomenclature system 4.1 The pref

35、ix TP shall be followed by a letter representing each category of thermoplastic elastomer, as detailed in Clause 5. 4.2 The abbreviated term for each category of thermoplastic elastomer shall be followed, after a hyphen, by a combination of symbols to describe a specific member of each category, as

36、detailed in Clause 6. 5 Categories of thermoplastic elastomer 5.1 TPA Polyamide thermoplastic elastomer, comprising a block copolymer of alternating hard and soft segments with amide chemical linkages in the hard blocks and ether and/or ester linkages in the soft blocks. 5.2 TPC Copolyester thermopl

37、astic elastomer, consisting of a block copolymer of alternating hard segments and soft segments, the chemical linkages in the main chain being ester and/or ether. 5.3 TPO Olefinic thermoplastic elastomer, consisting of a blend of a polyolefin and a conventional rubber, the rubber phase in the blend

38、having little or no crosslinking. 5.4 TPS Styrenic thermoplastic elastomer, consisting of at least a triblock copolymer of styrene and a specific diene, where the two end blocks (hard blocks) are polystyrene and the internal block (soft block or blocks) is a polydiene or hydrogenated polydiene. 5.5

39、TPU Urethane thermoplastic elastomer, consisting of a block copolymer of alternating hard and soft segments with urethane chemical linkages in the hard blocks and ether, ester or carbonate linkages or mixtures of them in the soft blocks. 5.6 TPV Thermoplastic rubber vulcanizate consisting of a blend

40、 of a thermoplastic material and a conventional rubber in which the rubber has been crosslinked by the process of dynamic vulcanization during the blending and mixing step. 5.7 TPZ Unclassified thermoplastic elastomer comprising any composition or structure other than those grouped in TPA, TPC, TPO,

41、 TPS, TPU and TPV. EN ISO 18064:200536 Materials in each TPE category 6.1 Polyamide TPEs (TPAs) The “TPA” group is sub-categorized into groups according to the linkages in the soft blocks. The following symbols are used: TPA-EE Soft segment with both ether and ester linkages TPA-ES Polyester soft se

42、gment TPA-ET Polyether soft segment 6.2 Copolyester TPEs (TPCs) The “TPC” group is sub-categorized into groups according to the linkages in the soft blocks. The following symbols are used: TPC-EE Soft segment with ester and ether linkages TPC-ES Polyester soft segment TPC-ET Polyether soft segment 6

43、.3 Olefinic TPEs (TPOs) The “TPO” group varies according to the nature of the thermoplastic polyolefin being used and the rubber type. A specific TPO is identified by a bracketed term comprising the standard abbreviation for the rubber type (see ISO 1629), a “+” sign and the standard abbreviation fo

44、r the thermoplastic type (see ISO 1043-1). The thermoplastic and the rubber type shall be listed in decreasing order of abundance in the TPO. A commercially available TPO type is described as follows: TPO-(EPDM+PP) Blend of ethylene-propylene-diene terpolymer with polypropylene, with no or little cr

45、osslinking of the EPDM phase, the amount of EPDM present being greater than that of PP 6.4 Styrenic TPEs (TPSs) The following symbols are used for the “TPS” group: TPS-SBS Block copolymer of styrene and butadiene TPS-SEBS Polystyrene-poly(ethylene-butylene)-polystyrene TPS-SEPS Polystyrene-poly(ethy

46、lene-propylene)-polystyrene TPS-SIS Block copolymer of styrene and isoprene NOTE TPS-SEBS is a block copolymer of styrene and butadiene in which the soft block comprises a mixture of hydrogenated cis-1,4-polybutadiene and 1,2-polybutadiene units. TPS-SEPS is a block copolymer of styrene and isoprene

47、 in which the polyisoprene block has been hydrogenated. EN ISO 18064:20054 6.5 Urethane TPEs (TPUs) The “TPU” group is sub-categorized into types according to the nature of the hydrocarbon moiety (aromatic or aliphatic) between the urethane linkages of the hard blocks, and according to the chemical

48、linkages (ether, ester, carbonate) in the soft blocks. The following symbols are used: TPU-ARES Aromatic hard segment, polyester soft segment TPU-ARET Aromatic hard segment, polyether soft segment TPU-AREE Aromatic hard segment, soft segment with ester and ether linkages TPU-ARCE Aromatic hard segme

49、nt, polycarbonate soft segment TPU-ARCL Aromatic hard segment, polycaprolactone soft segment TPU-ALES Aliphatic hard segment, polyester soft segment TPU-ALET Aliphatic hard segment, polyether soft segment 6.6 Dynamically vulcanized TPEs (TPVs) The “TPV” group varies depending on the nature of the thermoplastic material being used and the rubber type. A specific TPV is identified by a bracketed term comprising the standard abbreviation for the rubber (see ISO 1629), followed by a “+” sign and the standard abbreviation for the thermoplastic type (see ISO 1043-1