DIN ISO 20773-2017 Cigarettes - Determination of nicotine-free dry particulate matter and nicotine in sidestream smoke - Method using a routine analytical linear smoking machine eq卷.pdf

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1、March 2017 English price group 15No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 65.160!%bVq“2635178www.din.deDIN I

2、SO 20773Cigarettes Determination of nicotinefree dry particulate matter and nicotine in sidestream smoke Method using a routine analytical linear smoking machine equipped with a fishtail chimney (ISO 20773:2013),English translation of DIN ISO 20773:2017-03Zigaretten Bestimmung des nikotinfreien Troc

3、kenkondensats und des Nikotins im Nebenstromrauch Verfahren unter Verwendung einer linearen ZigarettenAbrauchmaschine fr Routineanalysen, ausgestattet mit einem FishtailAbzug (ISO 20773:2013),Englische bersetzung von DIN ISO 20773:2017-03Cigarettes Dtermination de la matire particulaire anhydre et e

4、xempte de nicotine et de la nicotine dans le courant secondaire de fume Mthode utilisant une machine fumer analytique de routine linaire quipe dune chemine individuelle en forme de queue de poisson (ISO 20773:2013),Traduction anglaise de DIN ISO 20773:2017-03www.beuth.deDocument comprises 30 pagesDT

5、ranslation by DIN-Sprachendienst.In case of doubt, the German-language original shall be considered authoritative.02.17 Introduction 61 Scope . 72 Normative references 73 Terms and definitions . 74 Principle 95 Apparatus . 96 Reagents . 127 Sampling and preparation of cigarettes 137.1 General 137.2

6、Symbols 137.3 Preparation of the cigarettes for smoking 147.4 Selection of test portions of cigarettes 147.5 Marking the butt length 157.6 Conditioning . 157.7 Preliminary tests before smoking .168 Preparation for the smoking run .168.1 Smoking plan .168.2 Preparation of mainstream and sidestream sm

7、oke traps and cigarette holders .168.3 Setting up the smoking machine 168.4 Assembly of fishtail chimney, sidestream smoke trap and impinger trap 169 Procedure for smoking run and collection of sidestream smoke 179.1 Preparation of fishtail chimney . 179.2 Preparation of impinger trap . 179.3 Settin

8、g the fishtail chimney flow rate . 179.4 Connection of sidestream smoke filter pad holders 179.5 Record the atmospheric conditions . 179.6 Loading the cigarettes 179.7 Smoking the cigarettes 1810 Determination of total particulate matter 1810.1 Total sidestream smoke particulate matter retained on f

9、ilter pads 1810.2 Calculation of total sidestream smoke particulate matter retained on filter pads .1910.3 Treatment of total sidestream smoke particulate matter retained on filter pads .1910.4 Extraction of sidestream smoke particulate matter from the fishtail chimney .1910.5 Estimation of sidestre

10、am smoke particulate matter in the fishtail chimney .2011 Determination of sidestream smoke nicotine 2111.1 Determination of nicotine in the sidestream smoke filter pad, Np2111.2 Determination of nicotine in the fishtail chimney extract, Nc2111.3 Determination of nicotine in the impinger trap, Ni.21

11、11.4 Calculation of total sidestream smoke nicotine, N 2112 Determination of nicotine-free dry sidestream smoke particulate matter .2212.1 Determination of nicotine-free dry sidestream smoke particulate matter on the filter pad 2212.2 Determination of total nicotine-free dry sidestream smoke particu

12、late matter 22A comma is used as the decimal marker.Contents PageNational foreword 4 National Annex (informative) Bibliography 5 DIN ISO 20773:2017-03 2.13.5 Test results. 2314 Repeatability and reproducibility .24Annex A (informative) Smoking plans .25Annex B (informative) Typical dilution factors

13、for estimation of chimney particulate matter .29Bibliography .3013 Test report 2213.1 General 2213.2 Characteristic data about the cigarette .2213.3 Data about sampling . 2313.4 Description of test . 23DIN ISO 20773:2017-03 3 National foreword This standard (ISO 20773:2013) has been prepared by Tech

14、nical Committee ISO/TC 126 “Tobacco and tobacco products” (Secretariat: DIN, Germany). The responsible German body involved in its preparation was DIN-Normenausschuss Lebensmittel und landwirtschaftliche Produkte (DIN Standards Committee Food and Agricultural Products), Working Committee NA 057-04-0

15、1 AA Tabak und Tabakerzeugnisse. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. DIN shall not be held responsible for identifying any or all such patent rights. The DIN Standard corresponding to the International Standard referre

16、d to in this document is as follows: ISO 2971 DIN ISO 2971 ISO 3308 DIN ISO 3308 ISO 3402 DIN ISO 3402 ISO 4387 DIN ISO 4387 ISO 6488 DIN ISO 6488 ISO 6565 DIN ISO 6565 ISO 8243 DIN ISO 8243 ISO 10315 DIN ISO 10315 ISO 10362-1 DIN ISO 10362-1 ISO 10362-2 DIN ISO 10362-2 ISO 13276 DIN ISO 13276 DIN I

17、SO 20773:2017-03 4 DIN ISO 20773:2017-03 5National Annex NA (informative) Bibliography DIN ISO 2971, Cigarettes and filter rods Determination of nominal diameter Method using a laser beam measuring apparatus DIN ISO 3308, Routine analytical cigarette smoking machine Definitions and standard conditio

18、ns DIN ISO 3402, Tobacco and tobacco products Atmosphere for conditioning and testing DIN ISO 4387, Cigarettes Determination of total and nicotine-free dry particulate matter using a routine analytical smoking machine DIN ISO 6488, Tobacco and tobacco products Determination of water content Karl Fis

19、cher method DIN ISO 6565, Tobacco and tobacco products Draw resistance of cigarettes and pressure drop of filter rods Standard conditions and measurement DIN ISO 8243, Cigarettes Sampling DIN ISO 10315, Cigarettes Determination of nicotine in smoke condensates Gas-chromatographic method DIN ISO 1036

20、2-1, Cigarettes Determination of water in smoke condensates Part 1: Gas-chromatographic method DIN ISO 10362-2, Cigarettes Determination of water in smoke condensates Part 2: Karl Fischer method DIN ISO 13276, Tobacco and tobacco products Determination of nicotine purity Gravimetric method using tun

21、gstosilicic acid IntroductionCigarettes are manufactured to close tolerances using strict quality control procedures.However, the main constituents involved in the manufacture are derived from natural products (such as tobacco and paper) and this results in a final product which is intrinsically var

22、iable. Further complexity arises as the cigarette is converted to cigarette smoke during smoking.The quantitative measurement of nicotine, of particulate matter and of nicotine-free dry particulate matter (NFDPM, sometimes referred to as “tar”) is therefore dependent on the arbitrary definition of t

23、he means used to generate and collect the smoke. In particular, the ambient conditions (e.g. temperature, humidity, air movement within the laboratory) under which the test pieces are conditioned and smoke is collected play a critical role in the accuracy of the measurement.Sidestream smoke in this

24、International Standard is understood to be the smoke that is evolved from the cigarette during the smoking run other than from the mouth end (which is called mainstream smoke).NOTE Sidestream smoke is distinguished from environmental tobacco smoke (ETS), which is a mixture of aged and diluted exhale

25、d mainstream smoke and aged and diluted sidestream smoke, and for the assessment of which the present method does not apply.From the time that scientists first attempted to determine nicotine and total and dry particulate matter yields in sidestream smoke, many different methods have been adopted. H

26、owever, experience has shown some procedures to be more reliable and more amenable to handling of large numbers of samples. With these factors in mind, during the 19992002 period, collaborative studies by a task force composed of CORESTA (www.coresta.org) members have shown that improvements in repe

27、atability and reproducibility result when some restrictions are placed upon the wide variety of methods and practices described in existing methods.This International Standard, produced after much collaborative experimentation by many laboratories in many countries, reflects the results of the optim

28、ization proposed and validated by the task force and provides one set of procedures that are the accepted reference procedures and for which repeatability and reproducibility of the determinations were assessed. Experience in the task force has shown how strict adherence to the detailed set up and c

29、onditions of the method, as well as the degree of proficiency of the operator, affect the precision of the results.Further, it is preferable that the selected method be compatible with different modes of cigarette equilibration or puffing parameters for the smoking of the tested pieces. The ISO stan

30、dards for the determination of mainstream smoke yields were, however, followed to the largest possible extent, although the machines used by the different laboratories were all of a linear type.This method is a machine method and it allows cigarettes to be smoked using a strictly controlled set of p

31、arameters. Thus it enables the sidestream smoke NFDPM and nicotine from cigarettes, when smoked by this procedure, to be compared and ranked. In the course of its studies, the task force demonstrated the value of comparing the analytical processes and their stability by use of the CORESTA monitor te

32、st piece for determining NFDPM and nicotine yields.Since the determinations of NFDPM and nicotine in sidestream smoke are by nature more complex and delicate than their counterparts performed on mainstream smoke, it is highly recommended to include a monitor test piece in the smoking plans, as is do

33、ne in mainstream smoke determinations. It is possible to use the CORESTA monitor or any other internally designed monitor test piece for this purpose. The use of an internationally recognized one is recommended.Cigarettes Determination of nicotine-free dry particulate matter and nicotine in sidestre

34、am smoke Method using a routine analytical linear smoking machine equipped with a fishtail chimneyDIN ISO 20773:2017-03 6 WARNING The use of this International Standard can involve hazardous materials, operations and equipment. This International Standard does not purport to address all the safety p

35、roblems associated with its use. It is the responsibility of the user of this International Standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.1 ScopeThis International Standard is applicable to the determination of to

36、tal particulate matter and to the subsequent determination of nicotine and nicotine-free dry particulate matter present in the sidestream smoke from cigarettes. The described method is specified using the ISO 3308 smoking parameters (puff volume, duration and frequency) and butt length, but it is te

37、chnically compatible with other smoking regimes.NOTE The method may not be directly adaptable to other sidestream smoke analytes.2 Normative referencesThe following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated refere

38、nces, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.ISO 2971, Cigarettes and filter rods Determination of nominal diameter Method using a non-contact optical measuring apparatusISO 3308, Routine analytical cig

39、arette-smoking machine Definitions and standard conditionsISO 3402, Tobacco and tobacco products Atmosphere for conditioning and testingISO 4387, Cigarettes Determination of total and nicotine-free dry particulate matter using a routine analytical smoking machineISO 6488, Tobacco and tobacco product

40、s Determination of water content Karl Fischer methodISO 6565, Tobacco and tobacco products Draw resistance of cigarettes and pressure drop of filter rods Standard conditions and measurementISO 10315, Cigarettes Determination of nicotine in smoke condensates Gas-chromatographic methodISO 10362-1, Cig

41、arettes Determination of water in smoke condensates Part 1: Gas-chromatographic method3 Terms and definitionsFor the purposes of this document, the following terms and definitions apply.DIN ISO 20773:2017-03 7 3.1total sidestream smoke particulate mattercrude sidestream smoke condensateportion of th

42、e sidestream smoke which is trapped on the sidestream smoke filter pad, together with that portion of the sidestream smoke which condenses on the wall of the fishtail chimneyNote 1 to entry: Expressed as milligrams per cigarette.3.2dry sidestream smoke particulate matterdry sidestream smoke condensa

43、tedry sidestream smoke particulate matter composed of the sum of the total particulate matter trapped on the sidestream smoke filter pad after deduction of its water content, plus the estimated nicotine-free dry particulate matter condensed on the walls of the sidestream smoke chimney (this estimate

44、 being obtained by a UV absorption method described below), plus the nicotine condensed on the walls of the sidestream smoke chimneyNote 1 to entry: Expressed as milligrams per cigarette.3.3nicotine-free dry sidestream smoke particulate matternicotine-free dry sidestream smoke condensatedry sidestre

45、am smoke particulate matter, after deduction of its nicotine contentNote 1 to entry: Expressed as milligrams per cigarette.3.4sidestream smoke nicotinesum of the nicotine condensed on the walls of the fishtail chimney, the nicotine collected on the sidestream smoke filter pad and the nicotine collec

46、ted in the impinger trapNote 1 to entry: Expressed as milligrams per cigarette.3.5smoking processuse of a smoking machine to smoke cigarettes from lighting to final puff3.6smoking runspecific smoking process to produce such sidestream smoke from a sample of cigarettes as is necessary for the determi

47、nation of the smoke components3.7laboratory samplesample intended for laboratory inspection or testing and which is representative of the gross sample or the sub-period sample3.8test samplecigarettes for test taken at random from the laboratory sample and which are representative of each of the incr

48、ements making up the laboratory sample3.9conditioning samplecigarettes selected from the test sample for conditioning prior to tests for sidestream smoke particulate matter and nicotine yield3.10test portiongroup of cigarettes prepared for a single determination and which is a random sample from the test sample or conditioning sample, as appropriateDIN ISO 20773:2017-03 8